SE174730C1

SE174730C1 -

Info

Publication number: SE174730C1
Authority: SE; Sweden
Prior art keywords: solvent; nitrite; polypyrrolidone; acidic; phytate
Prior art date: 1961-01-01

Application number

Other languages

English (en)

Swedish (sv)

Publication date

1961-01-01

1961-01-01 Publication of SE174730C1 publication Critical patent/SE174730C1/sv

Links

239000002904 solvent Substances 0.000 claims description 41
229920001007 Nylon 4 Polymers 0.000 claims description 39
230000002378 acidificating effect Effects 0.000 claims description 36
235000002949 phytic acid Nutrition 0.000 claims description 31
IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 27
-1 alkali metal salts Chemical class 0.000 claims description 25
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
239000000463 material Substances 0.000 claims description 21
239000000203 mixture Substances 0.000 claims description 21
IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 20
229940068041 phytic acid Drugs 0.000 claims description 20
239000000467 phytic acid Substances 0.000 claims description 20
238000000034 method Methods 0.000 claims description 12
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 11
239000002253 acid Substances 0.000 claims description 10
229910052783 alkali metal Inorganic materials 0.000 claims description 8
WPEXVRDUEAJUGY-UHFFFAOYSA-B hexacalcium;(2,3,4,5,6-pentaphosphonatooxycyclohexyl) phosphate Chemical compound [Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])(=O)OC1C(OP([O-])([O-])=O)C(OP([O-])([O-])=O)C(OP([O-])([O-])=O)C(OP([O-])([O-])=O)C1OP([O-])([O-])=O WPEXVRDUEAJUGY-UHFFFAOYSA-B 0.000 claims description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
150000001875 compounds Chemical class 0.000 claims description 5
229910052700 potassium Inorganic materials 0.000 claims description 5
239000011591 potassium Substances 0.000 claims description 5
239000003513 alkali Substances 0.000 claims description 4
238000002360 preparation method Methods 0.000 claims description 4
239000007864 aqueous solution Substances 0.000 claims description 3
238000009835 boiling Methods 0.000 claims description 2
238000010438 heat treatment Methods 0.000 claims description 2
IWEDUKDKQUXPLH-NFJZTGFVSA-L [Mg++].OP(O)(=O)O[C@H]1[C@@H](OP(O)(O)=O)C(OP(O)([O-])=O)[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)C1OP(O)([O-])=O Chemical compound [Mg++].OP(O)(=O)O[C@H]1[C@@H](OP(O)(O)=O)C(OP(O)([O-])=O)[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)C1OP(O)([O-])=O IWEDUKDKQUXPLH-NFJZTGFVSA-L 0.000 claims 2
FENRSEGZMITUEF-ATTCVCFYSA-E [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] FENRSEGZMITUEF-ATTCVCFYSA-E 0.000 claims 2
239000012456 homogeneous solution Substances 0.000 claims 2
229940083982 sodium phytate Drugs 0.000 claims 2
239000000243 solution Substances 0.000 description 75
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 57
229920000642 polymer Polymers 0.000 description 35
