SE327964B - - Google Patents

Info

Publication number
SE327964B
SE327964B SE13900/66A SE1390066A SE327964B SE 327964 B SE327964 B SE 327964B SE 13900/66 A SE13900/66 A SE 13900/66A SE 1390066 A SE1390066 A SE 1390066A SE 327964 B SE327964 B SE 327964B
Authority
SE
Sweden
Prior art keywords
hydroxy
metals
esters
metal
compounds
Prior art date
Application number
SE13900/66A
Inventor
N Grier
Original Assignee
Metalsalts Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metalsalts Corp filed Critical Metalsalts Corp
Publication of SE327964B publication Critical patent/SE327964B/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/20—Oxygen atoms
    • C07D215/24—Oxygen atoms attached in position 8
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/20—Oxygen atoms
    • C07D215/24—Oxygen atoms attached in position 8
    • C07D215/26—Alcohols; Ethers thereof
    • C07D215/30—Metal salts; Chelates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/38—Heterocyclic nitrogen compounds
    • C10M133/40—Six-membered ring containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds

Abstract

Quinolinol esters are added to lubricating oils containing compounds of metals other than alkali metals to bind the metals as quinolinates. The preferred esters are those of 2-ethyl hexoic, myristic, palmitic, stearic and other higher fatty acids which are not subject to oxidation. The amount of ester added is normally in the range 0.02-0.2% by weight of the oil. The esters may also be added to coating compositions to combine with compounds of metals other than alkali metals to form a coating composition which is mildew-proof. In an example, aquinolinol ester is added to a wire-coating composition containing linseed oil, zinc oxide and rubber.ALSO:A quinolate (oxinate) of a metal other than an alkali metal is prepared by reacting an ester of a hydroxyquinoline in the absence of water with a compound of a metal other than an alkali metal. The reaction may be carried out in solution in an organic solvent at elevated temperature. The esters used as starting materials are prepared by conventional methods. The acids from which the esters are formed may be a saturated or unsaturated mono- or polycarboxylic acid, e.g. formic, acetic, propionic, octoic, undecylic, lauric, myristic, palmitic, stearic, arachidic, undecylinic, oleic, linoleic, linolenic, palmitoleic, maleic, fumaric, succinic, glutaric, sebacic, phthalic, cinnamic, aconitic benzoic, phenylacetic, phenylpropionic, naphthenic, glycollic, citric, tartartaric, salicylic, and acetylsalicylic acid. The acids may also be those derived from naturally occurring oils and fats. The metal compounds used may be the salts of those acids used to form the esters or of other organic or inorganic acids. The compounds may alternatively be enolates. A mixture of compounds of different metals may be used. Suitable metals for use in the formation of the quinolinolates are, e.g. aluminium, beryllium, magnesium, calcium, strontium, barium, lead, zinc, mercury, tin, iron, nickel, cobalt, manganese, chromium, copper, cadmium, silver and thallium. The metals may be present in their higher or lower valency states where they have more than one valency state. The esters of substituted quinolinols, e.g. esters of 4 - methyl- 8 - hydroxy-; 4 - methyl - 2 - hydroxy-; 2-methyl-4-hydroxy-; 5,7-dichloro-8-hydroxy; 5,7-dibromo-8-hydroxy-; 5,7-diiodo-8-hydroxy-; 5-ethyl-7-bromo-8-hydroxy; 4-cyano-8-hydroxy-; 7-cyano-8-hydroxy- and 2-amino-8-hydroxy-quinolines may be used as starting materials although the preferred ester are those of 8-hydroxy-quinoline.ALSO:Metal quinolindates of metals other than alkali metals are used to treat fabrics, e.g. cotton, to make them mildew proof. The fabric is treated with a mixture of a quinolester and a compound of the metal concerned in an organic solvent and the quinolinolate is formed in situ. An example is given of the mildew proofing of cotton fabric by treating it with a solution of 8-quinolyl-2-ethyl-hexoate and copper octoate in mineral spirits thus depositing copper quinolinolate in the fabric.
SE13900/66A 1961-11-30 1966-10-13 SE327964B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US187999A US3307970A (en) 1961-11-30 1961-11-30 Preparations for the production of metal 8-hydroxy quinolinates and process for utilizing same

Publications (1)

Publication Number Publication Date
SE327964B true SE327964B (en) 1970-09-07

Family

ID=22691365

Family Applications (2)

Application Number Title Priority Date Filing Date
SE12877/62A SE324363B (en) 1961-11-30 1962-11-29
SE13900/66A SE327964B (en) 1961-11-30 1966-10-13

