RU2721135C2 - Composition for making paper, method and use thereof - Google Patents

Abstract

FIELD: paper industry.SUBSTANCE: papermaking additive composition contains a treated fermented microbial supernate and one or more non-ionic surfactants. Composition does not contain any active enzymes and living bacteria. pH of the composition is less than 5.0.EFFECT: improved separation of cellulose fibers from cellulose pulp, removal of impurities and/or contaminants from cellulose pulp and/or from paper material and removal of printing ink from cellulose pulp and/or from paper material.29 cl, 4 dwg, 7 ex

Description

[001] This application claims priority according to provisional application for US patent 62/208662, filed August 22, 2015, the contents of which are fully incorporated into this application by reference.

[002] Paper is an extremely important, useful, and multifunctional material, and tens of thousands of different products are produced annually on the basis of paper. The paper may be impregnated, coated, creped, moisture resistant, waxed, glossy, photosensitive, curved, curled, wrinkled, cut, dissolved, macerated, glued or embossed. Also, paper can be coated with fabric, plastic and metal. To systematize, various products made of paper can be divided into five broad categories: 1) newsprint and magazines; 2) printed and writing paper; 3) household and hygiene paper; 4) packaging materials and products; and 5) special paper. Accustomed to the fact that paper is a natural part of our daily lives, we sometimes forget how much our lives depend on this most important, renewable and developing raw material.

[003] The practical benefits of paper products have had a significant impact on the global economy. In 2015, the global production of paper-based products exceeded 300 million tons and was estimated at 500 billion US dollars. Corrugated and cardboard containers account for approximately 30% of production revenue. Other main products include cardboard (15%), bags, coated paper and impregnated paper (10%), and hygiene paper products (5%). The global pulp and paper industry is a multi-billion dollar industry, most of which are in the United States and China, producing more than 40% of all global products. However, Japan, Germany, Canada, South Korea, Sweden, Finland, Brazil, and Indonesia also have large pulp and paper industries. The main exporting and importing countries are the USA and Germany.

[004] In addition to being one of the dominant forces in the industry, the USA also consumes more paper products than any other country in the world, using one third (or approximately 100 million tons) of paper products produced in 2015. Such a high level The use and consumption of paper products is important for the US economy. In the United States, 450 manufacturing plants produce approximately $ 2 billion worth of products. About 150,000 people are directly employed in this industry, which creates a wage fund approaching 10 billion US dollars in volume. The pulp and paper industry is estimated to be the tenth largest employer in the United States.

[005] Paper manufacturing is a developed industry. The main components and processes that are currently used in the pulp and paper industry have been used for almost 100 years. Additionally, the production of pulp and paper is a large-scale production, which uses huge amounts of natural resources such as water and wood, chemicals and energy to produce pulp and paper. Thus, the development of industry, the large volume of production, the widespread use of material and energy resources, as well as the regulation of environmental protection, create a serious economic burden on manufacturers. However, innovations that improve or optimize productivity and / or paper production efficiency are still important and valuable. For example, because of the large volume of paper production, innovations that increase productivity and / or efficiency would lead to savings and / or increased profits of tens, if not hundreds of millions of dollars. In addition, innovations that reduce large amounts of energy consumption, as well as reduce the production of large amounts of wastewater and waste, would address important environmental issues that would also reduce environmental impact and reduce the economic burden. Thus, there is a great need to improve the papermaking process.

[006] Accordingly, there is a great need for paper manufacturing additives that are non-toxic, biodegradable and effective in improving or optimizing paper production productivity and / or efficiency.

Summary of invention

[007] Aspects of the present disclosure disclose additive compositions for papermaking. The disclosed paper manufacturing additive compositions include a processed fermented microbial supernatant and one or more nonionic surfactants. The disclosed paper manufacturing additive compositions may, if desired, also include one or more anionic surfactants. Additionally, the disclosed paper manufacture additive compositions may, if desired, also include a cellulose-cleaving enzyme. The disclosed paper additive compositions are biodegradable and generally non-toxic to humans, mammals, plants, and the environment.

[008] Aspects of the present disclosure disclose a papermaking additive kit. The disclosed papermaking additive kit includes the papermaking additive composition disclosed herein and instructions for using the compositions to improve or optimize paper production productivity and / or efficiency.

[009] Aspects of the present disclosure disclose methods for separating fibers from pulp. Disclosed methods include introducing an effective amount of the composition disclosed in this application into the pulp during the cooking and / or paper production phase. This use increases the separation of fibers from the raw material in the pulp.

[010] Aspects of the present disclosure disclose methods for removing impurities and / or contaminants from pulp and / or paper material. Disclosed methods include introducing an effective amount of the composition disclosed herein into pulp pulp during the cooking and / or paper production phase. Such an application removes impurities and / or contaminants from the pulp and / or paper material.

[011] Aspects of the present disclosure disclose methods for bleaching pulp and / or pulp material. Disclosed methods include introducing an effective amount of the composition disclosed herein into pulp pulp during the cooking and / or paper production phase. This use removes ink from the pulp and / or paper material.

[012] Aspects of the present disclosure disclose the use of a paper manufacture additive composition disclosed herein for separating fibers from pulp. The disclosed application includes introducing an effective amount of the composition disclosed herein into the pulp during the cooking and / or paper production phase to improve the separation of the pulp from the raw material in the pulp.

[013] Aspects of the present disclosure disclose the use of a paper manufacture additive composition disclosed herein to remove impurities and / or contaminants from pulp and / or paper material. The disclosed application includes introducing an effective amount of the composition disclosed herein into the pulp during the pulping and / or paper production phase to remove ink from the pulp and / or paper material.

[014] Aspects of the present disclosure disclose the use of a paper manufacture additive composition disclosed herein to bleach pulp and / or paper material. The disclosed application includes introducing an effective amount of the composition disclosed herein into the pulp during the pulping and / or paper manufacturing phase to remove ink from the pulp and / or paper material.

Brief Description of the Drawings

[015] FIG. 1A-C show a time-dependent improvement in the homogenization of fibers treated with the paper additive formulation disclosed herein in the cooking process; FIG. 1A shows fiber creepiness after 10 minutes; and FIG. 1B shows fiber creepiness after 20 minutes; FIG. 1C shows fiber creepiness after 30 minutes.

[016] FIG. 2 shows the purified fibers after processing the paper manufacture additive composition disclosed herein.

DETAILED DESCRIPTION OF THE INVENTION

[017] Paper is made from cellulose fibers, which are obtained from plant material, such as, for example, wood from deciduous or coniferous trees, rags, flax, cotton fluff and / or bagasse. Recycled paper can be reused to produce new paper products, where it is often mixed with fresh fibers. To give the special qualities of the finished paper products, you can use synthetic materials. Other products made from cellulose fibers include diapers, viscose, cellulose acetate and cellulose esters, which are used to make fabrics, packaging films and explosives.

[018] Typically, wood consists of 40% -50% of cellulose, 25% -35% of hemicellulose, 15% -30% of lignin and 2% -10% of extractables. In paper production, one of the main steps is to separate the pulp from the remaining components through extraction. As a rule, the higher the content of hemicellulose, lignin and extractable substances in paper, the lower its quality.

[019] Most modern paper production processes can be roughly divided into five separate working phases: 1) the cooking phase; 2) molding phase; 3) the pressing phase; 4) drying phase; and 5) the calendaring phase. The last four phases can be combined under the name “paper production phase”. The raw materials are processed and cleaned during the cellulosic pulp production phase to separate the cellulose fibers from lignin, extractables and other impurities in the raw material to form a wet pulp or cellulosic pulp containing about 99% water and called paper pulp. During the spinning phase, also known as the “wet phase”, the pulp is folded onto a movable net, also known as the “long net”, to dewater the pulp (by gravity or in vacuum) to form a continuous network of fibers. During the pressing phase, a network of fibers passes between the large shafts under high pressure to displace as much water as possible and form a pressed sheet. The pressed sheet then goes into the drying phase, during which it passes through a series of steam-heated drying cylinders, which reduces the water content to about 6%. Finally, during the calendering phase, the dried paper is made smooth and flat under high load and pressure using steel rolls to produce a finished uncut paper product. Uncut paper is rolled up for use in web presses such as newspaper presses, or cut into strips or cut into pieces to obtain sheets of paper for use in sheetfed presses.

[020] During the cooking phase, beneficial fibers are separated from lignin, extractables (eg, oleoresins and waxes) and other waste materials using chemical and / or mechanical procedures. For example, in chemical procedures, raw materials are processed into smaller particles, placed in a pressure boiler, called a digester, together with chemicals (with white liquor) and water, and processed under high pressure steam. Cooking destroys lignin-binding material, separating cellulosic fibers from the rest of the feed. The separated raw materials and spent chemical reagents are then sent to a reduction process, where the chemical reagents and energy for pulping are recovered using more stages of evaporation to concentrate the spent liquid for pulping (black liquor), which can then be burned as fuel.

[021] In mechanical procedures, the feed passes through a defibrer, where it is ground using a rotating stone in water lubricant, or where the heat generated during grinding softens the lignin that binds the fibers, and the mechanical forces separate the fibers to produce wood pulp. Alternatively, the feed passes through a refiner, where it is subjected to intense shearing forces arising between the rotating steel disk and the fixed plate. Raised knives are located on the surface of the disks, and the disks move relative to each other with a narrow gap. This action separates the fibers from the rest of the feed. Cutting also unravels the fibers, as a result of which the fibrils of the fibers are partially separated and protrude outward. Raw materials can also be softened by heating (thermomechanical softening) or impregnated by chemical treatment before being introduced into a digester or refiner to facilitate fiber formation (chemical thermomechanical softening).

[022] Regardless of whether the fibers are separated by a chemical, mechanical procedure, or a combination thereof, the treated pulp is pumped through a series of storage tanks, commonly called pools, for further processing. For example, cellulose can be washed to clean the fibers and remove residual lignin and other impurities, as well as sieved to remove remaining fiber bundles and achieve a more uniform quality and consistency. The treated cellulosic pulp can also be mixed in a mixing basin with other treated cellulosic pulp obtained from other sources of raw materials or from recycled paper products to obtain a mixed processed cellulosic pulp. Depending on the type of finished paper product you receive, the treated cellulosic pulp can also be passed through a series of pools in which various fillers are added to the treated cellulosic pulp to improve, for example, opacity, whiteness, mechanical strength, smoothness, ink absorption, and other properties. . For example, you can add bleach or other bleaching agents to bleach fibers and increase whiteness, you can add dyes and pigments to obtain colored paper, opacity agents such as calcium carbonate, clay and titanium dioxide, increasing opacity, which allows you to print on both sides. a sizing agent can be added to increase moisture resistance. The treated cellulosic pulp can also be processed to remove ink (discolor) and other impurities, which is usually required if the starting material was recycled used paper products. Finally, the pH can be adjusted and the treated cellulosic pulp diluted with water to form a homogeneous pulp for subsequent processing.

[023] The main purpose of the cooking phase is to remove from the cellulosic pulp the maximum amount of lignin, extractables and other wastes to increase the amount of separated pulp fibers present in the pulp without compromising the integrity and strength of the fibers, which ensures high fiber purity and quality. Another important goal of the cooking phase is to increase the surface area of the fibers, due to the partial separation of the fibrils of the fibers and their bulging outward, which contributes to their connection. Additionally, and especially this applies to recycled paper, another goal is to remove ink and adhesive contaminants that may affect the cleanliness and quality of the final paper product.

[024] Without wishing to be bound by their theory, the authors of the present invention believe that the paper additive additives disclosed in the present invention dissolve, disperse or otherwise destroy one or more components of the raw materials used to make the pulp. This mechanism of action is probably partly related to the ability of the paper manufacture additive compositions disclosed herein to destroy lignin and / or facilitate the separation of individual cellulose or hemicellulose fibers from fiber bundles. The end result is an improved separation of cellulose or hemicellulose fibers from fiber bundles, which ultimately leads to the production of better paper products in a more efficient and economical way. This mechanism of action is also probably partly related to the ability of paper additives additives disclosed in this application to destroy printing ink and other organic compounds considered impurities in raw materials obtained from recycled paper products.

[025] Regardless of the principle of operation, the paper additive compositions disclosed in this application, methods and applications provide alternative paper production methods that are not based on chemicals that are toxic to humans or the environment. Additionally, paper additive compositions, methods and uses disclosed in this application provide improved destruction of lignin and other impurities, which facilitates the recycling of waste water for reuse during the pulping or paper production phase, which also benefits humans and the environment. Also disclosed in this application are paper additives additives, methods and applications that do not require large energy expenditures, which can reduce overall energy consumption, which also benefits humans and the environment. Rather, the paper-additive additives disclosed in this application, methods and applications are likely to improve the separation of cellulose fibers, increase the surface area of the fibers, and also remove ink, adhesive and other impurities without sacrificing the integrity and strength of the fibers to achieve high purity and fiber quality. In addition, the paper additive compositions disclosed in the present application were found to be substantially non-toxic to humans and domestic animals and having minimal adverse effects on wildlife and the environment.

[026] Aspects of the present description of the invention partially disclose an additive composition for papermaking. The disclosed paper manufacturing additive compositions include a processed fermented microbial supernatant and one or more nonionic surfactants. The processed fermented microbial supernatant does not contain any living microorganisms, such as yeast or bacteria, and does not contain active enzymes, proenzymes that can be activated, or any enzymatic activity. Additionally, the composition of the additive for paper production does not contain any living microorganisms, such as yeast or bacteria, and also does not contain active enzymes, proenzymes that can be activated, or any enzymatic activity. The paper composition additive composition disclosed herein can be used in any individual or commercial paper manufacturing process.