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 24
239000000835 fiber Substances 0.000 description 21
239000003054 catalyst Substances 0.000 description 20
238000006116 polymerization reaction Methods 0.000 description 19
238000009987 spinning Methods 0.000 description 13
HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 11
239000012190 activator Substances 0.000 description 10
239000003795 chemical substances by application Substances 0.000 description 10
238000004519 manufacturing process Methods 0.000 description 10
238000007598 dipping method Methods 0.000 description 9
239000011521 glass Substances 0.000 description 9
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
241000700143 Castor fiber Species 0.000 description 7
125000004432 carbon atom Chemical group C* 0.000 description 7
239000000047 product Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
238000003756 stirring Methods 0.000 description 6
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 5
239000012298 atmosphere Substances 0.000 description 5
238000000578 dry spinning Methods 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
239000012312 sodium hydride Substances 0.000 description 5
229910000104 sodium hydride Inorganic materials 0.000 description 5
239000000126 substance Substances 0.000 description 5
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 4
150000001340 alkali metals Chemical class 0.000 description 4
238000000576 coating method Methods 0.000 description 4
235000019253 formic acid Nutrition 0.000 description 4
239000012299 nitrogen atmosphere Substances 0.000 description 4
239000004014 plasticizer Substances 0.000 description 4
229910052710 silicon Inorganic materials 0.000 description 4
239000010703 silicon Substances 0.000 description 4
229910052708 sodium Inorganic materials 0.000 description 4
239000011734 sodium Substances 0.000 description 4
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical group S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 3
229910052787 antimony Inorganic materials 0.000 description 3
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 3
239000000975 dye Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000000839 emulsion Substances 0.000 description 3
229910052744 lithium Inorganic materials 0.000 description 3
238000000465 moulding Methods 0.000 description 3
229910052698 phosphorus Inorganic materials 0.000 description 3
239000011574 phosphorus Substances 0.000 description 3
UUFVLCFBYUYLMD-UHFFFAOYSA-N (2-ethylphenyl)methyl nitrite Chemical compound N(=O)OCC1=C(C=CC=C1)CC UUFVLCFBYUYLMD-UHFFFAOYSA-N 0.000 description 2
RRLZZHQGPPIOCY-UHFFFAOYSA-N (5-ethyl-2-methylphenyl)methyl nitrite Chemical compound N(=O)OCC1=C(C=CC(=C1)CC)C RRLZZHQGPPIOCY-UHFFFAOYSA-N 0.000 description 2
YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
229920000742 Cotton Polymers 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
