JP3442814B2 - Detergent composition - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION [0001] FIELD OF THE INVENTION The present invention relates to a cleaning composition, and more particularly to a cleaning composition.
Include amorphous silicon dioxide or its methyl hydrogen
Water-insoluble polymer powder and water-insoluble
Is dispersed in aqueous surfactant solution
Having a solid / oil / water phase emulsion structure
Excellent stability when used with no stickiness
Excellent conditioning effects such as good comb-through
Cleaning composition. [0002] 2. Description of the Related Art In recent years, shampoos and other cleaning agents have been used.
The composition has various effects, not just detergency
Is becoming more common. Conditioning especially on the hair
The demand for shampoos that add a
Many types have been developed. In order to provide a conditioning effect
Add silicone to hair cosmetics to increase lubricity and water repellency
In addition, studies have been made to improve the usability,
There are a number of studies and reports (US Pat. No. 2,826,551,
No. 3964500). However, this technique is applied to cleaning agents.
Therefore, emulsify silicone in an aqueous solution using a surfactant.
Even if they are dispersed as separate solutions.
Lack of stability, especially for conditioning effects
Separation becomes remarkable when mixed in large amounts.
U. [0005] In addition, high viscosity silicone is separated into surfactants.
Hair cosmetics with a conditioning effect
Are disclosed (JP-A-61-210022,
JP-A 64-13012, JP-A 64-1301
No. 3 publication), but such hair cosmetics are applied to hair by continuous use.
High viscosity silicone accumulates, giving a sticky feeling and heavy oily feeling
Lack of hair
There was a point. On the other hand, silicone resin and silicone
To form a film with good setting properties on the hair surface
Hair cosmetics such as troches, hair sprays, and hair styling products
JP-A-61-162214,
JP-A-63-313713, JP-A-1-165509
Gazette). However, these are essentially hair setting agents
The need to form a silicone resin coating on the hair
As a result, the silicone resin is
Used by understanding. Therefore, they are not included in these hair cosmetics.
Wash the solvent-soluble silicone resin with shampoo etc.
When formulated in a cleaning agent, it gives a sticky feeling and stability over time
Most of them hurt. [0007] Hydrophobic powders such as silicone resin particles
Of a cross-linked polyacrylic acid
Makeup made by dispersing in aqueous phase using phenolic polymer compound
The materials are described in JP-A-2-19310. I
This cosmetic is related to foundations, etc.
Yes, good for systems with high viscosity, but for shampoos etc.
Cannot be applied to low viscosity systems where surfactants are indispensable, and
It did not improve the feel to the hair. [0008] Further, flexibility and smoothness using silica particles
Imparts anti-static properties, no stickiness, and hair styling
Japanese Patent Application Laid-Open No. Sho 57-1 / 1990
No. 40708, and fine particles such as silica particles.
Non-sticky, blended with powder
A hair styling agent having excellent setting power is disclosed in JP-A-4-124.
No. 121 is described. However, these
Hair cosmetics using silica particles are rinse or spray
-Formulated as a hair styling product, with high viscosity or shaking.
By maintaining the uniformity of the silica particles
When applied to cleaning agents such as shampoos that are low-viscosity
There were problems such as separation, and it was difficult to formulate the preparation. [0009] SUMMARY OF THE INVENTION Accordingly, an object of the present invention is as follows.
Is to disperse the silicone stably in the surfactant,
, No stickiness after drying, feeling of use and condition
Another object of the present invention is to provide a cleaning composition having an excellent cleaning effect. [0010] In such a situation, the present invention
The present inventors have conducted intensive studies and found that amorphous silicon dioxide
Element or its methyl hydrogen silicone treated product
Water-insoluble polymer powder in water-insoluble nonvolatile silicone
And further disperse it in an aqueous surfactant solution.
Cleaning composition is stable and free from stickiness.
The present invention was found to be excellent in
completed. That is, the present invention provides an amorphous silicon dioxide or
Is water, its methyl hydrogen silicone treated product
Mixing of insoluble polymer powder with water-insoluble nonvolatile silicone
Detergent composition in which the compound is dispersed in an aqueous surfactant solution
Is provided. The amorphous silicon dioxide used in the present invention
Is water, its methyl hydrogen silicone treated product
The insoluble polymer powder has an initial particle size even when formulated into a detergent.