[027] In one aspect of the present invention, the paper additive composition disclosed herein includes, for example, from about 75% to about 99% of the processed fermented microbial supernatant and from about 1% -25% of one or more nonionic surfactants. In another aspect of the present invention, the paper additive composition disclosed herein includes, for example, from about 80% to about 97% of the treated fermented microbial supernatant and from about 3% -20% of one or more non-ionic surfactants. In another aspect of the present invention, the paper additive composition disclosed herein includes, for example, from about 85% to about 95% of the treated fermented microbial supernatant and from about 5% -15% of one or more non-ionic surfactants. In another aspect of the present invention, the paper manufacture additive composition disclosed herein includes, for example, from about 87% to about 93% of the treated fermented microbial supernatant and from about 7% -13% of one or more non-ionic surfactants. In another aspect of the present invention, the paper additive composition disclosed herein includes, for example, from about 88% to about 92% of the treated fermented microbial supernatant and from about 8% -12% of one or more non-ionic surfactants. In another aspect of the present invention, the paper additive composition disclosed herein includes, for example, from about 89% to about 91% of the treated fermented microbial supernatant and from about 9% -11% of one or more non-ionic surfactants.

[028] Aspects of the present description of the invention partially disclose a fermented microbial supernatant. The fermented microbial supernatant disclosed herein can be obtained by culturing a yeast strain, a bacterial strain, or a combination of a yeast strain and a bacterial strain in a fermentation medium containing a sugar source, malt and a magnesium salt. In one aspect of the present invention, a single yeast strain is used in the fermentation medium. In another aspect of the present invention, two or more different strains of yeast are used in a fermentation medium. In another aspect of the present invention, a single bacterial strain is used in the fermentation medium. In another aspect of the present invention, two or more different strains of bacteria are used in a fermentation medium. In another aspect of the present invention, one or more different strains of yeast are used simultaneously with one or more different strains of bacteria in the fermentation medium. In another aspect of the present invention, two, three, four, five or more different strains of yeast are used simultaneously with two, three, four, five or more different strains of bacteria in the fermentation medium.

[029] The sugar source includes, but is not limited to, sucrose from molasses, unrefined cane sugar, soybeans, or mixtures thereof. Molasses typically contains up to about 50% sucrose in addition to reducing sugars such as glucose and maltose, as well as ash, organic sugar and a little water. The presence of sugars found in molasses type is important to stimulate the activity of enzymes, yeast and bacteria that form them. Although raw cane sugar molasses is preferred, other molasses such as beet molasses, honey molasses and the like can also be used as a natural source of materials necessary for enzymatic fermentation. The amount of molasses used in preparing the fermentation medium disclosed in this application is from about 40% to about 80%, and preferably from about 55% to about 75% by weight. It will be appreciated that the particular amount of molasses used may vary to obtain the optimum desired compositions.

[030] Unrefined cane sugar is a sugar product that has not been refined and contains molasses residues as well as other natural impurities. Although not well understood, it has been found that the presence of unrefined sugar in a fermentation reaction provides significantly improved properties compared to refined sugars, which contain residual chemicals used in bleaching and final refining and refining, which may have some harmful effects on yeast and malt enzymes. It has been found that the optimal biological and enzymatic properties of the disclosed fermentation medium are improved if some of the fermentable materials present in the mixture include unrefined sugar. The amount of unrefined sugar used in the preparation of the fermentation medium disclosed herein may be from about 10% to about 40% by weight, and preferably from about 10% to about 30% by weight. It will be appreciated that the specific amount of unrefined sugar used may vary to obtain the optimum desired compositions.

[031] The necessary enzymes that contribute to the fermentation reaction are obtained from malt or yeast and / or bacteria produce them. The particular type of malt used is preferably malt with active diastases, which contains enzymes, including diastase, maltase and amylase. It is also believed that malt increases the activity of yeast and / or bacteria in addition to the role in the overall effectiveness and activity of the enzymatic composition in the mixture of the final product. The amount of malt used in obtaining the fermentation medium disclosed in this application may be from about 3% to about 15% by weight, and preferably from about 7% to about 12% by weight. It will be appreciated that the particular amount of malt used may vary to obtain the optimum desired compositions.

[032] Fermentation is a metabolic process that leads to the destruction of carbohydrates and other complex organic substances to simpler substances such as sugars, acids, gases or alcohol. Fermentation can occur in yeast, bacteria and molds. Fermentation includes ethanol fermentation and lactic acid fermentation. Fermentation of lactic acid includes homoenzymatic fermentation and heteroenzymatic fermentation.

[033] Yeast is any fermenting fungus that can form the necessary enzymes for the fermentation reaction, which leads, for example, to the conversion of carbohydrates to carbon dioxide and alcohols. Active yeast during the fermentation reaction form a series of enzymes, including both hydrolytic and oxidative enzymes, such as invertase, catalase, lactase, maltase, carboxylase and others. Yeast includes yeast strains used in fermentation in the manufacture of food products, such as, for example, bean fermentation, dough fermentation, grain fermentation, vegetable fermentation, fruit fermentation, honey fermentation, fermentation with honey the use of dairy products, fermentation using fish, fermentation using meat and fermenting using tea. A non-exhaustive list of specific yeast genera used in the fermentation reaction disclosed herein includes, but is not limited to, Brettanomyces, Candida, Cyberlindnera, Cystofilobasidium, Debaryomyces, Dekkera, Fusarium, Geotrichum, Issatchenkia, Kazachstania, Kloeckeomy, Leucerverium, Kloeckeomy, Kluevericium, Kluevericium, Kluevericium, Kluevericium, Kluevericium, Kluevericium, Kluevericium, Klueverium, Klueverium, Kluever, Kluever Pediococcus, Penicillium, Pichia, Rhizopus, Rhodosporidium, Rhodotorula, Saccharomyces, Schizosaccharomyces, Thrichosporon, Torulaspora, Torulopsis, Verticillium, Yarrowia, Zygosaccharomyces and Zygotorulaspora. Types of yeast applicable in the fermentation reaction disclosed in this application include, but are not limited to. A non-exhaustive list of specific yeast species used in the fermentation reaction disclosed in this application includes, but is not limited to B. anomalus, B. bruxellensis, B. claussenii, B. custersianus, B. naardenensis, B. nanus, C. colliculosa, C. exiguous, C. humicola, C. kefyr, C. krusei, C. milleri, C. mycoderma, C. pelliculosa, C. rugose, C. stellate, C. tropicalis, C. utilis, C. valida, C. vini, C. zeylanoides, Cb. mrakii, Cs, infirmominiatum, D. hansenii, D. kloeckeri, Dk. anomala, Dk. bruxellensis, F. domesticum, G. candidum, I. orientalis, K. exigua, K. unispora, Kl. africana, Kl. apis, Kl. javanica, Ku. lactis, Ku. marxianus, Ku. marxianus, L. lecanii, M. hiemalis, M. plumbeus, M. racemosus, M. racemosus, N. intermedia, P. cerevisiae, Pn. album, Pn. camemberti, pn. caseifulvum, Pn. chrysogenum, Pn. commune, Pn. nalgiovense, Pn. roqueforti, Pn. solitum, Pi. fermentans, R. microspores, Rs. infirmominiatum, Rt. glutinis, Rt. minuta, Rt. rubra, S. bayanus, S. boulardii, S. carlsbergensis, S. cerevisiae, S. eubayanus, S. paradoxus, S. pastorianus, S. rouzii, S. uvarum, Sc. pombe, Th. beigelii, T. delbrueckii, T. franciscae, T. pretoriensis, T. microellipsoides, T. globosa, T. indica, T. maleeae, T. quercuum, To. versatilis, V. lecanii, Y. lipolytica, Z. bailii, Z. bisporus, Z. cidri, Z. fermentati, Z. florentinus, Z. kombuchaensis, Z. lentus, Z. mellis, Z. microellipsoides, Z. mrakii, Z. pseudorouxii and Z. rouxii and Zt. florentina. A preferred yeast species is Saccharomyces cerevisiae, commonly known as “baker's yeast”.

[034] Bacteria are any fermenting bacteria that can form the necessary enzymes for the fermentation reaction, which leads, for example, to the formation of alcohols, such as ethanol, or acids, such as acetic acid, lactic acid and / or succinic acid. A non-exhaustive list of specific bacterial genera used in the fermentation reaction disclosed herein includes, but is not limited to, Acetobacter, Arthrobacter, Aerococcus, Bacillus, Bifidobacterium, Brachybacterium, Brevibacterium, Barnobacterium, Carnobacterium, Coryneocacterobluceglu, Entericactum, Entericactum, Entericactum Halomonas, Kocuria, Lactobacillus, Lactococcus, Leuconostoc, Macrococcus, Microbacterium, Micrococcus, Neisseria, Oenococcus, Pediococcus, Propionibacterium, Proteus, Pseudomonas, Psychrobacterococococococcus, Salmonella, Sporolactobococococococcus, Strobocococococcus, Salmonella, Sporolactobocococococcus, A non-exhaustive list of specific types of bacteria used in the fermentation reaction disclosed in this application includes, but is not limited to A. aceti, A. fabarum, A. lovaniensis, A. malorum, A. orientalis, A. pasteurianus, A. pasteurianus, A. pomorum, A. syzygii, A. tropicalis, Ar. arilaitensis, Ar. Bergerei, Ar. Globiformis, Ar. nicotianae, Ar. variabilis, B. cereus, B. coagulans, B. licheniformis, B. pumilus, B. sphaericus, B. stearothermophilus, B. subtilis, B. adolescentis, B. animalis, B. bifidum, B. breve, B. infantis, B. lactis, B. longum, B. pseudolongum, B. thermophilum, Br. alimentarium, Br. alimentarium, Br. tyrofermentans, Br. tyrofermentans, Bv. aurantiacum, Bv. casei, Bv. linens, C. divergens, C. maltaromaticum, C. piscicola, C. ammoniagenes, Co. casei, Co.flavescens, Co. mooreparkense, Co. variabile, E. faecalis, E. faecium, G. azotocaptans, G. diazotrophicus, G. entanii, G. europaeus, G. hansenii, G. johannae, G. oboediens, G. xylinus, Gl. oxydans, H. alvei, Hl. elongate, K. rhizophila, K. rhizophila, K. varians, K. varians, L. acetotolerans, L. acidifarinae, L. acidipiscis, L. alimentarius, L. brevis, L. bucheri, L. cacaonum, L. casei, L. cellobiosus, L. collinoides, L. composti, L. coryniformis, L. crispatus, L. curvatus, L. delbrueckii, L. dextrinicus, L. diolivorans, L. fabifermentans, L. farciminis, L. fermentum, L. gasseri, L. ghanensis, L. hammesii, L. harbinensis, L. helveticus, L. hilgardii, L. homohiochii, L. jensenii, L. johnsonii, L. kefiranofaciens, L. kefiri, L. kimchi, L. kisonensis, L. kunkeei, L. mali, L. manihotivorans, L. mindensis, L. mucosae, L. nagelii, L. namuresis, L. nantesis, L. nodensis, L. oeni, L. otakiensis, L. panis, L. parabrevis, L. parabuchneri, L. paracasei, L. parakefiri, L. paralimentarius, L. paraplantarum, L. pentosus, L. perolens, L. plantarum, L. pobuzihii, L. pontis, L. rapi, L. reuteri, L. rhamnosus, L. rossiae, L. sakei, L. salivarius, L. sanfranciscensis, L. satsumensis, L. secaliphilus, L. senmaizu kei, L. siliginis, L. similis, L. spicheri, L. suebicus, L. sunkii, L. tucceti, L. vaccinostercus, L. versmoldesis, L. yamanashiensis, Lc. lactis, Lc. raffinolactis, Le. carnosum, Le. citreum, Le. fallax, Le. holzapfelii, Le. inhae, Le. kimchi, Le. lactis, Le. mesenteroides, Le. palmae, Le. Pseudomesenteroides, M. caseolyticus, Mb. foliorum, Mb gubbeenense, Mc. luteus, Mc. lylae, P. acidilactici, P. pentosaceusus, P. acidipropionici, P. freudenreichii, P. jensenii, P. thoenii, Pr. vulgaris, Ps. fluorescens, Py. celer, S. carnosus, S. condiment, S. equorum, S. fleurettii, S. piscifermentans, S. saphrophyticus, S. sciuri, S. simulans, S. succinus, S. vitulinus, S. warneri, S. xylosus, St. cremoris, St. gallolyticus, St. salivarius, St. thermophiles, St. griseus, T. halophilus, T. koreensis, W. beninensis, W. cibaria, W. fabaria, W. ghanesis, W. koreensis, W. paramesenteroides, W. thailandensis and Z. mobilis.

[035] Molds are any fermenting molds that can form the necessary enzymes for the fermentation reaction, which leads, for example, to the formation of alcohols, such as ethanol, or acids, such as acetic acid, lactic acid and / or succinic acid. A non-exhaustive list of specific molds used in the fermentation reaction disclosed herein includes, but is not limited to Aspergillus. A non-exhaustive list of specific mold species used in the fermentation reaction disclosed in this application includes, but is not limited to A. acidus, A. fumigatus, A. niger, A. oryzae, and A. sojae.

