SE464798B - CATALYST CONTAINING A SUBSTRATE, AN INTERMEDIATE OXID LAYER AND A CATALYTIC LAYER - Google Patents

CATALYST CONTAINING A SUBSTRATE, AN INTERMEDIATE OXID LAYER AND A CATALYTIC LAYER

Info

Publication number
SE464798B
SE464798B SE7413242A SE7413242A SE464798B SE 464798 B SE464798 B SE 464798B SE 7413242 A SE7413242 A SE 7413242A SE 7413242 A SE7413242 A SE 7413242A SE 464798 B SE464798 B SE 464798B
Authority
SE
Sweden
Prior art keywords
substrate
catalytic
aluminum
layer
trace
Prior art date
Application number
SE7413242A
Other languages
Swedish (sv)
Other versions
SE408137B (en
SE7413242L (en
Inventor
L A Heathcote
Original Assignee
Johnson Matthey Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB49501/73A external-priority patent/GB1492929A/en
Application filed by Johnson Matthey Co Ltd filed Critical Johnson Matthey Co Ltd
Publication of SE7413242L publication Critical patent/SE7413242L/xx
Publication of SE408137B publication Critical patent/SE408137B/en
Publication of SE464798B publication Critical patent/SE464798B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/20Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/24Nitric oxide (NO)
    • C01B21/26Preparation by catalytic or non-catalytic oxidation of ammonia
    • C01B21/265Preparation by catalytic or non-catalytic oxidation of ammonia characterised by the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/86Chromium
    • B01J23/866Nickel and chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0225Coating of metal substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/08Cleaning containers, e.g. tanks
    • B08B9/20Cleaning containers, e.g. tanks by using apparatus into or on to which containers, e.g. bottles, jars, cans are brought
    • B08B9/28Cleaning containers, e.g. tanks by using apparatus into or on to which containers, e.g. bottles, jars, cans are brought the apparatus cleaning by splash, spray, or jet application, with or without soaking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/208Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/104Silver
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20738Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20746Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20784Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/209Other metals
    • B01D2255/2092Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/70Non-metallic catalysts, additives or dopants
    • B01D2255/702Carbon
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N35/00Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
    • G01N35/02Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor using a plurality of sample containers moved by a conveyor system past one or more treatment or analysis stations
    • G01N35/04Details of the conveyor system
    • G01N2035/0401Sample carriers, cuvettes or reaction vessels
    • G01N2035/0437Cleaning cuvettes or reaction vessels
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N35/00Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
    • G01N35/08Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor using a stream of discrete samples flowing along a tube system, e.g. flow injection analysis
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N35/00Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
    • G01N35/10Devices for transferring samples or any liquids to, in, or from, the analysis apparatus, e.g. suction devices, injection devices
    • G01N35/1004Cleaning sample transfer devices
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Abstract

Catalysts and catalytic structures are provided comprising a substrate, an intermediate oxide layer and a catalytic layer. For example, the catalyst may comprise: (a) a metal substrate made from a heat and oxidation resistant alloy of iron including chromium (3-40) wt. %, aluminum (trace - 10) wt. %, cobalt (0 - 5.0) wt. %, nickel (trace 72) wt. % and carbon (0 - 0.5) wt. %, balance essentially iron, the metal substrate being extended on an assembly of at least two juxtaposed sheets made from the alloy with at least one sheet shaped so that when contacted with an adjacent sheet channels are formed therebetween for the passage of gaseous reactants through the substrate; (b) an aluminum oxide film on the surface of the extended metal substrate, the film being formed by oxidizing the surface of the metal substrate; (c) a high surface area aluminum coating disposed over the aluminum oxide film and keyed to the substrate through the film; and (d) a catalytic layer comprising at least one metal selected from the group consisting of ruthenium, rhodium, palladium, iridium, platinum, silver, gold, and alloys of at least one of such metals with at least one additional element comprising a base metal selected from the group consisting of aluminum, magnesium, chromium, molybdenum, tungsten, manganese, iron, rhenium, cobalt, titanium, vanadium, copper, zinc, cadmium, indium, thorium, bismuth, tin, lead, antimony, a lanthanide or an actinide, the base metal being present in an amount from a trace to 25 wt. % on the high surface area alumina coating. Such catalysts have been found to be useful for a wide variety of catalytic reactions, e.g. the catalytic oxidation of ammonia in the manufacture of nitric acid and the catalytic oxidation of organic compounds.
SE7413242A 1973-10-24 1974-10-21 CATALYST CONTAINING A SUBSTRATE, AN INTERMEDIATE OXID LAYER AND A CATALYTIC LAYER SE464798B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB49501/73A GB1492929A (en) 1973-10-24 1973-10-24 Catalytic structures having metallic substrates
GB3270374 1974-07-24

Publications (3)

Publication Number Publication Date
SE7413242L SE7413242L (en) 1975-04-25
SE408137B SE408137B (en) 1979-05-21
SE464798B true SE464798B (en) 1991-06-17

Family

ID=26261520

Family Applications (1)

Application Number Title Priority Date Filing Date
SE7413242A SE464798B (en) 1973-10-24 1974-10-21 CATALYST CONTAINING A SUBSTRATE, AN INTERMEDIATE OXID LAYER AND A CATALYTIC LAYER