QQZWEECEMNQSTG-UHFFFAOYSA-N Ethyl nitrite Chemical compound CCON=O QQZWEECEMNQSTG-UHFFFAOYSA-N 0.000 description 2
IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
229910021627 Tin(IV) chloride Inorganic materials 0.000 description 2
230000002411 adverse Effects 0.000 description 2
DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
239000000701 coagulant Substances 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000002485 combustion reaction Methods 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
BYLOHCRAPOSXLY-UHFFFAOYSA-N dichloro(diethyl)silane Chemical compound CC[Si](Cl)(Cl)CC BYLOHCRAPOSXLY-UHFFFAOYSA-N 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
239000003995 emulsifying agent Substances 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
150000004678 hydrides Chemical class 0.000 description 2
OWFXIOWLTKNBAP-UHFFFAOYSA-N isoamyl nitrite Chemical compound CC(C)CCON=O OWFXIOWLTKNBAP-UHFFFAOYSA-N 0.000 description 2
239000000178 monomer Substances 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 2
239000002966 varnish Substances 0.000 description 2
KJRATYQJAZZHJF-UHFFFAOYSA-N (2,3-dimethylphenyl)methyl nitrite Chemical compound N(=O)OCC1=C(C(=CC=C1)C)C KJRATYQJAZZHJF-UHFFFAOYSA-N 0.000 description 1
WFUYAIYHFGBAIX-UHFFFAOYSA-N (2,4-dimethylphenyl)methyl nitrite Chemical compound N(=O)OCC1=C(C=C(C=C1)C)C WFUYAIYHFGBAIX-UHFFFAOYSA-N 0.000 description 1
PGGCLZDWUUYLSQ-UHFFFAOYSA-N (2,6-dimethylphenyl)methyl nitrite Chemical compound N(=O)OCC1=C(C=CC=C1C)C PGGCLZDWUUYLSQ-UHFFFAOYSA-N 0.000 description 1
IZPKFSXKRLDAAS-UHFFFAOYSA-N (2-ethyl-4-methylphenyl)methyl nitrite Chemical compound N(=O)OCC1=C(C=C(C=C1)C)CC IZPKFSXKRLDAAS-UHFFFAOYSA-N 0.000 description 1
FJFXWXNFEDBSES-UHFFFAOYSA-N (2-ethyl-5-methylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC(=CC=C1CC)C FJFXWXNFEDBSES-UHFFFAOYSA-N 0.000 description 1
VNCXZMQKPSIFQQ-UHFFFAOYSA-N (2-ethyl-6-methylphenyl)methyl nitrite Chemical compound N(=O)OCC1=C(C=CC=C1CC)C VNCXZMQKPSIFQQ-UHFFFAOYSA-N 0.000 description 1
CGRGRUYZRJKXIT-UHFFFAOYSA-N (2-methylphenyl)methyl nitrite Chemical compound CC1=CC=CC=C1CON=O CGRGRUYZRJKXIT-UHFFFAOYSA-N 0.000 description 1
DKUSYSHQHUAWLD-UHFFFAOYSA-N (2-propylphenyl)methyl nitrite Chemical compound N(=O)OCC1=C(C=CC=C1)CCC DKUSYSHQHUAWLD-UHFFFAOYSA-N 0.000 description 1
QOTSAHYRPZDNCF-UHFFFAOYSA-N (3,5-dimethylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC(=CC(=C1)C)C QOTSAHYRPZDNCF-UHFFFAOYSA-N 0.000 description 1
BVRUGFSQCZACRM-UHFFFAOYSA-N (3-ethyl-4-methylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC(=C(C=C1)C)CC BVRUGFSQCZACRM-UHFFFAOYSA-N 0.000 description 1
KBHWCBIDYHJRLZ-UHFFFAOYSA-N (3-ethyl-5-methylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC(=CC(=C1)CC)C KBHWCBIDYHJRLZ-UHFFFAOYSA-N 0.000 description 1
SOWZQBWJPUOSKF-UHFFFAOYSA-N (3-ethylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC(=CC=C1)CC SOWZQBWJPUOSKF-UHFFFAOYSA-N 0.000 description 1
