IT950259B - PROCEDURE FOR THE RECOVERY OF CATALYTIC SYSTEMS CONSTITUTED BY COM PLEXES OF TRANSITION METALS WITH ORGANIC BINDERS - Google Patents

PROCEDURE FOR THE RECOVERY OF CATALYTIC SYSTEMS CONSTITUTED BY COM PLEXES OF TRANSITION METALS WITH ORGANIC BINDERS

Info

Publication number
IT950259B
IT950259B IT21932/72A IT2193272A IT950259B IT 950259 B IT950259 B IT 950259B IT 21932/72 A IT21932/72 A IT 21932/72A IT 2193272 A IT2193272 A IT 2193272A IT 950259 B IT950259 B IT 950259B
Authority
IT
Italy
Prior art keywords
recovery
procedure
transition metals
organic binders
catalytic systems
Prior art date
Application number
IT21932/72A
Other languages
Italian (it)
Inventor
G Gregorio
A Andreetta
Original Assignee
Montedison Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montedison Spa filed Critical Montedison Spa
Priority to IT21932/72A priority Critical patent/IT950259B/en
Priority to NL7303482A priority patent/NL7303482A/xx
Priority to CA166,325A priority patent/CA1023729A/en
Priority to FR7309079A priority patent/FR2176031B1/fr
Priority to JP48029569A priority patent/JPS493892A/ja
Priority to GB1261873A priority patent/GB1424818A/en
Priority to ES412656A priority patent/ES412656A1/en
Priority to BE128915A priority patent/BE796914A/en
Priority to DE2313102A priority patent/DE2313102A1/en
Application granted granted Critical
Publication of IT950259B publication Critical patent/IT950259B/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4023Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4023Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • B01J31/4053Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/2266Catalytic processes not covered by C07C5/23 - C07C5/31 with hydrides or organic compounds
    • C07C5/2293Catalytic processes not covered by C07C5/23 - C07C5/31 with hydrides or organic compounds containing phosphines, arsines, stibines, or bismuthines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/827Iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20Carbon compounds
    • B01J27/232Carbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22Organic complexes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24Phosphines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts
IT21932/72A 1972-03-16 1972-03-16 PROCEDURE FOR THE RECOVERY OF CATALYTIC SYSTEMS CONSTITUTED BY COM PLEXES OF TRANSITION METALS WITH ORGANIC BINDERS IT950259B (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
IT21932/72A IT950259B (en) 1972-03-16 1972-03-16 PROCEDURE FOR THE RECOVERY OF CATALYTIC SYSTEMS CONSTITUTED BY COM PLEXES OF TRANSITION METALS WITH ORGANIC BINDERS
NL7303482A NL7303482A (en) 1972-03-16 1973-03-13
CA166,325A CA1023729A (en) 1972-03-16 1973-03-14 Recovery of transition metal-organic ligand complex catalysts
FR7309079A FR2176031B1 (en) 1972-03-16 1973-03-14
JP48029569A JPS493892A (en) 1972-03-16 1973-03-15
GB1261873A GB1424818A (en) 1972-03-16 1973-03-15 Recovery of catalytic systems
ES412656A ES412656A1 (en) 1972-03-16 1973-03-15 Recovery of catalytic systems
BE128915A BE796914A (en) 1972-03-16 1973-03-16 PROCESS FOR RECOVERING CATALYTIC SYSTEMS CONSTITUTING OF COMPLEXES OF TRANSITION METALS WITH ORGANIC LIGANDS
DE2313102A DE2313102A1 (en) 1972-03-16 1973-03-16 PROCESS FOR THE RECOVERY OF CATALYST SYSTEMS, COMPOSED OF COMPLEXES OF TRANSITION METALS OF GROUP VIII OF THE PERIOD SYSTEM WITH LIGANDS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT21932/72A IT950259B (en) 1972-03-16 1972-03-16 PROCEDURE FOR THE RECOVERY OF CATALYTIC SYSTEMS CONSTITUTED BY COM PLEXES OF TRANSITION METALS WITH ORGANIC BINDERS

Publications (1)

Publication Number Publication Date
IT950259B true IT950259B (en) 1973-06-20

Family

ID=11189002

Family Applications (1)

Application Number Title Priority Date Filing Date
IT21932/72A IT950259B (en) 1972-03-16 1972-03-16 PROCEDURE FOR THE RECOVERY OF CATALYTIC SYSTEMS CONSTITUTED BY COM PLEXES OF TRANSITION METALS WITH ORGANIC BINDERS

Country Status (9)

Country Link
JP (1) JPS493892A (en)
BE (1) BE796914A (en)
CA (1) CA1023729A (en)
DE (1) DE2313102A1 (en)
ES (1) ES412656A1 (en)
FR (1) FR2176031B1 (en)
GB (1) GB1424818A (en)
IT (1) IT950259B (en)
NL (1) NL7303482A (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1036791A (en) * 1973-12-11 1978-08-22 Hannes Vallak Method of manufacturing steel ingots or castings
IT1007026B (en) * 1974-01-23 1976-10-30 Montedison Spa PROCEDURE FOR THE RECOVERY OF CATALYTIC SYSTEMS FROM CRUDE OF HYDROFORMILATION
JPS50153720A (en) * 1974-06-03 1975-12-11
JPS5638576B2 (en) * 1974-07-25 1981-09-08
DE2637262B2 (en) * 1976-08-19 1978-10-12 Erdoelchemie Gmbh, 5000 Koeln Recovery of rhodium catalysts homogeneously dissolved in organic media
EP0007768A3 (en) * 1978-07-27 1980-02-20 DAVY McKEE (LONDON) LIMITED Hydroformylation of alpha-olefinic compounds
US4463797A (en) * 1979-02-09 1984-08-07 Pyreflex Corp. Inhibiting shrinkage pipe formation of metal casting
DE3014044A1 (en) * 1980-04-11 1981-10-22 Vladlen Bencionovič Delnik Removing cobalt from hydroformylation reaction prods. - by treating with carbon di:oxide to form insoluble salts
GB2074166B (en) * 1980-04-16 1984-02-29 Union Carbide Corp Process for removing triorgano phosphine from an organic liquid
GB8618710D0 (en) * 1986-07-31 1986-09-10 Bp Chem Int Ltd Recovering metals
GB9218346D0 (en) * 1992-08-28 1992-10-14 Bp Chem Int Ltd Process
US5488175A (en) * 1993-09-16 1996-01-30 Shell Oil Company Hydroformylation process
CZ283697A3 (en) * 1996-09-11 1998-04-15 Mitsubishi Chemical Corporation Process for preparing solution of rhodium complex and the use thereof
US5981788A (en) * 1997-11-03 1999-11-09 General Electric Company Method for recovering and recycling catalyst constituents

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3641076A (en) * 1970-08-24 1972-02-08 Union Oil Co Catalyst recovery

Also Published As

Publication number Publication date
BE796914A (en) 1973-09-17
CA1023729A (en) 1978-01-03
NL7303482A (en) 1973-09-18
ES412656A1 (en) 1976-01-01
DE2313102A1 (en) 1973-09-27
GB1424818A (en) 1976-02-11
FR2176031A1 (en) 1973-10-26
FR2176031B1 (en) 1976-05-21
JPS493892A (en) 1974-01-14

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