RU99103684A - Washing and conditioning composition based on silicone and dialkyl ether and method for washing and conditioning keratin materials - Google Patents

Washing and conditioning composition based on silicone and dialkyl ether and method for washing and conditioning keratin materials

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RU99103684A
RU99103684A RU99103684/14A RU99103684A RU99103684A RU 99103684 A RU99103684 A RU 99103684A RU 99103684/14 A RU99103684/14 A RU 99103684/14A RU 99103684 A RU99103684 A RU 99103684A RU 99103684 A RU99103684 A RU 99103684A
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composition according
composition
mixtures
groups
silicones
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RU99103684/14A
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Анри СЕБАГ
Сандрин ДЕКОСТЕ
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Л'Ореаль
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1. Вспенивающая моющая и кондиционирующая композиция для кератиновых материалов, в частности, волос и кожи, отличающаяся тем, что она содержит в косметически приемлемой водной среде по меньшей мере один силикон, по меньшей мере одно поверхностно-активное вещество, обладающее моющими свойствами, и, по меньшей мере, один диалкиловый эфир, находящийся в твердом состоянии при температурам ниже или равной до 30°С и имеющий общую формулу (I)1. Foaming detergent and conditioning composition for keratin materials, in particular, hair and skin, characterized in that it contains in a cosmetically acceptable aqueous medium at least one silicone, at least one surfactant having detergent properties, and, at least one dialkyl ether in solid form at temperatures below or equal to 30 ° C and having the general formula (I) R-О-R’,R-O-R ’, где R и R’, одинаковые или различные, означают насыщенный или ненасыщенный, линейный или разветвленный алкильный радикал, содержащий от 12 до 30 атомов углерода, причем названная композиция обладает вспенивающей способностью, превышающей 50 мл, а количество находящихся в композиции поверхностно-активных веществ составляет от 5 до 50% от общей массы композиции.where R and R ', the same or different, mean a saturated or unsaturated, linear or branched alkyl radical containing from 12 to 30 carbon atoms, moreover, said composition has a foaming ability in excess of 50 ml, and the amount of surfactants present in the composition is from 5 to 50% of the total weight of the composition. 2. Композиция по п.1, отличающаяся тем, что R и R’ являются одинаковыми.2. The composition according to claim 1, characterized in that R and R ’are the same. 3. Композиция по п.2, отличающаяся тем, что R и R’ означают стеариловый радикал.3. The composition according to claim 2, characterized in that R and R ’mean stearyl radical. 4. Композиция по любому из пп.1-3, отличающаяся тем, что используемые силиконы выбраны из нерастворимых в композиции полиорганосилоксанов и находятся в виде масел, восков, смол и камедей.4. The composition according to any one of claims 1 to 3, characterized in that the silicones used are selected from polyorganosiloxanes insoluble in the composition and are in the form of oils, waxes, resins and gums. 5. Композиция по любому из пп.1-4, отличающаяся тем, что полиорганосилоксанами являются нелетучие полиорганосилоксаны, выбранные из числа полиалкилсилоксанов, полиарилсилоксанов, полиалкиларилсилоксанов, силиконовых камедей и смол, полиорганосилоксанов, модифицированных органическими функциональными группами, а также их смесей.5. The composition according to any one of claims 1 to 4, characterized in that the polyorganosiloxanes are non-volatile polyorganosiloxanes selected from polyalkylsiloxanes, polyarylsiloxanes, polyalkylarylsiloxanes, silicone gums and resins, organopolysiloxanes modified with organic functional groups, as well as mixtures thereof. 