SE446191B - Fergkensligt prepareringsmedel, vilket ger ett synligt indicium pa sitt herdingstillstand - Google Patents
Fergkensligt prepareringsmedel, vilket ger ett synligt indicium pa sitt herdingstillstandInfo
- Publication number
- SE446191B SE446191B SE7906608A SE7906608A SE446191B SE 446191 B SE446191 B SE 446191B SE 7906608 A SE7906608 A SE 7906608A SE 7906608 A SE7906608 A SE 7906608A SE 446191 B SE446191 B SE 446191B
- Authority
- SE
- Sweden
- Prior art keywords
- parts
- weight
- sensitive
- current state
- agent according
- Prior art date
Links
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical group [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 2
- 239000000806 elastomer Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 239000011256 inorganic filler Substances 0.000 claims 1
- 229910003475 inorganic filler Inorganic materials 0.000 claims 1
- 239000005011 phenolic resin Substances 0.000 claims 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 claims 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- -1 Pliobond 1012 Chemical compound 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- JATFWPJGBZKYIT-UHFFFAOYSA-N s-(benzotriazol-2-yl)thiohydroxylamine Chemical compound C1=CC=CC2=NN(SN)N=C21 JATFWPJGBZKYIT-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/26—Thermosensitive paints
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
- Epoxy Resins (AREA)
Description
' Ktdelar ftalocyaninblått, 0,5 - 3 delar svavel, 0,5 - 3 15 20 025 30 35 7906608-0 2 är blått vid rumstemperatur, blir ljusgrönt efter 10 minuters värmning vid 17500. När arbetsstyckena har ~ värmts under 30 min vid 175°C, har färgen övergått till mörkgrön och efter 45 min har den blivit brun. Genom att observera färgförändringen kan man alltså kontrol- . lera beskaffenheten av det framkallade limförbandet.
Ett föredraget recept för prepareringsmedlet enligt uppfinningen är (i vikt) 100 delar sampolymer av butadien och akrylnitril (32 - 33 % akrylnitril), 600 delar fenol-formaldehydharts av resoltyp, 0,5 - 10 delar N-oxidíetylenbensotriazol-2-sulfenamid, 5 - 80 delar kalciumkarbonat och 10 - 30 delar epoxiharts av epiklorhydrin och bisfenol A. Blandningen dispergeras i 5 - 30 viktprocent lösningsmedel eller åtminstone tillräckligt med lösningsmedel för att dispersionen skall kunna utbredas genom bestrykning eller svabbning.
Vilket som helst av de vanliga lösningsmedlen för mâlarfärger, såsom ketoner, klorerade kolväten, acetat, aromater eller alkoholer eller blandningar av dem, kan användas för rengöring av arbetsstyckena och framställning av dispersionen_ Ett föredraget lösnings- medel är en blandning av metylketon och butylacetat.
I stället för ftalocyaninblâtt i ovanstående recept kan man använda exempelvis ftalocyaninpigment, viktoriagrönt, kalkozingrönt eller "Calco"-alizarin- grönt för att ge liknande indicier på härdningen genom färgförändring.
De enligt uppfinningen användbara limmen är dispersioner i lösningsmedel av nitrilgummi och härd- bart fenol-formaldehydharts, såsom Pliobond 1012, 101M, 1018 eller 1063 från The Goodyear Tire & Rubber Company.
Representativa eteniskt omättade elaster är sampolymerer av butadien och akrylnitril, där akryl- nitrilhalten är 18 - 45 viktprocent, polybutadiener, _polyisoprener och sampolymerer av butadien och styren samt de närbesläktade gummiartade polymcrerna av diole- 7906608-0 3 finer med H - 10 kolatomer och Sampolymererna av sådana diolefíner med a-olefiner med 2 - 20 kolatomer.
Representativa epoxíhartser, som kan användas i ovanstående recept, är de i amerikanska patentskriften 5 3 719 629 beskrivna. Díglycidyleter av bisfenol A föredras.
Claims (2)
1. 0 7906608-0 PATENTKRAV 1. Färgkänsligt prepareringsmedel, vilket ger ett synligt indicium på sitt härdningstillstånd, innehållande 100 viktdelar eteniskt omättad elast, 300 - 800 viktdelar fenolharts i A- eller B-stadiet, O - 100 viktdelar oorganiskt fyllmedel, 10 - 30 viktdelar epoxiharts och 0,5 - 3 viktdelar svavel, k ä n n e t e c k n a t av att det även innehåller 0, 5 - .O viktdelar värmekänsligt färgämne.
