JPS63307811A - Shampoo composition and production thereof - Google Patents
Shampoo composition and production thereofInfo
- Publication number
- JPS63307811A JPS63307811A JP62141563A JP14156387A JPS63307811A JP S63307811 A JPS63307811 A JP S63307811A JP 62141563 A JP62141563 A JP 62141563A JP 14156387 A JP14156387 A JP 14156387A JP S63307811 A JPS63307811 A JP S63307811A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- amino
- emulsion
- formulas
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002453 shampoo Substances 0.000 title claims abstract description 36
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 41
- 239000000839 emulsion Substances 0.000 claims abstract description 34
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 10
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 9
- 239000002253 acid Substances 0.000 claims abstract description 8
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 7
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 7
- 239000003054 catalyst Substances 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000002585 base Substances 0.000 claims abstract description 3
- 239000002280 amphoteric surfactant Substances 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000003277 amino group Chemical group 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 229920005645 diorganopolysiloxane polymer Polymers 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 150000007530 organic bases Chemical class 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 125000005313 fatty acid group Chemical group 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 230000001804 emulsifying effect Effects 0.000 abstract description 3
- 230000003472 neutralizing effect Effects 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 2
- 230000000379 polymerizing effect Effects 0.000 abstract description 2
- 239000002563 ionic surfactant Substances 0.000 abstract 2
- 230000007794 irritation Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000087 stabilizing effect Effects 0.000 abstract 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 18
- -1 alkyl ether sulfates Chemical class 0.000 description 15
- 229960003237 betaine Drugs 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 6
- 229940043264 dodecyl sulfate Drugs 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000003755 preservative agent Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- SBRWJSVZWFZLBG-UHFFFAOYSA-N 2-(dimethylamino)pentanoic acid;dodecanamide Chemical compound CCCC(N(C)C)C(O)=O.CCCCCCCCCCCC(N)=O SBRWJSVZWFZLBG-UHFFFAOYSA-N 0.000 description 2
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical compound CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 210000004761 scalp Anatomy 0.000 description 2
- 239000003981 vehicle Substances 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- XXJGBENTLXFVFI-UHFFFAOYSA-N 1-amino-methylene Chemical compound N[CH2] XXJGBENTLXFVFI-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910006146 SO3M1 Inorganic materials 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Polymers CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、シャンプー組成物及びその製造方法に関する
。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a shampoo composition and a method for producing the same.
［従来の技術］
シャンプーは、適当な洗滌力を持つと同時に、頭皮、毛
髪に対する刺激があってはならない。従来のシャンプー
の多くは、アニオン系界面活性剤、たとえばアルキル硫
酸塩、アルキルエーテル硫酸塩、α−オレフィンスルホ
ン酸塩、アルキルリン酸エステル塩などを基剤とする。[Prior Art] Shampoos must have appropriate cleansing power and at the same time must not irritate the scalp and hair. Many conventional shampoos are based on anionic surfactants, such as alkyl sulfates, alkyl ether sulfates, alpha-olefin sulfonates, alkyl phosphate ester salts, and the like.
洗髪後の髪に、自然な艶、なめらかさ、しなやかさ、く
し通りの良さを与えるために、アミノ変性ポリシロキサ
ンを配合することが提案されている。例えば、特開昭６
０−５６９１６号公報では、アミノシロキサンの水性エ
マルジョン、ラウリルエーテル硫酸ナトリウムおよびリ
ルインジエタノールアミド等より成るシャンプーが開示
されている（実施例３）。該公報において界面活性剤は
、アニオン性又は非イオン性のもののみである。It has been proposed to incorporate amino-modified polysiloxanes into hair to give natural shine, smoothness, suppleness, and ease of combing to hair after washing. For example, JP-A-6
No. 0-56916 discloses a shampoo comprising an aqueous emulsion of aminosiloxane, sodium lauryl ether sulfate, lyluindiethanolamide, etc. (Example 3). In this publication, the surfactants are only anionic or nonionic.
特開昭５８−２１０００５号公報には、アミノ変性ポリ
シロキサン、界面活性剤、凍結−解凍安定性を与える添
加物（エチレングリコールなと）および水から成るリン
ス組成物が記載され、界面活性剤はカチオン性、アニオ
ン性および非イオン性界面活性剤である。特開昭６１−
６号公報には、アミノ変性シリコーンコンディショニン
グ剤約０．１〜約１０％、ジメチコーンコポリオール約
０．０１〜約１０％、脂質ビヒクル物質的０．１〜約１
０％、カチオン性界面活性剤ビヒクル物質約０．０５〜
約５％および残部の水から成るリンス組成物が開示され
る。JP-A-58-210005 describes a rinse composition consisting of an amino-modified polysiloxane, a surfactant, an additive (such as ethylene glycol) that provides freeze-thaw stability, and water. Cationic, anionic and nonionic surfactants. Unexamined Japanese Patent Publication 1986-
No. 6 contains about 0.1% to about 10% amino-modified silicone conditioning agent, about 0.01% to about 10% dimethicone copolyol, and 0.1% to about 1% lipid vehicle material.
0%, cationic surfactant vehicle material from about 0.05
A rinse composition comprising about 5% and the balance water is disclosed.
