SE7903291L - PROCEDURE FOR EPOXIDATION OF LOWER ALFA OLEFINES - Google Patents

PROCEDURE FOR EPOXIDATION OF LOWER ALFA OLEFINES

Info

Publication number
SE7903291L
SE7903291L SE7903291A SE7903291A SE7903291L SE 7903291 L SE7903291 L SE 7903291L SE 7903291 A SE7903291 A SE 7903291A SE 7903291 A SE7903291 A SE 7903291A SE 7903291 L SE7903291 L SE 7903291L
Authority
SE
Sweden
Prior art keywords
nrrl
microorganisms
methylomonas
epoxidation
oxygen
Prior art date
Application number
SE7903291A
Other languages
Swedish (sv)
Inventor
C-T Hou
R N Patel
A I Laskin
Original Assignee
Exxon Research Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research Engineering Co filed Critical Exxon Research Engineering Co
Publication of SE7903291L publication Critical patent/SE7903291L/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C12N9/0004—Oxidoreductases (1.)
    • C12N9/0071—Oxidoreductases (1.) acting on paired donors with incorporation of molecular oxygen (1.14)
    • C12N9/0073—Oxidoreductases (1.) acting on paired donors with incorporation of molecular oxygen (1.14) with NADH or NADPH as one donor, and incorporation of one atom of oxygen 1.14.13
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P17/00—Preparation of heterocyclic carbon compounds with only O, N, S, Se or Te as ring hetero atoms
    • C12P17/02—Oxygen as only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12Y—ENZYMES
    • C12Y114/00—Oxidoreductases acting on paired donors, with incorporation or reduction of molecular oxygen (1.14)
    • C12Y114/13—Oxidoreductases acting on paired donors, with incorporation or reduction of molecular oxygen (1.14) with NADH or NADPH as one donor, and incorporation of one atom of oxygen (1.14.13)
    • C12Y114/13025—Methane monooxygenase (1.14.13.25)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • Medicinal Chemistry (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)

Abstract

A process is disclosed for the epoxidation of C2-C4 alpha-olefins and dienes by contact with oxygen in the presence of the particulate fraction of microorganisms or enzyme preparations derived therefrom. The microorganisms or enzyme preparations derived therefrom are microorganisms which have been cultivated in a nutrient medium containing methane or dimethyl ether and oxygen. Preferred microorganisms are obligative or facultative methylotrophs. Especially suitable are strains having the following designations: Methylosinus trichosporium OB3B (NEEL B-11, 196); Methylosinus sporium 5 (NRRL B-11, 197); Methylocystis parvus OBBP (NRRL B-11, 198); Methylomonas methanica S1 (NRRL B=11, 199); Methylomonas albus BG 8 (NRRL B-11, 200); Methylobacter capsulatus Y (NRRL B-11, 201); Methylobacterium organophilum sp nov. (ATCC 27.886); Methylomonas sp AJ-3670 (FERM P-2400); Methylococcus 999 (NCIB Accession No. 11,083; and Methylomonas SM 3 (NCIB Accession No. 11,084). Propylene is the preferred alpha-olefin for employment in the process.
SE7903291A 1978-04-14 1979-04-12 PROCEDURE FOR EPOXIDATION OF LOWER ALFA OLEFINES SE7903291L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US89646778A 1978-04-14 1978-04-14
US2122779A 1979-03-16 1979-03-16

Publications (1)

Publication Number Publication Date
SE7903291L true SE7903291L (en) 1979-10-15

Family

ID=26694443

Family Applications (1)

Application Number Title Priority Date Filing Date
SE7903291A SE7903291L (en) 1978-04-14 1979-04-12 PROCEDURE FOR EPOXIDATION OF LOWER ALFA OLEFINES

Country Status (9)

Country Link
CA (1) CA1148488A (en)
CH (1) CH647805A5 (en)
DE (1) DE2915108C2 (en)
DK (1) DK154779A (en)
FR (1) FR2422652A1 (en)
GB (1) GB2019390B (en)
IT (1) IT1119721B (en)
NL (1) NL7902940A (en)
SE (1) SE7903291L (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5526806A (en) * 1978-08-11 1980-02-26 Baiorisaac Center:Kk Preparation of epoxides by immobilized microorganism
EP0042306A3 (en) * 1980-06-17 1983-02-09 Exxon Research And Engineering Company A low energy continuous process for increasing the oxidative state of an oxidisable organic substrate
US4348476A (en) * 1981-01-22 1982-09-07 Exxon Research And Engineering Co. Production of epoxides such as propylene oxide using packed catalytic bed containing moist resting cells exhibiting oxygenase activity
EP0088602A3 (en) * 1982-03-08 1984-03-28 Exxon Research And Engineering Company Microbiological oxidation process
NL8303082A (en) * 1983-09-05 1985-04-01 Delft Tech Hogeschool METHANOL DEHYDROGENASE ENZYME; METHOD FOR GROWING MICRO-ORGANISMS; CHEMICAL PRODUCTS; MICRO-ORGANISMS CATALYZED EPOXY DATES OR HYDROXYLATIONS; METHYLOTROPHIC MICROORGANISMS.
JPS6391078A (en) * 1986-10-03 1988-04-21 Idemitsu Kosan Co Ltd Novel bacterium and production of oxygen-containing compound using said bacterium
US5057221A (en) * 1988-12-19 1991-10-15 Weyerhaeuser Company Aerobic biological dehalogenation reactor
US5037551A (en) * 1988-12-19 1991-08-06 Weyerhaeuser Company High-flow rate capacity aerobic biological dehalogenation reactor
DE19753316A1 (en) 1997-12-02 1999-06-10 Clariant Gmbh Detergents, cleaning agents and disinfectants containing chlorine-active substances and fatty acid alkyl ester ethoxylates

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL291163A (en) * 1900-01-01

Also Published As

Publication number Publication date
IT7921833A0 (en) 1979-04-12
NL7902940A (en) 1979-10-16
CA1148488A (en) 1983-06-21
FR2422652A1 (en) 1979-11-09
DE2915108A1 (en) 1979-10-25
GB2019390B (en) 1982-07-07
DK154779A (en) 1979-10-15
GB2019390A (en) 1979-10-31
DE2915108C2 (en) 1984-08-23
IT1119721B (en) 1986-03-10
CH647805A5 (en) 1985-02-15

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