[036] It is believed that the actual amount of different types of formed enzymes depends on a number of factors, including the type of molasses and sugar used to produce the fermentation mixture. However, it is believed that the use of molasses and unrefined sugar provides optimal yield and enzyme activity. In one embodiment of the present invention, the amount of yeast used to produce the fermentation medium disclosed herein may be from about 0.2% to about 5% by weight, and preferably from about 1% to about 3% by weight. It will be appreciated that the specific amount of yeast used may vary to obtain the optimal desired compositions.

[037] The presence of a small amount of an inorganic catalyst, such as a magnesium salt, increases the activity of enzymes not only during the fermentation reaction, but also after in the product composition when exposed to organic waste and its destruction. A preferred magnesium salt is magnesium sulfate. The amount of magnesium salt used in preparing the fermentation medium disclosed in this application may be from about 0.1% to about 5% by weight and preferably from about 1% to about 3% by weight. It will be appreciated that the particular amount of magnesium salt used may vary to obtain the optimal desired compositions.

[038] A suitable amount of warm water is added to molasses, sucrose and magnesium salt to obtain a fermented microbial supernatant. Although the specific amount of water used is not critical, usually a suitable amount exceeds about 2-20 times the weight of the remaining ingredients used in the fermentation reaction of the fermentation medium. This amount of water is sufficient to allow easy mixing, as well as to activate yeast, bacteria and / or molds and to dissolve other materials. In addition, the water temperature should not be too high, since heating inactivates the malt and yeast enzymes necessary for fermentation. Therefore, the use of water with a temperature above 65 ° C should be avoided; a preferred temperature is in the range of from about 25 ° C to about 45 ° C. The use of cold water can cause the fermentation rate to be excessively low, so this should be avoided in cases where the reaction rate should be high. After mixing and dissolving the molasses, sugar and magnesium salt efficiently, malt and yeast are added, the mixture is stirred and left until the fermentation is almost complete. The reaction time may be from about 2 to about 5 days at a temperature of from about 20 ° C to about 45 ° C. The completion of fermentation can be determined by stopping the formation of gas bubbles in the reaction mixture. After the fermentation reaction is completed, the fermented microbial culture is centrifuged to remove the “precipitate” formed during fermentation. Formed fermented supernatant (typically from about 90% to about 98% by weight) is collected for subsequent processing.

[039] The fermented microbial supernatant contains biological nutrients, minerals and amino acids. Biological nutrients are typically present in an amount of from about 0.01% to about 1% of the total weight of the fermented microbial supernatant. Each individual biological nutrient is typically present in an amount of about 0.00001% to about 0.01% of the total weight of the fermented microbial supernatant. Examples of biological nutrients include, but are not limited to biotin, folic acid, glucans such as α-glucan and β-glucan, niacin, inositol, pantothenic acid, pyridoxine, riboflavin and thiamine. In aspects of this embodiment, the fermented microbial supernatant disclosed herein includes, for example, about 0.00001% to about 0.0011% biotin, from about 0.0006% to about 0.016% folic acid, from about 0.005% to about 15% niacin, from about 0.01% to about 1% inositol, from about 0.00017% to about 0.017% pantothenic acid, from about 0.0006% to about 0.016% pyridoxine, from about 0.002% to about 0.023% riboflavin and from about 0.001% to about 0.02% thiamine. In other aspects of this embodiment, the fermented microbial supernatant disclosed herein includes, for example, from about 0.00006% to about 0.0006% biotin, from about 0.001% to about 0.011% folic acid, from about 0.01 % to about 0.1% niacin, from about 0.08% to about 0.18% inositol, from about 0.002% to about 0.012% pantothenic acid, from about 0.001% to about 0.011% pyridoxine, from about 0.007% to about 0.017% riboflavin, from about 0.003% to about 0.013% of thiamine. In other aspects of this embodiment, the fermented microbial supernatant disclosed herein includes, for example, from about 0.00012% to about 0.0006% biotin, from about 0.001% to about 0.011% folic acid, from about 0.01 % to about 0.1% niacin, from about 0.08% to about 0.18% inositol, from about 0.003% to about 0.013% pantothenic acid, from about 0.001% to about 0.011% pyridoxine, from about 0.008% to about 0.017% riboflavin, from about 0.003% to about 0.013% of thiamine. In other aspects of this embodiment, the fermented microbial supernatant disclosed herein includes, for example, from about 0.00009% to about 0.0003% biotin, from about 0.004% to about 0.008% folic acid, from about 0.03 % to about 0.07% niacin, from about 0.11% to about 0.15% inositol, from about 0.006% to about 0.01% pantothenic acid, from about 0.004% to about 0.008% pyridoxine, from about 0, 01% to about 0.014% riboflavin, from about 0.006% to about 0.010% thiamine.

[040] Mineral substances are typically present in an amount of about 0.1% to about 20% of the total weight of the fermented microbial supernatant. Each individual mineral substance is typically present in an amount of about 0.0001% to about 5% of the total weight of the fermented microbial supernatant. Examples of minerals include, but are not limited to calcium, chromium, copper, iron, magnesium, phosphate, potassium, sodium, and zinc. In aspects of this embodiment, the fermented microbial supernatant disclosed herein includes, for example, from about 0.02% to about 0.3% calcium, from about 0.000002% to about 0.0016% chromium, from about 0 , 000009% to about 0.0014% copper, from about 0.00005% to about 0.02% iron, from about 0.001% to about 1.3% magnesium, from about 0.2% to about 14% phosphate, from from about 0.4% to about 16% potassium, from about 0.2% to about 15% sodium, and from about 0.08% to about 13% zinc. In other aspects of this embodiment of the present invention, the fermented microbial supernatant disclosed herein includes, for example, from about 0.07% to about 0.21% calcium, from about 0.000007% to about 0.0011% chromium, from about 0.00004% to about 0.0009% copper, from about 0.0001% to about 0.015% iron, from about 0.005% to about 0.9% magnesium, from about 0.7% to about 9% phosphate, from about 0.9% to about 11% potassium, from about 0.7% to about 10% sodium, and from about 0.3% to about 8% zinc. In other aspects of this embodiment, the fermented microbial supernatant disclosed herein includes, for example, from about 0.05% to about 1% calcium, from about 0.0001% to about 0.0009% chromium, from about 0, 00006% to about 0.0007% copper, from about 0.0001% to about 0.013% iron, from about 0.005% to about 1% magnesium, from about 0.1% to about 7% phosphate, from about 0.5% to about 9% potassium, from about 0.5% to about 8% sodium, and from about 0.5% to about 6% zinc. In other aspects of this embodiment, the fermented microbial supernatant disclosed herein includes, for example, from about 0.12% to about 0.16% calcium, from about 0.0002% to about 0.0006% chromium, from about 0.00009% to about 0.0004% copper, from about 0.0006% to about 0.01% iron, from about 0.01% to about 0.4% magnesium, from about 1% to about 4% phosphate, from about 2% to about 6% potassium, from about 1% to about 5% sodium, and from about 0.8% to about 3% zinc.

[041] Amino acids are typically present in an amount of about 20% to about 60% of the total weight of the fermented microbial supernatant. Each individual amino acid is typically present in an amount of about 0.1% to about 15% of the total weight of the fermented microbial supernatant. Examples of amino acids include, but are not limited to alanine, arginine, aspartic acid, cysteine, glutamic acid, glycine, lysine, methionine, phenylalanine, proline, serine and threonine. In aspects of this embodiment of the present invention, the fermented microbial supernatant disclosed herein includes, for example, from about 0.2% to about 16% alanine, from about 0.09% to about 15% arginine, from about 0.4% to about 18% aspartic acid, from about 0.003% to about 5% cysteine, from about 0.5% to about 20% glutamic acid, from about 0.09% to about 15% glycine, from about 0.09% to about 15 % lysine, from about 0.002% to about 5% methionine, from about 0.09% to about 15% phenylalanine, from about 0.09% to about 15% proline, from about 0.09% to about 15% serine, and from from about 0.09% to about 15% threonine. In other aspects of this embodiment, the fermented microbial supernatant disclosed herein includes, for example, from about 0.7% to about 11% alanine, from about 0.5% to about 10% arginine, from about 0.9% to about 13% aspartic acid, from about 0.008% to about 1.2% cysteine, from about 1% to about 15% glutamic acid, from about 0.5% to about 10% glycine, from about 0.8% to about 12% lysine, from about 0.2% to about 1.6% methionine, from about 0.5% to about 10% phenylalanine, from about 0.5% to about 10% proline, from about 0.5% to about 10% serine and from about 0.5% to about 10% threonine. In other aspects of this embodiment of the present invention, the fermented microbial supernatant disclosed herein includes, for example, from about 0.5% to about 9% alanine, from about 0.5% to about 8% arginine, from about 1% to about 11% aspartic acid, from about 0.01% to about 2% cysteine, from about 3% to about 13% glutamic acid, from about 0.5% to about 8% glycine, from about 1% to about 10% lysine, from about 0.3% to about 3% methionine, from about 0.5% to about 7% phenylalanine, from about 0.5% to about 7% proline, from about 0.5% to about 7% serine, and from about 0.5% to about 7% threonine. In other aspects of this embodiment, the fermented microbial supernatant disclosed herein includes, for example, from about 2% to about 6% alanine, from about 1% to about 5% arginine, from about 4% to about 8% aspartic acid from about 0.03% to about 0.7% cysteine, from about 6% to about 10% glutamic acid, from about 1% to about 5% glycine, from about 3% to about 7% lysine, from about 0, 7% to about 1.1% methionine, from about 1% to about 5% phenylalanine, from about 1% to about 5% proline, from about 1% to about 5% serine, and from about 1% to about 5% threonine.

[042] Aspects of the present description of the invention partially disclose a processed fermented microbial supernatant. A processed fermented microbial supernatant is a fermented microbial supernatant that is processed in such a way that it denatures, kills or otherwise destroys any remaining live yeast, active enzymes from yeast and malt, as well as any other microorganisms or enzymes from another source, which are disclosed in the present application is a fermented microbial supernatant. Non-limiting examples of suitable processing procedures include a high temperature boiling process, a high temperature and high pressure autoclaving process, or an irradiation process by treating the supernatant with ionizing radiation or any other sterilization process that denatures, kills or otherwise destroys any remaining live yeast that is active enzymes from yeast and malt, as well as any other microorganisms or enzymes from another source in the fermented microbial supernatant disclosed herein. Also, the processing processes described above can be applied individually, in combination with each other, or in combination with a pasteurization process, a chemical sterilization process, and a sterile filtration process to denature, kill, or otherwise destroy proteins such as enzymes and microorganisms such as yeast, bacteria, and / or molds present in the fermented microbial supernatant disclosed herein. All methods described above are processes known to specialists in this field of technology, as they are used in everyday practice in the field of production and / or sterilization of food products.

[043] The treated fermented microbial supernatant can then be stored in liquid form for later use. Alternatively, the treated fermented microbial supernatant can be spray dried by methods known in the art to obtain a dry powder. In the form of a dry powder, it can also be stored for later use.

[044] Any amount of the processed fermented microbial supernatant disclosed herein may be used in the disclosed paper manufacture additive composition, provided that the amount is suitable for the methods and uses disclosed herein. Factors used to determine the appropriate amount include, for example, the form (liquid or powder) of the processed fermented microbial supernatant, the specific commercial source of the processed fermented microbial supernatant, the specific method used to obtain the processed fermented microbial supernatant, the form for preparing the paper additive composition ( in the form of a concentrate or in the form of a finished product) and the desired dilution factor when receiving the composition of the additive for the production of paper from the concentrate. Typically, a larger amount of the liquid form of the treated fermented microbial supernatant is required compared to the powder form.

[045] In aspects of this embodiment of the present invention, the amount of processed fermented microbial supernatant used is, for example, from about 0.5% by weight, from about 1.0% by weight, from about 1.5% by weight, from about 2 0% by weight, from about 2.5% by weight, from about 3.0% by weight, from about 3.5% by weight, from about 4.0% by weight, from about 4.5% by weight from about 5.0% by weight, from about 6.0% by weight, from about 7.0% by weight, from about 7.5% by weight, from about 8.0% by weight, from about 9, 0% by weight or from about 10.0% by weight. In other aspects of this embodiment, the amount of processed fermented microbial supernatant used is, for example, at least 0.5% by weight, at least 1.0% by weight, at least 1.5% by weight, at least at least 2.0% by weight, at least 2.5% by weight, at least 3.0% by weight, at least 3.5% by weight, at least 4.0% by weight, at least at least 4.5% by weight, at least 5.0% by weight, at least 6.0% by weight, at least 7.0% by weight, at least 7.5% by weight, at least at least 8.0% by weight, at least 9.0% by weight, or at least 10.0% by weight. In other aspects of this embodiment, the amount of processed fermented microbial supernatant used is, for example, not more than 0.5% by weight, not more than 1.0% by weight, not more than 1.5% by weight, not more than 2.0 % by weight, not more than 2.5% by weight, not more than 3.0% by weight, not more than 3.5% by weight, not more than 4.0% by weight, not more than 4.5% by weight, not more than 5.0% by weight, not more than 6.0% by weight, not more than 7.0% by weight, not more than 7.5% by weight, not more than 8.0% by weight, not more than 9.0% by weight or not more than 10.0% by weight. In other aspects of this embodiment of the present invention, the amount of processed fermented microbial supernatant used is, for example, from about 0.1% to about 2.5% by weight, from about 0.1% to about 3.0% by weight, from about 0.1% to about 3.5% by weight, from about 0.1% to about 4.0% by weight, from about 0.1% to about 5.0% by weight, from about 0.5% to about 2.5% by weight, from about 0.5% to about 3.0% by weight, from about 0.5% to about 3.5% by weight, from about 0.5% to about 4.0% by weight, from about 0.5% to about 5.0% by weight, from about 1% to about 2.5% by weight, from about 1% to about 3.0% by weight, from about 1% to about 3.5% by weight, from about 1% to about 4.0% by weight, from about 1% to about 5.0% by weight, from approx. About 1% to about 6.0% by weight, from about 1% to about 7.0% by weight, from about 1% to about 8.0% by weight, from about 1% to about 9.0% by weight or from about 1% to about 10.0% by weight.