［発明が解決しようとする問題点］
上記のように、アミノ変性オルガノポリシロキサンを含
むシャンプーは従来提案されていた。かかるシャンプー
はアミノ変性オルガノポリシロキサン自体又はその単な
るエマルジョンを添加剤として含有している。一方、多
くのシャンプーは、洗滌力の強いアニオン系界面活性剤
を主成分として含む。ところが、実際にはアミノ変性オ
ルガノポリシロキサン自体又はそのエマルジョンを、ア
ニオン系界面活性剤を含むシャンプーに添加すると系が
不安定になり、凝集・分離が起りやすいという問題があ
ることが判った。[Problems to be Solved by the Invention] As described above, shampoos containing amino-modified organopolysiloxanes have been proposed in the past. Such shampoos contain as additives amino-modified organopolysiloxanes themselves or simple emulsions thereof. On the other hand, many shampoos contain anionic surfactants with strong cleaning power as their main ingredients. However, in reality, it has been found that when amino-modified organopolysiloxane itself or its emulsion is added to a shampoo containing an anionic surfactant, the system becomes unstable and aggregation and separation are likely to occur.
本発明の目的は、アニオン系界面活性剤を基剤とする公
知のシャンプーに更にアミノ変性オルガノポリシロキサ
ンエマルジョンを含め、系を不安定にすることなくアミ
ノ変性オルガノポリシロキサンの特性を生かしたシャン
プーを得ようとすることにある。The object of the present invention is to further incorporate an amino-modified organopolysiloxane emulsion into a known shampoo based on an anionic surfactant, thereby creating a shampoo that takes advantage of the properties of the amino-modified organopolysiloxane without destabilizing the system. It's about trying to get something.
［問題点を解決するための手段］
上記の問題点は、アニオン系界面活性剤を基剤とするシ
ャンプーにおいて、下記（Ａ）および（Ｂ）を含むこと
を特徴とするシャンプー組成物によって解決できること
が見い出された。[Means for Solving the Problems] The above problems can be solved by a shampoo composition containing the following (A) and (B) in a shampoo based on an anionic surfactant. was discovered.
（Ａ）環状ジオルガノポリシロキサンとアミノ基含有オ
ルガノトリアルコキシシランをカチオン系界面活性剤に
より水中に乳化後、アルカリ金属水酸化物を触媒として
乳化重合し、酸で中和して作られたアミノ変性オルガノ
ポシリシロキサンエマルジョン
（８）下記式（Ｉ）〜（Ｉ［Ｉ）に示す両性界面活性剤
から選択された少なくとも一種の両性界面活性剤
式（■）：
Ｎ ＣＨ２
Ｒ１−Ｃ−Ｎ−Ｃ２Ｈ４０Ｒ２
Ｈ２Ｒ３
・・・・・・・・・・・・・・・ （Ｉ＞〔式中、Ｒ
１は平均炭素数１０〜２０の脂肪酸根、Ｒ２は水素、Ｎ
ａ 又はＣＨ２Ｃ００Ｒ４（Ｒ４はＨ，Ｎａ又は有機塩
基である）、Ｒ３はＣＯＯＲ４，ＣＨ２ＣＯＯＲ４を表
ゎす〕のイミダゾリニウムベタイン系化合物および、
式（■）：
ＣＨ３
Ｒ５−Ｎ−（Ｃ町）ｎ−Ｒ５−（ＩＩ＞Ｈ３
〔式中、Ｒ５は炭素数１０〜２０のアルキル基であり、
Ｒ６はＣＯＯＲ７又はｓｏ３ Ｒ７（Ｒ７はＨ又はＮａ
である）、ｎは１〜３の整数を表わす〕のアルキルアミ
ノベタイン系化合物、および
式（■）：
〔式中、Ｒ８は炭素数１０〜２０のアルキル基であり、
Ｒ９は水素又はＮａ、ｍは２〜３の整数を表わす〕の７
ミドベタイン系化合物。(A) Amino acid produced by emulsifying cyclic diorganopolysiloxane and amino group-containing organotrialkoxysilane in water using a cationic surfactant, emulsion polymerizing using an alkali metal hydroxide as a catalyst, and neutralizing with acid. Modified organoposilysiloxane emulsion (8) At least one amphoteric surfactant selected from the amphoteric surfactants shown in the following formulas (I) to (I[I) Formula (■): N CH2 R1-C-N- C2H40R2 H2R3 ・・・・・・・・・・・・・・・ (I>[In the formula, R
1 is a fatty acid root with an average carbon number of 10 to 20, R2 is hydrogen, N
a or CH2C00R4 (R4 is H, Na or an organic base), R3 represents COOR4, CH2COOR4], and the formula (■): CH3 R5-N-(C town) n -R5-(II>H3 [wherein, R5 is an alkyl group having 10 to 20 carbon atoms,
R6 is COOR7 or so3 R7 (R7 is H or Na
), n represents an integer of 1 to 3], and an alkylaminobetaine compound of the formula (■): [wherein R8 is an alkyl group having 10 to 20 carbon atoms,
R9 is hydrogen or Na, m is an integer of 2 to 3]
Midobetaine compounds.
また、本発明は、アニオン系界面活性剤を基剤とし、環
状ジオルガノポリシロキサンとアミノ基含有オルガノト
リアルコキシシランをカチオン系界面活性剤により水中
に乳化後、アルカリ金属水酸化物を触媒として乳化重合
し、酸で中和して作られたアミノ変性オルガノポシリシ
ロキサンエマルジョンおよび前記式（Ｉ）〜（ＩＩＩ）
に示す両性界面活性剤の少なくとも一種を含むシャンプ
ーの製造法において、前記アミノ変性オルガノポリシロ
キサンエマルジョンと少くとも一種の前記両性界面活性
剤を配合した後にアニオン系界面活性剤を配合する事を
特徴とする方法である。Furthermore, the present invention emulsifies a cyclic diorganopolysiloxane and an amino group-containing organotrialkoxysilane in water using an anionic surfactant as a base, and then emulsifies the mixture using an alkali metal hydroxide as a catalyst. Amino-modified organoposilysiloxane emulsion prepared by polymerization and neutralization with acid and the formulas (I) to (III)
The method for producing a shampoo containing at least one amphoteric surfactant shown in the above is characterized in that an anionic surfactant is blended after the amino-modified organopolysiloxane emulsion and at least one amphoteric surfactant are blended. This is the way to do it.
