IT1087963B - ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS. - Google Patents
ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS.Info
- Publication number
- IT1087963B IT1087963B IT28666/77A IT2866677A IT1087963B IT 1087963 B IT1087963 B IT 1087963B IT 28666/77 A IT28666/77 A IT 28666/77A IT 2866677 A IT2866677 A IT 2866677A IT 1087963 B IT1087963 B IT 1087963B
- Authority
- IT
- Italy
- Prior art keywords
- complex
- transition metals
- clay minerals
- prochiral olefins
- asymmetrical hydrogenation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
- B01J31/1855—Triamide derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
- B01J31/187—Amide derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
- B01J31/188—Amide derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (20)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT28666/77A IT1087963B (en) | 1977-10-17 | 1977-10-17 | ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS. |
CA000311978A CA1148564A (en) | 1977-10-17 | 1978-09-25 | Asymmetric hydrogenation of prochiral olefines by complexes of transition metals immobilized in clay-like minerals |
AU40251/78A AU520574B2 (en) | 1977-10-17 | 1978-09-27 | Asymmetric hydrogenation of prochiral olefines |
ZA00785486A ZA785486B (en) | 1977-10-17 | 1978-09-27 | Asymmetric hydrogenation of prochiral olefines by complexes of transition metals immobilized in clay-like minerals |
JP12370578A JPS5466615A (en) | 1977-10-17 | 1978-10-09 | Unsymmetrical hydrogenation of protylal olefin |
YU02375/78A YU237578A (en) | 1977-10-17 | 1978-10-10 | Process for the asymmetric hydrogenization of prochiral olefines |
GB7840114A GB2006770B (en) | 1977-10-17 | 1978-10-11 | Asymmetric hydrogenation of prochiral ethylenically unsaturated compounds |
NL7810236A NL7810236A (en) | 1977-10-17 | 1978-10-11 | ASYMMETRICAL HYDROGENATION OF CYCLOALKENES WITH TRANSITION METAL COMPLEXES MADE IN CLAYY MINERALS. |
IL55733A IL55733A (en) | 1977-10-17 | 1978-10-13 | Method for the asymmetric hydrogenation of prochiral olefins by complexes of transition metals,supported on clayey minerals |
FR7829446A FR2405911A1 (en) | 1977-10-17 | 1978-10-16 | ASYMETRIC HYDROGENATION OF OLEFINS WITH ROTATORY POWER BY METAL COMPLEXES OF FIXED TRANSITIONS IN CLAY MINERALS |
DD78208480A DD139251A5 (en) | 1977-10-17 | 1978-10-16 | METHOD FOR THE ASYMMETRIC HYDROGENATION OF PROCHIRAL OLEFINES |
CS786724A CS208483B2 (en) | 1977-10-17 | 1978-10-16 | Method of asymetric hydrogenation |
CH1070078A CH636589A5 (en) | 1977-10-17 | 1978-10-16 | ASYMMETRICAL HYDROGENATION PROCEDURE OF PROCHIRAL OLEFINS. |
HU78SA3141A HU181953B (en) | 1977-10-17 | 1978-10-16 | Process for producing n-acetyl-alanin derivatives with catalytic hydrogenation |
NO783492A NO148778C (en) | 1977-10-17 | 1978-10-16 | PROCEDURE FOR ASYMMETRIC HYDROGENATION OF A PROCHIRAL OLEFIN |
DK461478A DK461478A (en) | 1977-10-17 | 1978-10-16 | PROCEDURE FOR HYDROGENATION OF PROCHIRAL OLEFINS WITH KINERAL REPLACEMENTS OF TRANSITION METALS IMMOBILIZED IN CLAY LIKE M |
LU80370A LU80370A1 (en) | 1977-10-17 | 1978-10-16 | ASYMETRIC HYDROGENATION OF OLEFINS WITH ROTATORY POWER BY METAL COMPLEXES OF FIXED TRANSITIONS IN CLAY MINERALS |
SE7810776A SE435923B (en) | 1977-10-17 | 1978-10-16 | PROCEDURE FOR ASYMMETRIC HYDRATION OF CERTAIN PROCHIRAL OLEFINES |
BE191166A BE871320A (en) | 1977-10-17 | 1978-10-17 | ASYMETRIC OLEFINS HYDROGENATION PROCESS |
DE2845216A DE2845216C2 (en) | 1977-10-17 | 1978-10-17 | Process for the preparation of N-acyl-α-amino carboxylic acids by asymmetric hydrogenation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT28666/77A IT1087963B (en) | 1977-10-17 | 1977-10-17 | ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS. |