And keep the form, most of them including water
Solvents such as water, methanol, ethanol, isopro
Panol, n-butanol, isobutanol, propyle
Glycol, acetone, methyl ethyl ketone, ethyl
Cellosolve, butyl cellosolve, cellosolve acetate
G, ethyl acetate, butyl acetate, tetrahydrofuran, di
Acetone alcohol, n-hexane, kerosene, benzene,
Toluene, xylene, chloroform, perchlorethylene
Insoluble in most organic solvents such as
It is. The water-insoluble polymer powder used in the present invention comprises:
"Science of Sol-Gel Method", pp. 59-60, Saio Sakuhana,
Agune Shofusha Co., Ltd., 1989.
The following equation (1) [0014] Embedded image A siloxane bond represented by the following formula:
Amorphous silicon dioxide with an intrinsically crosslinked network structure
is there. This is a structure in which the molecular surface is covered with silanol groups.
, Hydrophilic and chemically stable, white
It is an odorless powder. Further, such an amorphous silicon dioxide surface
The silanol group of methyl hydrogen silicone etc.
Use hydrophobic silica particles treated in the usual way
Can be. Such amorphous silicon dioxide or methyl thereof
Hydrogen silicone treated product (hereinafter "silica powder")
), The smaller the average particle size, the more stable the aging becomes.
In order to improve the average particle size is in the range of 0.01 to 500 μm
Are preferred, and in consideration of the improvement of the feel when drying,
In particular, those having an average particle size in the range of 0.1 to 10 μm are preferred.
No. The shape of the particles is not particularly limited.
For improvement, a spherical shape is preferable. Commercially available silica powder satisfying the above conditions
For example, Sildex manufactured by Asahi Glass Co., Ltd., Shinnichi
Esquartz manufactured by Tekko Chemical Co., Ltd., manufactured by Admax Co., Ltd.
Admafine and the like. [0019] [0020] [0021] [0022] [0023] [0024] Water-insoluble polymer powder of the present detergent composition
To 0.01 to 10% by weight (hereinafter simply referred to as “%”).
), And particularly preferably 0.05 to 2%.
If the blending amount of this powder is less than 0.01%, sufficient powder
Dispersion stabilizing effect and conditioning effect are not obtained,
If it exceeds 10%, the powder precipitates, which is not preferable. In addition, the water-insoluble nonvolatile system used in the present invention
As a cone, a liquid or paste at room temperature and pressure is used.
Water-insoluble and non-volatile silicone, for example,
63-313713 and the like.
Tyl polysiloxane, methylphenyl polysiloxane,
Polyether-modified silicone, amino-modified silicone,
Fatty acid-modified silicone, fluorine-modified silicone, cyclic silicone
Silicone, alkyl-modified silicone, alcohol-modified silicone
Silicone, aliphatic alcohol-modified silicone, etc.
However, more specifically, the following (1) to (11)
One. (1) Dimethyl polysiloxane (CH_Three)_ThreeSiO [(CH_Three)_TwoSiO]_aSi (CH_Three)_Three          (1) [Where a represents a number from 0 to 20,000] (2) Methylphenylpolysiloxane [0029] Embedded image Where b, c and d are b + c + d = 10
Shows the number from 10,000 to 10,000. However, when c = 0, d ≠ 0
And c ≠ 0 when d = 0. ] (3) Amino-modified silicone Has at least one aminoalkyl group in one molecule
Amino-modified silicone which is a polymer of organosiloxane
Polymer. Forming this amino-modified silicone polymer
Organosiloxane contains some other than aminoalkyl groups.
Those containing a methyl group as an active group are generally used,
Other alkyl groups such as ethyl group and propyl group; vinyl
Alkenyl groups such as phenyl and allyl; phenyl, naph
Aryl groups such as tyl group; cyclo groups such as cyclohexyl group
A loalkyl group; a hydroxy group, a hydroxyalkyl group,
Oxyalkylene group or polyoxyalkylene group
Can be included. Included in amino-modified silicone polymer
Representative examples of the aminoalkyl group represented by the following general formula (3)
Or (4). [0032] Embedded imageR¹As the divalent hydrocarbon group of
Group, ethylene group, propylene group, butylene group, -CH_TwoC
H (CH_Three) CH_TwoAn alkylene group such as-,-(CH_Two)_Two−C₆H_Four−
Such as an alkylene arylene group.
Of these, alkylene groups, particularly propylene groups, are preferred.