[046] In other aspects of this embodiment, the amount of processed fermented microbial supernatant used is, for example, approximately 15.0% by weight, approximately 20.0% by weight, approximately 25.0% by weight, approximately 30.0% by weight, approximately 35.0% by weight, approximately 40.0% by weight, approximately 45.0% by weight, approximately 50.0% by weight, approximately 55.0% by weight, approximately 60.0% by weight approximately 65.0% by weight, approximately 70.0% by weight, approximately 75.0% by weight, approximately 80.0% by weight, approximately 85.0% by weight, or approximately 90.0% by weight. In other aspects of this embodiment, the amount of processed fermented microbial supernatant used is, for example, at least 15.0% by weight, at least 20.0% by weight, at least 25.0% by weight, at least at least 30.0% by weight, at least 35.0% by weight, at least 40.0% by weight, at least 45.0% by weight, at least 50.0% by weight, at least at least 55.0% by weight, at least 60.0% by weight, at least 65.0% by weight, at least 70.0% by weight, at least 75.0% by weight, at least at least 80.0% by weight, at least 85.0% by weight, or at least 90.0% by weight. In other aspects of this embodiment, the amount of processed fermented microbial supernatant used is, for example, not more than 15.0% by weight, not more than 20.0% by weight, not more than 25.0% by weight, not more than 30.0 % by weight, not more than 35.0% by weight, not more than 40.0% by weight, not more than 45.0% by weight, not more than 50.0% by weight, not more than 55.0% by weight, not more than 60.0% by weight, not more than 65.0% by weight, not more than 70.0% by weight, not more than 75.0% by weight, not more than 80.0% by weight, not more than 85.0% by weight or not more than 90.0% by weight.

[047] In other aspects of this embodiment of the present invention, the amount of processed fermented microbial supernatant used is, for example, from about 5% to about 7.5% by weight, from about 5% to about 10% by weight, from about 5% to about 15% by weight, from about 5% to about 20% by weight, from about 5% to about 25% by weight, from about 5% to about 30% by weight, from about 5% to about 35% by weight, from about 5% to about 40% by weight, from about 5% to about 45% by weight, from about 5% to about 50% by weight, from about 5% to about 55% by weight, from about 5% to about 60% by weight, from about 5% to about 65% by weight, from about 5% to about 70% by weight, from about 5% to about 75% by weight, from about 5% to about 80% by weight, from about 5% to about 85% by weight, from about 5% to about 90% by weight, from about 5% to about 95% by weight, from about 10% to about 15% by weight, from about 10 % to about 20% by weight, from about 10% to about 25% by weight, from about 10% to about 30% by weight, from about 10% to about 35% by weight, from about 10% to about 40% by weight weight, from about 10% to about 45% by weight, from about 10% to about 50% by weight, from about 10% to about 55% by weight, from about 10% to about 60% by weight, from about 10% up to about 65% by weight, from about 10% to about 70% by weight, from about 10% to about 75% by weight, from about 10% to about 80% by weight, from about 10% to about 85% by weight , from about 10% to about 90% by weight, from about 10% to about 95% by weight, from about 15% to about 20% by weight, from about 15% to about 25% by weight, from about 15% to about 30% by weight, from about 15% to about 35% by weight, from about 15% to about 40% by weight, from about 15% to about 45% by weight, from about 15% to about 50% by weight, from about 15% to about 55 % by weight, from about 15% to about 60% by weight, from about 15% to about 65% by weight, from about 15% to about 70% by weight, from about 15% to about 75% by weight, from about 15% to about 80% by weight, from about 15% to about 85% by weight, from about 15% to about 90% by weight, from about 15% to about 95% by weight, from about 25% to about 25% by weight, from about 25% to approx. a total of 30% by weight, from about 25% to about 35% by weight, from about 25% to about 40% by weight, from about 25% to about 45% by weight, from about 25% to about 50% by weight, from about 25% to about 55% by weight, from about 25% to about 60% by weight, from about 25% to about 65% by weight, from about 25% to about 70% by weight, from about 25% to about 75% by weight, from about 25% to about 80% by weight, from about 25% to about 85% by weight, from about 25% to about 90% by weight, from about 25% to about 95% by weight, from about 25% to about 30% by weight, from about 25% to about 35% by weight, from about 25% to about 40% by weight, from about 25% to about 45% by weight, from about 25% to about 50 % by weight, from about 25% to about 55% by weight, from about 25% to about 60% by weight, from about 25% to about 65% by weight, from about 25% to about 70% by weight, from about 25% to about 75% by weight, from about 25% to about 80% by weight, from about 25% to about 85% by weight, from about 25% to about 90% by weight, from about 25% to about 95% by weight, from about 30% to about 35% by weight, from about 30% to about 40% by weight, from about 30% to about 45% by weight, from about 30% to about 50% by weight, from about 30% to about 55% by weight, from about 30% to about 60% by weight, from about 30% to about 65% by weight, from about 30% to about 70% by weight, from about 30% to about 75% by weight, from about 30% to about 80 % by weight, from approximately 30% to about 85% by weight, from about 30% to about 90% by weight, from about 30% to about 95% by weight, from about 35% to about 40% by weight, from about 35% to about 45% by weight, from about 35% to about 50% by weight, from about 35% to about 55% by weight, from about 35% to about 60% by weight, from about 35% to about 65% by weight, from about 35 % to about 70% by weight, from about 35% to about 75% by weight, from about 35% to about 80% by weight, from about 35% to about 85% by weight, from about 35% to about 90% by weight weight, from about 35% to about 95% by weight, from about 40% to about 45% by weight, from about 40% to about 50% by weight, from about 40% to about 55% by weight, from about 40% up to approximately 60% by weight, from approx specifically 40% to about 65% by weight, from about 40% to about 70% by weight, from about 40% to about 75% by weight, from about 40% to about 80% by weight, from about 40% to about 85 % by weight, from about 40% to about 90% by weight, from about 40% to about 95% by weight, from about 45% to about 50% by weight, from about 45% to about 55% by weight, from about 45% to about 60% by weight, from about 45% to about 65% by weight, from about 45% to about 70% by weight, from about 45% to about 75% by weight, from about 45% to about 80% by weight, from about 45% to about 85% by weight, from about 45% to about 90% by weight, from about 45% to about 95% by weight, from about 50% to about 55% by weight, from about 50 % to about 60% by weight, p about 50% to about 65% by weight, from about 50% to about 70% by weight, from about 50% to about 75% by weight, from about 50% to about 80% by weight, from about 50% to about 85 % by weight, from about 50% to about 90% by weight, from about 50% to about 95% by weight, from about 55% to about 60% by weight, from about 55% to about 65% by weight, from about 55% to about 70% by weight, from about 55% to about 75% by weight, from about 55% to about 80% by weight, from about 55% to about 85% by weight, from about 55% to about 90% by weight, from about 55% to about 95% by weight, from about 60% to about 65% by weight, from about 60% to about 70% by weight, from about 60% to about 75% by weight, from about 60 % to about 80% by weight y, from about 60% to about 85% by weight, from about 60% to about 90% by weight, from about 60% to about 95% by weight, from about 65% to about 70% by weight, from about 65% up to about 75% by weight, from about 65% to about 80% by weight, from about 65% to about 85% by weight, from about 65% to about 90% by weight, from about 65% to about 95% by weight from about 70% to about 75% by weight, from about 70% to about 80% by weight, from about 70% to about 85% by weight, from about 70% to about 90% by weight, from about 70% to about 95% by weight, from about 75% to about 80% by weight, from about 75% to about 85% by weight, from about 75% to about 90% by weight, from about 75% to about 95% by weight, from about 80% to about 85% by weight, from about 80% to about 90% by weight, from about 80% to about 95% by weight, from about 85% to about 90% by weight, from about 85% to about 95% by weight or from about 90 % to about 95% by weight.

[048] Aspects of the present description of the invention partially disclose a surfactant. Surfactants are compounds that reduce the surface tension of a liquid, facilitating spreading and reducing surface tension at the interface between two liquids or a liquid and a solid. Either one surfactant can be mixed with the buffer solution disclosed in this application, or more surfactants can be mixed with the buffer solution disclosed in this application. Suitable surfactants include, but are not limited to ionic surfactants, zwitterionic (amphoteric) surfactants, nonionic surfactants, or any combination thereof. The surfactants used in the method disclosed in this application may vary at the discretion of a person skilled in the art and, as a rule, depend in part on the particular buffer used, on the eluted protein, and on the conductivity values used.

[049] Ionic surfactants include anionic surfactants. Anionic surfactants include those based on permanent functional groups attached to the head, such as, for example, sulfate, sulfonate, phosphate, carboxylate, or pH-dependent anionic surfactants. Anionic surfactants include, but are not limited to, alkyl sulfates such as ammonium lauryl sulfate and sodium lauryl sulfate (sodium dodecyl sulfate); alkyl ether sulfates such as sodium laureth sulfate and sodium myreth sulfate; docusates such as sodium dioctyl sulfosuccinate; fluorosurfactant sulfonates, such as perfluorooctanesulfonate and perfluorobutanesulfonate; alkyl diphenyl oxide disulfonates, such as DOWFAX ™ 2A1 (disodium lauryl phenyl ether disulfonate), DOWFAX ™ 3B2 (disodium decyl phenyl ether disulfonate), DOWFAX ™ C10L (disodium decyl phenyl di disulfon) DOW disulfonate potassium phosphate polyether ether copolymers such as TRITON ™ H-55 and TRITON ™ H-66; alkylbenzenesulfonates; alkylaryl ether phosphates; alkyl ether phosphates; alkyl carboxylates such as salts of fatty acids and sodium stearate; sodium lauroyl sarcosinate; carboxylate fluorosurfactants such as perfluorononanoate and perfluorooctanoate; and sodium hexyl phenyl ether sulfonate (DOWFAX ™ C6L).

[050] Ionic surfactants also include cationic surfactants. Cationic surfactants include those based on permanent or pH-dependent cationic surfactants, such as, for example, primary, secondary or tertiary amines. Cationic surfactants include, but are not limited to, alkyltrimethylammonium salts such as cetyltrimethylammonium bromide (CTAB, cetyl trimethylammonium bromide) and cetyltrimethylammonium chloride (CTAC, cetyl trimethylammonium chloride); cetylpyridinium chloride (CPC, cetylpyridinium chloride); polyethoxylated tall amine (POEA, polyethoxylated tallow amine); benzalkonium chloride (BAC, benzalkonium chloride); benzethonium chloride (BZT, benzethonium chloride); 5-bromo-5-nitro-1,3-dioxane; dimethyldioctadecylammonium chloride; and dioctadecylmethylammonium bromide (DODAB, dioctadecyldimethylammonium bromide), as well as pH-dependent primary, secondary or tertiary amines, as surfactants, where primary amines acquire a positive charge at a pH above 10 or secondary amines acquire a positive charge at pH below 4 times as much as Other useful anionic surfactants include anionic surfactants are bio-based, including, but not limited STEPONOL ^® AM 30-KE, ammonium lauryl sulfate, and STEPONOL ^® EHS, sodium 2-ethylhexylsulphate. Such biologically based surfactants are not synthetic molecules, but are anionic biosurfactants derived from organic material such as plants.

[051] Zwitterionic surfactants are based on primary, secondary or tertiary amines or quaternary ammonium cations with a sulfonate, carboxylate or phosphate. Zwitterionic surfactants include, but are not limited to 3 - [(3-chloroamidopropyl) dimethylammonium] -1-propanesulfonate (CHAPS); sultaines such as cocamidopropylhydroxysultaine; betaines such as cocamidopropyl betaine; or lecithins.

[052] Nonionic surfactants are less denaturing and are used, respectively, to solubilize membrane proteins and lipids while maintaining protein-protein interactions. Nonionic surfactants include polyester nonionic surfactants, polyhydroxy nonionic surfactants and biosurfactants. Nonionic surfactants include alcohol ethoxylates, alkyl phenol ethoxylates, phenol ethoxylates, amide ethoxylates, glyceride ethoxylates, fatty acid ethoxylates and fatty amine ethoxylates. The nonionic surfactant disclosed herein may have the general formula H (OCH ₂ CH ₂ ) _x OC ₆ H ₄ R ¹ , (OCH ₂ CH ₂ ) _x OR ² or H (OCH ₂ CH ₂ ) _x OC (O) R ² , where x represents the number of moles of ethylene oxide added to the alkyl phenol and / or fatty alcohol or fatty acid, R ¹ represents a long chain alkyl group and R ² represents a long chain aliphatic group. In aspects of this embodiment, R ¹ is a C ₇ -C ₁₀ alkyl group and / or R ² is a C ₁₂ -C ₂₀ aliphatic group. Other useful nonionic surfactants include nonionic surfactants bio-based, including, but not limited STEPOSOL ^® MET-10U, the resulting metathesis nonionic surfactant being unsaturated short chain amide. Such biologically based surfactants are not synthetic molecules, but are nonionic biosurfactants derived from organic material such as plants.

