GB891858A - Improvements in or relating to oil-soluble soaps of polyvalent metals - Google Patents
Improvements in or relating to oil-soluble soaps of polyvalent metalsInfo
- Publication number
- GB891858A GB891858A GB24194/59A GB2419459A GB891858A GB 891858 A GB891858 A GB 891858A GB 24194/59 A GB24194/59 A GB 24194/59A GB 2419459 A GB2419459 A GB 2419459A GB 891858 A GB891858 A GB 891858A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acids
- carbon atoms
- acid
- metal
- naphthenic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 5
- 239000002184 metal Substances 0.000 title abstract 5
- 239000000344 soap Substances 0.000 title abstract 4
- 150000002739 metals Chemical class 0.000 title abstract 3
- 239000002253 acid Substances 0.000 abstract 7
- 150000007513 acids Chemical class 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- -1 marium Chemical class 0.000 abstract 3
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical class CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 239000011575 calcium Substances 0.000 abstract 2
- 235000019253 formic acid Nutrition 0.000 abstract 2
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 abstract 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 abstract 2
- 150000002736 metal compounds Chemical class 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004435 Oxo alcohol Substances 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 235000011054 acetic acid Nutrition 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 150000004674 formic acids Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 235000014655 lactic acid Nutrition 0.000 abstract 1
- 239000011133 lead Substances 0.000 abstract 1
- 235000021388 linseed oil Nutrition 0.000 abstract 1
- 239000000944 linseed oil Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 235000019260 propionic acid Nutrition 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D15/00—Manufacture of resin soap or soaps derived from naphthenic acids; Compositions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
In the preparation of oil-soluble soaps of polyvalent metals and organic aliphatic or cycloaliphatic carboxylic acids containing more than 6 carbon atoms, by reacting a finely powdered oxide or hydroxide of the metal with the acid, the process is catalysed by the presence of a salt derived from the metal and an aliphatic carboxylic acid containing less than 4 carbon atoms in the molecule and which may be formed in situ. Soaps derived from linseed oil fatty acids, oleic, stearic, naphthenic, pelargonic, 3,5,5-trimethyl-hexanoic, 2-ethyl hexanoic acids, and acids obtained by the Fischer-Tropsch synthesis and branched-chain acids from oxo-alcohols, and metals such as marium, calcium, cobalt, copper, iron, lead, magnesium, manganese, mercury and zinc are referred to, and the acids containing less than 4 carbon atoms are selected from acetic, propionic, lactic or formic acids. In examples, the aliphatic carboxylic acid, e.g. acetic or propionic, and the metal oxide or hydronide, e.g. litharge, in solution in an organic solvent or water form the intermediate soap to which the acid containing more than 6 carbon atoms, e.g. naphthenic, and ethylhexanoic acids in white spirit or xylene is added and the product separated; or alternatively the higher acid, e.g. naphthenic or saturated iso-carboxylic acids, is mixed with the metal compound, e.g. litharge, cobalt hydroxide, and calcium or mercuric oxides, in a solvent such as white spirit, and acetic or formic acid added with or before the metal compound, the lower acids and water are then distilled off. Specification 451,735 is referred to.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL1156812X | 1958-07-17 | ||
NL891858X | 1958-07-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB891858A true GB891858A (en) | 1962-03-21 |
Family
ID=33032454
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB24194/59A Expired GB891858A (en) | 1958-07-17 | 1959-07-14 | Improvements in or relating to oil-soluble soaps of polyvalent metals |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB891858A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3367869A (en) * | 1965-06-18 | 1968-02-06 | British Petroleum Co | Alkaline lubricating oil |