No. R^ThreeAnd R^FourAs a monovalent hydrocarbon group of the methyl group,
Ethyl, propyl, hexyl and phenyl groups
Can be Also R^ThreeAnd R^FourAre both hydrogen atoms or monovalent charcoal
May be a hydride group;^ThreeIs a hydrogen atom and R^FourBut
It may be a monovalent hydrocarbon group. Furthermore, the preference for d and e
New values are e = 0 and f = 1. Hydroxyalkyl group
Is represented by the following general formula (5). −R¹OH (5) [Wherein, R¹Has the same meaning as above) Representative of oxyalkylene group and polyoxyalkylene group
A typical example is shown by the following general formula (6). − (R¹)_g−O− (C_iH_2iO)_h-H (6) [Wherein, R¹Has the same meaning as described above, and g is 0 or 1.
And h is an integer of 1 to 100, i is an integer of 1 to 5
Show) (6) Among the hydroxyalkyl groups represented by the formula,
Preferred is g = 1, h is an integer of 3 to 70, i is 2 or
3 is obtained. Here, when h is 2 or 3,
They may be connected in a lock shape or a random shape. this is
The same applies to other combinations of integers of i. Typical
An amino-modified silicone polymer is represented by the following general formula (7) or
It is represented by (8). [0034] Embedded image [Wherein, R^FiveIs a methyl or hydroxy group
And R⁶Represents a methyl group or a hydrogen atom. R⁷Is
Represents a substituted aminoalkyl group (3) or (4);⁸Is
Hydroxy group, hydroxyalkyl group, oxyalkylene
A polyoxyalkylene group, j, k, l
Represents an integer that depends on the molecular weight.
A preferred amino-modified silicone polymer has the following general formula (9)
Is represented by [0036] Embedded image[Wherein, R⁷Is the aforementioned aminoalkyl group
(3) or (4), wherein m and n are integers depending on the molecular weight.
The amino-modified silicone of the present invention
A typical polymer is represented by the following general formula (10).
Having an average molecular weight of about 3,000 to 100,000
0, which is an amodimethicone (Amodi methicone).
methicone) in the CTFA dictionary (Co, USA)
smetic Ingredient Diction
ary) It is described in the third edition. [0038] Embedded image [Wherein, o and p have a molecular weight of 3,000 to 1]
Indicates an integer that depends on 00,000] (4) Fatty acid-modified silicone [0041] Embedded image Wherein q, r and s are from 1 to 1000
Number, t represents a number from 0 to 10, and R⁹Is C_uH _{2u + 1}(U = 9 ~
21)] (5) Alcohol-modified silicone [0044] Embedded image [Wherein, v and w are each 1 to 1000 (preferably
Preferably 1 to 200), and R ^TenIs C_xH_2x(X =
0-4)] (6) Aliphatic alcohol-modified silicone [0047] Embedded image Wherein y is from 1 to 1000 (preferably 1
-100), z is 1-500 (preferably 1-50),
a 'is a number from 0 to 500 (preferably 0 to 50), b' is
Represents a number from 0 to 5, R¹¹Is C_c′ H_2c′₊₁(C '= 4-2
2)] (7) Low HLB polyether-modified silicone
(HLB <8) [0050] Embedded image [Wherein, R¹²Is (18) or (19) below
Wherein d 'and e' have a molecular weight of 2,000
Show the number from 0 to 100,000] [0052] − (R¹³)_{f '}−O− (C_{g '}H_{2g '})_{h '}-H (18) [Wherein, R¹³Represents a divalent hydrocarbon group, and f ′ is 0 or
1, g 'represents an integer of 1 to 5, and h' represents 1 to 20.
Represents an integer of R¹³Examples of the divalent hydrocarbon group include a methylene group and an ethylene group.
Group, propylene group, butylene group, -CH_TwoCH (CH_Three) CH_Two−
A branched alkylene group such as-(CH_Two)_Two−C ₆H_Four-
Such alkylene arylene groups and the like,
Of these, an alkylene group, particularly a propylene group, is preferred. formula
In the group represented by (18), f ′ = 1, g ′ is 2 or
3 and h ′ is preferably an integer of 5 to 15. This
Here, h '-C_{g '}H_{2g '}O- is those whose g 'is 2 or 3.
May be bonded in a block shape or a random shape. [0053] Embedded image [Wherein, R¹³Has the same meaning as above,
f 'represents 0 or 1, and i' represents an integer of 0 to 10] Among the groups represented by (19), f ′ = 1 and i ′ is 2 to 4
Is preferably an integer. (8) Epoxy-modified silicone [0056] Embedded image [Wherein j 'is 1 to 500 (preferably 1)
~ 250) and k 'is 1 to 50 (preferably 1 to 3).