[053] Non-limiting examples of surfactants include alkyl ethers polioksietilenglikolsorbitana (or ethoxylated sorbitan esters), such as polysorbate-20-sorbitan monooleate (TWEEN ^® 20), polysorbate-40-sorbitan monooleate (TWEEN ^® 40), polysorbate-60-sorbitan monooleate (TWEEN ^® 60), polysorbate-61-sorbitan monooleate (TWEEN ^® 61), polysorbate-65-sorbitan monooleate (TWEEN ^® 65), polysorbate-80-sorbitan monooleate (TWEEN ^® 80), polysorbate-81-sorbitan monooleate (TWEEN ^® 81) and polysorbate-85 -sorbitanmonooleat (TWEEN ^® 85); sorbitol esters such as sorbitan monooleate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate and sorbitan monstearate; polyglycerol esters such as glycerol monooleate, glycerol monolaurate, glycerol monopalmitate, glycerol monostearate, glycerol trioleate, glycerol ricinoleate, glycerol tristearate, mono- and diglycerides and glycerol triacetate; ethoxylated polyglycerol esters; alkyl glucosides such as arachidyl glucoside, C _12-20 alkyl glucoside, capryl / capryl glucoside, cetearyl glucoside, coco-glucoside, ethyl glucoside and lauryl glucoside, decyl glucoside; ethoxylated alkyl glucosides; sucrose esters such as sucrose monooleate, sucrose monolaurate, sucrose monopalmitate, sucrose monostearate, sucrose trioleate, sucrose ricinoleate, sucrose tristearate, sucrose diglycerides and sucrose triacetate; ethoxylated sucrose ester; amine oxides; ethoxylated alcohols; ethoxylated aliphatic alcohols; alkyl amines; ethoxylated alkyl amines; ethoxylated alkyl phenols such as ethoxylated nonylphenol and ethoxylated octylphenol; alkyl polysaccharides; ethoxylated alkyl polysaccharides; ethoxylated fatty acids, such as ethoxylated castor oil; ethoxylated fatty alcohols such as ethoxylated cetyl oleyl alcohol, ethoxylated cetyl stearyl alcohol, ethoxylated decyl alcohol, ethoxylated dodecyl alcohol and ethoxylated tridecyl alcohol; ethoxylated fatty amines; poloxamers (copolymers of polyethylene and polypropylene), such as Poloxamer 124 (PLURONIC ^® L44), Poloxamer 181 (PLURONIC ^® L61), Poloxamer 182 (PLURONIC ^® L62), Poloxamer 184 (PLURONIC ^® L64), Poloxamer 188 (PLURONIC ^® L64), Poloxamer 188 (PLURONIC ^® F68), poloxamer 237 (PLURONIC ^® F87), poloxamer 338 (PLURONIC ^® L108) and poloxamer 407 (PLURONIC ^® F127); linear secondary alcohol ethoxylates such as TERGITOL ™ 15-S-5, TERGITOL ™ 15-S-7, TERGITOL ™ 15-S-9, TERGITOL ™ 15-S-12, TERGITOL ™ 15-S-15, TERGITOL ™ 15 -S-20, TERGITOL ™ 15-S-30 and TERGITOL ™ 15-S-40; polyglycol ethers of alkyl phenols; polyethylene glycol alkylaryl ethers; polyoxyethylene alkyl ethers such as octaethylene glycol monododecyl ether, pentaetilenglikolya monododecyl ether, BRIJ ^® 30 and BRIJ ^® 35; 2-dodecoxyethanol (LUBROL ^® -PX); octylphenyl polyoxyethylene ethers such as polyoxyethylene (4-5) -p-t-octylphenol (TRITON ^® X-45) and polyoxyethylene octylphenyl ether (TRITON ^® X-100); polyoxyethylene glycol alkyl phenyl esters such as Nonoxynol-9; fenoksipolietoksietanoly such as octylphenoxy polyethoxy ethanol and nonylphenoxy polyethoxy ethanol (IGEPAL ^® CA-630 or NONIDET ™ P-40); glucoside alkyl esters such as octyl glucopyranoside; maltoside alkyl esters such as dodecyl maltopyranoside; thioglucoside alkyl esters such as heptylthioglucopyranoside; digitonins; glycerol alkyl esters such as glycerol laurate; alkylaryl polyethersulfates; alcohol sulfonates; sorbitan alkyl esters; cocamide ethanolamines such as cocamide monoethanolamine and cocamide diethanolamine; sucrose monolaurate; dodecyldimethylamine oxide and sodium cholate. Other non-limiting examples of surfactants useful in the methods disclosed herein are, for example, in Winslow, et al., Methods and Compositions for Simultaneously Isolating Hemoglobin from Red Blood Cells and Inactivating Viruses, US 2008/0138790; Pharmaceutical Dosage Forms and Drug Delivery Systems ( . Howard C. Ansel et al, eds, Lippincott Williams & Wilkins Publishers, 7 ^th ed 1999..); Remington: The Science and Practice of Pharmacy (Alfonso R. Gennaro ed, Lippincott, Williams & Wilkins, 2000 20 ^th ed..); Goodman &Gilman's The Pharmacological Basis of Therapeutics (Joel G. Hardman et al., Eds., McGraw-Hill Professional, 10 ^th ed. 2001); and Handbook of Pharmaceutical Excipients (Raymond C. Rowe et al., APhA Publications, 4 ^th edition 2003), each of which is incorporated herein by reference in its entirety.

[054] Nonionic surfactants act synergistically, enhancing the action of the fermented microbial supernatant. In addition, it has been shown that the nonionic surfactants used in the paper production additive compositions disclosed in this application are compatible with accelerated chemical reactions. Thus, in one embodiment of the present invention, the paper composition additive disclosed herein contains only one or more non-ionic surfactants. In another embodiment of the present invention, the paper additive composition disclosed herein contains only one or more non-ionic surfactants and one or more anionic surfactants. In another embodiment of the invention, the paper additive composition disclosed herein does not contain any cationic surfactants. In another embodiment of the present invention, the paper composition additive composition disclosed herein does not contain any cationic surfactants or zwitterionic surfactants. In another embodiment of the present invention, the paper additive composition disclosed herein does not contain any ionic surfactants. In another embodiment of the present invention, the paper manufacture additive composition disclosed herein does not contain any ionic surfactants or zwitterionic surfactants.

[055] Any amount of surfactant disclosed in this application may be used, provided that the amount is suitable for the methods and uses disclosed in this application. In aspects of this embodiment of the present invention, the amount of surfactant used is, for example, about 0.01% by weight, about 0.05% by weight, about 0.075% by weight, about 0.1% by weight, about 0.2% by weight weight, approximately 0.3% by weight, approximately 0.4% by weight, approximately 0.5% by weight, approximately 0.6% by weight, approximately 0.7% by weight, approximately 0.8% by weight, approximately 0.9% by weight, approximately 1.0% by weight, approximately 1.5% by weight, approximately 2.0% by weight, approximately 2.5% by weight, approximately 3.0% by weight, approximately 4 0% by weight, approximately 5.0% by weight, approximately 6.0% by weight, approximately 7.0% by weight, approximately 7.5% by weight, approximately 8.0% by weight, approximately 9.0 % by weight or approximately 10.0% by weight. In other aspects of this embodiment, the amount of surfactant used is, for example, at least 0.01% by weight, at least 0.05% by weight, at least 0.075% by weight, at least 0.1% by weight, at least 0.25% by weight, at least 0.5% by weight, at least 0.75% by weight, at least 1.0% by weight, at least 1.5% by weight, at least 2.0% by weight, at least 2.5% by weight, at least 3.0% by weight, at least 4.0% by weight, at least 5.0% by weight, at least 6.0% by weight, at least 7.0% by weight, at least 7.5% by weight, at least 8.0% by weight, at least 9.0% by weight or at least 10.0% by weight. In other aspects of this embodiment of the present invention, the amount of surfactant used is, for example, at least 0.01% by weight, at least 0.05% by weight, at least 0.075% by weight, at least 0.1% by weight, not less than 0.25% by weight, not less than 0.5% by weight, not less than 0.75% by weight, not less than 1.0% by weight, not less than 1.5% by weight, not less than 2.0% by weight, at least 2.5% by weight, at least 3.0% by weight, at least 4.0% by weight, at least 5.0% by weight, at least 6.0% by weight, at least 7.5% by weight, at least 8.0% by weight, at least 9.0% by weight or at least 10.0% by weight.

[056] In other aspects of this embodiment, the amount of surfactant used is, for example, from about 0.1% by weight to about 0.5% by weight, from about 0.1% by weight to about 0.75% by weight weight, from about 0.1% by weight to about 1.0% by weight, from about 0.1% by weight to about 1.5% by weight, from about 0.1% by weight to about 2.0% by weight, from about 0.1% by weight to about 2.5% by weight, from about 0.2% by weight to about 0.5% by weight, from about 0.2% by weight to about 0.75 % by weight, from about 0.2% by weight to about 1.0% by weight, from about 0.2% by weight to about 1.5% by weight, from about 0.2% by weight to about 2, 0% by weight, from about 0.2% by weight to about 2.5% by weight, from about 0.5% by weight to about 1.0% by weight, from about 0.5% by weight to approx. but 1.5% by weight, from about 0.5% by weight to about 2.0% by weight, from about 0.5% by weight to about 2.5% by weight, from about 0.5% by weight up to about 3.0% by weight, from about 0.5% by weight to about 4.0% by weight, from about 0.5% by weight to about 5.0% by weight, from about 1.0% by weight weight to about 2.5% by weight, from about 1.0% by weight to about 3.0% by weight, from about 1.0% by weight to about 4.0% by weight, from about 1.0% by weight to about 5.0% by weight, from about 1.0% by weight to about 6.0% by weight, from about 1.0% by weight to about 7.0% by weight, from about 1.0 % by weight to about 7.5% by weight, from about 1.0% by weight to about 8.0% by weight, from about 1.0% by weight to about 9.0% by weight, from about 1, 0% by weight to about 10.0% by weight, from about 2.0% by weight to at about 2.5% by weight, from about 2.0% by weight to about 3.0% by weight, from about 2.0% by weight to about 4.0% by weight, from about 2.0% by weight up to about 5.0% by weight, from about 2.0% by weight to about 6.0% by weight, from about 2.0% by weight to about 7.0% by weight, from about 2.0% by weight weight to about 7.5% by weight, from about 2.0% by weight to about 8.0% by weight, from about 2.0% by weight to about 9.0% by weight, from about 2.0% by weight to about 10.0% by weight, from about 5.0% by weight to about 6.0% by weight, from about 5.0% by weight to about 7.0% by weight, from about 5.0 % by weight to about 7.5% by weight, from about 5.0% by weight to about 8.0% by weight, from about 5.0% by weight to about 9.0% by weight, from about 5, 0% by weight to about 10.0% by weight, from about 5.0% by weight ecu up to about 11.0% by weight, from about 5.0% by weight to about 12.0% by weight, from about 5.0% by weight to about 13.0% by weight, from about 5.0% by weight to about 14.0% by weight, or from about 5.0% by weight to about 15.0% by weight.

[057] Aspects of the present description of the invention partially disclose the pH value of the paper production additive composition disclosed herein. The final pH value of the paper additive composition is typically acidic, which provides a longer shelf life for the composition. In aspects of this embodiment, the pH of the paper additive composition disclosed herein is, for example, about 2, about 2.5, about 3, about 3.5, about 4, about 4.5, about 5, about 5.5 or about 6. In other aspects of this embodiment of the present invention, the pH of the paper additive composition disclosed herein is, for example, at least 2, at least 2.5, at least 3, at least 3.5, at least 4, at least 4.5, at least 5, at least 5.5, or at least 6. In other aspects of this embodiment of the present invention, the pH value of the additive composition disclosed herein is for paper production is, for example, not more than 2, not more than 2.5, not more than 3, not more than 3.5, not more than 4, not more than 4.5, not more than 5, not more than 5.5 or not more than 6. In the other In many aspects of this embodiment, the pH of the paper additive composition disclosed herein is, for example, from about 2 to about 3, from about 2 to about 3.5, from about 2 to about 4, from about 2 to about 4.5, from about 2 to about 5, from about 2 to about 5.5, from about 2 to about 6, from about 2.5 to about 3, from about 2.5 to about 3.5, from about 2 5 to about 4, from about 2.5 to about 4.5, from about 2.5 to about 5, from about 2.5 to about 5.5, from about 2.5 to about 6, from about 3 to about 3.5, from about 3 to about 4, from about 3 to about 4.2, from about 3 to about 4.5, from about 3 to about 4.7, from about about 3 to about 5, from about 3 to about 5.2, from about 3 to about 5.5, from about 3 to about 6, from about 3.5 to about 4, from about 3.5 to about 4.2 , from about 3.5 to about 4.5, from about 3.5 to about 4.7, from about 3.5 to about 5, from about 3.5 to about 5.2, from about 3.5 to about 5.5, from about 3.5 to about 6, from about 3.7 to about 4.0, from about 3.7 to about 4.2, from about 3.7 to about 4.5, from about 3, 7 to about 5.2, from about 3.7 to about 5.5, or from about 3.7 to about 6.0.

