SE461768B - Samlarreagenskomposition och foerfarande foer skumflotation - Google Patents
Samlarreagenskomposition och foerfarande foer skumflotationInfo
- Publication number
- SE461768B SE461768B SE8702987A SE8702987A SE461768B SE 461768 B SE461768 B SE 461768B SE 8702987 A SE8702987 A SE 8702987A SE 8702987 A SE8702987 A SE 8702987A SE 461768 B SE461768 B SE 461768B
- Authority
- SE
- Sweden
- Prior art keywords
- omega
- hydrocarbyl
- substituted
- composition according
- alkyl
- Prior art date
Links
- 239000003153 chemical reaction reagent Substances 0.000 title claims description 61
- 239000000203 mixture Substances 0.000 title claims description 56
- 238000000034 method Methods 0.000 title claims description 37
- 239000006260 foam Substances 0.000 title claims description 29
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 94
- 239000011707 mineral Substances 0.000 claims description 94
- 238000005188 flotation Methods 0.000 claims description 57
- -1 hydroxy, amino Chemical group 0.000 claims description 38
- 239000010949 copper Substances 0.000 claims description 35
- 229910052751 metal Inorganic materials 0.000 claims description 34
- 239000002184 metal Substances 0.000 claims description 34
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 33
- 125000000217 alkyl group Chemical group 0.000 claims description 30
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 27
- 229910052802 copper Inorganic materials 0.000 claims description 24
- 125000005843 halogen group Chemical group 0.000 claims description 21
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 20
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims description 19
- 239000004215 Carbon black (E152) Substances 0.000 claims description 18
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- 125000001931 aliphatic group Chemical group 0.000 claims description 18
- 150000001875 compounds Chemical class 0.000 claims description 18
- 125000000623 heterocyclic group Chemical class 0.000 claims description 18
- 239000011133 lead Substances 0.000 claims description 18
- 125000003342 alkenyl group Chemical group 0.000 claims description 16
- 229930195733 hydrocarbon Natural products 0.000 claims description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims description 15
- 229910052592 oxide mineral Inorganic materials 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 239000011701 zinc Substances 0.000 claims description 12
- 125000000392 cycloalkenyl group Chemical group 0.000 claims description 11
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 11
- 229910052750 molybdenum Inorganic materials 0.000 claims description 11
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 10
- 150000003973 alkyl amines Chemical class 0.000 claims description 10
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 10
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 239000011733 molybdenum Substances 0.000 claims description 10
- 229910052717 sulfur Inorganic materials 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 125000004122 cyclic group Chemical group 0.000 claims description 9
- 229920006395 saturated elastomer Polymers 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- 229910052709 silver Inorganic materials 0.000 claims description 8
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 7
- 125000000304 alkynyl group Chemical group 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- 150000001721 carbon Chemical group 0.000 claims description 6
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- 125000005499 phosphonyl group Chemical group 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 125000000101 thioether group Chemical group 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000011651 chromium Substances 0.000 claims description 5
