RU96106069A - SOLID METAL HYDROXIDE SOLUTION AND SOLID METAL OXIDE SOLUTION WITH HIGH ASPECT RELATIONS AND METHODS FOR PRODUCING THEM - Google Patents

SOLID METAL HYDROXIDE SOLUTION AND SOLID METAL OXIDE SOLUTION WITH HIGH ASPECT RELATIONS AND METHODS FOR PRODUCING THEM

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Publication number
RU96106069A
RU96106069A RU96106069/02A RU96106069A RU96106069A RU 96106069 A RU96106069 A RU 96106069A RU 96106069/02 A RU96106069/02 A RU 96106069/02A RU 96106069 A RU96106069 A RU 96106069A RU 96106069 A RU96106069 A RU 96106069A
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RU
Russia
Prior art keywords
solid metal
solid solution
metal oxide
high aspect
metal hydroxide
Prior art date
Application number
RU96106069/02A
Other languages
Russian (ru)
Other versions
RU2147556C1 (en
Inventor
Шигео Мията
Рюиши Ишибаши
Ацуя Кавасе
Ясунори Китано
Original Assignee
Татехо Кемикал Индастриз Ко., Лтд.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority claimed from JP7086410A external-priority patent/JP2966755B2/en
Application filed by Татехо Кемикал Индастриз Ко., Лтд. filed Critical Татехо Кемикал Индастриз Ко., Лтд.
Publication of RU96106069A publication Critical patent/RU96106069A/en
Application granted granted Critical
Publication of RU2147556C1 publication Critical patent/RU2147556C1/en

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Claims (5)

1. Твердый раствор гидроксида металла с высоким аспектным отношением формулы 1
Mg1 - M2+ • (OH)2,
где M2+ представляет собой ион по меньшей мере одного двухвалентного металла, выбранный из группы, включающей Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+, x находится в интервале 0,01 < x < 0,5, предпочтительно 0,1 < x < 0,3, отличающийся тем, что кристалл имеет форму гексагональной пластинки, средняя толщина которой составляет 0,01 - 0,5 мкм, средний диаметр - 1 - 10 мкм, а аспектное отношение - не менее 10.
1. Solid solution of metal hydroxide with a high aspect ratio of the formula 1
Mg 1 - M 2+ • (OH) 2 ,
where M 2+ is an ion of at least one divalent metal selected from the group comprising Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ , Cu 2+ , Zn 2+ , x is in the range of 0.01 <x <0.5, preferably 0.1 <x <0.3, characterized in that the crystal has the shape of a hexagonal plate, the average thickness of which is 0.01-0.5 μm, the average diameter is 1-10 μm, and aspect ratio - not less than 10.
2. Твердый раствор оксида металла с высоким аспектным отношением формулы 2
Mg1 - yM2+yO,
где M2+ представляет собой ион по меньшей мере одного двухвалентного металла, выбранный из группы, включающей Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+, y находится в интервале 0,01 < y < 0,5, предпочтительно 0,1 < y < 0,3, отличающегося тем, что кристалл имеет форму гексагональной пластинки, средняя толщина которой составляет 0,01 - 0,5 мкм, средний диаметр - 1 - 10 мкм, а аспектное отношение - не менее 10.
2. A solid solution of a metal oxide with a high aspect ratio of the formula 2
Mg 1 - yM 2+ yO,
where M 2+ is an ion of at least one divalent metal selected from the group consisting of Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ , Cu 2+ , Zn 2+ , y is in the range of 0.01 <y <0.5, preferably 0.1 <y <0.3, characterized in that the crystal has the shape of a hexagonal plate, the average thickness of which is 0.01 - 0.5 μm, the average diameter is 1 - 10 μm, and aspect ratio - not less than 10.
3. Твердый раствор гидроксида или оксида металла по пп.1 и 2, где M2+ в формуле 1 или 2 представляет собой Zn2+.3. A solid solution of a hydroxide or metal oxide according to claims 1 and 2, where M 2+ in the formula 1 or 2 is Zn 2+ . 4. Способ получения твердого раствора гидроксида металла по п.1, включающий гидратирование твердого раствора оксида металла формулы 3, средний диаметр частицы первичного кристалла которого составляет 2 - 10 мкм, в присутствии монокарбоновой кислоты и/или оксимонокарбоновой кислоты в водной среде,
Mg1 - zM2+zO,
где M2+ представляет собой ион по меньшей мере одного двухвалентного металла, выбранный из группы, включающей Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+, z находится в интервале 0,01 < z < 0,5.
4. A method of obtaining a solid solution of a metal hydroxide according to claim 1, comprising hydrating a solid solution of a metal oxide of formula 3, the average particle diameter of the primary crystal is 2-10 microns, in the presence of monocarboxylic acid and / or oximonocarboxylic acid in an aqueous medium,
Mg 1 - zM 2+ zO,
where M 2+ is an ion of at least one divalent metal selected from the group comprising Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ , Cu 2+ , Zn 2+ , z is in the range of 0.01 <z <0.5.
5. Способ получения твердого раствора оксида металла по п.2, включающий обжиг твердого раствора гидроксида металла по п.1 при температуре не менее 400oC.5. A method of obtaining a solid solution of a metal oxide according to claim 2, comprising burning a solid solution of a metal hydroxide according to claim 1 at a temperature of at least 400 o C.
RU96106069A 1995-03-17 1996-03-15 Solid metal hydroxide solution and solid metal oxide solution with high aspect ratios and methods for preparation thereof RU2147556C1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP7086410A JP2966755B2 (en) 1995-03-17 1995-03-17 High aspect ratio metal hydroxide or metal oxide solid solution and method for producing them
JP7-86410 1995-03-17