6. Композиция по любому из пп.1-5, отличающаяся тем, что:6. The composition according to any one of claims 1 to 5, characterized in that: (а) полиалкилсилоксаны выбраны из полидиметилсилоксанов с концевыми триметилсилильными группами; полидиметилсилоксанов с концевыми диметилсиланольными группами; полиалкил-С1-С20-силоксанов;(a) polyalkylsiloxanes selected from trimethylsilyl terminated polydimethylsiloxanes; dimethylsilanol terminated polydimethylsiloxanes; polyalkyl-C 1 -C 20 siloxanes; (б) полиалкиларилсилоксаны выбраны из полидиметилметилфенилсилоксанов, полидиметилдифенилсилоксанов, линейных или разветвленных, с вязкостью от 1·10-5 до 5·10-2 м2/о (25°С);(b) polyalkylarylsiloxanes selected from polydimethylmethylphenylsiloxanes, polydimethyldiphenylsiloxanes, linear or branched, with a viscosity of from 1 · 10 -5 to 5 · 10 -2 m 2 / about (25 ° C); (в) силиконовые камеди выбраны из полидиорганосилоксанов, обладающих молекулярной массой в пределах от 200 000 до 1 000 000, используемых либо индивидуально, либо в смеси с растворителем;(c) silicone gums are selected from polydiorganosiloxanes having a molecular weight ranging from 200,000 to 1,000,000, used either individually or in admixture with a solvent; (г) смолы выбраны из числа смол, состоящих из следующих звеньев:(g) resins selected from among the resins consisting of the following units: R3SiO1/2, R2SiO2/2, RSiO3/2 и SiO4/2, в которых R представляет собой углеводородную группу с 1-16 атомами углерода или фенильную группу;R 3 SiO 1/2 , R 2 SiO 2/2 , RSiO 3/2 and SiO 4/2 , in which R represents a hydrocarbon group with 1-16 carbon atoms or a phenyl group; (д) модифицированные органические силиконы выбраны из силиконов, содержащих в своей структуре одну или несколько органических функциональных групп, связанных посредством углеводородного радикала.(e) modified organic silicones are selected from silicones containing in their structure one or more organic functional groups linked by a hydrocarbon radical. 7. Композиция по п.6, отличающаяся тему что применяемые индивидуально или в виде смеси силиконовые камеди выбраны из следующих соединений и смесей полидиметилсилоксан, полидиметилсилоксан/метилвинилсилолсаны, полидиметилсилоксан/дифенилсилоксан, полидиметилсилоксан/фенилметилсилоксан, полидиметилсилоксан/дифенилсилоксан/метилвинилсилоксаны, а также следующих смесей: смеси полидиметилсилоксана, гидроксилированного по концу цепи, с циклическим полидиметилсилоксаном; смеси полидиметилсилоксановой камеди с циклическим силиконом; смеси полидиметилсилоксанов с различной вязкостью.7. The composition according to claim 6, characterized in that the silicone gums used individually or as a mixture are selected from the following compounds and mixtures polydimethylsiloxane, polydimethylsiloxane / methylvinylsiloxane, polydimethylsiloxane / diphenylsiloxane, polydimethylsiloxane / phenylmethylsiloxane / dimethylsiloxane / dimethylsiloxane / dimethyl mixtures of chain-terminated hydroxylated polydimethylsiloxane with cyclic polydimethylsiloxane; mixtures of polydimethylsiloxane gum with cyclic silicone; mixtures of polydimethylsiloxanes with various viscosities. 8. Композиция по п.6, отличающаяся тем, что модифицированные органические силиконы выбраны из полиорганосилоксанов, содержащих:8. The composition according to claim 6, characterized in that the modified organic silicones are selected from polyorganosiloxanes containing: а) полиэтиленокси- и/или полипропиленокси-группы;a) polyethyleneoxy and / or polypropyleneoxy groups; б) замещенные или незамещенные аминогруппы;b) substituted or unsubstituted amino groups; в) тиоловые группы;c) thiol groups; г) алкокси-группы;d) alkoxy groups; д) гидроксиалкильные группы формулыd) hydroxyalkyl groups of the formula
Figure 00000001
Figure 00000001
 где R3, одинаковые или различные, означают метил или фенил, причем по меньшей мере 60 мол.% радикалов R3 составляет метил; R’3 - двухвалентная С2-С18-алкиленовая цепь; р=1-30; и q=l-150;wherein R 3 , identical or different, is methyl or phenyl, wherein at least 60 mol% of R 3 radicals is methyl; R ' 3 is a divalent C 2 -C 18 alkylene chain; p = 1-30; and q = l-150; е) ацилоксиалкильные группы формулы:e) acyloxyalkyl groups of the formula:
Figure 00000002
Figure 00000002