0), R¹⁴Is an alkylene group having 1 to 3 carbon atoms
Show) (9) Fluorine-modified silicone [0059] Embedded image Wherein l 'is 1 to 400 (preferably 1
~ 250).] (10) Cyclic silicone [0062] Embedded image[Wherein, m ′ represents a number of 3 to 8,^FifteenIs
Represents an alkyl group having 1 to 3 carbon atoms] (11) Alkyl-modified silicone [0065] Embedded image Wherein o 'and p' are each 0 to 500 (preferably
Preferably 1 to 200. However, when o '= p' = 0
I), R¹⁶Is an alkyl group having 2 to 18 carbon atoms,
R¹⁷Is C_{q '}H_{2q '}(Q '= 0-4)] [0067] Embedded image Wherein r 'and s' are each 1 to 1000
(Preferably 1 to 200), and R¹⁸Is 1 carbon
Represents an alkyl group of 0 to 16] These water-insoluble nonvolatile silicones are simply
Can be used alone or in combination of two or more
It is preferable to add 0.01 to 10% during the formation. Also,
These silicones are used by mixing them with various viscosities.
You can also. These silicones can be used alone or mixed
Those with a viscosity of 1000 cs or more are stable with time and feel
Is also most preferable and preferable. In the present invention, water-insoluble polymer powder and water
The compounding ratio of the insoluble nonvolatile silicone depends on the type
Water-insoluble polymer powder: water-insoluble
Volatile silicone = 1: 100-90: 100 (weight
Ratio), especially 1: 100 to 1:20 (weight ratio).
preferable. Further, in the cleaning composition of the present invention, water-insoluble
Water-soluble polymer powder and water-insoluble nonvolatile silicone
It is preferable to add 0.1 to 10.0% in total. As the surfactant used in the present invention, aniline
Any of amphoteric, amphoteric and nonionic may be used,
Specifically, the following are exemplified. Anionic surfactant: (1) Straight chain having an alkyl group having an average of 10 to 16 carbon atoms
Or a branched-chain alkylbenzene sulfonate. (2) Linear or branched alkyl having 10 to 20 average carbon atoms
Having an average of 0.5 to 1 in one molecule.
8 moles of ethylene oxide, propylene oxide,
Butylene oxide, ethylene oxide and propylene
The oxide has a ratio of 0.1 / 9.9 to 9.9 / 0.1.
Or, the content of ethylene oxide and butylene oxide is 0.
Alkyl or alkyl added at a ratio of 1 / 9.9 to 9.9 / 0.1
Is alkenyl ether sulfate. (3) an alkyl group or alkenyl having an average of 10 to 20 carbon atoms
Alkyl or alkenyl sulfate having a phenyl group. (4) O having an average of 10 to 20 carbon atoms in one molecule
Refin sulfonate. (5) A compound having an average of 10 to 20 carbon atoms in one molecule.
Lucane sulfonate. (6) Saturation having an average of 10 to 24 carbon atoms in one molecule
Sum or unsaturated fatty acid salts. (7) an alkyl group or alkenyl having an average of 10 to 20 carbon atoms
Having 0.5 to 8 moles of ethylene per molecule
Oxide, propylene oxide, butylene oxide
, Ethylene oxide and propylene oxide in an amount of 0.
In a ratio of 1 / 9.9 to 9.9 / 0.1 or ethylene oxide
0.1 / 9.9-9 for oxide and butylene oxide.
Alkyl or alkenyl ether added in a ratio of 9 / 0.1
Tercarboxylate. (8) an alkyl group having an average of 10 to 20 carbon atoms or
Is an α-sulfofatty acid salt having an alkenyl group or an ester.