CMCMBYOPMPDUIV-UHFFFAOYSA-N (3-methylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC(=CC=C1)C CMCMBYOPMPDUIV-UHFFFAOYSA-N 0.000 description 1
FWHLGGONOGHSFL-UHFFFAOYSA-N (3-propylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC(=CC=C1)CCC FWHLGGONOGHSFL-UHFFFAOYSA-N 0.000 description 1
HFYJLNVXOOFLJM-UHFFFAOYSA-N (4-ethyl-2-methylphenyl)methyl nitrite Chemical compound N(=O)OCC1=C(C=C(C=C1)CC)C HFYJLNVXOOFLJM-UHFFFAOYSA-N 0.000 description 1
CTVCEHQFCOSACW-UHFFFAOYSA-N (4-ethyl-3-methylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC(=C(C=C1)CC)C CTVCEHQFCOSACW-UHFFFAOYSA-N 0.000 description 1
ZJQWUYHYLPUYEL-UHFFFAOYSA-N (4-ethylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC=C(C=C1)CC ZJQWUYHYLPUYEL-UHFFFAOYSA-N 0.000 description 1
PHDLSMHAYVETTC-UHFFFAOYSA-N (4-methylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC=C(C=C1)C PHDLSMHAYVETTC-UHFFFAOYSA-N 0.000 description 1
WGCLUVZLLAOWFS-UHFFFAOYSA-N (4-propylphenyl)methyl nitrite Chemical compound N(=O)OCC1=CC=C(C=C1)CCC WGCLUVZLLAOWFS-UHFFFAOYSA-N 0.000 description 1
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
OGFAWKRXZLGJSK-UHFFFAOYSA-N 1-(2,4-dihydroxyphenyl)-2-(4-nitrophenyl)ethanone Chemical compound OC1=CC(O)=CC=C1C(=O)CC1=CC=C([N+]([O-])=O)C=C1 OGFAWKRXZLGJSK-UHFFFAOYSA-N 0.000 description 1
YLHUPYSUKYAIBW-UHFFFAOYSA-N 1-acetylpyrrolidin-2-one Chemical compound CC(=O)N1CCCC1=O YLHUPYSUKYAIBW-UHFFFAOYSA-N 0.000 description 1
YIHYSPHLIOTYAG-UHFFFAOYSA-N 1-phenylethyl nitrite Chemical compound O=NOC(C)C1=CC=CC=C1 YIHYSPHLIOTYAG-UHFFFAOYSA-N 0.000 description 1
PKJBRKTYYNRVSN-UHFFFAOYSA-N 10-(aminomethyl)-9,10-dihydroanthracene-1,2-diol Chemical compound OC1=CC=C2C(CN)C3=CC=CC=C3CC2=C1O PKJBRKTYYNRVSN-UHFFFAOYSA-N 0.000 description 1
YURNBPLUXKYSOL-UHFFFAOYSA-N 2,2,2-trichloroethyl nitrite Chemical compound ClC(Cl)(Cl)CON=O YURNBPLUXKYSOL-UHFFFAOYSA-N 0.000 description 1
NFSDYGZDUJCSLO-UHFFFAOYSA-N 2,2-dichlorobutyl nitrite Chemical compound N(=O)OCC(CC)(Cl)Cl NFSDYGZDUJCSLO-UHFFFAOYSA-N 0.000 description 1
XVZSESWZNHSGAM-UHFFFAOYSA-N 2,2-dichloroethyl nitrite Chemical compound ClC(Cl)CON=O XVZSESWZNHSGAM-UHFFFAOYSA-N 0.000 description 1
XWYMAIGJUGLIBY-UHFFFAOYSA-N 2,2-dichloroheptyl nitrite Chemical compound N(=O)OCC(CCCCC)(Cl)Cl XWYMAIGJUGLIBY-UHFFFAOYSA-N 0.000 description 1
GSHKAJUKUYTBBX-UHFFFAOYSA-N 2,2-dichlorohexyl nitrite Chemical compound N(=O)OCC(CCCC)(Cl)Cl GSHKAJUKUYTBBX-UHFFFAOYSA-N 0.000 description 1
OIIJSTBHOUROAD-UHFFFAOYSA-N 2,2-dichlorononyl nitrite Chemical compound N(=O)OCC(CCCCCCC)(Cl)Cl OIIJSTBHOUROAD-UHFFFAOYSA-N 0.000 description 1
BJNVONMQIRJYJP-UHFFFAOYSA-N 2,2-dichlorooctyl nitrite Chemical compound N(=O)OCC(CCCCCC)(Cl)Cl BJNVONMQIRJYJP-UHFFFAOYSA-N 0.000 description 1
WVJQGYDBDONSEN-UHFFFAOYSA-N 2,2-dichloropentyl nitrite Chemical compound N(=O)OCC(CCC)(Cl)Cl WVJQGYDBDONSEN-UHFFFAOYSA-N 0.000 description 1
KFLXUTVTHHDBSY-UHFFFAOYSA-N 2,2-dichloropropyl nitrite Chemical compound N(=O)OCC(C)(Cl)Cl KFLXUTVTHHDBSY-UHFFFAOYSA-N 0.000 description 1
