RU97110060A - DERIVATIVES 2 [(2-ALKOXI-6-TRIFTOROMETHYLPYRIMIDIN-4-IL) -OXYMETHYLENE] PHENYLACETIC ACID, METHODS AND INTERMEDIATE PRODUCTS FOR THEIR PRODUCTION AND THEIR APPLICATION - Google Patents

DERIVATIVES 2 [(2-ALKOXI-6-TRIFTOROMETHYLPYRIMIDIN-4-IL) -OXYMETHYLENE] PHENYLACETIC ACID, METHODS AND INTERMEDIATE PRODUCTS FOR THEIR PRODUCTION AND THEIR APPLICATION

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Publication number
RU97110060A
RU97110060A RU97110060/04A RU97110060A RU97110060A RU 97110060 A RU97110060 A RU 97110060A RU 97110060/04 A RU97110060/04 A RU 97110060/04A RU 97110060 A RU97110060 A RU 97110060A RU 97110060 A RU97110060 A RU 97110060A
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Russia
Prior art keywords
formula
compounds
harmful fungi
derivatives
alkyl
Prior art date
Application number
RU97110060/04A
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Russian (ru)
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RU2166500C2 (en
Inventor
Кирстген Рейнхард
Обердорф Клаус
Шютц Франц
Теобальд Ханс
Харриес Фолькер
Original Assignee
Басф Акциенгезельшафт
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Priority claimed from DE4440930A external-priority patent/DE4440930A1/en
Priority claimed from DE1995126661 external-priority patent/DE19526661A1/en
Application filed by Басф Акциенгезельшафт filed Critical Басф Акциенгезельшафт
Publication of RU97110060A publication Critical patent/RU97110060A/en
Application granted granted Critical
Publication of RU2166500C2 publication Critical patent/RU2166500C2/en

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Claims (1)

1. Производные 2-[(2-алкокси-6-трифторметилпиримидин-4-ил)оксиметилен] фенилуксусной кислоты формулы I
Figure 00000001

в которой индекс и заместители имеют следующее значение:
U означает СН или N;
V означает О или NН;
R означает С1-С6алкил;
R1 означает циано, галоген, С1-С4алкил, С1-С4галоген алкил, С1-С4алкокси, С1-С6галогеналкокси и фенил;
n означает 0 или целое число от 1 до 4, причем радикалы R1 могут быть различными, если значение n больше 1.1. Derivatives of 2 - [(2-alkoxy-6-trifluoromethylpyrimidin-4-yl) oxymethylene] phenylacetic acid of the formula I
Figure 00000001

in which the index and substituents have the following meaning:
U means CH or N;
V is O or NH;
R is C 1 -C 6 alkyl;
R 1 is cyano, halogen, C 1 -C 4 alkyl, C 1 -C 4 halogen alkyl, C 1 -C 4 alkoxy, C 1 -C 6 haloalkoxy and phenyl;
n means 0 or an integer from 1 to 4, and the radicals R 1 may be different if the value of n is greater than 1. 2. Соединения формулы I по п. 1, в которых U означает СН, а V означает О. 2. The compounds of formula I according to claim 1, in which U means CH, and V means O. 3. Соединения формулы I по п. 1, в которых U означает N, а V означает О. 3. The compounds of formula I under item 1, in which U means N, and V means O. 4. Соединения формулы I по п. 1, в которых и означает N, а V означает NН. 4. The compounds of formula I according to claim 1, in which is N, and V is NH. 5. Способ получения соединений формулы I по п. 1, отличающийся тем, что пиримидин-4-ол формулы II
Figure 00000002

по известной методике в инертном органическом растворителе в присутствии основания подвергают взаимодействию с производным бензила формулы III
Figure 00000003

в которой X представляет собой нуклеофильно заменяемую уходящую группу.5. The method of producing compounds of formula I according to claim 1, characterized in that the pyrimidin-4-ol of formula II
Figure 00000002

according to a known method, in an inert organic solvent in the presence of a base, is reacted with a benzyl derivative of formula III
Figure 00000003

in which X is a nucleophilically replaceable leaving group. 6. Способ получения соединений формулы I по п. 1, отличающийся тем, что производное сульфона формулы IV
Figure 00000004

