IT1087963B - ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS. - Google Patents

ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS.

Info

Publication number
IT1087963B
IT1087963B IT28666/77A IT2866677A IT1087963B IT 1087963 B IT1087963 B IT 1087963B IT 28666/77 A IT28666/77 A IT 28666/77A IT 2866677 A IT2866677 A IT 2866677A IT 1087963 B IT1087963 B IT 1087963B
Authority
IT
Italy
Prior art keywords
complex
transition metals
clay minerals
prochiral olefins
asymmetrical hydrogenation
Prior art date
Application number
IT28666/77A
Other languages
Italian (it)
Original Assignee
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Snam Progetti filed Critical Snam Progetti
Priority to IT28666/77A priority Critical patent/IT1087963B/en
Priority to CA000311978A priority patent/CA1148564A/en
Priority to AU40251/78A priority patent/AU520574B2/en
Priority to ZA00785486A priority patent/ZA785486B/en
Priority to JP12370578A priority patent/JPS5466615A/en
Priority to YU02375/78A priority patent/YU237578A/en
Priority to NL7810236A priority patent/NL7810236A/en
Priority to GB7840114A priority patent/GB2006770B/en
Priority to IL55733A priority patent/IL55733A/en
Priority to NO783492A priority patent/NO148778C/en
Priority to FR7829446A priority patent/FR2405911A1/en
Priority to DD78208480A priority patent/DD139251A5/en
Priority to CS786724A priority patent/CS208483B2/en
Priority to CH1070078A priority patent/CH636589A5/en
Priority to HU78SA3141A priority patent/HU181953B/en
Priority to DK461478A priority patent/DK461478A/en
Priority to LU80370A priority patent/LU80370A1/en
Priority to SE7810776A priority patent/SE435923B/en
Priority to BE191166A priority patent/BE871320A/en
Priority to DE2845216A priority patent/DE2845216C2/en
Application granted granted Critical
Publication of IT1087963B publication Critical patent/IT1087963B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B01J31/1855—Triamide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B01J31/187—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
IT28666/77A 1977-10-17 1977-10-17 ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS. IT1087963B (en)

Priority Applications (20)

Application Number Priority Date Filing Date Title
IT28666/77A IT1087963B (en) 1977-10-17 1977-10-17 ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS.
CA000311978A CA1148564A (en) 1977-10-17 1978-09-25 Asymmetric hydrogenation of prochiral olefines by complexes of transition metals immobilized in clay-like minerals
AU40251/78A AU520574B2 (en) 1977-10-17 1978-09-27 Asymmetric hydrogenation of prochiral olefines
ZA00785486A ZA785486B (en) 1977-10-17 1978-09-27 Asymmetric hydrogenation of prochiral olefines by complexes of transition metals immobilized in clay-like minerals
JP12370578A JPS5466615A (en) 1977-10-17 1978-10-09 Unsymmetrical hydrogenation of protylal olefin
YU02375/78A YU237578A (en) 1977-10-17 1978-10-10 Process for the asymmetric hydrogenization of prochiral olefines
GB7840114A GB2006770B (en) 1977-10-17 1978-10-11 Asymmetric hydrogenation of prochiral ethylenically unsaturated compounds
NL7810236A NL7810236A (en) 1977-10-17 1978-10-11 ASYMMETRICAL HYDROGENATION OF CYCLOALKENES WITH TRANSITION METAL COMPLEXES MADE IN CLAYY MINERALS.
IL55733A IL55733A (en) 1977-10-17 1978-10-13 Method for the asymmetric hydrogenation of prochiral olefins by complexes of transition metals,supported on clayey minerals
FR7829446A FR2405911A1 (en) 1977-10-17 1978-10-16 ASYMETRIC HYDROGENATION OF OLEFINS WITH ROTATORY POWER BY METAL COMPLEXES OF FIXED TRANSITIONS IN CLAY MINERALS
DD78208480A DD139251A5 (en) 1977-10-17 1978-10-16 METHOD FOR THE ASYMMETRIC HYDROGENATION OF PROCHIRAL OLEFINES
CS786724A CS208483B2 (en) 1977-10-17 1978-10-16 Method of asymetric hydrogenation
CH1070078A CH636589A5 (en) 1977-10-17 1978-10-16 ASYMMETRICAL HYDROGENATION PROCEDURE OF PROCHIRAL OLEFINS.
HU78SA3141A HU181953B (en) 1977-10-17 1978-10-16 Process for producing n-acetyl-alanin derivatives with catalytic hydrogenation
NO783492A NO148778C (en) 1977-10-17 1978-10-16 PROCEDURE FOR ASYMMETRIC HYDROGENATION OF A PROCHIRAL OLEFIN
DK461478A DK461478A (en) 1977-10-17 1978-10-16 PROCEDURE FOR HYDROGENATION OF PROCHIRAL OLEFINS WITH KINERAL REPLACEMENTS OF TRANSITION METALS IMMOBILIZED IN CLAY LIKE M
LU80370A LU80370A1 (en) 1977-10-17 1978-10-16 ASYMETRIC HYDROGENATION OF OLEFINS WITH ROTATORY POWER BY METAL COMPLEXES OF FIXED TRANSITIONS IN CLAY MINERALS
SE7810776A SE435923B (en) 1977-10-17 1978-10-16 PROCEDURE FOR ASYMMETRIC HYDRATION OF CERTAIN PROCHIRAL OLEFINES
BE191166A BE871320A (en) 1977-10-17 1978-10-17 ASYMETRIC OLEFINS HYDROGENATION PROCESS
DE2845216A DE2845216C2 (en) 1977-10-17 1978-10-17 Process for the preparation of N-acyl-α-amino carboxylic acids by asymmetric hydrogenation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT28666/77A IT1087963B (en) 1977-10-17 1977-10-17 ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS.