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 5
- 125000004434 sulfur atom Chemical group 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052770 Uranium Inorganic materials 0.000 claims description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 239000002932 luster Substances 0.000 claims description 4
- 239000002923 metal particle Substances 0.000 claims description 4
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical group S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 229910052954 pentlandite Inorganic materials 0.000 claims description 4
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 claims description 3
- WAITXWGCJQLPGH-UHFFFAOYSA-N 1-ethylsulfanyloctane Chemical compound CCCCCCCCSCC WAITXWGCJQLPGH-UHFFFAOYSA-N 0.000 claims description 3
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 3
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- SUEKLQICDHYPAC-UHFFFAOYSA-N 2-hexylsulfanylethanamine Chemical compound CCCCCCSCCN SUEKLQICDHYPAC-UHFFFAOYSA-N 0.000 claims description 2
- AHNVIKAHAZJYGD-UHFFFAOYSA-N N-ethyl-2-hexylsulfanylethanamine Chemical compound CCCCCCSCCNCC AHNVIKAHAZJYGD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052961 molybdenite Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 claims description 2
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 13
- 239000004088 foaming agent Substances 0.000 description 13
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 description 13
- 229910052569 sulfide mineral Inorganic materials 0.000 description 13
- 239000012141 concentrate Substances 0.000 description 9
- 230000003750 conditioning effect Effects 0.000 description 7
- 238000011084 recovery Methods 0.000 description 7
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 235000011941 Tilia x europaea Nutrition 0.000 description 6
- 239000004571 lime Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000013589 supplement Substances 0.000 description 5
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 150000002019 disulfides Chemical class 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000005077 polysulfide Substances 0.000 description 4
- 229920001021 polysulfide Polymers 0.000 description 4
- 150000008117 polysulfides Polymers 0.000 description 4
- 229910052683 pyrite Inorganic materials 0.000 description 4
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 4
- 239000011028 pyrite Substances 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 150000001924 cycloalkanes Chemical class 0.000 description 3
- 150000001925 cycloalkenes Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 150000003568 thioethers Chemical group 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 3
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 2
- AHCJTMBRROLNHV-UHFFFAOYSA-N 1-methylsulfanyloctane Chemical compound CCCCCCCCSC AHCJTMBRROLNHV-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001345 alkine derivatives Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052972 bournonite Inorganic materials 0.000 description 2
- 229910052951 chalcopyrite Inorganic materials 0.000 description 2
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 239000012991 xanthate Substances 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
- BGSBXDJLUNXANY-UHFFFAOYSA-N 1-butylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCC BGSBXDJLUNXANY-UHFFFAOYSA-N 0.000 description 1
- HYUPOCGXBZUYFY-UHFFFAOYSA-N 1-butylsulfanylheptane Chemical compound CCCCCCCSCCCC HYUPOCGXBZUYFY-UHFFFAOYSA-N 0.000 description 1
- YZUHMAFUXBPUKH-UHFFFAOYSA-N 1-butylsulfanylhexane Chemical compound CCCCCCSCCCC YZUHMAFUXBPUKH-UHFFFAOYSA-N 0.000 description 1
- FWRIVMHSSSZAFD-UHFFFAOYSA-N 1-butylsulfanylnonane Chemical compound CCCCCCCCCSCCCC FWRIVMHSSSZAFD-UHFFFAOYSA-N 0.000 description 1
