SE7704738L - PROCEDURE FOR PRODUCTION OF NEW OPTICALLY ACTIVE ASSOCIATIONS - Google Patents

PROCEDURE FOR PRODUCTION OF NEW OPTICALLY ACTIVE ASSOCIATIONS

Info

Publication number
SE7704738L
SE7704738L SE7704738A SE7704738A SE7704738L SE 7704738 L SE7704738 L SE 7704738L SE 7704738 A SE7704738 A SE 7704738A SE 7704738 A SE7704738 A SE 7704738A SE 7704738 L SE7704738 L SE 7704738L
Authority
SE
Sweden
Prior art keywords
asymmetrical
procedure
production
optically active
new optically
Prior art date
Application number
SE7704738A
Other languages
Swedish (sv)
Other versions
SE434918B (en
Inventor
M Fiorini
M Giongo
F Marcati
W Marconi
Original Assignee
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IT2265376A external-priority patent/IT1063212B/en
Priority claimed from IT2013977A external-priority patent/IT1113753B/en
Application filed by Snam Progetti filed Critical Snam Progetti
Publication of SE7704738L publication Critical patent/SE7704738L/en
Publication of SE434918B publication Critical patent/SE434918B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
    • C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
    • C07D317/50—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
    • C07D317/60—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/46—Phosphinous acids [R2POH], [R2P(= O)H]: Thiophosphinous acids including[R2PSH]; [R2P(=S)H]; Aminophosphines [R2PNH2]; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
    • C07F9/4883—Amides or esteramides thereof, e.g. RP(NR'2)2 or RP(XR')(NR''2) (X = O, S)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

For the asymmetrical hydrogenation of substrates selected from prochiral olefins and compounds containing CO and/or CN groups, the olefin of interest here is contacted with a complex of a transition metal with an asymmetrical aminophosphine. The asymmetrical aminophosphine is selected from those of the formula PR@(NR<2>R<3>)3-x where R<1>, R<2> and R<3> are as defined in the claims. The catalytic system as a means for carrying out the abovementioned asymmetrical hydrogenation contains a complex obtained by a reaction starting from compounds of the formula (R<3>R<2>N)nX and a coordination compound of a metal from the transition series.
SE7704738A 1976-04-26 1977-04-25 CATALYST SYSTEM AND ITS USE FOR ASYMMETRIC HYDRATION SE434918B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT2265376A IT1063212B (en) 1976-04-26 1976-04-26 Asymmetric hydrogenation of olefins, carbonyl cpds. or nitriles - using transition metal complex of asymmetric amino-phosphine
IT2013977A IT1113753B (en) 1977-02-10 1977-02-10 Asymmetric hydrogenation of olefins, carbonyl cpds. or nitriles - using transition metal complex of asymmetric amino-phosphine

Publications (2)

Publication Number Publication Date
SE7704738L true SE7704738L (en) 1977-10-27
SE434918B SE434918B (en) 1984-08-27

Family

ID=26327413

Family Applications (2)

Application Number Title Priority Date Filing Date
SE7704738A SE434918B (en) 1976-04-26 1977-04-25 CATALYST SYSTEM AND ITS USE FOR ASYMMETRIC HYDRATION
SE8304837A SE460066B (en) 1976-04-26 1983-09-09 ASYMMETRIC AMINOPHOSPHINES AND APPLICATION OF THESE FOODS PREPARATION OF CATALYSTS FOR HYDROGENATION OF OLEFINES TO OPTICALLY ACTIVE COMPOUNDS

Family Applications After (1)

Application Number Title Priority Date Filing Date
SE8304837A SE460066B (en) 1976-04-26 1983-09-09 ASYMMETRIC AMINOPHOSPHINES AND APPLICATION OF THESE FOODS PREPARATION OF CATALYSTS FOR HYDROGENATION OF OLEFINES TO OPTICALLY ACTIVE COMPOUNDS

Country Status (15)

Country Link
JP (1) JPS52151127A (en)
AU (2) AU523259B2 (en)
CA (1) CA1109074A (en)
CH (1) CH629166A5 (en)
DD (2) DD137233A5 (en)
DE (3) DE2718533C3 (en)
DK (1) DK180877A (en)
FR (1) FR2349555A1 (en)
GB (1) GB1580461A (en)
HU (2) HUT33991A (en)
LU (1) LU77197A1 (en)
NL (1) NL180096C (en)
NO (2) NO771419L (en)
SE (2) SE434918B (en)
YU (1) YU107577A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1087963B (en) * 1977-10-17 1985-06-04 Snam Progetti ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS.

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2116905A5 (en) * 1970-12-10 1972-07-21 Inst Francais Du Petrole NEW BIDENT COORDINATES, THEIR MANUFACTURING AND THEIR APPLICATIONS

Also Published As

Publication number Publication date
DE2718533B2 (en) 1979-12-20
GB1580461A (en) 1980-12-03
SE460066B (en) 1989-09-04
DD137233A5 (en) 1979-08-22
DE2718533A1 (en) 1977-11-24
FR2349555B1 (en) 1980-12-26
SE434918B (en) 1984-08-27
JPS52151127A (en) 1977-12-15
AU2440777A (en) 1979-03-08
JPS633871B2 (en) 1988-01-26
AU523259B2 (en) 1982-07-22
AU3054684A (en) 1984-12-20
DE2759684C2 (en) 1986-05-28
NL180096B (en) 1986-08-01
AU572169B2 (en) 1988-05-05
HUT33991A (en) 1985-01-28
SE8304837D0 (en) 1983-09-09
NL7704570A (en) 1977-10-28
NO773738L (en) 1977-10-27
DE2759683B1 (en) 1980-07-17
DK180877A (en) 1977-10-27
DD132487A5 (en) 1978-10-04
HUT34037A (en) 1985-01-28
NL180096C (en) 1987-01-02
CH629166A5 (en) 1982-04-15
DE2718533C3 (en) 1980-08-28
LU77197A1 (en) 1977-08-17
YU107577A (en) 1983-02-28
FR2349555A1 (en) 1977-11-25
CA1109074A (en) 1981-09-15
NO771419L (en) 1977-10-27
DE2759683C3 (en) 1981-10-15
SE8304837L (en) 1983-09-09

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