Publications (2)

Publication Number Publication Date
RU96106069A true RU96106069A (en) 1998-05-27
RU2147556C1 RU2147556C1 (en) 2000-04-20

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Country Status (13)

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US (1) US5759509A (en)
EP (1) EP0732302B1 (en)
JP (1) JP2966755B2 (en)
KR (1) KR100218989B1 (en)
CN (2) CN1075042C (en)
DE (1) DE69603761T2 (en)
ES (1) ES2136365T3 (en)
IL (1) IL117434A (en)
IN (1) IN187186B (en)
MY (1) MY118740A (en)
RU (1) RU2147556C1 (en)
SG (1) SG45413A1 (en)
TW (1) TW336217B (en)

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IL124061A (en) 1997-04-15 2001-01-11 Taheto Chemical Ind Co Ltd Solid solutions of metal hydroxide and metal oxide and their preparation
CN1177760C (en) * 1998-12-14 2004-12-01 协和化学工业株式会社 Magnesium hydroxide particles, process for producing same, and resin composition contg. such particles
WO2003022954A1 (en) * 2001-09-10 2003-03-20 Japan Represented By President Of Tokyo Institute Of Technology Method for producing ultraviolet absorbing material
JP4828113B2 (en) * 2004-11-05 2011-11-30 株式会社海水化学研究所 Nitrate nitrogen reducing agent
FR2888243B1 (en) * 2005-07-06 2007-09-14 Michelin Soc Tech RUBBER COMPOSITION FOR REINFORCED PNEUMATIC MAGNESIUM HYDROXIDE PLATELETS.
US7892447B2 (en) * 2006-08-11 2011-02-22 Aqua Resources Corporation Nanoplatelet metal hydroxides and methods of preparing same
JP5839602B2 (en) * 2010-10-12 2016-01-06 協和化学工業株式会社 High aspect ratio magnesium hydroxide
TWI583779B (en) * 2012-01-20 2017-05-21 Kyowa Chem Ind Co Ltd Heat transfer modifier
CN109906202B (en) * 2016-09-07 2022-01-18 协和化学工业株式会社 Fine-particle composite metal hydroxide, fired product thereof, process for producing the same, and resin composition thereof

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US3803191A (en) * 1971-03-24 1974-04-09 Graham Magnetics Inc Acicular salts and their preparation
JPH085990B2 (en) * 1991-02-06 1996-01-24 株式会社海水化学研究所 Flame retardant, and flame retardant resin and / or rubber composition
US5401442A (en) * 1991-02-06 1995-03-28 Kabushiki Kaisha Kaisui Kagau Kenkyujo Composite metal hydroxide and its use
JP3157545B2 (en) * 1991-06-06 2001-04-16 株式会社海水化学研究所 Fibrous composite metal hydroxide and method for producing the same
JPH05112669A (en) * 1991-10-18 1993-05-07 Kyowa Chem Ind Co Ltd Flame retardant, its production and flame-retardant resin composition incorporated with the same
JP3154535B2 (en) * 1991-12-24 2001-04-09 株式会社海水化学研究所 Composite metal hydroxide and use thereof
JP2937602B2 (en) * 1992-01-13 1999-08-23 株式会社海水化学研究所 Thermal conductive composite metal oxide and use thereof
JP3115934B2 (en) * 1992-03-16 2000-12-11 協和化学工業株式会社 Flame retardant aid, flame retardant and flame retardant resin composition
JP3384816B2 (en) * 1992-03-30 2003-03-10 株式会社海水化学研究所 Composite metal oxide-containing resin composition and method for producing the oxide

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