- UNIAPWPIAGJFDG-UHFFFAOYSA-N 1-butylsulfanyloctane Chemical compound CCCCCCCCSCCCC UNIAPWPIAGJFDG-UHFFFAOYSA-N 0.000 description 1
- RNEUXBDXTNIASG-UHFFFAOYSA-N 1-butylsulfanylpentane Chemical compound CCCCCSCCCC RNEUXBDXTNIASG-UHFFFAOYSA-N 0.000 description 1
- XLWHZUYTRGNUML-UHFFFAOYSA-N 1-decylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCCCCC XLWHZUYTRGNUML-UHFFFAOYSA-N 0.000 description 1
- PYPULUCCVXMPFP-UHFFFAOYSA-N 1-ethylsulfanylheptane Chemical compound CCCCCCCSCC PYPULUCCVXMPFP-UHFFFAOYSA-N 0.000 description 1
- MGVUJBCOCITTRS-UHFFFAOYSA-N 1-ethylsulfanylhexane Chemical compound CCCCCCSCC MGVUJBCOCITTRS-UHFFFAOYSA-N 0.000 description 1
- LUAABLIRQSWMGZ-UHFFFAOYSA-N 1-ethylsulfanylnonane Chemical compound CCCCCCCCCSCC LUAABLIRQSWMGZ-UHFFFAOYSA-N 0.000 description 1
- HYNUNWWVWIDFNI-UHFFFAOYSA-N 1-heptylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCC HYNUNWWVWIDFNI-UHFFFAOYSA-N 0.000 description 1
- BMONIUVCBPWHMH-UHFFFAOYSA-N 1-heptylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCC BMONIUVCBPWHMH-UHFFFAOYSA-N 0.000 description 1
- LEMIDOZYVQXGLI-UHFFFAOYSA-N 1-heptylsulfanylheptane Chemical compound CCCCCCCSCCCCCCC LEMIDOZYVQXGLI-UHFFFAOYSA-N 0.000 description 1
- RGMJJEGCPWGPIO-UHFFFAOYSA-N 1-heptylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCCC RGMJJEGCPWGPIO-UHFFFAOYSA-N 0.000 description 1
- VOSRYWCOCVSNOU-UHFFFAOYSA-N 1-heptylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCCCCC VOSRYWCOCVSNOU-UHFFFAOYSA-N 0.000 description 1
- AHFXEIBVMODMFA-UHFFFAOYSA-N 1-hexylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCC AHFXEIBVMODMFA-UHFFFAOYSA-N 0.000 description 1
- UUGCJTQYUMVCAB-UHFFFAOYSA-N 1-hexylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCC UUGCJTQYUMVCAB-UHFFFAOYSA-N 0.000 description 1
- MPSAONKRRWETTC-UHFFFAOYSA-N 1-hexylsulfanylheptane Chemical compound CCCCCCCSCCCCCC MPSAONKRRWETTC-UHFFFAOYSA-N 0.000 description 1
- OSCWDJOYYNCZON-UHFFFAOYSA-N 1-hexylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCC OSCWDJOYYNCZON-UHFFFAOYSA-N 0.000 description 1
- LENOFRMWVZUVHH-UHFFFAOYSA-N 1-hexylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCCCC LENOFRMWVZUVHH-UHFFFAOYSA-N 0.000 description 1
- HKGUUZAACYBIID-UHFFFAOYSA-N 1-methylsulfanyldecane Chemical compound CCCCCCCCCCSC HKGUUZAACYBIID-UHFFFAOYSA-N 0.000 description 1
- FJDWJOQOEZRIDJ-UHFFFAOYSA-N 1-methylsulfanylheptane Chemical compound CCCCCCCSC FJDWJOQOEZRIDJ-UHFFFAOYSA-N 0.000 description 1
- LZRXQHHKXDXOIC-UHFFFAOYSA-N 1-methylsulfanylhexane Chemical compound CCCCCCSC LZRXQHHKXDXOIC-UHFFFAOYSA-N 0.000 description 1
- FCRSULZJMFDBIK-UHFFFAOYSA-N 1-methylsulfanylnonane Chemical compound CCCCCCCCCSC FCRSULZJMFDBIK-UHFFFAOYSA-N 0.000 description 1
- UWHYFRCJGNMMSJ-UHFFFAOYSA-N 1-nonylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCCCC UWHYFRCJGNMMSJ-UHFFFAOYSA-N 0.000 description 1
- ARGFAAQZPLNHAK-UHFFFAOYSA-N 1-nonylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCCCC ARGFAAQZPLNHAK-UHFFFAOYSA-N 0.000 description 1
- KMKSVAGOBVUFRO-UHFFFAOYSA-N 1-nonylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCCCCC KMKSVAGOBVUFRO-UHFFFAOYSA-N 0.000 description 1
- DOTUVVYROYQYEQ-UHFFFAOYSA-N 1-nonylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCCCCCCC DOTUVVYROYQYEQ-UHFFFAOYSA-N 0.000 description 1
- YWNBSWRNQJVBMN-UHFFFAOYSA-N 1-octylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCCC YWNBSWRNQJVBMN-UHFFFAOYSA-N 0.000 description 1
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- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- VIWUSEFNWFZOTP-UHFFFAOYSA-N octylsulfanylcyclohexane Chemical compound CCCCCCCCSC1CCCCC1 VIWUSEFNWFZOTP-UHFFFAOYSA-N 0.000 description 1
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- ZBXVHTJPXJLHKM-UHFFFAOYSA-N propylsulfanylcycloheptane Chemical compound CCCSC1CCCCCC1 ZBXVHTJPXJLHKM-UHFFFAOYSA-N 0.000 description 1