Publications (1)

Publication Number Publication Date
IT1087963B true IT1087963B (en) 1985-06-04

Family

ID=11223981

Family Applications (1)

Application Number Title Priority Date Filing Date
IT28666/77A IT1087963B (en) 1977-10-17 1977-10-17 ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS.

Country Status (20)

Country Link
JP (1) JPS5466615A (en)
AU (1) AU520574B2 (en)
BE (1) BE871320A (en)
CA (1) CA1148564A (en)
CH (1) CH636589A5 (en)
CS (1) CS208483B2 (en)
DD (1) DD139251A5 (en)
DE (1) DE2845216C2 (en)
DK (1) DK461478A (en)
FR (1) FR2405911A1 (en)
GB (1) GB2006770B (en)
HU (1) HU181953B (en)
IL (1) IL55733A (en)
IT (1) IT1087963B (en)
LU (1) LU80370A1 (en)
NL (1) NL7810236A (en)
NO (1) NO148778C (en)
SE (1) SE435923B (en)
YU (1) YU237578A (en)
ZA (1) ZA785486B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HU190864B (en) * 1983-12-08 1986-11-28 Alkaloida Vegyeszeti Gyar Process for production of phenil-alanin derivatives
GB8519008D0 (en) * 1985-07-27 1985-09-04 British Petroleum Co Plc Chemical process

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4008281A (en) * 1973-12-03 1977-02-15 Monsanto Company Asymmetric catalysis
CA1109074A (en) * 1976-04-26 1981-09-15 Mario Fiorini Asymmetrical hydrogenation and related means for this purpose

Also Published As

Publication number Publication date
CH636589A5 (en) 1983-06-15
AU4025178A (en) 1980-04-03
DE2845216A1 (en) 1979-04-19
NL7810236A (en) 1979-04-19
DK461478A (en) 1979-04-18
FR2405911A1 (en) 1979-05-11
NO148778B (en) 1983-09-05
YU237578A (en) 1983-01-21
IL55733A0 (en) 1978-12-17
SE7810776L (en) 1979-04-18
ZA785486B (en) 1979-09-26
CA1148564A (en) 1983-06-21
BE871320A (en) 1979-04-17
AU520574B2 (en) 1982-02-11
GB2006770A (en) 1979-05-10
DD139251A5 (en) 1979-12-19
LU80370A1 (en) 1979-03-19
IL55733A (en) 1981-11-30
SE435923B (en) 1984-10-29
JPS5466615A (en) 1979-05-29
NO783492L (en) 1979-04-18
HU181953B (en) 1983-11-28
NO148778C (en) 1983-12-14
DE2845216C2 (en) 1984-05-10
CS208483B2 (en) 1981-09-15
GB2006770B (en) 1982-03-17
FR2405911B1 (en) 1981-03-20

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