Le. (9) C8-C24 acyl group and free carboxylic acid
An N-acylamino acid type surfactant having a residue. (10) an alkyl or alkenyl group having 8 to 24 carbon atoms
Phosphoric acid mono- or diester-type surfactants having (11) Poly having an alkyl group having an average carbon number of 8 to 16
Oxyethylene alkyl sulfosuccinate monoester
salt. An amphoteric surfactant: (12) C8-C24 alkyl and alkenyl groups also
Α-addition type having an acyl group, secondary amide type,
Or tertiary amide type imidazoline amphoteric surfactants. (13) Alkyl and alkenyl groups having 8 to 24 carbon atoms
Or carbobetaine based on acyl group, amidobeta
In-based, sulfobetaine-based, hydroxysulfobetaine
Or amidosulfobetaine amphoteric surfactants. Nonionic surfactant: (14) Higher having a long-chain acyl group having 10 to 20 carbon atoms
With fatty acid alkanolamide or alkylene oxide
Addictive. (15) The following general formula R¹⁹−O− (R²⁰O)_{t '}− (G)_{u '} [Wherein, R¹⁹Is a linear or branched alkyl having 6 to 18 carbon atoms
A kill group or an alkenyl group;²⁰Has 2 to 4 carbon atoms
G represents an alkylene group, and G represents a reducing sugar having 5 to 6 carbon atoms.
And t 'is a number from 0 to 10, and u' is a number from 1 to 10.]
Alkyl glycoside surfactants mentioned. Of these surfactants, (2) a
Alkyl ether sulfate, (3) alkyl sulfate, (1
0) long chain alkyl phosphate monoester salt, (11) sulf
Anionic surfactants such as succinic acid monoester salts;
(12) Amphoteric surfactant such as imidazoline amphoteric surfactant
Non-active agents such as (15) alkyl glycoside surfactants
Ionic surfactants are preferred. These surfactants may be used alone or in combination of two or more.
Can be used in combination, and 5 to 30 in the total composition
%, Particularly preferably 10 to 20%. The cleaning composition of the present invention comprises
Other components used in ordinary cleaning agents such as shampoos, examples
For example, ethylene glycol distearate, ethylene glycol
Suspending agents such as coal monostearate, propylene glyco
Dissolving agents such as ethanol and glycerin, ethanol, inorganic salts,
Grade alcohol, hydroxymethyl cellulose, hydroxy
Siethyl cellulose, hydroxypropyl cellulose,
Methyl cellulose, viscosity modifiers such as natural polymers,
Other fragrances, dyes, UV absorbers, antioxidants, anti-dandruff agents,
Bactericides, preservatives, pH adjusters, etc., if necessary
be able to. The balance is water, usually 50-90.
%, Preferably 60 to 80%. The cleaning composition of the present invention has a water-insoluble
Mix well with molecular powder and water-insoluble nonvolatile silicone
And preferably dispersed using a surfactant.
Prepare and mix this with water containing surfactants and other ingredients
It is manufactured by adding to a liquid and dispersing. The cleaning composition of the present invention thus obtained is
Good for hair shampoo, body shampoo, etc.
Good. [0081] The present invention will be described in more detail with reference to the following examples.
However, the present invention is not limited to these.
In addition, stability over time, moist feeling when drying after washing hair
The evaluation of stickiness and stickiness was performed by the following method. (Stability over time) 9 cm in a 10 cm high storage bottle
Add shampoo and store at 50 ° C for 10 days.
From the top, silicone and particle settling from below
It was measured and evaluated according to the following criteria. [0083] [Table 1] Evaluation ◎: 0 mm floating from the top or 0 mm sediment from the bottom (stable with time)
Excellent in nature) ：: Floating less than 3 mm from the top or settling less than 3 mm from the bottom
(Slightly superior in stability over time) △: 3 mm or more sedimentation from the bottom 3 mm or more floating (time
Less stable) (Finger Street and Smooth Feeling) Healthy Japanese Woman
20g (15cm length) of sexual hair
Apply 1 g of pump and lather for 1 minute, then run for 30 seconds
Rinsing followed by towel drying. In addition, dry
And dry in a dry state.