アニオン系界面活性剤、特定のアミノ変性オルガノポリ
シロキサンエマルジョン及び特定の両性界面活性剤を組
み合せることは、シャンプーにおいては勿論、リンスに
おいても知られていない。Combining an anionic surfactant, a specific amino-modified organopolysiloxane emulsion, and a specific amphoteric surfactant is not known in shampoos or even in rinses.
前述した特開昭６０−５６９１６号公報に開示されるシ
ャンプーは、特定の両性界面活性剤を含まないので、経
日安定性に劣る。また特開昭５８−２１００５ ＠及び
特開昭６１−６号公報に開示されるものは、夫々、リン
スおよびコンディショニング組成物に関するものであり
、やはり特定の両性界面活性剤の使用に言及していない
。The shampoo disclosed in JP-A No. 60-56916 mentioned above does not contain a specific amphoteric surfactant, and therefore has poor stability over time. Furthermore, the disclosures in JP-A-58-21005@ and JP-A-61-6 relate to rinsing and conditioning compositions, respectively, and also do not mention the use of specific amphoteric surfactants. .
本発明のアミノ変性オルガノポリシロキサンエマルジョ
ン自体は公知であり、環状ジオルガノポリシロキサンと
アミノ基含有オルガノトリアルコキシシランをカチオン
系界面活性剤で水中に乳化後、アルカリ金属水酸化物を
触媒として乳化重合し、酸で中和して得ることができる
。環状ジオルガノポリシロキサンとしては、式
（式中、Ｒ１はメチル基、エチル基、プロピル基等のア
ルキル基、ｎは３〜８の整数である。〕が例示される。The amino-modified organopolysiloxane emulsion of the present invention itself is known, and after emulsifying a cyclic diorganopolysiloxane and an amino group-containing organotrialkoxysilane in water with a cationic surfactant, emulsion polymerization is carried out using an alkali metal hydroxide as a catalyst. It can be obtained by neutralizing it with acid. Examples of the cyclic diorganopolysiloxane include the formula (wherein R1 is an alkyl group such as a methyl group, ethyl group, or propyl group, and n is an integer from 3 to 8).
アミノ基含有オルガノトリアルコキシシランとしては、
式
等のアルキル基であり、Ｒ３，Ｒ４はメチレン基、エチ
レン基、プロピレン基、ブチレン基等のアルキレン基で
あり、Ｒ３，Ｒ４は同一でも、また異なっていてもよい
〕
が例示される。As amino group-containing organotrialkoxysilane,
is an alkyl group such as the formula, R3 and R4 are alkylene groups such as a methylene group, an ethylene group, a propylene group, a butylene group, and R3 and R4 may be the same or different.
該アミノ基含有オルガノトリアルコキシシランの具体例
としては（ＣＨ３０＞３８！ ＣＨ２ＣＨ２ＣＨ２ＮＨ
ＣＨ２ＣＨ２ＮＨ２、（ＣＨ３ＣＨ２０＞ ３ Ｓ！
ＣＨ２ＣＨ２ＣＨ２Ｎ ＨＣＨ２Ｈ３
ＣＨ２ＮＨ２、（ＣＨ３０＞ ３３！ ＣＨ２ＣＨＣＨ
２ＮＨＣＨ２ＣＨ２Ｎ町、
ＣＨ３
■
（ＣＨ３０ＨＯ）３ Ｓｉ ＣＨ２ＣＨ２ＣＨ２ＮＨＣ
Ｈ２ＣＨ２ＣＨ２ＮＨ２がある。Specific examples of the amino group-containing organotrialkoxysilane include (CH30>38! CH2CH2CH2NH
CH2CH2NH2, (CH3CH20> 3 S!
CH2CH2CH2N HCH2H3 CH2NH2, (CH30> 33! CH2CHCH
2NHCH2CH2N town, CH3 ■ (CH30HO)3 Si CH2CH2CH2NHC
There is H2CH2CH2NH2.
本発明のアミノ変性オルガノポリシロキサンの構造の代
表例は、米国Ｃｏｓｍｅｔｉｃ Ｉｎｇｒｅｄｉｅｎｔ
Ｄｉｃｔｉｏｎａｒｙ（Ｔｈｉｒｄ Ｅｄｉｔｉｏｎ）
の１８ページ、ＡＨＯＤＩ）ｆＥＴＨＩｃＯＮＥの項に
記載されている式（式中、ｐ及びｑは分子量３，０００
〜ｓｏ、ｏｏｏを満す数である）で示されるもの、又は
これの水酸基をアルコキシ基で置換したものであり、分
子量は３．０００〜５０，０００である。A representative example of the structure of the amino-modified organopolysiloxane of the present invention is
Dictionary (Third Edition)
page 18 of AHODI) fETHIcONE (where p and q are molecular weight 3,000
~so, ooo), or its hydroxyl group is substituted with an alkoxy group, and its molecular weight is 3.000 to 50,000.
好ましいアミノ変性オルガノポリシロキサンエマルジョ
ンの市販品としては、５Ｍ８７０２Ｇ （トーレ・シリ
コーン株式会社）やＤＣ９２９（ダウ・コーニング株式
会社）等が挙げられる。Preferred commercially available amino-modified organopolysiloxane emulsions include 5M8702G (Torre Silicone Co., Ltd.) and DC929 (Dow Corning Co., Ltd.).