[058] Aspects of the present description of the invention partially disclose an enzyme. The paper additive composition disclosed herein may, if desired, also contain an enzyme. Enzymes useful in the production of cellulosic pulp and paper include enzymes that enhance bleaching, improve bleaching, modify fiber structure, help control sewage pollution, remove resins and sticky substances (adhesives), and modify starch; All this leads to increased productivity, reduced environmental damage and reduced energy consumption. For example, amylases are used to break down starch molecules to reduce viscosity. Xylanases (hemicellulases) are used to break down hemicelluloses, which increases the efficiency of the bleaching process and increases whiteness. Lipases break down triglyceride bonds to form fatty acids and are used to control resins during the cooking phase. Cellulases and xylanases hydrolyze microfibrils, causing swelling of the fibers, which makes the fibers more flexible, and also facilitates the removal of printing ink and adhesives. Esterases break down ester bonds in ink particles and polymers used in printing inks, and in adhesive materials. Non-limiting examples of enzymes useful in the production of cellulose pulp and paper include cellulase, xylanase, lipase, esterase, amylase, pectinase, catalase, laccase, peroxidase, pulpase DI, pulpase RF and pulpase BL.

[059] Aspects of the present description of the invention partially disclose a paper additive composition that is biodegradable. The biodegradable paper manufacture additive composition disclosed in this application is a composition that is susceptible to decomposition, erosion, absorption, decomposition, or destruction to an almost complete or significant degree after use in accordance with the methods and uses disclosed herein. In aspects of this embodiment of the present invention, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, at least 99% of the production additive composition disclosed herein The paper is biodegradable, for example, in about 1 day, about 2 days, about 3 days, about 4 days, about 5 days, about 6 days, or about 7 days. In other aspects of this embodiment, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, at least 99% of the additive composition disclosed herein paper production is biodegradable, for example, from about 1 to about 2 days, from about 1 to about 3 days, from about 1 to about 4 days, from about 1 to about 5 days, from about 1 to about 6 days, from about 1 to about 7 days, from about 2 to about 3 days, from about 2 to about 4 days, from about 2 to about 5 days, from about 2 to about 6 days, from about 2 to about 7 days, from about 3 to about 4 days, from about 3 to about 5 days, from about 3 to about 6 days, from about 3 to about 7 days, from from about 4 to about 5 days, from about 4 to about 6 days, from about 4 to about 7 days, from about 5 to about 6 days, from about 5 to about 7 days, or from about 6 to about 7 days.

[060] In aspects of this embodiment, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, at least 99% of the composition disclosed herein papermaking additives undergo biodegradation, for example, in about 7 days, about 8 days, about 9 days, about 10 days, about 11 days, about 12 days, about 13 days, or about 14 days. In other aspects of this embodiment, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, at least 99% of the additive composition disclosed herein paper production is biodegradable, for example, from about 7 to about 8 days, from about 7 to about 9 days, from about 7 to about 10 days, from about 7 to about 11 days, from about 7 to about 12 days, from about 7 to about 13 days, from about 7 to about 14 days, from about 8 to about 9 days, from about 8 to about 10 days, from about 8 to about 11 days, from about 8 to about 12 days, from about 8 to about 13 days, from about 8 to about 14 days, from about 9 to about 10 days, from about 9 to about 11 days, from about 9 to about 12 days, from about 9 to about 13 days, from about 9 to about 14 days, from about 9 to about 11 days, from about 9 to about 12 days, from about 9 to about 13 days from about 9 to about 14 days, from about 10 to about 11 days, from about 10 to about 12 days, from about 10 to about 13 days, from about 10 to about 14 days, from about 11 to about 12 days, from from about 11 to about 13 days, from about 11 to about 14 days, from about 12 to about 13 days, from about 12 to about 14 days, or from about 13 to about 14 days.

[061] In aspects of this embodiment of the present invention, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, at least 99% of the composition disclosed herein additives for the manufacture of paper undergoes biodegradation, for example, in approximately 15 days, approximately 16 days, approximately 17 days, approximately 18 days, approximately 19 days, approximately 20 days, or approximately 21 days. In other aspects of this embodiment, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, at least 99% of the additive composition disclosed herein paper production is biodegradable, for example, from about 15 to about 16 days, from about 15 to about 17 days, from about 15 to about 18 days, from about 15 to about 19 days, from about 15 to about 20 days, from about 15 to about 21 days, from about 16 to about 17 days, from about 16 to about 18 days, from about 16 to about 19 days, from about 16 to about 20 days, from about 16 to about 21 days, from about 17 to about 18 days, from about 17 to about 19 days, from about 17 to about 20 days, from about 17 up to about 21 days, from about 18 to about 19 days, from about 18 to about 20 days, from about 18 to about 21 days, from about 19 to about 20 days, from about 19 to about 21 days, or from about 20 to about 21 days.

[062] Aspects of the present description of the invention partially disclose kits containing one or more components useful for implementing the method or application disclosed herein. Kits are a convenient form of combining components useful for implementing the method or application disclosed herein that facilitates or improves commercial sales. For example, a kit may comprise a paper manufacture additive composition disclosed herein and one or more reagents useful for implementing a method or use disclosed herein, such as, for example, one or more solvents and / or one or more carriers.

[063] Kits typically include a suitable container, for example, a box or other closed container, containing one or more components useful for carrying out the method or application disclosed herein. Additionally, the kits disclosed herein typically include separate containers, for example, a bottle, bottle, flask, or other closed container containing one or more components. For example, a kit may include a container for the paper manufacture additive composition disclosed herein and a separate container for one or more reagents included in the kit. Kits can be portable, for example, they can be transported and used in remote areas, such as commercial or industrial facilities or agricultural fields. Other kits can be used in living quarters.

[064] The kit disclosed herein may include labels or package inserts. Labels or package inserts include “printed matter”, which may be presented as a separate material, packaging material (eg, carton), or may be attached or attached to a container containing a kit component. Labels or package inserts may further include computer-readable media such as a disk (e.g., hard disk, flash memory), an optical disk, such as a CD or DVD-ROM / RAM, DVD, MP3, magnetic tape or electrical media, such as RAM (Random Access Memory, Random Access Memory) and ROM (Read Only Memory, read only memory) or their hybrids, such as magnetic / optical storage media, flash media or memory cards. Labels or package inserts may contain information describing one or more components, the dose, frequency or time of administration of the dose, information about the individual components. Labels or package inserts may contain information describing the manufacturer, lot numbers, manufacturer's address and production date. Labels or package inserts may contain information about the condition or condition under which the kit component can be used. Labels or package inserts may contain instructions for using one or more kit components in the method or application disclosed herein. Instructions may include the dose, frequency or duration of administration and instructions for implementing any of the methods or applications, or the processing protocols described herein, as well as a warning about possible dangers or situations in which kit components should not be used.

[065] Aspects of the present description of the invention partially disclose a method for separating fibers from pulp. The method for separating fibers from cellulosic pulp disclosed in this application includes introducing an effective amount of the paper additive composition disclosed herein to pulp during the pulping and / or paper preparation phase. This introduction leads to improved separation of the fibers from the raw materials present in the pulp.

[066] Aspects of the present description of the invention partially disclose methods for removing contaminants and / or impurities from cellulosic pulp and / or paper material. The method disclosed herein for removing contaminants and / or impurities from cellulosic pulp and / or paper material during the paper making phase involves adding an effective amount of the paper making additive composition disclosed herein during the cooking and / or paper making phase. This introduction removes contaminants and / or impurities from the pulp and / or paper material that are formed during the cooking and / or paper preparation phase.

[067] Aspects of the present description of the invention partially disclose methods for removing ink from cellulose pulp and / or paper material. The method for removing ink from cellulosic pulp and / or paper material disclosed in the present application comprises applying an effective amount of an additive composition disclosed herein for papermaking during the cooking and / or paper production phase. This introduction removes the printing ink from the pulp and / or paper material that is formed during the cooking and / or paper preparation phase.

[068] Aspects of the present disclosure disclose the use of a paper manufacture additive composition disclosed herein for separating fibers from pulp. The use of a paper manufacture additive for separating the fibers from the pulp disclosed in the present application includes introducing an effective amount of the paper additive composition into the pulp during the cooking and / or paper preparation phase to improve the separation of the fibers from the raw materials present in the pulp.

[069] Aspects of the present disclosure disclose the use of a paper manufacturing additive composition disclosed herein to remove contaminants and / or impurities from cellulose pulp and / or paper material. The disclosed application includes introducing an effective amount of the paper additive composition into the pulp during the cooking and / or paper preparation phase to remove impurities and / or impurities from the pulp and / or paper material that are formed during the cooking and / or paper preparation phase .

[070] Aspects of the present disclosure disclose the use of a paper manufacturing additive composition disclosed herein to remove printing ink from cellulose pulp and / or paper material. The disclosed application includes introducing an effective amount of the paper additive composition into the pulp during the cooking and / or paper preparation phase to remove ink from the pulp and / or paper material that is formed during the cooking and / or paper preparation phase.

[071] Contaminants and / or impurities typically contain resins, waxes, fats, fatty acids and their esters and unsaponifiables, phytosterols, salts and other water-soluble substances and non-volatile hydrocarbons, as well as printing ink, adhesives, plastic and other additives. Such contaminants and / or impurities are generally referred to as extractables. Inks are made from pigment, a pigment carrier and additives introduced into the mold to reduce smearing, plucking of fibers and other printing problems associated with inks.

[072] the Combination of non-ionic surfactant and processed fermented microbial supernatant in the paper additive additives disclosed in this application enhances the in situ chemical reactions of molecular structures, in particular chemical bonds found in polysaccharide and lipid based components present in the feed, used to obtain cellulose pulp and paper material, in particular, chemical bonds of lipid-based components. In situ chemical reactions dissolve, disperse, or otherwise destroy one or more components of the feed.

[073] Not wanting to be bound by any theory, the authors of the present invention believe that when a paper additive composition is added to an aqueous medium, spontaneous formation of ultrafine microbubbles with a unique structure and high reactivity occurs. These "functionalized" microbubbles have a highly reactive outer shell consisting of one or more non-ionic surfactants and components from the treated fermented microbial supernatant, and an inner core containing air. A highly reactive shell provides a significant increase in the mass of oxygen transferred to the aqueous medium and accelerated biocatalysis of the molecular structures of the compounds, which in combination provides synergistic functionality. As for mass oxygen transfer, this functionality increases the rate of oxygen transfer and increases the level of dissolved oxygen in the aqueous medium, which far exceeds the solubility limits expected under Henry's law and are at levels that simply cannot be achieved with mechanical aeration systems . The components of the treated fermented microbial supernatant appear to have a negative effect on the ability of nonionic surfactants to create a well-organized micellar membrane. The result is free molecular packing of these fermented components and surfactants that “functionalized” the shell, making it more permeable to gases, thereby creating more favorable conditions for mass gas transfer. Thus, this oxygen transfer function increases the availability of oxygen in the aquatic environment. As for accelerated biocatalysis, this function reduces the transition energy necessary for the catalytic reaction, creating a reaction platform that increases local concentrations of reagents, promoting electron donation and stimulating chemical reactions in electron-poor sites. Thus, this biocatalysis function provides the cleavage of chemical bonds, including glycoside and ester bonds present in the compound. Thus, the “functionalized” shell of microbubbles has catalytic activity, similar to traditional enzyme systems, but does not require any enzymes. Thus, the use of the paper additive composition disclosed in the present application creates “functionalized” microbubbles that increase the dispersion of oxygen, which increases the level of dissolved oxygen and accelerates molecular interactions, leading to catalytic destruction of the compounds.

[074] Upon contact with the raw materials used to produce cellulose pulp, the “functionalized” shell chemically interacts with lignin and lipid-based material components so that it contributes to electron donation or stimulates chemical reactions at electron-poor sites, which ensures cleavage of chemical bonds, including glycosidic and ester bonds present in lignin and other extractable substances. Similarly, in contact with impurities or pollutants, including printing ink, a “functionalized” shell chemically interacts with impurities and pollutants so that it promotes electron donation or stimulates reactions in electron-poor sites, which mediates the cleavage of chemical bonds, including glycoside and ester bonds present in impurities and pollutants. These interactions, apparently, are a form of hydrolysis using beta oxidation, where, in addition to using the components of the “functionalized” shell, the oxygen present in the nucleus of the microbubble is also used. Thus, the properties of the “functionalized” shell and the ability of the nucleus to transport oxygen act synergistically, contributing to the destruction of chemical bonds in situ, including glycosidic and ester bonds present in lignin, extractable substances, impurities and pollutants.

[075] The use of the paper manufacture additive composition disclosed herein can be carried out by any method that exposes the feedstock, impurity and / or contaminant to the disclosed paper manufacture additive compositions so that it provides proper breaking of the bonds of one or more components of the feedstock, impurities and / or pollutants. For example, exposure can be achieved by introducing the paper additive composition into the cellulosic pulp contained in the storage tank during the cooking phase into the paper pulp contained in the storage tank during the molding phase.

