RU94041192A - Металлоцены, способ их получения, способ и катализатор для получения полиолефинов, полимерное формованное изделие - Google Patents

Металлоцены, способ их получения, способ и катализатор для получения полиолефинов, полимерное формованное изделие

Info

Publication number
RU94041192A
RU94041192A RU94041192/04A RU94041192A RU94041192A RU 94041192 A RU94041192 A RU 94041192A RU 94041192/04 A RU94041192/04 A RU 94041192/04A RU 94041192 A RU94041192 A RU 94041192A RU 94041192 A RU94041192 A RU 94041192A
Authority
RU
Russia
Prior art keywords
production
catalyst
metallocenes
polyolefins
molded article
Prior art date
Application number
RU94041192/04A
Other languages
English (en)
Other versions
RU2147587C1 (ru
Inventor
Кюбер Франк
De]
Аулбах Михаель
Бахманн Бернд
Шпалек Вальтер
Винтер Анлреас
Original Assignee
Хехст АГ (DE)
Хехст АГ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Хехст АГ (DE), Хехст АГ filed Critical Хехст АГ (DE)
Publication of RU94041192A publication Critical patent/RU94041192A/ru
Application granted granted Critical
Publication of RU2147587C1 publication Critical patent/RU2147587C1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Изобретение относится к многоядерному маталлоценовому соединению формулы, способу его получения и его применению в составе катализатора для полимеризации олефинов.

Claims (1)

  1. Изобретение относится к многоядерному маталлоценовому соединению формулы
    Figure 00000001
    , способу его получения и его применению в составе катализатора для полимеризации олефинов.
RU94041192A 1993-11-24 1994-11-23 Металлоцены, способ их получения, каталитическая система, способ получения полиолефинов и полимерное формованное изделие RU2147587C1 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DEP4340018.3 1993-11-24
DE4340018A DE4340018A1 (de) 1993-11-24 1993-11-24 Metallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
DEP4344687.6 1993-12-27
DEP4344708.2 1993-12-27

Publications (2)

Publication Number Publication Date
RU94041192A true RU94041192A (ru) 1996-12-27
RU2147587C1 RU2147587C1 (ru) 2000-04-20

Family

ID=6503314

Family Applications (1)

Application Number Title Priority Date Filing Date
RU94041192A RU2147587C1 (ru) 1993-11-24 1994-11-23 Металлоцены, способ их получения, каталитическая система, способ получения полиолефинов и полимерное формованное изделие

Country Status (3)

Country Link
DE (1) DE4340018A1 (ru)
RU (1) RU2147587C1 (ru)
ZA (1) ZA949285B (ru)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19527047A1 (de) * 1995-07-25 1997-01-30 Danubia Petrochem Deutschland Metallocene mit silylsubstituierten Brücken und deren Einsatz für die Olefinpolymerisation
DE19544828A1 (de) * 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere

Also Published As

Publication number Publication date
ZA949285B (en) 1995-06-30
DE4340018A1 (de) 1995-06-01
RU2147587C1 (ru) 2000-04-20

Similar Documents

Publication Publication Date Title
RU94045142A (ru) Металлоцены, содержащая их каталитическая система, способ полимеризации олефинов, полиолефин, формованное изделие
RU94045143A (ru) Металлоцены, содержащая их каталитическая система, способ получения полиолефинов, полиолефин
RU94033101A (ru) Способ получения полимеров этилена и продукты, полученные из них
NO993295D0 (no) Polymerisasjon av olefiner
BR0016725B1 (pt) sistema catalisador compreendendo pelo menos um composto organometálico, pelo menos uma base de lewis, pelo menos um suporte e pelo menos um composto de organoelemento, uso do mesmo, e, processo para preparar poliolefinas.
RU94046276A (ru) Способ получения этиленового полимера
RU95105023A (ru) Ароматические сополиамиды, способ их получения, формованное изделие и способ его получения
DE58906565D1 (de) Verfahren zur Herstellung eines Ethylen-Propylen-Copolymers.
ATE127128T1 (de) Hafnium-metalocen-katalysator für olefinpolymerisation.
FI945486A0 (fi) Metalloseeneja, menetelmä niiden valmistamiseksi sekä niiden käyttö katalyytteinä
HUP0003363A2 (hu) Alfa-olefinek előállítása
RU94043772A (ru) Пропинил-диароматические соединения, фармацевтические и косметические составы на их основе
KR927003650A (ko) 트리메틸알루미늄 혼합물, 실리카겔 및 메탈로센으로부터 제조된 올레핀 중합 촉매
EP2261269A3 (en) Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene
RU95103105A (ru) Ацетамиды, способ их получения, содержащая их фармацевтическая композиция и способ ее получения
RU95106684A (ru) Би-ароматические ацетиленовые соединения с группой адамантила, фармацевтическая и косметическая композиция на их основе
DE69024463D1 (de) Verfahren zur Herstellung von Metallocenen
RU94040253A (ru) Катализаторная система на основе металлоцена для полимеризации алкенов с 2 - 10 атомами углерода и способ получения полимеров алкена с 2 - 10 атомами углерода
DE69410614T2 (de) Bis-naphthalimide für die behandlung von krebs
RU94041192A (ru) Металлоцены, способ их получения, способ и катализатор для получения полиолефинов, полимерное формованное изделие
RU94026252A (ru) Модифицированные эластомерные полипропилены, способ модификации эластомерных полипропиленов, композиция на основе полиолефинов и неолефиновых термопластов
BR0115359A (pt) Método para a preparação de uma composição catalisadora e seu uso em um processo de polimerização
CY1112050T1 (el) Νεα 2-αλογονοποιημενα παραγωγα της 5-0- δεσοσαμινυλερυθρονολιδης α, η διαδικασια της παρασκευης τους και η εφαρμογη τους ως φαρμακευτικα προϊοντα
MY134869A (en) Bridged metallocene compounds, process for their preparation and their use as catalysts for the polymerization of olefins
RU94014631A (ru) Производные 4-хиномиодигидропиридина, смесь их изомеров или отдельные изомеры и их соли