GUPPJWOWRLWBBF-UHFFFAOYSA-N 2-butoxyethyl nitrite Chemical compound CCCCOCCON=O GUPPJWOWRLWBBF-UHFFFAOYSA-N 0.000 description 1
CKQXOKVMMGYJPB-UHFFFAOYSA-N 2-decoxyethyl nitrite Chemical compound N(=O)OCCOCCCCCCCCCC CKQXOKVMMGYJPB-UHFFFAOYSA-N 0.000 description 1
JRMAQQQTXDJDNC-UHFFFAOYSA-M 2-ethoxy-2-oxoacetate Chemical compound CCOC(=O)C([O-])=O JRMAQQQTXDJDNC-UHFFFAOYSA-M 0.000 description 1
UAQPVXNVJIGRGE-UHFFFAOYSA-N 2-ethoxyethyl nitrite Chemical compound CCOCCON=O UAQPVXNVJIGRGE-UHFFFAOYSA-N 0.000 description 1
QUKKRMYHOCZLKY-UHFFFAOYSA-N 2-hexoxyethyl nitrite Chemical compound N(=O)OCCOCCCCCC QUKKRMYHOCZLKY-UHFFFAOYSA-N 0.000 description 1
GXBAFHQYDLBBBY-UHFFFAOYSA-N 2-methoxyethyl nitrite Chemical compound COCCON=O GXBAFHQYDLBBBY-UHFFFAOYSA-N 0.000 description 1
FGDJHGPPHOORRZ-UHFFFAOYSA-N 2-nitrobutyl nitrite Chemical compound N(=O)OCC(CC)[N+](=O)[O-] FGDJHGPPHOORRZ-UHFFFAOYSA-N 0.000 description 1
XKRWIYCCFQAARH-UHFFFAOYSA-N 2-nitrodecyl nitrite Chemical compound N(=O)OCC(CCCCCCCC)[N+](=O)[O-] XKRWIYCCFQAARH-UHFFFAOYSA-N 0.000 description 1
PPJWCZHWEBPXMJ-UHFFFAOYSA-N 2-nitroethyl nitrite Chemical compound [O-][N+](=O)CCON=O PPJWCZHWEBPXMJ-UHFFFAOYSA-N 0.000 description 1
KBCUFRSPKYOJKR-UHFFFAOYSA-N 2-nitroheptyl nitrite Chemical compound N(=O)OCC(CCCCC)[N+](=O)[O-] KBCUFRSPKYOJKR-UHFFFAOYSA-N 0.000 description 1
OETFRUUVXMHIBH-UHFFFAOYSA-N 2-nitrohexyl nitrite Chemical compound N(=O)OCC(CCCC)[N+](=O)[O-] OETFRUUVXMHIBH-UHFFFAOYSA-N 0.000 description 1
GWTFGGXSCWKROO-UHFFFAOYSA-N 2-nitropentyl nitrite Chemical compound N(=O)OCC(CCC)[N+](=O)[O-] GWTFGGXSCWKROO-UHFFFAOYSA-N 0.000 description 1
QXRBETGODACJDG-UHFFFAOYSA-N 2-nitropropyl nitrite Chemical compound N(=O)OCC(C)[N+](=O)[O-] QXRBETGODACJDG-UHFFFAOYSA-N 0.000 description 1
OUGLSNTXELKDIJ-UHFFFAOYSA-N 2-octoxyethyl nitrite Chemical compound N(=O)OCCOCCCCCCCC OUGLSNTXELKDIJ-UHFFFAOYSA-N 0.000 description 1
PNXYLNUETUJKLH-UHFFFAOYSA-N 2-pentoxyethyl nitrite Chemical compound N(=O)OCCOCCCCC PNXYLNUETUJKLH-UHFFFAOYSA-N 0.000 description 1
CPCYUIQFFBWFKF-UHFFFAOYSA-N 2-propoxyethyl nitrite Chemical compound CCCOCCON=O CPCYUIQFFBWFKF-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
JQJPBYFTQAANLE-UHFFFAOYSA-N Butyl nitrite Chemical compound CCCCON=O JQJPBYFTQAANLE-UHFFFAOYSA-N 0.000 description 1
SLZLQDYHCYJSJZ-UHFFFAOYSA-N ClCC([SiH](Cl)Cl)CCl Chemical compound ClCC([SiH](Cl)Cl)CCl SLZLQDYHCYJSJZ-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
PHSPJQZRQAJPPF-UHFFFAOYSA-N N-alpha-Methylhistamine Chemical compound CNCCC1=CN=CN1 PHSPJQZRQAJPPF-UHFFFAOYSA-N 0.000 description 1
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
239000004141 Sodium laurylsulphate Substances 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
229910021623 Tin(IV) bromide Inorganic materials 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
NYRAVIYBIHCEGB-UHFFFAOYSA-N [K].[Ca] Chemical compound [K].[Ca] NYRAVIYBIHCEGB-UHFFFAOYSA-N 0.000 description 1