в которой Ra означает С1-С4алкил, в присутствии основания подвергают взаимодействию со спиртом формулы V
HO-R
7. Применение пиримидин-4-олов формулы II по п. 5 в качестве промежуточных продуктов для получения соединений формулы I по п. 1.6. The method of producing compounds of formula I according to claim 1, characterized in that the sulfone derivative of formula IV
Figure 00000004

in which R a means 1 -C 4 alkyl, in the presence of a base, is reacted with an alcohol of formula V
HO-R
7. The use of pyrimidine-4-ols of the formula II according to claim 5 as intermediate products for the preparation of compounds of the formula I according to claim 1. 8. Производные сульфона формулы IV по п. 6. 8. The sulfone derivatives of formula IV according to claim 6. 9. Применение производных сульфона формулы IV по п. 6 в качестве промежуточных продуктов. 9. The use of sulfone derivatives of the formula IV according to claim 6 as intermediates. 10. Средство, предназначенное для борьбы с вредителями и вредоносными грибами, содержащее твердый либо жидкий наполнитель и соединение формулы I по п. 1. 10. A tool designed to combat pests and harmful fungi, containing solid or liquid filler and the compound of the formula I according to claim 1. 11. Способ борьбы с вредителями и вредоносными грибами, отличающийся тем, что вредителей, соответственно вредоносные грибы либо требующие защиты от поражения ими материалы, растения, почву или семена обрабатывают эффективным количеством соединения формулы I по п. 1. 11. A method of controlling pests and harmful fungi, characterized in that pests, respectively, harmful fungi, or those requiring protection from damaging them, materials, plants, soil or seeds are treated with an effective amount of a compound of formula I according to claim 1. 12. Применение соединений формулы I по п. 1 для получения средства, пригодного для борьбы с вредителями или вредоносными грибами. 12. The use of compounds of the formula I according to claim 1 for obtaining an agent suitable for controlling pests or harmful fungi. 13. Применение соединений формулы I по п. 1 для борьбы с вредителями или с вредоносными грибами. 13. The use of compounds of the formula I according to claim 1 for controlling pests or harmful fungi.
RU97110060/04A 1994-11-17 1995-11-07 Derivatives of 2-[(2-alkoxy-6-trifluoromethylpyrimidine-4-yl)- oxymethylene]- phenylacetic acid, method of their synthesis, agent for control of pests and intermediate compounds RU2166500C2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DEP4440930.3 1994-11-17
DE4440930A DE4440930A1 (en) 1994-11-17 1994-11-17 New 2-pyrimidinyl:oxy:methyl:phenyl-3-methoxy-acrylate derivs
DE19526661.7 1995-07-21
DE1995126661 DE19526661A1 (en) 1995-07-21 1995-07-21 New phenylacetic acid derivs. useful as fungicides, insecticides, nematocides and acaricides

Publications (2)

Publication Number Publication Date
RU97110060A true RU97110060A (en) 1999-05-27
RU2166500C2 RU2166500C2 (en) 2001-05-10

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US (1) US5935965A (en)
EP (1) EP0792267B1 (en)
JP (1) JP3973230B2 (en)
KR (1) KR100421400B1 (en)
CN (1) CN1100764C (en)
AR (1) AR001048A1 (en)
AT (1) ATE172196T1 (en)
AU (1) AU698417B2 (en)
BG (1) BG63499B1 (en)
BR (1) BR9509786A (en)
CA (1) CA2204039C (en)
CO (1) CO4650142A1 (en)
CZ (1) CZ288259B6 (en)
DE (1) DE59503946D1 (en)
DK (1) DK0792267T3 (en)
ES (1) ES2124597T3 (en)
HU (1) HU215791B (en)
IL (1) IL115899A (en)
NZ (1) NZ295382A (en)
PL (1) PL183426B1 (en)
RU (1) RU2166500C2 (en)
SK (1) SK281783B6 (en)
TR (1) TR199501451A2 (en)
TW (1) TW308589B (en)
UA (1) UA50725C2 (en)
WO (1) WO1996016047A1 (en)

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