[076] The undiluted form of the paper manufacture additive composition disclosed in this application can be used in the methods and applications disclosed in this application. Alternatively, it is possible, if desired, to dilute the paper additive composition disclosed herein, and those skilled in the art are aware of the possibility of diluting such compositions. Dilution of the paper additive composition disclosed in this application is typically carried out using water, although other suitable diluents can be used if they allow microbubbles to form, as described herein. In aspects of this embodiment, the paper additive composition is diluted, for example, 1:10, 1:25, 1:50, 1:75, 1: 100, 1: 200, 1: 300, 1: 400, 1: 500, 1: 600, 1: 700, 1: 800, 1: 900, 1: 1000, 1: 2000, 1: 3000, 1: 4000, 1: 5000, 1: 6000, 1: 7000, 1: 8000, 1: 9000, 1: 10000, 1: 20,000, 1: 30,000, 1: 40,000, 1: 50,000, 1: 60,000, 1: 70,000, 1: 80,000, 1: 90,000 or 1: 100,000. In other aspects of this embodiment of the present invention, the paper additive composition is diluted with, for example, at least 1:10, at least 1:25, at least 1:50, at least 1:75, at least 1: 100, at least 1: 200, at least 1: 300, at least 1: 400, at least 1: 500, at least 1: 600, at least 1: 700, at least 1 : 800, at least 1: 900, at least 1: 1000, at least 1: 2000, at least 1: 3000, at least 1: 4000, at least 1: 5000, at least 1: 6000, at least 1: 7000, at least 1: 8000, at least 1: 9000, at least 1: 10000, at least 1: 20,000, at least 1: 30,000, at least 1: 40,000 at least 1: 50,000, at least 1: 60,000, at least 1: 70,000, at least 1: 80,000, at least 1: 90,000, or at least 1: 100,000. In other aspects of this embodiment of the present invention, the paper additive composition is diluted in a ratio of, for example, not more than 1:10, not more than 1:25, not more than 1:50, not more than 1:75, not more than 1: 100, not more than 1: 200, no more than 1: 300, no more than 1: 400, no more than 1: 500, no more than 1: 600, no more than 1: 700, no more than 1: 800, no more than 1: 900, no more than 1 : 1000, no more than 1: 2000, no more than 1: 3000, no more than 1: 4000, no more than 1: 5000, no more than 1: 6000, no more than 1: 7000, no more than 1: 8000, no more than 1: 9000 , no more than 1: 10000, no more than 1: 20,000, no more than 1: 30,000, no more than 1: 40,000, no more than 1: 50,000, no more than 1: 60,000, no more than 1: 70,000, no more than 1: 80,000, not more more than 1: 90,000 or not more than 1: 100,000.

[077] In other aspects of this embodiment of the present invention, the paper additive composition is diluted in a ratio of, for example, from about 1: 1 to about 1:10, from about 1: 1 to about 1:25, from about 1: 1 to from about 1:50, from about 1: 1 to about 1:75, from about 1: 1 to about 1: 100, from about 1: 2 to about 1:10, from about 1: 2 to about 1:25, from from about 1: 2 to about 1:50, from about 1: 2 to about 1:75, from about 1: 2 to about 1: 100, from about 1:10 to about 1:25, from about 1:10 to about 1:50, from about 1:10 to about 1:75, from about 1:10 to about 1: 100, from about 1:10 to about 1: 125, from about 1:10 to about 1: 150, from about 1:10 to about 1: 175, from about 1:10 to about 1: 200, from from about 1:10 to about 1: 225, from about 1:10 to about 1: 250, from about 1:50 to about 1: 100, from about 1:50 to about 1: 200, from about 1:50 to about 1: 300, from about 1:50 to about 1: 400, from about 1:50 to about 1: 500, from about 1:50 to about 1: 600, from about 1:50 to about 1: 700, from about 1:50 to about 1: 800, from about 1:50 to about 1: 900, from about 1:50 to about 1: 1000, from about 1: 100 to about 1: 200, from about 1: 100 to about 1 : 300, from about 1: 100 to about 1: 400, from about 1: 100 to about 1: 500, from about 1: 100 to about 1: 600, from about 1: 100 to about 1: 700, from about 1 : 100 to about 1: 800, from about 1: 100 to about 1: 900, from about 1: 100 to about specifically 1: 1000, from about 1: 500 to about 1: 1000, from about 1: 500 to about 1: 2000, from about 1: 500 to about 1: 3000, from about 1: 500 to about 1: 4000, from from about 1: 500 to about 1: 5000, from about 1: 500 to about 1: 6000, from about 1: 500 to about 1: 7000, from about 1: 500 to about 1: 8000, from about 1: 500 to about 1: 9000, from about 1: 500 to about 1: 10000, from about 1: 1000 to about 1: 2000, from about 1: 1000 to about 1: 3000, from about 1: 1000 to about 1: 4000, from about 1: 1000 to about 1: 5000, from about 1: 1000 to about 1: 6000, from about 1: 1000 to about 1: 7000, from about 1: 1000 to about 1: 8000, from about 1: 1000 to about 1 : 9000, from about 1: 1000 to about 1: 10000, from about 1: 5000 to about 1: 10000, from about 1: 5000 to about 1: 20,000, from about 1: 5000 to about 1: 30,000, from about 1: 5000 to about 1: 40,000, from about 1: 5000 to about 1: 50,000, from about 1: 5000 to about 1: 60,000, from about 1: 5000 to about 1: 70,000, from about 1: 5000 to about 1: 80,000, from about 1: 5000 to about 1: 90,000, from about 1: 5000 to about 1: 100000, from about 1: 10000 to about 1: 20,000, from about 1: 10,000 to about 1: 30,000, from about 1: 10,000 to about 1: 40,000, from about 1: 10,000 to about 1: 50,000, from from about 1: 10000 to about 1: 60,000, from about 1: 10000 to about 1: 70,000, from about 1: 10,000 to about 1: 80,000, from about 1: 10,000 to about 1: 90,000, from about 1: 10,000 to about 1: 100000.

[078] The additive composition for papermaking disclosed in this application is added in an effective amount. An effective amount of the paper additive composition disclosed in this application may be an amount sufficient to achieve a high degree of purity and quality of fibers. In aspects of this embodiment of the present invention, an effective amount improves the separation of cellulose fibers, increases the surface area of the fibers, removes ink, adhesives and / or other impurities or contaminants, or any combination thereof. Preferably, an effective amount does not violate the integrity and strength of the fibers. The actual effective amount of the disclosed paper manufacture additive composition is determined by the routine screening procedures used to evaluate the basic activity and effectiveness of the paper manufacture additive composition disclosed herein. Such screening procedures are well known to those skilled in the art. It is expected that the additive composition disclosed herein with an increased level of activity can be used in smaller amounts and concentrations, while the use of such compositions with a reduced level of activity may require larger amounts or concentrations to achieve the same main effect.

[079] An effective amount of the paper additive composition disclosed in this application can be estimated by the purity and quality of the pulp and paper products produced. The Technical Association of Pulp and Paper Industry (TAPPI, Technical Association of Pulp and Paper Industry) and the International Organization for Standardization (ISO) have developed standard methods for assessing the purity and quality of finished pulp, see, for example, TAPPI T 203 cm-99 "Content of alpha, beta and gamma cellulose in pulp pulp"; TAPPI standard T 235 cm-85 "Alkali solubility R10 and R18"; TAPPI T 430 cm-09 standard “Copper number of pulp, paper and paperboard”; TAPPI standard T 236 cm-99 "Kappa number of pulp pulp"; Standard TAPPI T 230 om-99 "Viscosity of pulp"; TAPPI T 452 om-08 standard “Whiteness of pulp, paper and paperboard”; Standard TAPPI T 235 cm-85 “Carboxyl content”; Standard TAPPI T 204 cm-97 “Solvent extractable wood and pulp materials”; and TAPPI T 211 om-93 Standard “Ash in Pulp, Paper and Cardboard: Ashing at 525 ° C”.

[080] One aspect of high purity and quality of the fiber is the yield of cellulose. As a rule, the higher the yield of cellulosic material from raw materials, the higher the purity and quality of the fiber. Typically, wood consists of approximately 40-50% cellulose and 25% -35% hemicellulose. Extraction of more than 70% of the cellulosic material is generally considered a high yield of cellulose.

[081] In one embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to provide a high yield of pulp. In aspects of this embodiment, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to provide a high pulp yield of, for example, about 70%, about 75%, about 80%, about 85%, about 86%, about 87%, approximately 88%, approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96%, approximately 97%, approximately 98% or approximately 99% . In other aspects of this embodiment, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to provide a high pulp yield of, for example, at least 70%, at least 75%, at least 80%, at least at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91%, at least 92%, at least 93 %, at least 94%, at least 95%, at least 96%, at least 97%, at least 98%, or at least 99%. In other aspects of this embodiment, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to provide a high pulp yield of, for example, not more than 70%, not more than 75%, not more than 80%, not more than 85%, no more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91%, no more than 92%, no more than 93%, no more than 94%, no more than 95%, no more than 96%, no more than 97%, no more than 98% or no more than 99%. In other aspects of this embodiment of the present invention, the method or use disclosed herein provides, for example, from about 70% to about 80%, from about 70% to about 85%, from about 70% to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95%, from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about 93%, from about 85% to about 95%, from approximately 85% to approximately 97%, from approximately 85% to approximately 99%, from approximately 90% to approximately 93%, from approximately 90% to approximately 95%, from approximately but 90% to about 97%, from about 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97% or from about 95% to about 99%.

[082] In another embodiment of the present invention, the method or use disclosed herein provides a high yield of cellulose. In aspects of this embodiment of the present invention, the method or use disclosed herein provides, for example, about 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96%, approximately 97%, approximately 98%, or approximately 99%. In other aspects of this embodiment of the present invention, the method or use disclosed herein provides, for example, at least 70%, at least 75%, at least 80%, at least 85%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91%, at least 92%, at least 93%, at least 94% at least 95%, at least 96%, at least 97%, at least 98%, or at least 99%. In other aspects of this embodiment of the present invention, the method or use disclosed herein provides, for example, not more than 70%, not more than 75%, not more than 80%, not more than 85%, not more than 86%, not more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91%, no more than 92%, no more than 93%, no more than 94%, no more than 95%, no more than 96%, no more 97%, not more than 98% or not more than 99%. In other aspects of this embodiment of the present invention, the method or use disclosed herein provides, for example, from about 70% to about 80%, from about 70% to about 85%, from about 70% to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95%, from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about 93%, from about 85% to about 95%, from approximately 85% to approximately 97%, from approximately 85% to approximately 99%, from approximately 90% to approximately 93%, from approximately 90% to approximately 95%, from approximately but 90% to about 97%, from about 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97% or from about 95% to about 99%.

[083] Another aspect of the high purity and quality of the fibers is the content of alpha, beta and gamma cellulose in the treated cellulose or in the resulting paper product. Typically, alpha cellulose is an indicator of high molecular weight intact cellulose, beta cellulose is an indicator of degraded cellulose, and gamma a gamma cellulose is an indicator of hemicellulose. There are more analyzes that measure the cellulose content of treated pulp pulp.

[084] In the analysis of the cellulose content, the fractions of alpha, beta and gamma cellulose are separated using a mercerizing alkaline solution in which alpha cellulose remains insoluble, beta cellulose precipitates upon addition of acid, and gamma cellulose remains in solution. For example, alpha cellulose is a cellulosic fraction resistant to treatment with a 17.5% and 9.45% sodium hydroxide solution under the conditions of the study. Beta-cellulose is a soluble fraction that re-precipitates upon acidification of the solution; gamma cellulose is the fraction remaining in solution. Soluble fractions containing beta-cellulose and gamma-cellulose are determined volumetrically by oxidation with potassium dichromate, and the content of alpha-cellulose as an insoluble fraction is obtained by the difference using the following formulas: AC% = 100 - (6.85 (V ₂ - V ₁ ) × N × 20) / A × W, where AC% is the percentage of alpha cellulose, V ₁ is the titration (in milliliters) of the cellulose filtrate, V ₂ is the titration (in milliliters) of a blank sample, N is the exact value the normality of the solution of iron-ammonium sulfate, A yaet the volume (in milliliters) of the filtrate cellulose used for oxidation, and W is the weight of the pulp sample after drying in an oven. GC% = (6.85 (V4 - V3) × N × 20) / (25 × W), where GC% is the percentage of gamma cellulose, V ₃ is the titration (in milliliters) of the solution after precipitation of beta cellulose, V ₄ is the titration (in milliliters) of a blank sample, N is the exact normality of the iron-ammonium sulfate solution, and W is the weight of the cellulose sample after drying in an oven. BC% = 100 - (AC% + GC%), where BC% is the percentage of beta cellulose, where AC% is the percentage of alpha cellulose and where GC% is the percentage of gamma cellulose. A standard study of cellulose composition is described, for example, in TAPPI Standard T 203 cm-99 “Alpha, Beta and Gamma Cellulose Content in Cellulose Pulp”, the entire contents of which are incorporated herein by reference.

[085] In an alkali resistance study, retention of cellulosic material when using at least two alkali solutions with different concentrations provides information on the content of high molecular weight carbohydrates (intact cellulose or alpha cellulose) in the treated cellulose pulp. Alkali, as a rule, is sodium hydroxide, and most often used concentrations are 18%, 10% and 5% (mass / mass). For example, a 10% solution of sodium hydroxide dissolves both degraded cellulose and hemicellulose, which indicates the total amount of insoluble cellulosic material (10% alkali retention or R ₁₀ value). Thus, the value of R ₁₀ includes the amount of alpha-cellulose (intact cellulose). However, only hemicellulose dissolves in an 18% sodium hydroxide solution, which allows us to estimate the amount of both alpha and beta cellulose that remain in the insoluble fraction (retention in 18% alkali or R ₁₈ value). To analyze the solubility of cellulose in alkali, a known mass of kiln-dried recycled cellulose is treated with sodium hydroxide solution for 60 minutes at 20 ° C, washed in acetic acid, dried and the insoluble cellulosic material is weighed. Resistance to alkali, R _c , is expressed as a percentage by weight using the following formula: m1 × 100 / m ₀ , where R _c is the alkali resistance, m ₀ is the mass of the test portion in grams, calculated on the basis of the mass of kiln dried in the oven, and m ₁ represents the mass of the dried in the furnace insoluble in alkali fraction in grams. When conducting alkali resistance studies using 10% alkali solutions, R _c corresponds to R ₁₀ , using 18% alkali solutions, R _c corresponds to R ₁₈ . A standard alkali solubility study is described, for example, in ISO (International Organization for Standardization) 699: 2015, Cellulose: Determination of Alkali Resistance, the entire contents of which are incorporated herein by reference.