上記のアミノ変性オルガノポリシロキサンの乳化重合に
用いられる好ましいカチオン系界面活性剤としては、
あり、ｎは平均値で１〜２である］
が例示されるが、これらに限定されない。その他に必要
に応じて、安定化剤としてＨＬＢ８以上のノニオン系界
面活性剤が添加される。良好な乳化のためにはカチオン
系界面活性剤が必要である。Preferred cationic surfactants used in the emulsion polymerization of the above amino-modified organopolysiloxane include, but are not limited to, the following, where n is 1 to 2 on average. In addition, a nonionic surfactant having an HLB of 8 or more may be added as a stabilizer if necessary. Cationic surfactants are required for good emulsification.
乳化重合で用いられるアルカリ金属水酸化物としては、
ＫＯＨ，Ｎａ ＯＨ，Ｌｉ ＯＨ等が例示される。中和
のための酸としては、酢酸、リン酸、シュウ酸、塩酸、
硫酸等が例示される。Alkali metal hydroxides used in emulsion polymerization include:
Examples include KOH, NaOH, LiOH, and the like. Acids for neutralization include acetic acid, phosphoric acid, oxalic acid, hydrochloric acid,
Examples include sulfuric acid.
アミノ変性オルガノポリシロキサンエマルジョン中のア
ミノ変性オルガノポリシロキサンの含有量は、通常２０
〜６０重間％、特に３０〜５０重量％である。The content of amino-modified organopolysiloxane in the amino-modified organopolysiloxane emulsion is usually 20
~60% by weight, especially 30-50% by weight.
本発明において用いられる両性界面活性剤は、式（Ｉ）
〜（ＩＩＩ）に示す公知のものから選択される。好まし
いものとしては、式（Ｉ）からは２−アルキル−Ｎ−カ
ルボキシメチル−
シイミダゾリニウムベタイン、式（Ｉ［）からは、ラウ
リルジメチルアミノ酢酸ベタイン、ヤシ油脂肪酸ジメチ
ルアミノスルホベタイン、式（ＩＩＩ）からはヤシ油脂
肪酸アミドプロビルジメチルアミノ酢酸ベタイン等が挙
げられる。The amphoteric surfactant used in the present invention has the formula (I)
It is selected from the known ones shown in ~(III). Preferred examples include 2-alkyl-N-carboxymethyl-ciimidazolinium betaine from formula (I), lauryl dimethylaminoacetic acid betaine, coconut oil fatty acid dimethylaminosulfobetaine from formula (I [), III) includes coconut oil fatty acid amidoprobyl dimethylaminoacetic acid betaine and the like.
本発明においてアニオン系界面活性剤は、シャンプーの
ために慣用されているもののいずれでも良く、特に限定
されない。たとえば、Ｒ−０８０３Ｍ（Ｒは１０〜１６
個の炭素原子を持つアルキル基、Ｍは塩を生成するカチ
オン）で示されるアルキル硫酸塩、例えばラウリル硫酸
トリエタノールアミノやラウリル硫酸アンモニウム等、
ＲＯ （ＣＩ−１２ ｃｔ−＋２ｏ＞。ＳＯ３Ｍ１ （
Ｒはアルキル、Ｍは塩を生成するカチオン、ｎ＝２〜４
）で示されるアルキルエーテル硫酸塩、例えばポリオキ
シエチレンラウリルエーテル硫酸ナトリウム等、Ｒ−Ｃ
Ｈ２−ＣＩ−１ （ＯＨ）（ＣＨ２）。In the present invention, the anionic surfactant may be any one commonly used for shampoos, and is not particularly limited. For example, R-0803M (R is 10-16
Alkyl sulfates represented by an alkyl group having 5 carbon atoms, M is a cation that forms a salt, such as triethanolamino lauryl sulfate and ammonium lauryl sulfate,
RO (CI-12 ct-+2o>.SO3M1 (
R is alkyl, M is a cation that forms a salt, n = 2-4
), such as sodium polyoxyethylene lauryl ether sulfate, R-C
H2-CI-1 (OH)(CH2).
３０ Ｎａ又はＲ−Ｃ）（＝ＣＩ−を二（ＣＨ２）ｎ
ＳＯ３Ｎａ（Ｒはアルキル基）で示されるα−オレフィ
ンスルホン酸塩、および石けん、例えばヤシ油脂肪酸カ
リウム等、グリセリンモノアルキルエステルモノ硫酸塩
、モノアルキルスルホコハク酸エステル、蛋白・脂肪酸
縮合物、アシルザルコシン酸塩、アシルグルタミン酸塩
、アルキルリン酸エステル塩類、ショ糖脂肪酸エステル
類などがある。30 Na or R-C) (=CI-2(CH2)n
α-olefin sulfonate represented by SO3Na (R is an alkyl group), soap, such as potassium coconut oil fatty acid, glycerin monoalkyl ester monosulfate, monoalkyl sulfosuccinate, protein/fatty acid condensate, acyl sarcosinate , acyl glutamates, alkyl phosphate ester salts, sucrose fatty acid esters, etc.
本発明のシャンプー組成物の製造において、前記の７ミ
ノ変性オルガノポリシロキサンエマルジヨンを前記の両
性界面活性剤と混合した後にアニオン系界面活性剤を加
えることが好ましい。この順序を逆にして、アミノ変性
オルガノポリシロキサンエマルジョンをアニオン系界面
活性剤と混合した後に両性界面活性剤を加えたのでは、
経口安定なシャンプー組成物は（ｑられず、アミノ変性
オルガノポリシロキサンが凝集する傾向がある。両性界
面活性剤を一切加えない場合には、シャンプー系の経日
安定性は一層悪い。In producing the shampoo composition of the present invention, it is preferable to add an anionic surfactant after mixing the 7-mino-modified organopolysiloxane emulsion with the amphoteric surfactant. If this order was reversed and the amino-modified organopolysiloxane emulsion was mixed with the anionic surfactant, then the amphoteric surfactant was added.