Country Status (6)

Country Link
JP (1) JPS5823138B2 (en)
CA (1) CA1078364A (en)
DE (1) DE2450664A1 (en)
FR (1) FR2257336A1 (en)
IT (1) IT1024675B (en)
SE (1) SE464798B (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE426787B (en) * 1976-03-12 1983-02-14 Johnson Matthey Co Ltd CATALYST DEVICE
GB1568391A (en) * 1976-04-14 1980-05-29 Atomic Energy Authority Uk Catalysts having metallic substrates
GB1590023A (en) * 1976-08-24 1981-05-28 Johnson Matthey Co Ltd Catalytic decomposition of nitrogen oxides
DE2857147C2 (en) * 1977-11-01 1987-03-26 Atomic Energy Authority Uk Process for coating a substrate with a refractory material
US4289855A (en) * 1977-12-30 1981-09-15 Oxoid Limited Safety catalyst systems
JPS5926341B2 (en) * 1978-07-06 1984-06-26 日立造船株式会社 Denitration catalyst with porous film
US4331631A (en) * 1979-11-28 1982-05-25 General Motors Corporation Enhanced oxide whisker growth on peeled Al-containing stainless steel foil
DE3010950A1 (en) * 1980-03-21 1981-10-01 Hoechst Ag, 6000 Frankfurt METHOD FOR PRODUCING AND USING A CATALYST SUPPORT
FR2479323B1 (en) * 1980-03-31 1987-03-20 Johnson Matthey Plc ANTI-POLLUTION PROCESS AND DEVICE FOR EXHAUST GAS OF INTERNAL COMBUSTION ENGINE WITH TURBO-COMPRESSOR
US4415537A (en) * 1982-02-01 1983-11-15 United Technologies Corporation Catalytic combustor
DE3501330C1 (en) * 1985-01-17 1986-01-23 Kraftanlagen Ag, 6900 Heidelberg Carrier matrix for taking up catalytically active compounds and method for producing the carrier matrix
US4686155A (en) * 1985-06-04 1987-08-11 Armco Inc. Oxidation resistant ferrous base foil and method therefor
DE3640025A1 (en) * 1985-11-26 1987-05-27 Toyota Motor Co Ltd MONOLITHIC CATALYST CARRIER AND MONOLITHIC CATALYST FOR USE TO CLEAN EXHAUST GAS
JPS6388040A (en) * 1986-09-30 1988-04-19 Nippon Engeruharudo Kk Catalyst for purifying exhaust gas for vehicle and its preparation
JPH0657320B2 (en) * 1987-07-31 1994-08-03 マツダ株式会社 Exhaust gas purification catalyst manufacturing method
US5427601A (en) * 1990-11-29 1995-06-27 Ngk Insulators, Ltd. Sintered metal bodies and manufacturing method therefor
FI90464C (en) * 1991-02-21 1994-02-10 Kemira Oy Catalyst
DK170529B1 (en) * 1992-03-23 1995-10-16 Topsoe Haldor As Ammonia oxidation catalyst
EP0578840B1 (en) 1992-06-10 1996-12-18 Siemens Aktiengesellschaft Process for preparing a catalyst
EP0645171B1 (en) * 1993-09-21 1997-11-26 National Science Council Palladium-alloy catalyst for thermal decomposition of NO
DE19610345C1 (en) * 1996-03-18 1997-11-20 Krupp Vdm Gmbh Catalysts used with peracid(s or hydrogen peroxide to remove dyes from textile effluent
DE10128130B4 (en) * 2001-06-09 2007-07-05 Mol Katalysatortechnik Gmbh Process for the oxidative purification of gaseous media and full metal catalyst
JP2006320893A (en) * 2005-04-18 2006-11-30 Tokyo Univ Of Agriculture & Technology Selective reduction catalyst for nitrogen oxide
CN106224667B (en) * 2016-07-29 2018-07-17 盐城丰工机械有限公司 A kind of quick firm flange of connection
CN106247048B (en) * 2016-07-29 2018-08-31 盐城丰工机械有限公司 A kind of efficient sealed flange
CN106247058B (en) * 2016-07-29 2018-08-31 盐城丰工机械有限公司 A kind of multi-pipeline connecting flange
CN110048132A (en) * 2019-04-29 2019-07-23 济南大学 A kind of three-dimensional preparation method for propping up forked Pt-Cu-Mn alloy nanoparticle
CN110048133A (en) * 2019-04-29 2019-07-23 济南大学 A kind of preparation method of cross cube Pt-Cu-Mn alloy nanoparticle

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3437605A (en) * 1965-01-26 1969-04-08 Engelhard Ind Inc Method of preparing a supported catalyst

Also Published As

Publication number Publication date
JPS5823138B2 (en) 1983-05-13
SE408137B (en) 1979-05-21
IT1024675B (en) 1978-07-20
DE2450664A1 (en) 1975-04-30
JPS50112293A (en) 1975-09-03
SE7413242L (en) 1975-04-25
FR2257336A1 (en) 1975-08-08
FR2257336B1 (en) 1982-09-03
CA1078364A (en) 1980-05-27

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