MSJIBCNUPFPONA-UHFFFAOYSA-N [K].[Sr] Chemical compound [K].[Sr] MSJIBCNUPFPONA-UHFFFAOYSA-N 0.000 description 1
VEUACKUBDLVUAC-UHFFFAOYSA-N [Na].[Ca] Chemical compound [Na].[Ca] VEUACKUBDLVUAC-UHFFFAOYSA-N 0.000 description 1
MHXMXAVFXINHAZ-UHFFFAOYSA-N [Sb].[NH4+].[Cl-] Chemical compound [Sb].[NH4+].[Cl-] MHXMXAVFXINHAZ-UHFFFAOYSA-N 0.000 description 1
KWVFUTDPKIKVQW-UHFFFAOYSA-N [Sr].[Na] Chemical compound [Sr].[Na] KWVFUTDPKIKVQW-UHFFFAOYSA-N 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
125000004183 alkoxy alkyl group Chemical group 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Chemical compound Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 description 1
CECABOMBVQNBEC-UHFFFAOYSA-K aluminium iodide Chemical compound I[Al](I)I CECABOMBVQNBEC-UHFFFAOYSA-K 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
229960003116 amyl nitrite Drugs 0.000 description 1
VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000001746 atrial effect Effects 0.000 description 1
IYYGLLJDALWAMD-UHFFFAOYSA-N benzyl nitrite Chemical compound O=NOCC1=CC=CC=C1 IYYGLLJDALWAMD-UHFFFAOYSA-N 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 description 1
TXKAQZRUJUNDHI-UHFFFAOYSA-K bismuth tribromide Chemical compound Br[Bi](Br)Br TXKAQZRUJUNDHI-UHFFFAOYSA-K 0.000 description 1
125000001246 bromo group Chemical group Br* 0.000 description 1
FQEKAFQSVPLXON-UHFFFAOYSA-N butyl(trichloro)silane Chemical compound CCCC[Si](Cl)(Cl)Cl FQEKAFQSVPLXON-UHFFFAOYSA-N 0.000 description 1
ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 1
VAWSWDPVUFTPQO-UHFFFAOYSA-N calcium strontium Chemical compound [Ca].[Sr] VAWSWDPVUFTPQO-UHFFFAOYSA-N 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
SXUKVAAVKCDPPR-UHFFFAOYSA-N decyl nitrite Chemical compound CCCCCCCCCCON=O SXUKVAAVKCDPPR-UHFFFAOYSA-N 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
239000002360 explosive Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
238000000227 grinding Methods 0.000 description 1
125000001188 haloalkyl group Chemical group 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical group 0.000 description 1
IAHLQSRLEFUEMK-UHFFFAOYSA-N heptyl nitrite Chemical compound CCCCCCCON=O IAHLQSRLEFUEMK-UHFFFAOYSA-N 0.000 description 1
SGRWGISGVDVSJV-UHFFFAOYSA-N hexyl nitrite Chemical compound CCCCCCON=O SGRWGISGVDVSJV-UHFFFAOYSA-N 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
APNSGVMLAYLYCT-UHFFFAOYSA-N isobutyl nitrite Chemical compound CC(C)CON=O APNSGVMLAYLYCT-UHFFFAOYSA-N 0.000 description 1
SKRDXYBATCVEMS-UHFFFAOYSA-N isopropyl nitrite Chemical compound CC(C)ON=O SKRDXYBATCVEMS-UHFFFAOYSA-N 0.000 description 1
239000004922 lacquer Substances 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
SWHAQEYMVUEVNF-UHFFFAOYSA-N magnesium potassium Chemical compound [Mg].[K] SWHAQEYMVUEVNF-UHFFFAOYSA-N 0.000 description 1
239000000289 melt material Substances 0.000 description 1
238000002074 melt spinning Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