Orally stable shampoo compositions have a tendency to aggregate and the amino-modified organopolysiloxanes tend to aggregate. If no amphoteric surfactant is added, the stability of the shampoo system over time is even worse.
前記両性界面活性剤と、前記アミノ変性オルガノポリシ
ロキサンエマルジョン中のアミノ変性オルガノポリシロ
キサンとの重量比は、系の安定性のために゛１１０．８
以上であることが好ましい。この比が１１０．８未満で
は、アミノ変性オルガノポリシロキサンが凝集する傾向
がある。The weight ratio of the amphoteric surfactant to the amino-modified organopolysiloxane in the amino-modified organopolysiloxane emulsion is set to 110.8 for system stability.
It is preferable that it is above. When this ratio is less than 110.8, the amino-modified organopolysiloxane tends to aggregate.
本発明のシャンプー組成物に含有される界面活性剤の含
有量は、本発明の効果を損なわない範囲で適宜定められ
るが、好ましくはアニオン系界面活性剤が５〜２０重量
％、アミノ変性オルガノポリシロキサンエマルジョンが
０．５〜ｉｏｉｍ％、両性界面活性剤が１〜１０重量％
である。The content of the surfactant contained in the shampoo composition of the present invention is appropriately determined within a range that does not impair the effects of the present invention, but preferably the anionic surfactant is 5 to 20% by weight, the amino-modified organopolymer Siloxane emulsion 0.5-ioim%, amphoteric surfactant 1-10% by weight
It is.
本発明のシャンプー組成物は、慣用の他の成分、たとえ
ば香料、防腐剤、色素、泡立て剤などを更に含むことが
できる。The shampoo compositions of the present invention may further include other conventional ingredients such as perfumes, preservatives, pigments, lathering agents, and the like.
［発明の効果］
本発明のシャンプーは、アニオン系界面活性剤を含むこ
とによる優れた洗滌力、特定のアミノ変性オルガノポリ
シロキサンエマルジョンを含むことによる洗髪後の髪の
自然な艶、なめらかさ、しなやかさ、くし通りの良さを
示し、かつ特定の両性界面活性剤を配合したことにより
系が安定化されており、長期間保存してもアミノ変性オ
ルガノポリシロキサンの凝集がない。[Effects of the Invention] The shampoo of the present invention has excellent cleaning power due to the inclusion of an anionic surfactant, and the natural shine, smoothness, and suppleness of hair after washing due to the inclusion of a specific amino-modified organopolysiloxane emulsion. It exhibits good combability, and the system is stabilized by incorporating a specific amphoteric surfactant, so there is no aggregation of the amino-modified organopolysiloxane even after long-term storage.
［実 施 例］ 以下、実施例により本発明を更に説明する。[Example] The present invention will be further explained below with reference to Examples.
実施例で用いたアミノ変性オルガノポリシロキサンエマ
ルジョンは、下、記の如くに作られた。The amino-modified organopolysiloxane emulsion used in the examples was prepared as described below.
水６０部にヘキサデシルトリメチルアンモニウムクロラ
イド５部を溶解した。別の容器でγ−（β−アミノエチ
ル）アミノプロピルトリエトキシシラン１．５部とオク
タメチルシクロテトラシロキサン３８．５部とを予め混
合した。次いで攪拌しながら両者を混合し、コロイドミ
ル乳化機を用いて５／１０００インチの間隔で２回通過
させた。次に水酸化ナトリウムでｐ旧２．５に調整した
後、８０’Ｃで３時間加熱、３０℃で６時間保持した俊
に酢酸でｐ１１７とした。次に安定化のために、ポリオ
キシエチレン（９）ノニルフェニルエーテル０．５部を
添加攪拌し、アミノ変性オルガノポリシロキサンエマル
ジョンを得た。5 parts of hexadecyltrimethylammonium chloride were dissolved in 60 parts of water. In a separate container, 1.5 parts of γ-(β-aminoethyl)aminopropyltriethoxysilane and 38.5 parts of octamethylcyclotetrasiloxane were mixed in advance. The two were then mixed with stirring and passed through a colloid mill emulsifier twice at 5/1000 inch intervals. Next, the pH was adjusted to 2.5 with sodium hydroxide, heated at 80'C for 3 hours, held at 30C for 6 hours, and then adjusted to p117 with acetic acid. Next, for stabilization, 0.5 part of polyoxyethylene (9) nonylphenyl ether was added and stirred to obtain an amino-modified organopolysiloxane emulsion.
このアミノ変性オルガノポリシロキサンエマルジョンは
、前記の式においてはｐ＝１００ 、 Ｑ＝２、分子量
約８０００のアミノ変性ポリシロキサンを主成分とし、
これを約４０重量％含むカチオン水性エマルジョンであ
る。This amino-modified organopolysiloxane emulsion has as its main component an amino-modified polysiloxane with p=100, Q=2, and a molecular weight of about 8000 in the above formula,
This is a cationic aqueous emulsion containing about 40% by weight.
実施例 １ 下記組成のシャンプーを作った。Example 1 A shampoo with the following composition was made.