- GRTPNKMNAOQMOK-UHFFFAOYSA-N propylsulfanylcyclohexane Chemical compound CCCSC1CCCCC1 GRTPNKMNAOQMOK-UHFFFAOYSA-N 0.000 description 1
- RQCUQPZTBNLEHH-UHFFFAOYSA-N propylsulfanylcyclooctane Chemical compound CCCSC1CCCCCCC1 RQCUQPZTBNLEHH-UHFFFAOYSA-N 0.000 description 1
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 1
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- 239000000344 soap Substances 0.000 description 1
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- 229910052959 stibnite Inorganic materials 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229910052970 tennantite Inorganic materials 0.000 description 1
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- GWBUNZLLLLDXMD-UHFFFAOYSA-H tricopper;dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[O-]C([O-])=O.[O-]C([O-])=O GWBUNZLLLLDXMD-UHFFFAOYSA-H 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/01—Organic compounds containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/014—Organic compounds containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/025—Precious metal ores
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lubricants (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US80288285A | 1985-11-29 | 1985-11-29 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE8702987L SE8702987L (sv) | 1987-07-28 |
| SE8702987D0 SE8702987D0 (sv) | 1987-07-28 |
| SE461768B true SE461768B (sv) | 1990-03-26 |
Family
ID=25184982
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8702987A SE461768B (sv) | 1985-11-29 | 1987-07-28 | Samlarreagenskomposition och foerfarande foer skumflotation |
Country Status (18)
| Country | Link |
|---|---|
| JP (1) | JPS62129160A (pl) |
| CN (1) | CN1014247B (pl) |
| AU (1) | AU588579B2 (pl) |
| BR (1) | BR8607004A (pl) |
| CA (1) | CA1268565A (pl) |
| ES (1) | ES8706045A1 (pl) |
| FI (1) | FI82395C (pl) |
| MX (1) | MX173645B (pl) |
| PH (1) | PH23458A (pl) |
| PL (1) | PL147852B1 (pl) |
| RO (1) | RO100034B1 (pl) |
| RU (1) | RU1839638C (pl) |
| SE (1) | SE461768B (pl) |
| WO (1) | WO1987003222A1 (pl) |
| YU (1) | YU45766B (pl) |
| ZA (1) | ZA861170B (pl) |
| ZM (1) | ZM1586A1 (pl) |
| ZW (1) | ZW4186A1 (pl) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PH24537A (en) * | 1985-11-29 | 1990-08-03 | Dow Chemical Co | Collector composition for the froth flotation of mineral values |
| US4826588A (en) * | 1988-04-28 | 1989-05-02 | The Dow Chemical Company | Pyrite depressants useful in the separation of pyrite from coal |
| US5700369A (en) * | 1997-01-14 | 1997-12-23 | Guangzhou Institute Of Geochemistry Chinese Academy Of Sciences | Process for adsorboaggregational flotation of Carlin type natural gold ore dressing |
| US8734757B2 (en) * | 2008-04-04 | 2014-05-27 | Bhp Billiton Ssm Development Pty Ltd. | Odor control |
| CN102941160A (zh) * | 2012-12-13 | 2013-02-27 | 贵州大学 | 一种硅酸盐矿物浮选捕收剂 |
| US20200048735A1 (en) | 2017-03-23 | 2020-02-13 | Nouryon Chemicals International B.V. | Process to treat metal or mineral ores and collector composition therefor |
| WO2019113082A1 (en) | 2017-12-06 | 2019-06-13 | Dow Global Technologies Llc | A collector formulation to enhance metal recovery in mining applications |
| EP3636346A1 (en) | 2018-10-08 | 2020-04-15 | Nouryon Chemicals International B.V. | Process to treat ores and collector composition therefor |
| CN110015727B (zh) * | 2019-05-09 | 2021-07-09 | 安徽工业大学 | 一种电解气浮除去水体中微塑料的方法 |
| WO2021013991A1 (en) * | 2019-07-24 | 2021-01-28 | Basf Se | Collector composition |
| CN111068924B (zh) * | 2019-12-23 | 2020-10-16 | 中南大学 | 2-氰基-n-(取代氨甲酰)乙酰胺类化合物在含钙矿物浮选中的应用 |
| CN114192273B (zh) * | 2021-11-29 | 2024-08-02 | 浙江遂昌汇金有色金属有限公司 | 一种含贵金属固废无害化、资源化处理工艺 |
| CN114798184B (zh) * | 2022-05-16 | 2024-01-23 | 北京盈翔科技有限公司 | 用于铜金矿浮选的高效起泡剂及其应用方法 |