The sensation was evaluated organoleptically according to the following criteria. [0085] [Table 2] Evaluation (sticky / finger) ◎: Not sticky, smooth finger passage ○: Slightly non-sticky and slightly good finger passage Δ: Sticky, poor finger passing (Smooth feeling) ◎: Slip feeling is given to hair and it is very dry ：: Hair has a slight slipperiness and is slightly dry △: no slippery hair [0086] [0087] [0088] [0089] [0090] [0091] [0092] [0093] [0094] [0095] [0096] [0097] Embodiment 1 A shampoo having the following formulation is produced by the following method,
For these, daily stability, stickiness,
Rasara feeling was evaluated. The results are shown in Table 27 and Table 28. [0099] [Table 11]   (Product 1 of the present invention) (1) Sodium polyoxyethylene lauryl ether sulfate       (EO 3) 16% (2) Silica powder (manufactured by Nippon Steel Chemical Co., Ltd., Esquartz M-0.5,       0.6% (3) Dimethyl polysiloxane (1,000 cs) 2.4% (4) Preservatives, coloring agents, perfumes (5) Water balance [0100] [Table 12]   (Invention product 2) (1) Sodium polyoxyethylene lauryl ether sulfate       (EO 3) 16% (2) Silica powder (manufactured by Nippon Steel Chemical Co., Ltd., Esquartz M-1,       0.6% (3) Dimethylpolysiloxane (50,000cs) 2.4% (4) Preservatives, coloring agents, perfumes (5) Water balance [0101] [Table 13]   (Product 3 of the present invention) (1) Sodium polyoxyethylene lauryl ether sulfate       (EO 3) 16% (2) Silica powder (manufactured by Asahi Glass Co., Ltd., Sildex L-31,       0.6% (3) Dimethylpolysiloxane * 2.4% (4) Cationized cellulose 0.4% (5) Preservatives, coloring agents, perfumes (6) Water balance *: 20% dimethylpolysiloxane of 20 million cs or more
Of 80% dimethylpolysiloxane with 100cs [0102] [Table 14]   (Product 4 of the present invention) (1) Sodium polyoxyethylene lauryl ether sulfate       (EO 3) 16% (2) Silica powder (manufactured by Asahi Glass Co., Ltd., Sildex L-51,       0.6% (3) Dimethyl polysiloxane (100,000 cs) 2.4% (4) Preservatives, coloring agents, perfumes (5) Water balance [0103] [Table 15]   (Invention product 5) (1) Amidoamine-type amphoteric surfactant 16% (2) Silica powder (manufactured by Asahi Glass Co., Ltd., Sildex L-31,       0.6% (3) Dimethylpolysiloxane (10,000cs) 2.0% (4) Methylphenyl polysiloxane (100cs) 0.5% (5) Polydimethyldiallyl ammonium chloride / acryl       Amide copolymer (Mercoat 550, Merck) 0.5% (6) Preservatives, coloring agents, perfumes (7) Water balance [0104] [Table 16]   (Product 6 of the present invention) (1) Triethanolamine lauryl sulfate 16% (2) Silica powder (manufactured by Nippon Steel Chemical Co., Ltd., Esquartz M-0.5,       0.5%) (3) Dimethylpolysiloxane (100,000cs) 2.5% (4) Cationized cellulose 0.5% (5) Zpt (zinc pyrithione) 0.8% (6) Polyvinyl alcohol 1.0% (7) Preservatives, coloring agents, fragrances (8) Water balance [0105] [Table 17]   (Product 7 of the present invention) (1) Triethanolamine lauryl sulfate 16% (2) Silica powder (manufactured by Asahi Glass Co., Ltd., Sildex L-51,       0.5% (3) Dimethylpolysiloxane (100,000cs) 2.0% (4) Fatty acid alcohol-modified silicone (100cs) 0.5% (5) Octopirox 0.5% (6) Preservatives, coloring agents, perfumes (7) Water balance [0106] [Table 18]   (Product 8 of the present invention) (1) polyoxyethylene (4) coconut oil alkyl sulfosuccinic acid       Disodium 10% (2) Triethanolamine lauryl sulfate 10% (3) Silica powder (manufactured by Asahi Glass Co., Ltd., Sildex L-51,       0.5% (4) Dimethylpolysiloxane (100,000cs) 2.5% (5) Stearyl trimethyl ammonium chloride 0.5% (6) Ethylene glycol distearate 2.0% (7) Lauric acid diethanolamide 2.0% (8) Preservatives, coloring agents, fragrances (9) Water balance Production method of products 1 to 8 of the present invention Mix silica powder and dimethylpolysiloxane well,
After emulsifying and dispersing with the surfactant of the part, the remaining surfactant
And water, a cationized polymer, a quaternized ammonium salt,
Mix in an aqueous solution such as diethanolamide urate
Preservatives, colorants, and fragrances were added. Also, the product 6 of the present invention