重量％
アミノ変性ポリシロキサンエマルジョン １０．０２−
アルキル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシイミ
ダゾリニウムベタイン ５．Ｏラウリル硫酸トリエタ
ノールアミノ １０．０香 料
０．３防 腐 剤
０．１色 素 微 山水
残部
攪拌装置を備えた容器に所定量の水を入れ、これにアミ
ノ変性オルガノポリシロキサンエマルジョン、２−アル
キル−
Ｎ−ヒドロキシイミダゾリニウムベタインを添加して均
一に攪拌溶解した。更に、ラウリル硫酸トリエタノール
アミノおよび防腐剤を上記溶液に加え均一に攪拌溶解し
た。半透明乳白色の均一な液体になった後に、香料、色
素を添加した。Weight% Amino-modified polysiloxane emulsion 10.02-
Alkyl-N-carboxymethyl-N-hydroxyimidazolinium betaine 5. O lauryl sulfate triethanolamino 10.0 fragrance
0.3 Preservative
0.1 Pigment Pour a predetermined amount of water into a container equipped with a stirring device, add the amino-modified organopolysiloxane emulsion and 2-alkyl-N-hydroxyimidazolinium betaine, and stir to dissolve uniformly. did. Further, triethanolamino lauryl sulfate and a preservative were added to the above solution and uniformly dissolved by stirring. After the mixture became a translucent milky white homogeneous liquid, fragrance and coloring were added.
このように調製したシャンプー組成物は、４０℃で３ケ
月貯蔵したときの経口安定性が良好であった。The shampoo composition thus prepared had good oral stability when stored at 40°C for 3 months.
該シャンプー組成物を用いて洗髪したところ、良好な洗
滌力と共に、洗髪後の自然な艶、なめらかさ、しなやか
さ、くし通りの良さ等に優れていた。When the shampoo composition was used to wash hair, the hair had good washing power and was excellent in natural shine, smoothness, suppleness, and ease of combing after washing.
実施例 ２ 下記組成のシャンプーを作った。Example 2 A shampoo with the following composition was made.
・ 重量％
アミノ変性ポリシロキサンエマルジョン ５．０ラウロ
イルアミドプロピル
ジメチルアミノ酢酸ベタイン ３．０ラウリル
硫酸トリエタノールアミノ １２．０香
料 ０．３防 腐 剤
０．１水 残部
攪拌装置を備えた容器に、所定量の水を入れ、これにア
ミノ変性ポリシロキサンエマルジョン、次にラウロイル
アミドプロビルジメチルアミノ酢酸ベタインを添加して
攪拌溶解した。半透明乳白の均一な液体になった後に、
ラウリル硫酸トリエタノールアミノを加えて均一に攪拌
溶解した。更に、防腐剤、次いで、香料を添加した。こ
のように調製したシャンプー組成物の４０℃における経
口安定性は良好であった。尚、比較のために、上記調製
の際に、ラウロイルアミドプロピルジメチルアミノ酢酸
ベタインを添加する前に、ラウリル硫酸トリエタノール
アミノを加えて、以下同様に調製をした場合、調製直後
は乳白濁の液体となり、調製後、室温で１時間以内にア
ミノ変性ポリシロキサンの凝集が発生し分離した。- Weight% Amino-modified polysiloxane emulsion 5.0 Lauroylamidopropyldimethylaminoacetic acid betaine 3.0 Lauryl sulfate triethanolamino 12.0 Fragrance
Materials: 0.3 Preservatives: 0.1 Water The remainder: Pour the specified amount of water into a container equipped with a stirring device, add the amino-modified polysiloxane emulsion, then add the lauroylamide propyl dimethylaminoacetic acid betaine and stir. Dissolved. After it becomes a translucent milky white homogeneous liquid,
Lauryl sulfate triethanolamino was added and stirred to dissolve uniformly. Additionally, preservatives were added, followed by perfume. The shampoo composition thus prepared had good oral stability at 40°C. For comparison, when preparing the above, add lauryl sulfate triethanolamino before adding lauroylamide propyldimethylaminoacetic acid betaine and prepare in the same manner. After preparation, the amino-modified polysiloxane aggregated and separated within 1 hour at room temperature.
上記の本発明のシャンプーを用いて洗髪したところ、実
施例１と同様の良好な結果が得られた。When hair was washed using the above shampoo of the present invention, good results similar to those in Example 1 were obtained.
実施例 ３
下記の表のように組成比を種々変えたシャンプーを作っ
た。Example 3 Shampoos were made with various composition ratios as shown in the table below.
ラウリルジメチルアミノ酢酸ベタインとアミノ変性オル
ガノポリシロキサンエマルジョンを適当な比で用いるこ
とにより、シャンプーの経日安定性が著しく向上したこ
とが判る。It can be seen that by using an appropriate ratio of lauryldimethylaminoacetic acid betaine and amino-modified organopolysiloxane emulsion, the stability of the shampoo over time was significantly improved.
本発明により、経日安定性に優れ、適度の洗滌力を持ち
、頭皮、毛髪に対し刺激がなく、洗った後の髪に自然な
艶、なめらかさ、しなやかさ、くし通りの良さを与える
シャンプー組成物が得られた。The present invention provides a shampoo that has excellent stability over time, has moderate cleansing power, does not irritate the scalp or hair, and gives hair natural luster, smoothness, suppleness, and ease of combing after washing. A composition was obtained.
出 願 人 鐘 紡 株 式 会 社
トーレ・シリコーン株式会社Applicant Kanebo Co., Ltd. Toray Silicone Co., Ltd.