Publications (1)
Publication Number | Publication Date |
---|---|
IT1087963B true IT1087963B (en) | 1985-06-04 |
Family
ID=11223981
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT28666/77A IT1087963B (en) | 1977-10-17 | 1977-10-17 | ASYMMETRICAL HYDROGENATION OF PROCHIRAL OLEFINS BY COMPLEX OF TRANSITION METALS IMMOBILIZED IN CLAY MINERALS. |
Country Status (20)
Country | Link |
---|---|
JP (1) | JPS5466615A (en) |
AU (1) | AU520574B2 (en) |
BE (1) | BE871320A (en) |
CA (1) | CA1148564A (en) |
CH (1) | CH636589A5 (en) |
CS (1) | CS208483B2 (en) |
DD (1) | DD139251A5 (en) |
DE (1) | DE2845216C2 (en) |
DK (1) | DK461478A (en) |
FR (1) | FR2405911A1 (en) |
GB (1) | GB2006770B (en) |
HU (1) | HU181953B (en) |
IL (1) | IL55733A (en) |
IT (1) | IT1087963B (en) |
LU (1) | LU80370A1 (en) |
NL (1) | NL7810236A (en) |
NO (1) | NO148778C (en) |
SE (1) | SE435923B (en) |
YU (1) | YU237578A (en) |
ZA (1) | ZA785486B (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
HU190864B (en) * | 1983-12-08 | 1986-11-28 | Alkaloida Vegyeszeti Gyar | Process for production of phenil-alanin derivatives |
GB8519008D0 (en) * | 1985-07-27 | 1985-09-04 | British Petroleum Co Plc | Chemical process |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4008281A (en) * | 1973-12-03 | 1977-02-15 | Monsanto Company | Asymmetric catalysis |
CA1109074A (en) * | 1976-04-26 | 1981-09-15 | Mario Fiorini | Asymmetrical hydrogenation and related means for this purpose |
-
1977
- 1977-10-17 IT IT28666/77A patent/IT1087963B/en active
-
1978
- 1978-09-25 CA CA000311978A patent/CA1148564A/en not_active Expired
- 1978-09-27 ZA ZA00785486A patent/ZA785486B/en unknown
- 1978-09-27 AU AU40251/78A patent/AU520574B2/en not_active Expired
- 1978-10-09 JP JP12370578A patent/JPS5466615A/en active Pending
- 1978-10-10 YU YU02375/78A patent/YU237578A/en unknown
- 1978-10-11 GB GB7840114A patent/GB2006770B/en not_active Expired
- 1978-10-11 NL NL7810236A patent/NL7810236A/en not_active Application Discontinuation
- 1978-10-13 IL IL55733A patent/IL55733A/en unknown
- 1978-10-16 HU HU78SA3141A patent/HU181953B/en unknown
- 1978-10-16 DD DD78208480A patent/DD139251A5/en unknown
- 1978-10-16 DK DK461478A patent/DK461478A/en not_active Application Discontinuation
- 1978-10-16 NO NO783492A patent/NO148778C/en unknown
- 1978-10-16 CS CS786724A patent/CS208483B2/en unknown
- 1978-10-16 CH CH1070078A patent/CH636589A5/en not_active IP Right Cessation
- 1978-10-16 FR FR7829446A patent/FR2405911A1/en active Granted
- 1978-10-16 SE SE7810776A patent/SE435923B/en unknown
- 1978-10-16 LU LU80370A patent/LU80370A1/en unknown
- 1978-10-17 DE DE2845216A patent/DE2845216C2/en not_active Expired
- 1978-10-17 BE BE191166A patent/BE871320A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CH636589A5 (en) | 1983-06-15 |
AU4025178A (en) | 1980-04-03 |
DE2845216A1 (en) | 1979-04-19 |
NL7810236A (en) | 1979-04-19 |
DK461478A (en) | 1979-04-18 |
FR2405911A1 (en) | 1979-05-11 |
NO148778B (en) | 1983-09-05 |
YU237578A (en) | 1983-01-21 |
IL55733A0 (en) | 1978-12-17 |
SE7810776L (en) | 1979-04-18 |
ZA785486B (en) | 1979-09-26 |
CA1148564A (en) | 1983-06-21 |
BE871320A (en) | 1979-04-17 |
AU520574B2 (en) | 1982-02-11 |
GB2006770A (en) | 1979-05-10 |
DD139251A5 (en) | 1979-12-19 |
LU80370A1 (en) | 1979-03-19 |
IL55733A (en) | 1981-11-30 |
SE435923B (en) | 1984-10-29 |
JPS5466615A (en) | 1979-05-29 |
NO783492L (en) | 1979-04-18 |
HU181953B (en) | 1983-11-28 |
NO148778C (en) | 1983-12-14 |
DE2845216C2 (en) | 1984-05-10 |
CS208483B2 (en) | 1981-09-15 |
GB2006770B (en) | 1982-03-17 |
FR2405911B1 (en) | 1981-03-20 |
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