2. Medel enligt patentkravet 1, k ä n n e t e c k n a t av att det värmekänsliga färgämnet är ftalocyaninblâtt. 13. Medel enligt patentkravet 1, k ä n n e t e c k n a t av att det även innehåller 0,5 - 3 viktdelar sulfenamidaccelera- tor: 4._ Medel enligt patentkravet 1, k ä n n e t e c k n a t av att epoxihartset är diglycidyleter av bisfenol A.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/932,873 US4166058A (en) | 1978-08-11 | 1978-08-11 | Heat sensitive primer exhibiting color change and containing a resin blend, elemental sulfur, and a dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE7906608L SE7906608L (sv) | 1980-02-12 |
| SE446191B true SE446191B (sv) | 1986-08-18 |
Family
ID=25463093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7906608A SE446191B (sv) | 1978-08-11 | 1979-08-06 | Fergkensligt prepareringsmedel, vilket ger ett synligt indicium pa sitt herdingstillstand |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4166058A (sv) |
| JP (1) | JPS5525498A (sv) |
| CA (1) | CA1133163A (sv) |
| DE (1) | DE2929987A1 (sv) |
| FR (1) | FR2433038A1 (sv) |
| GB (1) | GB2028349B (sv) |
| IT (1) | IT1117777B (sv) |
| SE (1) | SE446191B (sv) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3047635A1 (de) * | 1980-12-17 | 1982-07-22 | Hilti AG, 9494 Schaan | Klebeverfahren mittels schmelzklebstoff sowie mittel zur durchfuehrung des verfahrens |
| DE3125393A1 (de) * | 1981-06-27 | 1983-01-13 | Dr.Ing.H.C. F. Porsche Ag, 7000 Stuttgart | "verbindung von wenigstens zwei wandungen" |
| JPS5852374A (ja) * | 1981-09-24 | 1983-03-28 | Sakura Color Prod Corp | ゴム加硫標識用インキ組成物 |
| GB2147591B (en) * | 1983-10-06 | 1986-12-31 | Muanyagipari Kutato Intezet | Curing unsaturated polyester resins |
| US5039731A (en) * | 1986-10-20 | 1991-08-13 | Lord Corporation | Metal coating compositions including linear polyester polyurethane |
| US4755251A (en) * | 1987-02-09 | 1988-07-05 | Ashland Oil, Inc. | Bonding method employing primer for fiberglass reinforced polyester |
| JPS63222061A (ja) * | 1987-03-11 | 1988-09-14 | 株式会社アイジー技術研究所 | セラミツクボ−ド |
| GB2234974A (en) * | 1989-08-11 | 1991-02-20 | Marks Spencer Plc | Adhesives |
| US4999101A (en) * | 1989-11-02 | 1991-03-12 | Alusuisse Lonza-Services Ltd | Preheat indicator |
| DE4112649A1 (de) * | 1991-04-18 | 1992-10-22 | Preh Elektro Feinmechanik | Klebemittel und klebeverfahren |
| DE19504532A1 (de) * | 1995-02-11 | 1996-08-14 | Abb Management Ag | Verfahren zur Herstellung eines Isolators |
| DK1424973T3 (da) * | 2001-04-23 | 2010-06-14 | Euro Celtique Sa | Bortskaffelsessystem til transdermal doseringsform |
| KR101407131B1 (ko) * | 2002-06-10 | 2014-06-19 | 유로-셀티크 소시에떼 아노뉨 | 경피 전달 장치에 포함된 활성 성분의 오용을 방지하는 경피 전달 장치의 처리 시스템 |
| US20060264546A1 (en) * | 2003-04-11 | 2006-11-23 | 3M Innovative Properties Company | Pavement marking material |
| JP4267953B2 (ja) * | 2003-04-11 | 2009-05-27 | スリーエム イノベイティブ プロパティズ カンパニー | 仮設用マーキング材及び仮設用路面標示体 |
| EP3483231A1 (en) * | 2017-11-14 | 2019-05-15 | 3M Innovative Properties Company | Color changing composition |
| US11180663B2 (en) | 2019-04-26 | 2021-11-23 | Raytheon Technologies Corporation | Color changing adhesive bond primer |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1126977A (en) * | 1965-04-14 | 1968-09-11 | Celanese Coatings Co | Resinous compositions |
| BE752121A (en) * | 1966-09-26 | 1970-12-01 | A W | Fixation of temperature-indicating pigments |
| US3480691A (en) * | 1967-09-05 | 1969-11-25 | Armitage & Co John L | Primer coating compositions containing carboxylated butadiene acrylonitrile copolymer,vinyl chloride copolymer,a polyacrylate,an epoxide resin and a phenol-formaldehyde resin |
| BE795367A (fr) * | 1971-03-31 | 1973-08-13 | Dow Chemical Co | Compositions de revetement a base d'interpolymeres aminoethyles |
| US3780132A (en) * | 1971-12-22 | 1973-12-18 | Du Pont | Primer composition containing epoxide resins,phenol formaldehyde resin,tetraalkyl silicates,and silane coupling agents |
| FR2228097A1 (en) * | 1973-05-03 | 1974-11-29 | Inst Ljuminoforov I Osobo | Melt thermoindicator contg. carboxylic acid deriv. - and poly-vinyl-butyral-modified resol phenolic resin soln. |
| US4020038A (en) * | 1975-09-19 | 1977-04-26 | The Goodyear Tire & Rubber Company | Paintable rubber composition and products prepared therefrom |
-
1978
- 1978-08-11 US US05/932,873 patent/US4166058A/en not_active Expired - Lifetime
-
1979
- 1979-07-05 CA CA331,234A patent/CA1133163A/en not_active Expired
- 1979-07-17 GB GB7924864A patent/GB2028349B/en not_active Expired
- 1979-07-24 DE DE19792929987 patent/DE2929987A1/de active Granted
- 1979-07-26 IT IT49872/79A patent/IT1117777B/it active
- 1979-08-02 FR FR7919857A patent/FR2433038A1/fr active Granted
- 1979-08-06 SE SE7906608A patent/SE446191B/sv not_active IP Right Cessation
- 1979-08-11 JP JP10270779A patent/JPS5525498A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE2929987A1 (de) | 1980-02-21 |
| GB2028349B (en) | 1982-09-29 |
| DE2929987C2 (sv) | 1987-12-03 |
| IT7949872A0 (it) | 1979-07-26 |
| US4166058A (en) | 1979-08-28 |
| IT1117777B (it) | 1986-02-24 |
| FR2433038A1 (fr) | 1980-03-07 |
| JPS5525498A (en) | 1980-02-23 |
| CA1133163A (en) | 1982-10-05 |
| JPS6228837B2 (sv) | 1987-06-23 |
| SE7906608L (sv) | 1980-02-12 |
| GB2028349A (en) | 1980-03-05 |
| FR2433038B1 (sv) | 1982-04-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |
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