 где R4 означает метил, фенил, -OCOR5 или гидроксил, причем по меньшей мере один из радикалов R4 на один атом кремния является гидроксилом;where R 4 means methyl, phenyl, -OCOR 5 or hydroxyl, and at least one of the radicals R 4 on one silicon atom is hydroxyl; R’4 означает метил или фенил, причем по меньшей мере 60 мол.% радикалов R4 и R’4, являются метилами;R ′ 4 is methyl or phenyl, wherein at least 60 mol% of the radicals R 4 and R ′ 4 are methyl; R5 означает алкил или алкенил с 8-20 атомами углерода;R 5 means alkyl or alkenyl with 8-20 carbon atoms; R" означает линейный или разветвленный двухвалентный С2-C18-алкиленовый радикал;R "means a linear or branched divalent C 2 -C 18 alkylene radical; r=1-120;r is 1-120; р=1-30;p = 1-30; q=0 или ниже 0,5 р, причем p+q=l-30, а полиорганосилоксаны формулы (VI) могут содержать группы:q = 0 or below 0.5 p, with p + q = l-30, and the polyorganosiloxanes of formula (VI) may contain groups:
Figure 00000003
Figure 00000003
 в количестве, не превышающем 15% от суммы p+q+r;in an amount not exceeding 15% of the sum p + q + r; ж) алкилкарбоксильные группы,g) alkylcarboxyl groups, з) 2-гидроксиалкилсульфонатные группы,h) 2-hydroxyalkylsulfonate groups, и) 2-гидроксиалкилтиосульфонатные группы,i) 2-hydroxyalkylthiosulfonate groups, к) гидроксиациламиногруппы.j) hydroxyacylamino groups. 9. Композиция по любому из пп.1-8, отличающаяся тем, что полиорганосилоксаны выбраны из полиалкилсилоксанов с концевыми триметилсилильными группами, полиалкилсилоксанов с концевыми диметилсиланольными группами, полиалкиларилсилоксанов, смесей двух полидиметилсилоксанов, состоящих из камеди и масла, имеющих различную вязкость, смесей органосилоксанов с циклическими силиконами и полиорганосилоксановых смол.9. A composition according to any one of claims 1 to 8, characterized in that the polyorganosiloxanes are selected from trimethylsilyl terminated polyalkylsiloxanes, dimethylsilanol terminated polyalkylsiloxanes, polyalkyl aryl siloxanes, mixtures of two polydimethylsiloxanes consisting of gum and oil having different viscosities, mixtures of various organosiloxanes with mixtures cyclic silicones and polyorganosiloxane resins. 10. Композиция по любому из пп.1-4, отличающаяся тем, что силиконами являются летучие силиконы.10. The composition according to any one of claims 1 to 4, characterized in that the silicones are volatile silicones. 11. Композиция по п.10, отличающаяся тем, что летучие силиконы выбраны из:11. The composition of claim 10, wherein the volatile silicones are selected from: - циклических силиконов, содержащих 3-7 атомов кремния;- cyclic silicones containing 3-7 silicon atoms; - циклополимеров типа диметилсилоксаны/метилалкилсилоксан, имеющих структуру:- cyclopolymers of the type dimethylsiloxanes / methylalkylsiloxane having the structure:
Figure 00000004
Figure 00000004
 где D означает группу: -Sl(СН3)2-O- и D’ группу -Si(СН3) (C8H17)-O-;where D means a group: —Sl (CH 3 ) 2 —O— and a D ′ group —Si (CH 3 ) (C 8 H 17 ) —O—; смесей циклических силиконов с кремнийорганическими соединениями;mixtures of cyclic silicones with organosilicon compounds; летучих линейных силиконов с 2-9 атомами кремния, обладающих вязкостью ниже или равной 5·10-6 м2/о (25°С).volatile linear silicones with 2-9 silicon atoms having a viscosity lower than or equal to 5 · 10 -6 m 2 / o (25 ° C). 12. Композиция по любому из пп.1-11, отличающаяся тем, что моющие поверхностно-активные вещества выбраны из анионных, амфотерных, цвиттерионных и не ионных поверхностно-активных агентов, или их смесей.12. The composition according to any one of claims 1 to 11, characterized in that the detergent surfactants are selected from anionic, amphoteric, zwitterionic and non-ionic surfactants, or mixtures thereof. 13. Композиция по любому из пп.1-12, отличающаяся тем, что используемые смеси ПАВ выбраны из смесей анионных ПАВ и амфотерных, цвиттерионных и не ионных поверхностно-активных веществ.13. The composition according to any one of claims 1 to 12, characterized in that the surfactant mixtures used are selected from mixtures of anionic surfactants and amphoteric, zwitterionic and non-ionic surfactants. 