SG11201909208TA - Catalyst system and process for producing bisphenol-a - Google Patents

Catalyst system and process for producing bisphenol-a

Info

Publication number
SG11201909208TA
SG11201909208TA SG11201909208TA SG11201909208TA SG 11201909208T A SG11201909208T A SG 11201909208TA SG 11201909208T A SG11201909208T A SG 11201909208TA SG 11201909208T A SG11201909208T A SG 11201909208TA
Authority
SG
Singapore
Prior art keywords
international
catalyst
pct
applicant
rule
Prior art date
Application number
Inventor
Christopher Papile
Original Assignee
Badger Licensing Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Badger Licensing Llc filed Critical Badger Licensing Llc
Publication of SG11201909208TA publication Critical patent/SG11201909208TA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0217—Mercaptans or thiols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B01J2231/347—1,2-additions, e.g. aldol or Knoevenagel condensations via cationic intermediates, e.g. bisphenol A type processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0279—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the cationic portion being acyclic or nitrogen being a substituent on a ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
    • C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
    • C07C39/16—Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 01 November 2018 (01.11.2018) WIPO I PCT mu °million ono mitimiloit imio oimIE (10) International Publication Number WO 2018/200278 Al (51) International Patent Classification: B01J 31/10 (2006.01) C07C 3 9 / 1 6 (2006.01) C07C 37/20 (2006.01) (21) International Application Number: PCT/US2018/028082 (22) International Filing Date: 18 April 2018 (18.04.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/489,262 24 April 2017 (24.04.2017) US (71) Applicant: BADGER LICENSING LLC [US/US]; One Financial Center, Boston, Massachusetts 02111 (US). (72) Inventor: PAPILE, Christopher; 285 Third St. #406, Cambridge, Massachusetts 02142 (US). (74) Agent: ROBERTS, Peter; Roberts Mlotkowski Safran Cole & Calderon, P.C., Suite 500, 7918 Jones Branch Dri- ve, McLean, Virginia 22102 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3)) W O 20 18/ 200 27 8 Al Declarations under Rule 4.17: as to applicant's entitlement to apply for and be granted a patent (Rule 4.1700) as to the applicant's entitlement to claim the priority of the earlier application (Rule 4.17(iii)) (54) Title: CATALYST SYSTEM AND PROCESS FOR PRODUCING BISPHENOL-A (57) : A catalyst system useful in the production of bisphenol-A comprises (a) an acidic heterogeneous catalyst; (b) a first catalyst promoter comprising at least one organic sulfur- containing compound; and (c) a second catalyst promoter different from the first catalyst promoter and comprising at least one organic Bronsted acidic ionic compound..
SG11201909208T 2017-04-24 2018-04-18 Catalyst system and process for producing bisphenol-a SG11201909208TA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762489262P 2017-04-24 2017-04-24
PCT/US2018/028082 WO2018200278A1 (en) 2017-04-24 2018-04-18 Catalyst system and process for producing bisphenol-a

Publications (1)

Publication Number Publication Date
SG11201909208TA true SG11201909208TA (en) 2019-11-28

Family

ID=62186525

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201909208T SG11201909208TA (en) 2017-04-24 2018-04-18 Catalyst system and process for producing bisphenol-a

Country Status (8)

Country Link
US (1) US11260378B2 (en)
EP (1) EP3615209A1 (en)
JP (1) JP7117324B2 (en)
KR (1) KR102534540B1 (en)
CN (1) CN110545916A (en)
SG (1) SG11201909208TA (en)
TW (1) TW201902573A (en)
WO (1) WO2018200278A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112778206B (en) * 2021-01-07 2023-01-17 南京工业大学 Preparation method and application of high-absorption chrome tanning auxiliary containing ketosulfonate structure
CN113101979B (en) * 2021-04-22 2022-07-05 江南大学 Lewis acid promoted compound protonic acid and catalytic application thereof
CN115888825A (en) * 2022-10-11 2023-04-04 江苏全邦材料科技有限公司 Bisphenol A synthetic composite resin catalyst and preparation method thereof

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5075511A (en) * 1986-10-30 1991-12-24 Shell Oil Company Process and alkylmercaptoamine catalyst for production of bisphenol-A
JPH07103058B2 (en) * 1987-12-04 1995-11-08 三井東圧化学株式会社 Method for producing bisphenol A
CN1034398C (en) * 1991-09-16 1997-04-02 中国石油化工总公司 Prodn. technology and apparatus of on-exchange resin catalyst used in bisphenol synthesis
US5414152A (en) * 1994-05-10 1995-05-09 General Electric Company Method for extending the activity of acidic ion exchange catalysts
US6673737B2 (en) 2001-05-30 2004-01-06 Exxonmobil Research And Engineering Company Ionic liquid compositions
JP4152655B2 (en) 2002-03-29 2008-09-17 出光興産株式会社 Method for producing bisphenol A
CN100494203C (en) 2002-04-05 2009-06-03 南阿拉巴马大学 Functionalized ionic liquids, and methods of use thereof
JP4147202B2 (en) * 2003-09-30 2008-09-10 三井化学株式会社 Modified acidic ion exchange resin catalyst and method for producing bisphenols using the same
CN1238110C (en) * 2003-11-13 2006-01-25 中国石油化工股份有限公司 Bisphenol A synthetic catalyst and preparation method thereof
DE102004005723A1 (en) 2004-02-05 2005-08-25 Bayer Materialscience Ag Preparation of bisphenol A with reduced sulfur content
EP1785188B1 (en) * 2004-07-02 2013-08-07 Mitsui Chemicals, Inc. Modified ion exchange resin and process for producing bisphenols
EP2021311B1 (en) 2006-05-04 2011-08-10 Badger Licensing LLC Improved process for the manufacture of polyphenols
JP2009189998A (en) * 2008-02-18 2009-08-27 Mitsui Chemicals Inc Modified ion-exchange resinand production method of bisphenols
US7858830B2 (en) 2008-10-28 2010-12-28 Badger Licensing Llc Process for recovering phenol from a BPA waste stream
CN103483154B (en) 2009-01-22 2016-07-06 三菱化学株式会社 The manufacture method of bisphenol compound
CN103547554A (en) * 2011-05-02 2014-01-29 沙特基础创新塑料Ip私人有限责任公司 High purity bisphenol A and polycarbonate materials prepared therefrom
US8431749B2 (en) 2011-06-06 2013-04-30 Badger Licensing Llc Recovery of phenol and acetone from bisphenol-A streams
TWI557103B (en) 2011-06-06 2016-11-11 貝吉特許有限責任公司 Treatment of bisphenol-a residue streams
US9732022B2 (en) 2012-10-29 2017-08-15 Sabic Global Technologies B.V. Recovery of materials from a mother liquor residue

Also Published As

Publication number Publication date
KR20190136094A (en) 2019-12-09
EP3615209A1 (en) 2020-03-04
WO2018200278A1 (en) 2018-11-01
JP2020517446A (en) 2020-06-18
KR102534540B1 (en) 2023-05-18
US11260378B2 (en) 2022-03-01
JP7117324B2 (en) 2022-08-12
CN110545916A (en) 2019-12-06
TW201902573A (en) 2019-01-16
US20200047170A1 (en) 2020-02-13

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