FR2588863A1 (en) * | 1985-10-18 | 1987-04-24 | Rhone Poulenc Spec Chim | PROCESS FOR THE PREPARATION OF ALKALINE SALTS OF TRIFLUOROACETIC ACID IN ANHYDROUS AND CRYSTALLIZED CONDITIONS |
WO1992006945A1 (en) * | 1990-10-19 | 1992-04-30 | Exxon Chemical Patents Inc. | Metal carboxylates |
RU2451051C2 (en) * | 2010-06-22 | 2012-05-20 | Общество с ограниченной ответственностью "Новые технологии" (ООО "Новые технологии") | Method of producing siccative for paint material |
RU2485155C1 (en) * | 2011-12-27 | 2013-06-20 | Общество с ограниченной ответственностью "Новые технологии" (ООО "Новые технологии") | Method of producing siccative for paint materials |
CN111484802A (en) * | 2020-05-25 | 2020-08-04 | 郑州中岳高新材料有限公司 | Preparation method of low-cost efficient drier |
WO2023225494A1 (en) * | 2022-05-16 | 2023-11-23 | Heritage Research Group, Llc | Unrefined neodecanoic acid source as a raw material for h2s scavenging metal carboxylate |
-
1959
- 1959-07-14 GB GB24194/59A patent/GB891858A/en not_active Expired
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3367869A (en) * | 1965-06-18 | 1968-02-06 | British Petroleum Co | Alkaline lubricating oil |
FR2588863A1 (en) * | 1985-10-18 | 1987-04-24 | Rhone Poulenc Spec Chim | PROCESS FOR THE PREPARATION OF ALKALINE SALTS OF TRIFLUOROACETIC ACID IN ANHYDROUS AND CRYSTALLIZED CONDITIONS |
EP0222673A1 (en) * | 1985-10-18 | 1987-05-20 | Rhone-Poulenc Chimie | Process for the preparation of anhydrous crystalline alkali metal salts of trifluoroacetic acid |
US4760177A (en) * | 1985-10-18 | 1988-07-26 | Rhone Poulenc Specialties Chimiques | Process for preparing alkali metal salts of trifluoroacetic acid in the anhydrous and crystalline state |
WO1992006945A1 (en) * | 1990-10-19 | 1992-04-30 | Exxon Chemical Patents Inc. | Metal carboxylates |
RU2451051C2 (en) * | 2010-06-22 | 2012-05-20 | Общество с ограниченной ответственностью "Новые технологии" (ООО "Новые технологии") | Method of producing siccative for paint material |
RU2485155C1 (en) * | 2011-12-27 | 2013-06-20 | Общество с ограниченной ответственностью "Новые технологии" (ООО "Новые технологии") | Method of producing siccative for paint materials |
CN111484802A (en) * | 2020-05-25 | 2020-08-04 | 郑州中岳高新材料有限公司 | Preparation method of low-cost efficient drier |
WO2023225494A1 (en) * | 2022-05-16 | 2023-11-23 | Heritage Research Group, Llc | Unrefined neodecanoic acid source as a raw material for h2s scavenging metal carboxylate |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB972804A (en) | Improvements relating to metal-organic compounds | |
GB891858A (en) | Improvements in or relating to oil-soluble soaps of polyvalent metals | |
GB705308A (en) | Phosphonic acid derivatives and lubricating compositions containing the same | |
GB778567A (en) | Metal soap-salt complexes, and lubricating grease compositions containing them | |
GB648518A (en) | Improvements relating to compositions having fungicidal and/or fungistatic properties | |
US4599201A (en) | Process for preparing ceric carboxylates | |
US2951808A (en) | Lubricant compositions containing metal salts of aromatic hydroxy carboxylic acids as antioxidants | |
FR2069063A5 (en) | ||
SE327964B (en) | ||
GB789855A (en) | Improved lubricating greases | |
US3121728A (en) | Production of monocarboxylic acids from large ring alicyclic alcohols | |
US3897469A (en) | Process for the production of di- and polyhydroxycarboxylic acids | |
GB793484A (en) | Improved grease compositions | |
GB1028425A (en) | Process for the production of highly concentrated solutions of metal soaps | |
GB775027A (en) | Improvements in or relating to complex metal salt-soap compounds | |
US2909485A (en) | Method of preparing mixed-salt containing lubricants | |
US2962441A (en) | Alkali fusion products of cyclohexenones in lubricant manufacture | |
GB891470A (en) | Condensation products derived from carboxylic acids | |
JPH10120615A (en) | Production of fatty acid metallic soap containing fatty acid salt of molybdenum | |
GB1289003A (en) | ||
GB785509A (en) | Grease composition | |
US2513060A (en) | Lubricant compositions containing organic oxidized and sulfurized esters | |
GB985217A (en) | The process for the production of metal soaps of epoxidised fatty acids | |
GB825805A (en) | Improvements in or relating to metal soap driers suitable for use in coating compositions: and compositions containing such driers | |
GB890386A (en) | A polypropylene grease |