SG11201406918UA - Gas-steam efficient cogeneration process and system based on biomass gasification and methanation - Google Patents

Gas-steam efficient cogeneration process and system based on biomass gasification and methanation

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Publication number
SG11201406918UA
SG11201406918UA SG11201406918UA SG11201406918UA SG11201406918UA SG 11201406918U A SG11201406918U A SG 11201406918UA SG 11201406918U A SG11201406918U A SG 11201406918UA SG 11201406918U A SG11201406918U A SG 11201406918UA SG 11201406918U A SG11201406918U A SG 11201406918UA
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SG
Singapore
Prior art keywords
unit
methanation
gas
hubei
lllll
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SG11201406918UA
Inventor
Weiguang Yang
Yan Gong
Xiaodong Zhan
Dechen Song
Original Assignee
Sunshine Kaidi New Energy Group Co Ltd
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Application filed by Sunshine Kaidi New Energy Group Co Ltd filed Critical Sunshine Kaidi New Energy Group Co Ltd
Publication of SG11201406918UA publication Critical patent/SG11201406918UA/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08Production of synthetic natural gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/86Other features combined with waste-heat boilers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B27/00Instantaneous or flash steam boilers
    • F22B27/14Instantaneous or flash steam boilers built-up from heat-exchange elements arranged within a confined chamber having heat-retaining walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22GSUPERHEATING OF STEAM
    • F22G1/00Steam superheating characterised by heating method
    • F22G1/02Steam superheating characterised by heating method with heat supply by hot flue gases from the furnace of the steam boiler
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0916Biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656Conversion of synthesis gas to chemicals
    • C10J2300/1662Conversion of synthesis gas to chemicals to methane (SNG)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1687Integration of gasification processes with another plant or parts within the plant with steam generation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/04Organic compounds
    • C10L2200/0461Fractions defined by their origin
    • C10L2200/0469Renewables or materials of biological origin
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/04Gasification
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/06Heat exchange, direct or indirect
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/10Recycling of a stream within the process or apparatus to reuse elsewhere therein
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/42Fischer-Tropsch steps
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Industrial Gases (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

(i2) (19) mm m ran=/ ..,_, (10) mwm* (43) gR^^H 2013 ^ 10 13 31 0 (31.10.2013) WIPO I PCT WO 2013/159662 A1 F22B 1/18 (2006.01) PCT/CN2013/074232 2013^4^16 0 (16.04.2013) (51) C10L 3/08 (2006.01) C10L 3/10 (2006.01) (21) Hfictflflf#: (22) (25) Ifff: (26) (30) 201210128134.2 2012^4^27 0 (27.04.2012) CN (71) $i#A: (SUN­ SHINE KAEDI NEW ENERGY GROUP CO., LTD.) [CN/CN]; ^ R\K Hubei 430223 (CN) = (72) IzMX (YANG,Weiguang); Hubei 430223 (CN) = M$k (GONG, Yan); ^ S Mit X M , Hubei 430223 (CN) = M (ZHAN, Xiaodong); 4^ SWb^3^X.TiT Hubei 430223 (CN)= E (SONG, Dechen); ^ Jf&&. ffSicit# —^gfliaicM, Hubei 430223 (CN) = (74) ftIA: (WUHAN KAIYUAN INTELLECTUAL PROPERTY AGENT LTD.); ^ S Mit it SUX?t |X 145 14 M, Hubei 430015 (CN) = (8D I)''): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KM, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, (54) Title: GAS-STEAM EFFICIENT COGENERATION PROCESS AND SYSTEM BASED ON BIOMASS GASIFICATION AND METHANATION (54) AA NATURAL GAS PIPELINE BB PRODUCT CC SUBSTITUTE NATURAL GAS DD METHANE CONCENTRATION UNIT EE CRUDE NATURAL GAS FF METHANATION UNIT GG PURIFIED SYNTHETIC GAS HH PURIFICATION UNIT II CRUDE SYNTHETIC GAS JJ TRANSFORMATION UNIT KK GASIFIED GAS LL GASIFICATION UNIT MM OXYGEN NN AIR-SEPARATION DEVICE OO COMBUSTION GAS TURBINE PP INTERMEDIATE PRESSURE SUPERHEATED STEAM QQ STEAM TURBINE CJ 0\ T-H cn i-H o CJ o & (57) Abstract: The present invention provides gas-steam a efficient cogeneration process and system based on biomass gasification and methanation, comprising a biomass gasification unit, a transformation unit, a purification unit, a methanation unit, and a meth - ane concentration unit. The gasification unit utilizes a locally-external constant high-temperature heat source airflow bed which can remarkably improve effective gas compositions of CO and H 2 and improve biomass gasification efficiency. The gasification unit can greatly reduce the quantity of tar produced at a high temperature, improves the carbon conversion rate, and removes investment on a tar removing device. In the process of methanation, the conversion efficiency of CO reaches 100%, and the conversion efficiency of H 2 reaches 99%. Also, a large amount of by-product intermediate pressure superheated steam is produced, and power consumption of a circulation compressor in the traditional methanation process is reduced. The present invention has the advantages that biomass energy can be converted into clean, high-calorific-value, and convenient-for-use natural gas, and large a amount of heat released in the biomass gasification and methanation reaction can be efficiently recycled through a mode of producing high-quality superheated steam. (57) mSI: WO 2013/159662 A11 lllll llllllll II llllll III lllll lllll III III III lllll lllll lllll lllll lllll llll llll lllllll llll llll QA, RO, RS, RU, RW, SC, SD, SE, SG, SK, SL, SM, ST, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, VC, VN,ZA,ZM,ZWo CI, CM, GA, GN, GQ, GW, ML, MR, NE, SN, TD, (84) TG) ° UP): ARIPO (BW, GM, KE, GH, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, UG, ZM, ZW), M (AM, _ H 21 &(3)) = AZ, BY, KG, KZ, RU, TJ, TM), (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, 71: > zHj£co^nH 2 nrmmm, ¥^a^co$t^i*ioo%, nmm^99%-, 2 mmmmm ^ tB =
SG11201406918UA 2012-04-27 2013-04-16 Gas-steam efficient cogeneration process and system based on biomass gasification and methanation SG11201406918UA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201210128134.2A CN102660339B (en) 2012-04-27 2012-04-27 Gas-steam efficient cogeneration process and system based on biomass gasification and methanation
PCT/CN2013/074232 WO2013159662A1 (en) 2012-04-27 2013-04-16 Gas-steam efficient cogeneration process and system based on biomass gasification and methanation

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SG11201406918UA true SG11201406918UA (en) 2015-01-29

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US (2) US9593286B2 (en)
EP (1) EP2843031A4 (en)
JP (1) JP5959721B2 (en)
KR (1) KR101739494B1 (en)
CN (1) CN102660339B (en)
AP (1) AP2014008078A0 (en)
AU (1) AU2013252316B2 (en)
BR (1) BR112014026705A2 (en)
CA (1) CA2871701A1 (en)
IN (1) IN2014MN02282A (en)
MX (1) MX362684B (en)
MY (1) MY170247A (en)
RU (1) RU2583785C1 (en)
SG (1) SG11201406918UA (en)
WO (1) WO2013159662A1 (en)
ZA (1) ZA201408643B (en)

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CN109207220B (en) * 2017-06-29 2020-10-30 中国石油化工股份有限公司 Methanation process for preparing synthetic natural gas from coal-based synthetic gas
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