BLLFVUPNHCTMSV-UHFFFAOYSA-N methyl nitrite Chemical compound CON=O BLLFVUPNHCTMSV-UHFFFAOYSA-N 0.000 description 1
239000005055 methyl trichlorosilane Substances 0.000 description 1
JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 1
238000005065 mining Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
150000002826 nitrites Chemical class 0.000 description 1
125000004971 nitroalkyl group Chemical group 0.000 description 1
RGLUKHFGBSKWIL-UHFFFAOYSA-N nonyl nitrite Chemical compound CCCCCCCCCON=O RGLUKHFGBSKWIL-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
239000005054 phenyltrichlorosilane Substances 0.000 description 1
UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
OBCUTHMOOONNBS-UHFFFAOYSA-N phosphorus pentafluoride Chemical compound FP(F)(F)(F)F OBCUTHMOOONNBS-UHFFFAOYSA-N 0.000 description 1
FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
WKFBZNUBXWCCHG-UHFFFAOYSA-N phosphorus trifluoride Chemical compound FP(F)F WKFBZNUBXWCCHG-UHFFFAOYSA-N 0.000 description 1
PZHNNJXWQYFUTD-UHFFFAOYSA-N phosphorus triiodide Chemical compound IP(I)I PZHNNJXWQYFUTD-UHFFFAOYSA-N 0.000 description 1
239000000049 pigment Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
GDNULDIPPDQVRH-UHFFFAOYSA-N potassium;pyrrolidin-2-one Chemical compound [K].O=C1CCCN1 GDNULDIPPDQVRH-UHFFFAOYSA-N 0.000 description 1
239000000843 powder Substances 0.000 description 1
KAOQVXHBVNKNHA-UHFFFAOYSA-N propyl nitrite Chemical compound CCCON=O KAOQVXHBVNKNHA-UHFFFAOYSA-N 0.000 description 1
239000005053 propyltrichlorosilane Substances 0.000 description 1
239000004576 sand Substances 0.000 description 1
FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical group [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000012209 synthetic fiber Substances 0.000 description 1
PJYXVICYYHGLSW-UHFFFAOYSA-J tetrachloroplumbane Chemical compound Cl[Pb](Cl)(Cl)Cl PJYXVICYYHGLSW-UHFFFAOYSA-J 0.000 description 1
239000004753 textile Substances 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
LTSUHJWLSNQKIP-UHFFFAOYSA-J tin(iv) bromide Chemical compound Br[Sn](Br)(Br)Br LTSUHJWLSNQKIP-UHFFFAOYSA-J 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
238000011282 treatment Methods 0.000 description 1
GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
ZOYFEXPFPVDYIS-UHFFFAOYSA-N trichloro(ethyl)silane Chemical compound CC[Si](Cl)(Cl)Cl ZOYFEXPFPVDYIS-UHFFFAOYSA-N 0.000 description 1
ORVMIVQULIKXCP-UHFFFAOYSA-N trichloro(phenyl)silane Chemical compound Cl[Si](Cl)(Cl)C1=CC=CC=C1 ORVMIVQULIKXCP-UHFFFAOYSA-N 0.000 description 1
DOEHJNBEOVLHGL-UHFFFAOYSA-N trichloro(propyl)silane Chemical compound CCC[Si](Cl)(Cl)Cl DOEHJNBEOVLHGL-UHFFFAOYSA-N 0.000 description 1
239000005051 trimethylchlorosilane Substances 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1
239000005050 vinyl trichlorosilane Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
238000003466 welding Methods 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1