14. Композиция по любому из пп.1-13, отличающаяся тем, что силикон или силиконы находятся в количествах от 0,05 до 20%, предпочтительно от 0,1 до 10% от общей массы композиции.14. The composition according to any one of claims 1 to 13, characterized in that the silicone or silicones are in amounts from 0.05 to 20%, preferably from 0.1 to 10%, of the total weight of the composition. 15. Композиция по любому из пп.1-14, отличающаяся тем, что диалкиловые эфиры формулы (I) находятся в количестве от 0,1 до 10%, предпочтительно от 0,5 до 5% от общей массы композиции.15. The composition according to any one of claims 1 to 14, characterized in that the dialkyl ethers of the formula (I) are in an amount of from 0.1 to 10%, preferably from 0.5 to 5%, of the total weight of the composition. 16. Композиция по любому из пп.1-15, отличающаяся тем, что поверхностно-активные вещества находятся в количестве от 5 до 50%, предпочтительно от 8 до 35% от общей массы композиции.16. The composition according to any one of claims 1 to 15, characterized in that the surfactants are in an amount of from 5 to 50%, preferably from 8 to 35%, of the total weight of the composition. 17. Композиция по любому из пп.1-16, отличающаяся тем, что рН композиции составляет от 3 до 9, предпочтительно от 3 до 8.17. The composition according to any one of claims 1 to 16, characterized in that the pH of the composition is from 3 to 9, preferably from 3 to 8. 18. Композиция по любому из пп.1-17, отличающаяся тем, что водная среда представляет собой воду или смесь воды с косметически приемлемым растворителем, выбранным из классов низших спиртов С1-С4, алкиленгиколей и простых гликолевых эфиров.18. A composition according to any one of claims 1 to 17, characterized in that the aqueous medium is water or a mixture of water with a cosmetically acceptable solvent selected from the classes of C 1 -C 4 lower alcohols, alkylene glycols and glycol ethers. 19. Композиция по любому из пп.1-18, отличающаяся тем, что она дополнительно содержит регулирующие вязкость агенты, выбранные электролиты, или загущающие агенты в количествах до 10% от общей массы композиции.19. The composition according to any one of claims 1 to 18, characterized in that it further comprises viscosity regulating agents, selected electrolytes, or thickening agents in amounts up to 10% of the total weight of the composition. 20. Композиция по любому из пп.1-19, отличающаяся тем, что она дополнительно содержат до 3% агентов, придающих композиции перламутровый блеск и/или корректоров тона.20. The composition according to any one of claims 1 to 19, characterized in that it additionally contains up to 3% of agents that impart a pearlescent shine and / or tone correctors to the composition. 21. Композиция по любому из пп.1-20, отличающаяся тем, что она дополнительно содержит один или несколько адьювантов предназначенных для улучшения косметических свойств композиции и выбранных из катионных ПАВ, анионных, не ионных, катионных или амфотерных полимеров или протеинов, которые могут содержать четвертичные аммониевые группы.21. The composition according to any one of claims 1 to 20, characterized in that it further comprises one or more adjuvants intended to improve the cosmetic properties of the composition and selected from cationic surfactants, anionic, non-ionic, cationic or amphoteric polymers or proteins that may contain Quaternary ammonium groups. 22. Композиция по п.21, отличающаяся тем, что катионные полимеры выбраны из числа полимеров, содержащих первичные, вторичные, третичные и/или четвертичные аминогруппы, составляющие часть полимерной цепи или непосредственно с ней связанные, и имеющих молекулярную массу от 500 до 5 000 000.22. The composition according to item 21, wherein the cationic polymers are selected from polymers containing primary, secondary, tertiary and / or Quaternary amino groups that are part of the polymer chain or directly associated with it, and having a molecular weight of from 500 to 5,000 000 23. Композиция по п.22, отличающаяся тем, что катионные полимеры выбраны из четвертичных производных эфиров целлюлозы, циклополимеров, катионных полисахаридов и их смесей.23. The composition according to p. 22, characterized in that the cationic polymers are selected from quaternary derivatives of cellulose ethers, cyclopolymers, cationic polysaccharides and mixtures thereof. 