Preliminary dispersion of Zpt in polyvinyl alcohol
Let it mix at the end. Regarding the product 8 of the present invention, a suspending agent
As ethylene glycol distearate from 60 to 7
Formulated at 0 ° C. and allowed to cool slowly. Also, amidoami
N-lauroyl-N-carboxy
Xymethyl- (2-hydroxyethyl) ethylenediamine
Sodium was used. [0108] [Table 19]   (Comparative product 1) (1) Sodium polyoxyethylene lauryl ether sulfate       (EO 3) 16% (2) Cationized cellulose 0.4% (3) Preservatives, coloring agents, fragrances (4) Water balance [0109] [Table 20]   (Comparative product 2) (1) Sodium polyoxyethylene lauryl ether sulfate       (EO 3) 16% (2) Dimethyl polysiloxane (1,000 cs) 2.4% (3) Preservatives, coloring agents, fragrances (4) Water balance [0110] [Table 21]   (Comparative product 3) (1) Sodium polyoxyethylene lauryl ether sulfate       (EO 3) 16% (2) Dimethylpolysiloxane (50,000cs) 2.4% (3) Preservatives, coloring agents, fragrances (4) Water balance [0111] [Table 22]   (Comparative product 4) (1) Sodium polyoxyethylene lauryl ether sulfate       (EO 3) 16% (2) Cationized cellulose 0.4% (3) Dimethylpolysiloxane (50,000cs) 2.4% (4) Preservatives, coloring agents, perfumes (5) Water balance [0112] [Table 23]   (Comparative product 5) (1) Amidoamine-type amphoteric surfactant 16% (2) Dimethylpolysiloxane (10,000cs) 2.0% (3) Methylphenyl polysiloxane (100cs) 0.5% (4) Polydimethyldiallylammonium chloride /       Acrylamide copolymer (manufactured by Merck, Marko 550) 0.5% (5) Preservatives, coloring agents, perfumes (6) Water balance [0113] [Table 24]   (Comparative product 6) (1) Triethanolamine lauryl sulfate 16% (2) Dimethylpolysiloxane (100,000cs) 2.5% (3) Cationized cellulose 0.5% (4) Zpt (zinc pyrithione) 0.8% (5) Polyvinyl alcohol 1.0% (6) Preservatives, coloring agents, perfumes (7) Water balance [0114] [Table 25]   (Comparative product 7) (1) Triethanolamine lauryl sulfate 16% (2) Dimethylpolysiloxane (100,000cs) 2.0% (3) Fatty alcohol modified silicone (100cs) 0.5% (4) Octopirox 0.5% (5) Preservatives, coloring agents, perfumes (6) Water balance [0115] [Table 26]   (Comparative product 8) (1) polyoxyethylene (4) coconut oil alkyl sulfosuccinic acid       Disodium 10% (2) Triethanolamine lauryl sulfate 10% (3) Dimethylpolysiloxane (100,000cs) 2.5% (4) Stearyl trimethyl ammonium chloride 0.5% (5) Ethylene glycol distearate 2.0% (6) Lauric acid diethanolamide 2.0% (7) Preservatives, coloring agents, fragrances (8) Water balance Production method of comparative products 1 to 8 Thoroughly mix the silicone compound and milk with some surfactants.
After the dispersion, the remaining surfactant, water and cationized
Limmer, quaternary ammonium salt, diethanolate laurate
Luamide and other aqueous solutions, sufficient preservatives, colorants,
Perfume was added. In addition, regarding Comparative Product 1,
Sodium ethylene lauryl ether sulfate, cationized
After mixing cellulose and water, preservatives, colorants, fragrances
Was added. Further, with respect to Comparative Product 5, polyvinyl alcohol
The Zpt is predispersed during the coal and compounded last. ratio
With respect to Comparative Example 7, ethylene glycol was used as a suspending agent.
Distearate at 60-70 ° C and cool slowly
I let it. Amidoamine-type amphoteric surfactants include N
-Lauroyl-N-carboxymethyl- (2-hydroxy
(Shiethyl) ethylenediamine sodium was used. [0117] [Table 27] [0118] [Table 28] [0119] [0120] [0121] [0122] [0123] [0124] [0125] The cleaning composition of the present invention contains silicone.
It is stable for a long time
It has excellent conditioning effect.

────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-3-184906 (JP, A) JP-A-5-310533 (JP, A) (58) Fields investigated (Int. Cl. ⁷ , DB name) A61K 7/00-7/50

Claims (1)

(57) [Claim 1] A mixture of a water-insoluble polymer powder and a water-insoluble non-volatile silicone, which is amorphous silicon dioxide or a methylhydrogensilicone-treated product thereof, in an aqueous surfactant solution A detergent composition dispersed in a composition.