Family Applications Before (1)

Application Number Title Priority Date Filing Date
SE12877/62A SE324363B (en) 1961-11-30 1962-11-29

Country Status (11)

Country Link
US (1) US3307970A (en)
BE (1) BE625529A (en)
BR (1) BR6244976D0 (en)
CH (1) CH432118A (en)
DE (2) DE1444098A1 (en)
ES (1) ES283065A1 (en)
FR (1) FR1359124A (en)
GB (1) GB1032051A (en)
NL (1) NL286201A (en)
NO (1) NO116714B (en)
SE (2) SE324363B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3622377A (en) * 1969-08-27 1971-11-23 Us Agriculture Process for applying copper 8-quinolinolate to cellulosics from solvent system
BE790326A (en) * 1971-10-20 1973-04-19 Pechiney Ugine Kuhlmann NEW HYDROXYQUINOLEINE DERIVATIVE
US3872128A (en) * 1972-03-08 1975-03-18 Union Carbide Corp Antimicrobial hydroxy quinoline, ethylene-acrylic polymer compositions
HU185805B (en) * 1980-12-30 1985-04-28 Autoipari Kutato Intezet Lubricant compesition
US8801972B2 (en) * 2011-02-14 2014-08-12 Indian Institute Of Technology Kanpur Zinc chalcogenides, doped zinc chalcogenides, and methods of making
CN110476988B (en) * 2019-09-17 2021-08-03 嘉兴市世诚科技有限公司 Bactericidal composition for preventing and treating crop bacterial diseases and application thereof

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2030033A (en) * 1933-06-10 1936-02-04 Standard Oil Co Treatment of cracked petroleum distillates
US2255597A (en) * 1939-11-10 1941-09-09 Du Pont Stabilization of organic substances
US2372588A (en) * 1940-06-19 1945-03-27 Shell Dev Compounded mineral oil
US2298640A (en) * 1942-05-13 1942-10-13 Lubri Zol Corp Lubricating composition
US2363778A (en) * 1942-12-01 1944-11-28 Du Pont Stabilization of organic substances
US2381863A (en) * 1943-05-01 1945-08-14 Monsanto Chemicals Method of fungusproofing textiles
US2526948A (en) * 1945-10-23 1950-10-24 Phillips Petroleum Co Process of treating textiles with half-acid amide derivatives
US2523114A (en) * 1949-01-22 1950-09-19 Standard Oil Dev Co Methoxy dicyclopentadiene mercuric chloride for controlling parasites
US2666058A (en) * 1950-05-16 1954-01-12 Ciba Pharm Prod Inc Undecylenic acid esters of 8-hydroxyquinolines
US2608556A (en) * 1950-07-10 1952-08-26 Scient Oil Compounding Company Preparation of a soluble metal quinolinolate
US2755280A (en) * 1952-02-29 1956-07-17 Geigy Chem Corp Solubilization of metallic-8-quinolinolates
US2799615A (en) * 1953-05-23 1957-07-16 Riedel De Haen Ag Process of preparing fungicidal 8-hydroxyquinoline compositions
US2979434A (en) * 1953-12-07 1961-04-11 Monsanto Chemicals Polyamine nematocides
US2745832A (en) * 1954-03-08 1956-05-15 Nuodex Products Co Inc Metal quinolinolates and methods of making the same
US2895837A (en) * 1956-12-26 1959-07-21 Cfmc New complex solutions and dispersions and process for their preparation
US2991183A (en) * 1958-01-02 1961-07-04 Metalsalts Corp Fungicidal and bactericidal compositions
US3017362A (en) * 1958-06-12 1962-01-16 Universal Oil Prod Co Hydrocarbon oil composition
NL111525C (en) * 1958-07-28
US3031402A (en) * 1959-07-27 1962-04-24 Sinclair Refining Co Lubricant composition

Also Published As

Publication number Publication date
NO116714B (en) 1969-05-12
DE1284019C2 (en) 1969-08-07
CH432118A (en) 1967-09-15
US3307970A (en) 1967-03-07
FR1359124A (en) 1964-04-24
SE324363B (en) 1970-06-01
BR6244976D0 (en) 1973-05-15
GB1032051A (en) 1966-06-08
ES283065A1 (en) 1963-05-01
CH1410162A4 (en) 1966-09-30
BE625529A (en) 1963-03-15
DE1444098A1 (en) 1970-01-22
DE1284019B (en) 1968-11-28
NL286201A (en)

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