Claims (3)
おいて、下記（Ａ）および（Ｂ）を含むことを特徴とす
るシャンプー組成物 （Ａ）環状ジオルガノポリシロキサンとアミノ基含有オ
ルガノトリアルコキシシランをカチオン系界面活性剤に
より水中に乳化後、アルカリ金属水酸化物を触媒として
乳化重合し、酸で中和して作られたアミノ変性オルガノ
ポシリシロキサンエマルジョン （Ｂ）下記式（ I ）〜（III）に示す両性界面活性剤か
ら選択された少なくとも一種の両性界面活性剤 ▲数式、化学式、表等があります▼・・・（ I ） 〔式中、Ｒ＿１は平均炭素数１０〜２０の脂肪酸根、Ｒ
＿２は水素、Ｎａ又はＣＨ＿２ＣＯＯＲ＿４（Ｒ＿４は
Ｈ、Ｎａ又は有機塩基である）、Ｒ＿３はＣＯＯＲ＿４
、ＣＨ＿２ＣＯＯＲ＿４を表わす〕のイミダゾリニウム
ベタイン系化合物および、 式（II）： ▲数式、化学式、表等があります▼・・・（II） 〔式中、Ｒ＿５は炭素数１０〜２０のアルキル基であり
、Ｒ＿６はＣＯＯＲ＿７又はＳＯ＿３Ｒ＿７（Ｒ＿７は
Ｈ又はＮａである）、ｎは１〜３の整数を表わす〕のア
ルキルアミノベタイン系化合物、および 式（III）： ▲数式、化学式、表等があります▼・・・（III） 〔式中、Ｒ＿８は炭素数１０〜２０のアルキル基であり
、Ｒ＿９は水素又はＮａ、ｍは２〜３の整数を表わす）
のアミドベタイン系化合物。(1) A shampoo composition based on an anionic surfactant, characterized by containing the following (A) and (B): (A) a cyclic diorganopolysiloxane and an amino group-containing organotrialkoxysilane; is emulsified in water with a cationic surfactant, emulsion polymerized using an alkali metal hydroxide as a catalyst, and neutralized with an acid to create an amino-modified organoposilysiloxane emulsion (B) with the following formulas (I) to ( At least one amphoteric surfactant selected from the amphoteric surfactants shown in III) ▲There are mathematical formulas, chemical formulas, tables, etc.▼...(I) [In the formula, R_1 is a fatty acid group with an average carbon number of 10 to 20 ,R
_2 is hydrogen, Na or CH_2COOR_4 (R_4 is H, Na or an organic base), R_3 is COOR_4
, CH_2COOR_4] and the formula (II): ▲Mathematical formulas, chemical formulas, tables, etc. are available▼...(II) [In the formula, R_5 is an alkyl group having 10 to 20 carbon atoms] (R_6 is COOR_7 or SO_3R_7 (R_7 is H or Na), n represents an integer from 1 to 3], and formula (III): ▲There are mathematical formulas, chemical formulas, tables, etc.▼ ...(III) [In the formula, R_8 is an alkyl group having 10 to 20 carbon atoms, R_9 is hydrogen or Na, and m represents an integer of 2 to 3.]
amidobetaine compounds.
サンエマルジョン中のアミノ変性オルガノポリシロキサ
ンとの配合重量比が１／０．８以上である特許請求の範
囲第（１）項のシャンプー組成物。(2) The shampoo composition according to claim (1), wherein the blending weight ratio of the amphoteric surfactant to the amino-modified organopolysiloxane in the amino-modified organopolysiloxane emulsion is 1/0.8 or more.
ノポリシロキサンとアミノ基含有オルガノトリアルコキ
シシランをカチオン系界面活性剤により水中に乳化後、
アルカリ金属水酸化物を触媒として乳化重合し、酸で中
和して作られたアミノ変性オルガノポシリシロキサンエ
マルジョン及び下記式（ I ）〜（III）に示す両性界面
活性剤の少なくとも一種を含むシャンプーの製造法にお
いて、前記アミノ変性オルガノポリシロキサンエマルジ
ョンと少くとも一種の前記両性界面活性剤を配合した後
にアニオン系界面活性剤を配合する事を特徴とする方法 式（ I ）： ▲数式、化学式、表等があります▼・・・（ I ） 〔式中、Ｒ＿１は平均炭素数１０〜２０の脂肪酸根、Ｒ
＿２は水素、Ｎａ又はＣＨ＿２ＣＯＯＲ＿４（Ｒ＿４は
Ｈ、Ｎａ又は有機塩基である）、Ｒ＿３はＣＯＯＲ＿４
、ＣＨ＿２ＣＯＯＲ＿４を表わす〕のイミダゾリニウム
ベタイン系化合物および、 式（II）： ▲数式、化学式、表等があります▼・・・（II） （式中、Ｒ＿５は炭素数１０〜２０のアルキル基であり
、Ｒ＿６はＣＯＯＲ＿７又はＳＯ＿３Ｒ＿７（Ｒ＿７は
Ｈ又はＮａである）、ｎは１〜３の整数を表わす）のア
ルキルアミノベタイン系化合物、および 式（III）： ▲数式、化学式、表等があります▼・・・（III） 〔式中、Ｒ＿８は炭素数１０〜２０のアルキル基であり
、Ｒ＿９は水素又はＮａ、ｍは２〜３の整数を表わす）
のアミドベタイン系化合物。(3) Using an anionic surfactant as a base, cyclic diorganopolysiloxane and amino group-containing organotrialkoxysilane are emulsified in water with a cationic surfactant,
A shampoo containing an amino-modified organoposilysiloxane emulsion produced by emulsion polymerization using an alkali metal hydroxide as a catalyst and neutralization with an acid, and at least one amphoteric surfactant represented by the following formulas (I) to (III). In the production method, the method formula (I) is characterized in that an anionic surfactant is blended after blending the amino-modified organopolysiloxane emulsion with at least one of the amphoteric surfactants: ▲Mathematical formula, chemical formula, There are tables, etc. ▼...(I) [In the formula, R_1 is a fatty acid root with an average carbon number of 10 to 20, R
_2 is hydrogen, Na or CH_2COOR_4 (R_4 is H, Na or an organic base), R_3 is COOR_4
, representing CH_2COOR_4] and formula (II): ▲Mathematical formulas, chemical formulas, tables, etc. are available▼...(II) (In the formula, R_5 is an alkyl group having 10 to 20 carbon atoms. Yes, R_6 is COOR_7 or SO_3R_7 (R_7 is H or Na, n represents an integer from 1 to 3), an alkylaminobetaine compound, and formula (III): ▲There are mathematical formulas, chemical formulas, tables, etc.▼ ...(III) [In the formula, R_8 is an alkyl group having 10 to 20 carbon atoms, R_9 is hydrogen or Na, and m represents an integer of 2 to 3.]