24. Композиция по п.23, отличающаяся тем, что циклополимер выбран из гомополимеров хлорида диалилдиметиламмония и сополимеров хлорида диаллилдиметиламмония с акриламидом.24. The composition according to p. 23, characterized in that the cyclopolymer is selected from homopolymers of diallyldimethylammonium chloride and copolymers of diallyldimethylammonium chloride with acrylamide. 25. Композиция по п.23, отличающаяся тем, что четвертичные производные эфиров целлюлозы представляют собой гидроксиэтил целлюлозы, прореагировавшие с эпоксидом, замещенным триметиламмониевой группой.25. The composition according to item 23, wherein the quaternary derivatives of cellulose ethers are hydroxyethyl cellulose, reacted with an epoxide substituted by a trimethylammonium group. 26. Композиция по п.23, отличающаяся тем, что катионные полисахариды выбраны из гуаровых смол, модифицированных солью 2,3-эпоксипропилтриметиламмония.26. The composition according to item 23, wherein the cationic polysaccharides are selected from guar gums modified with 2,3-epoxypropyltrimethylammonium salt. 27. Композиция по любому из пп.1-26, отличающаяся тем, что амфотерный полимер представляет собой сополимер диалкилдиаллиламмония и акриловой или метакриловой кислоты и/или хитозан, частично модифицированный двухосновной карбоновой кислотой.27. The composition according to any one of claims 1 to 26, characterized in that the amphoteric polymer is a copolymer of dialkyl diallylammonium and acrylic or methacrylic acid and / or chitosan, partially modified with dibasic carboxylic acid. 28. Композиция по любому из пп.1-27, отличающаяся тем, что она содержит различные косметически приемлемые добавки, выбранные из духов, консервантов, комплексообразующих агентов, пенных синергистов, стабилизаторов пены, подкисляющих или подщелачивающих агентов.28. The composition according to any one of claims 1 to 27, characterized in that it contains various cosmetically acceptable additives selected from perfumes, preservatives, complexing agents, foam synergists, foam stabilizers, acidifying or alkalizing agents. 29. Композиция, определенная в любом из пп.1-28, используемая в качестве шампуня.29. The composition as defined in any one of claims 1 to 28, used as a shampoo. 30. Композиция, определенная в любом из пп.1-28, используемая в качестве геля для душа.30. The composition as defined in any one of claims 1 to 28, used as a shower gel. 31. Способ мытья и кондиционирования кератиновых материалов, отличающийся тем, что на эти материалы наносят по меньшей мере одну композицию, описанную в любом из пп.1-28, и после возможной выдержки в течение некоторого времени обработанные материалы ополаскивают водой.31. A method of washing and conditioning keratin materials, characterized in that at least one composition described in any one of claims 1 to 28 is applied to these materials, and after possible exposure for some time, the treated materials are rinsed with water. 32. Применение жирного диалкилового эфира, определенного в одном из пп.1-3, в качестве агента, суспендируюшего силикон во вспенивающей моющей и кондиционирующей композиции, содержащей в косметически приемлемой среде поверхностно-активные вещества.32. The use of fatty dialkyl ether, as defined in one of claims 1 to 3, as an agent, suspending silicone in a foaming detergent and conditioning composition containing surfactants in a cosmetically acceptable medium.
RU99103684/14A 1996-07-23 1997-07-21 Washing and conditioning composition on base of silicone and dialkyl ether and method of washing and conditioning of keratin materials RU2161952C2 (en)

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FR9609252A FR2751532B1 (en) 1996-07-23 1996-07-23 WASHING AND CONDITIONING COMPOSITIONS BASED ON SILICONE AND DIALKYLETHER
FR9609252 1996-07-23

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