| CN115228594B (zh) * | 2022-07-25 | 2025-01-07 | 中南大学 | 氧化锑矿的浮选预活化剂及其活化和浮选方法 |
| CN115445779B (zh) * | 2022-09-29 | 2024-08-23 | 中南大学 | 一种辉钼矿和方铅矿选择性浮选分离的药剂和方法 |
| CN115739399B (zh) * | 2022-12-22 | 2024-10-01 | 沈阳有色金属研究院有限公司 | 一种用于浮选有色金属硫化矿的复合捕收剂及其制备方法和应用 |
| WO2024172017A1 (ja) * | 2023-02-15 | 2024-08-22 | 住友化学株式会社 | 浮選剤およびヒ素非含有銅鉱物の回収方法 |
| CN119608400B (zh) * | 2023-09-13 | 2026-03-03 | 中国石油天然气集团有限公司 | 靶向重晶石捕收剂及其制备和应用 |
| CN118179751A (zh) * | 2024-04-11 | 2024-06-14 | 昆明理工大学 | 一种磁黄铁矿组合捕收剂及其制备方法和应用 |
| CN118698748B (zh) * | 2024-08-27 | 2024-11-12 | 中南大学 | 浮选镍硫化矿的捕收剂、浮选药剂和方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2169313A (en) * | 1938-09-24 | 1939-08-15 | Minerals Separation North Us | Concentration of metalliferous ores by flotation |
| US3328442A (en) * | 1963-12-18 | 1967-06-27 | Massachusetts College Of Pharm | Anti-radiation compounds and their preparation |
| US3397238A (en) * | 1965-11-16 | 1968-08-13 | Pfizer & Co C | Process for the preparation of alkyl ethers of amino-alcohols |
| US4086273A (en) * | 1976-04-14 | 1978-04-25 | The Dow Chemical Company | Process for making beta-aminoethyl sulfides from aliphatic mercaptans and 2-oxazolines |
| US4326067A (en) * | 1980-12-03 | 1982-04-20 | The Dow Chemical Company | Process for making N-(2-aminoethyl)amides |
| CA1270076A (en) * | 1985-05-31 | 1990-06-05 | The Dow Chemical Company | Collectors for the selective froth flotation of mineral sulfides |
| ZM1386A1 (en) * | 1985-07-12 | 1988-12-30 | Dow Chemical Co | Novel collector compositions for froth flotation |
| PH24537A (en) * | 1985-11-29 | 1990-08-03 | Dow Chemical Co | Collector composition for the froth flotation of mineral values |
-
1986
- 1986-02-14 CA CA000501882A patent/CA1268565A/en not_active Expired - Fee Related
- 1986-02-14 PH PH33418A patent/PH23458A/en unknown
- 1986-02-14 ES ES552033A patent/ES8706045A1/es not_active Expired
- 1986-02-17 PL PL1986257989A patent/PL147852B1/pl unknown
- 1986-02-17 ZW ZW41/86A patent/ZW4186A1/xx unknown
- 1986-02-17 MX MX001572A patent/MX173645B/es unknown
- 1986-02-17 ZA ZA861170A patent/ZA861170B/xx unknown
- 1986-02-17 YU YU23086A patent/YU45766B/sh unknown
- 1986-02-17 ZM ZM15/86A patent/ZM1586A1/xx unknown
- 1986-02-17 CN CN86101495A patent/CN1014247B/zh not_active Expired
- 1986-02-18 BR BR8607004A patent/BR8607004A/pt not_active IP Right Cessation
- 1986-02-18 AU AU55437/86A patent/AU588579B2/en not_active Ceased
- 1986-02-18 WO PCT/US1986/000342 patent/WO1987003222A1/en not_active Ceased
- 1986-09-03 JP JP61207631A patent/JPS62129160A/ja active Pending
- 1986-12-18 RO RO12922786A patent/RO100034B1/ro unknown
-
1987
- 1987-07-22 RU SU874203131A patent/RU1839638C/ru active
- 1987-07-28 FI FI873288A patent/FI82395C/fi not_active IP Right Cessation
- 1987-07-28 SE SE8702987A patent/SE461768B/sv not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR8607004A (pt) | 1987-12-01 |
| ES8706045A1 (es) | 1987-06-01 |
| FI873288A0 (fi) | 1987-07-28 |
| WO1987003222A1 (en) | 1987-06-04 |
| RO100034B1 (en) | 1992-05-25 |
| ZA861170B (en) | 1987-10-28 |
| AU5543786A (en) | 1987-07-01 |
| CA1268565A (en) | 1990-05-01 |
| ZW4186A1 (en) | 1987-09-09 |
| PH23458A (en) | 1989-08-07 |
| YU45766B (sh) | 1992-07-20 |
| AU588579B2 (en) | 1989-09-21 |
| JPS62129160A (ja) | 1987-06-11 |
| CN86101495A (zh) | 1987-06-03 |
| FI82395B (fi) | 1990-11-30 |
| PL257989A1 (en) | 1987-06-01 |
| PL147852B1 (en) | 1989-08-31 |
| SE8702987L (sv) | 1987-07-28 |
| ES552033A0 (es) | 1987-06-01 |
| FI873288L (fi) | 1987-07-28 |
| FI82395C (fi) | 1991-03-11 |
| YU23086A (en) | 1988-06-30 |
| ZM1586A1 (en) | 1988-12-30 |
| CN1014247B (zh) | 1991-10-09 |
| RU1839638C (ru) | 1993-12-30 |
| MX173645B (es) | 1994-03-22 |
| SE8702987D0 (sv) | 1987-07-28 |
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