amidobetaine compounds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62141563A JP2568086B2 (en) | 1987-06-08 | 1987-06-08 | SHAMP-COMPOSITION AND METHOD OF MANUFACTURING THE SAME |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62141563A JP2568086B2 (en) | 1987-06-08 | 1987-06-08 | SHAMP-COMPOSITION AND METHOD OF MANUFACTURING THE SAME |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63307811A true JPS63307811A (en) | 1988-12-15 |
| JP2568086B2 JP2568086B2 (en) | 1996-12-25 |
Family
ID=15294882
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62141563A Expired - Lifetime JP2568086B2 (en) | 1987-06-08 | 1987-06-08 | SHAMP-COMPOSITION AND METHOD OF MANUFACTURING THE SAME |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2568086B2 (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02160712A (en) * | 1988-12-13 | 1990-06-20 | Kobayashi Kose Co Ltd | Conditioning shampoo |
| WO1997046211A1 (en) * | 1996-06-07 | 1997-12-11 | L'oreal | Detergent cosmetic compositions and use |
| JP2000178358A (en) * | 1998-10-06 | 2000-06-27 | General Electric Co <Ge> | Aminofunctional silicone emulsion |
| US6290942B1 (en) | 1998-05-28 | 2001-09-18 | Shin-Etsu Chemical Co., Ltd. | Carboxyl-bearing silicone emulsions method of making and hair preparations |
| KR100318809B1 (en) * | 1995-09-29 | 2002-03-08 | 조지안느 플로 | Topical composition containing a grafted silicone polymer and an amino silicone |
| US6953572B1 (en) | 1999-09-27 | 2005-10-11 | L'oreal | Cosmetic compositions based on partly neutralized organic silicon compounds |
| US6953584B1 (en) | 1999-09-27 | 2005-10-11 | L'oreal | Cosmetic compositions based on organic silicon compounds comprising at least a non basic solubilising function |
| US7244420B1 (en) | 1999-09-27 | 2007-07-17 | L'oreal | Cosmetic composition based on organic silicon compounds comprising at least a function with a cosmetic effect |
| JP2009263369A (en) * | 2008-04-25 | 2009-11-12 | L'oreal Sa | Cosmetic composition comprising at least one organic silicon atom-containing compound, at least one cationic surfactant and at least one organic acid, and cosmetic treatment method using the composition |
| JP2012501340A (en) * | 2008-08-29 | 2012-01-19 | ダウ コーニング コーポレーション | Silicone organic hybrid emulsion in personal care applications |
-
1987
- 1987-06-08 JP JP62141563A patent/JP2568086B2/en not_active Expired - Lifetime
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02160712A (en) * | 1988-12-13 | 1990-06-20 | Kobayashi Kose Co Ltd | Conditioning shampoo |
| JP2612756B2 (en) * | 1988-12-13 | 1997-05-21 | 株式会社コーセー | Conditioning shampoo |
| KR100318809B1 (en) * | 1995-09-29 | 2002-03-08 | 조지안느 플로 | Topical composition containing a grafted silicone polymer and an amino silicone |
| FR2749507A1 (en) * | 1996-06-07 | 1997-12-12 | Oreal | DETERGENT COSMETIC COMPOSITIONS AND USE |
| WO1997046211A1 (en) * | 1996-06-07 | 1997-12-11 | L'oreal | Detergent cosmetic compositions and use |
| US6290942B1 (en) | 1998-05-28 | 2001-09-18 | Shin-Etsu Chemical Co., Ltd. | Carboxyl-bearing silicone emulsions method of making and hair preparations |
| JP2000178358A (en) * | 1998-10-06 | 2000-06-27 | General Electric Co <Ge> | Aminofunctional silicone emulsion |
| JP2011080082A (en) * | 1998-10-06 | 2011-04-21 | Momentive Performance Materials Inc | Aminofunctional silicone emulsion |
| US6953572B1 (en) | 1999-09-27 | 2005-10-11 | L'oreal | Cosmetic compositions based on partly neutralized organic silicon compounds |
| US6953584B1 (en) | 1999-09-27 | 2005-10-11 | L'oreal | Cosmetic compositions based on organic silicon compounds comprising at least a non basic solubilising function |
| US7244420B1 (en) | 1999-09-27 | 2007-07-17 | L'oreal | Cosmetic composition based on organic silicon compounds comprising at least a function with a cosmetic effect |
| JP2009263369A (en) * | 2008-04-25 | 2009-11-12 | L'oreal Sa | Cosmetic composition comprising at least one organic silicon atom-containing compound, at least one cationic surfactant and at least one organic acid, and cosmetic treatment method using the composition |
| JP2012501340A (en) * | 2008-08-29 | 2012-01-19 | ダウ コーニング コーポレーション | Silicone organic hybrid emulsion in personal care applications |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2568086B2 (en) | 1996-12-25 |
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