[086] In an alkali solubility study, the solubility of cellulosic material in two solutions with different alkali concentrations provides information on the content of low molecular weight carbohydrates (disrupted cellulose or beta cellulose) and hemicellulose in the treated cellulose pulp. Alkali, as a rule, is sodium hydroxide, and the concentration, most often, is 18% and 10% (mass / mass). For example, a 10% sodium hydroxide solution dissolves both degraded cellulose and hemicellulose, which indicates the total amount of soluble cellulosic material (solubility in 10% alkali or S ₁₀ value). Thus, the S ₁₀ value includes the total amount of hemicellulose and beta cellulose (disrupted cellulose). However, only hemicellulose dissolves in an 18% sodium hydroxide solution, which allows us to estimate the amount of remaining hemicellulose present in the cellulose pulp (solubility in 18% alkali or S ₁₈ value). Thus, the amount of beta cellulose (broken pulp) can be determined by subtracting the S ₁₀ value from the S ₁₈ value (S ₁₈ minus S ₁₀ ). Additionally, the content of alpha-cellulose can be calculated on the basis of the study of solubility in alkali, determining the total amount of cellulosic material and subtracting the value of S ₁₀ . To conduct an alkali solubility study, the cellulose pulp is treated with a sodium hydroxide solution and the dissolved organic substances are oxidized with potassium dichromate. Iron (II) -ammonium sulfate is used to titrate the excess potassium dichromate and the spent amount of potassium dichromate is used to calculate the cellulose equivalent. The soluble cellulose fraction is expressed as a percentage by weight of kiln dried pulp using the following formula: S _c = 6.85 (V ₂ - V ₁ ) × c × 100 / m × V, where S _c is alkali solubility, V is volume the filtrate used in the oxidation, in milliliters, V ₁ is the volume of iron (II) ammonium sulfate used in the titration of the test solution, in milliliters, V ₂ is the volume of iron (II) ammonium sulfate used in the control study, in milliliters, c is the concentration of a solution of iron (II) -ammonium sulfate in mol / liter, m is the mass of the analyzed sample, calculated by the weight of the material dried in the oven, in grams; and 6.85 is an empirical coefficient showing the amount of cellulose equivalent to 1/6 mol of potassium dichromate in milligrams. When conducting an alkali solubility study using 10% alkali solutions, S _c corresponds to S ₁₀ , using 18% alkali solutions, S _c corresponds to S ₁₈ . Standard alkali solubility studies are described, for example, in TAPPI Standard T 235 cm-09 “Cellulose Solubility in Alkali at 25 ° C” and in ISO 692 Standard “Cellulose: Determination of Solubility in Alkali”, the contents of which are fully included in this application by reference.

[087] In a study of the viscosity of cellulose, the viscosity of the treated pulp is determined. Cellulose viscosity is an indicator of the average degree of cellulose polymerization. Increased cellulose viscosity is an indication of longer pulp chain length and less degradation. Thus, the higher the viscosity of cellulose, the more intact and high molecular weight cellulose (alpha cellulose) is in the treated cellulose pulp, and, accordingly, the less degraded cellulose (beta cellulose) is present in the cellulose pulp. A standard viscosity study is described, for example, in TAPPI Standard T 230 om-99 “Pulp Viscosity”, the entire contents of which are incorporated herein by reference.

[088] In one embodiment of the present invention, an effective amount of the disclosed paper additive composition is an amount sufficient to produce a high alpha cellulose content in the treated pulp pulp. In aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to produce an alpha cellulose content in the treated pulp pulp of, for example, about 70%, about 75%, about 80%, about 85%, about 86%, approximately 87%, approximately 88%, approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximate But 96%, approximately 97%, approximately 98%, or approximately 99%. In aspects of this embodiment, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to produce an alpha cellulose content in the treated pulp pulp equal to, for example, at least 70%, at least 75%, at least 80% at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91%, at least 92%, at at least 93%, at least 94%, at least 95%, at least m Here are 96%, at least 97%, at least 98%, or at least 99%. In other aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to produce an alpha cellulose content in the treated cellulose pulp of, for example, not more than 70%, not more than 75%, not more than 80%, not more than 85%, no more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91%, no more than 92%, no more than 93%, no more than 94%, not more than 95%, no more than 96%, no more than 97%, no more than 98% or no more than 99%. In other aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to produce an alpha cellulose content in the treated pulp pulp of, for example, from about 70% to about 80%, from about 70% to about 85 %, from about 70% to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from specifically 75% to about 90%, from about 75% to about 95%, from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about 93%, from about 85% to about 95%, from about 85% to about 97%, from about 85% to about 99%, from about 90% to about 93%, from about 90% to about 95%, from about 90% to about 97%, from approx. specifically 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97%, or from about 95% to about 99%

[089] In one embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to produce a low beta cellulose content in the treated cellulose pulp. In aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to produce a beta cellulose content in the treated pulp pulp equal to, for example, about 5%, about 10%, about 15%, about 20%, about 25%, approximately 30% or approximately 35%. In aspects of this embodiment, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to produce beta cellulose content in the treated pulp pulp equal to, for example, not more than 5%, not more than 10%, not more than 15%, not more 20%, not more than 25%, not more than 30% or not more than 35%. In aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to produce a beta cellulose content in the treated pulp pulp of, for example, from about 5% to about 10%, from about 5% to about 15% from about 5% to about 20%, from about 5% to about 25%, from about 5% to about 30%, from about 5% to about 35%, from about 10% to about 15%, from about 10% to about 20%, from about 10% to about 25%, from about 10% to about 30%, from about 10% to about 35%, from about 15% to about 20%, from about 15% to about 25%, from about 15% to about 30%, from about 15% to about 35%, from about 20% to about 25%, from about 20 % to about 30%, from about 20% to about 35%, from about 25% to about 30%, from about 25% to about 35%, or from about 30% to about 35%.

[090] In one embodiment of the present invention, an effective amount of the disclosed paper manufacturing additive composition is an amount sufficient to produce a low gamma cellulose content in the treated cellulose pulp. In aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to obtain a gamma cellulose content in the treated pulp pulp equal to, for example, about 5%, about 10%, about 15%, about 20%, about 25%, approximately 30% or approximately 35%. In aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to produce a gamma cellulose content in the treated cellulose pulp of, for example, not more than 5%, not more than 10%, not more than 15%, not more than 20%, not more than 25%, not more than 30% or not more than 35%. In aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to provide a gamma cellulose content in the treated pulp pulp of, for example, from about 5% to about 10%, from about 5% to about 15% from about 5% to about 20%, from about 5% to about 25%, from about 5% to about 30%, from about 5% to about 35%, from about 10% to about 15%, from about 10% to about 20%, from about 10% to about 25%, from about 10% to about 30%, from about 10% to about 35%, from about 15% to about 20%, from about 15% to about 25%, from about 15% to about 30%, from about 15% to about 35%, from about 20% to about 25%, from about 2 0% to about 30%, from about 20% to about 35%, from about 25% to about 30%, from about 25% to about 35%, or from about 30% to about 35%.

[091] In one embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to produce a high viscosity treated pulp. In aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacturing additive composition is an amount sufficient to obtain a viscosity of the treated pulp pulp equal to, for example, about 5 mPa приблизительноs, about 10 mPa⋅s, about 15 mPa⋅s, about 20 mPa ⋅ s, approximately 25 mPa⋅s, approximately 30 mPa⋅s, approximately 35 mPa⋅s, approximately 45 mPa⋅s, or approximately 50 mPa⋅s. In aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to obtain a viscosity of the treated pulp pulp equal to, for example, at least 5 mPaПs, at least 10 mPa⋅s, at least 15 mPa ⋅ s, at least 20 mPa⋅s, at least 25 mPa⋅s, at least 30 mPa⋅s, at least 35 mPa⋅s, at least 40 mPa⋅s, at least 45 mPa⋅s or at least 50 mPa⋅s. In other aspects of this embodiment of the present invention, an effective amount of the disclosed paper additive composition is an amount sufficient to obtain a viscosity of the treated pulp pulp equal to, for example, not more than 5 mPa⋅s, not more than 10 mPa⋅s, not more than 15 mPa⋅s , no more than 20 mPa⋅s, no more than 25 mPa⋅s, no more than 30 mPa⋅s, no more than 35 mPa⋅s, no more than 40 mPa⋅s, no more than 45 mPa⋅s or no more than 50 mPa⋅s. In other aspects of this embodiment of the present invention, an effective amount of the disclosed paper manufacture additive composition is an amount sufficient to obtain a viscosity of the treated pulp pulp equal to, for example, from about 5 mPa 10s to about 10 mPa⋅s to about 15 mPa⋅s, from about 5 mPa⋅s to about 20 mPa⋅s, from about 5 mPa⋅s to about 25 mPa⋅s, from about 5 mPa⋅s to about 30 mPa⋅s, from about 5 mPa⋅s to about 35 mPa⋅s, from about 5 mPa⋅s to about 40 mPa⋅s, from about 5 mPa⋅s to about 45 mPa⋅s, from about 5 mPa⋅s to about 50 mPa⋅s, from about 10 mPa⋅s to about 15 mPa⋅s, from about 10 mPa⋅s to about 20 mPa⋅s, from about 10 mPa⋅s to about 25 mPa⋅s, from about 10 mPa⋅s to about 30 mPa⋅ s, from about 10 mPa⋅s to about 35 mPa⋅s, from about 10 mPa⋅s to about 40 mPa⋅s, from about 10 mPa⋅s up to about 45 mPa⋅s, from about 10 mPa доs to about 50 mPa⋅s, from about 15 mPa доs to about 20 mPa⋅s, from about 15 mPa⋅s to about 25 mPa⋅s, from about 15 mPa⋅ ⋅ s to about 30 mPa⋅s, from about 15 mPa⋅s to about 35 mPa⋅s, from about 15 mPa⋅s to about 40 mPa⋅s, from about 15 mPa⋅s to about 45 mPa⋅s, from about 15 mPa⋅s to about 50 mPa⋅s, from about 20 mPa⋅s to about 25 mPa⋅s, from about 20 mPa⋅s to pr about 30 mPa⋅s, from about 20 mPa⋅s to about 35 mPa⋅s, from about 20 mPa⋅s to about 40 mPa⋅s, from about 20 mPa⋅s to about 45 mPa⋅s, from about 20 mPa⋅ s to about 50 mPa⋅s, from about 25 mPa⋅s to about 30 mPa⋅s, from about 25 mPa⋅s to about 35 mPa⋅s, from about 25 mPa⋅s to about 40 mPa⋅s, from about 25 mPa⋅s to about 45 mPa⋅s, from about 25 mPa⋅s to about 50 mPa⋅s, from about 30 mPa⋅s to about a total of 35 mPa отs, from about 30 mPa⋅s to about 40 mPa⋅s, from about 30 mPa⋅s to about 45 mPa⋅s, from about 30 mPa⋅s to about 50 mPa⋅s, from about 35 mPa⋅ s to about 40 mPa⋅s, from about 35 mPa⋅s to about 45 mPa⋅s, from about 35 mPa⋅s to about 50 mPa⋅s, from about 40 mPa⋅s to about 45 mPa⋅s, from about 40 mPa⋅s to about 50 mPa⋅s or from about 45 mPa⋅s to about 50 mPa⋅s.

[092] In one embodiment of the present invention, the method or application disclosed in the present application provides for the production of treated cellulose pulp with a high alpha cellulose content. In aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated cellulose pulp with an alpha cellulose content of, for example, about 70%, about 75%, about 80%, about 85%, about 86%, about 87 %, approximately 88%, approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96%, approximately 97%, approximately 98%, or approximately 99%. In aspects of this embodiment of the present invention, the method or application disclosed herein provides for the preparation of treated pulp with an alpha cellulose content of, for example, at least 70%, at least 75%, at least 80%, at least 85 %, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98%, or at least 99%. In other aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated cellulose pulp with an alpha cellulose content of, for example, not more than 70%, not more than 75%, not more than 80%, not more than 85%, not more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91%, no more than 92%, no more than 93%, no more than 94%, no more than 95%, not more than 96%, not more than 97%, not more than 98% or not more than 99%. In other aspects of this embodiment of the present invention, the method or use disclosed herein provides for the production of treated cellulose pulp with an alpha cellulose content of, for example, from about 70% to about 80%, from about 70% to about 85%, from about 70 % to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95% , from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about 93%, from about 85% to about 95%, from about 85% to about 97%, from about 85% to about 99%, from about 90% to about 93%, from about specifically 90% to about 95%, from about 90% to about 97%, from about 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97%, or from about 95% to about 99%.

[093] In one embodiment of the present invention, the method or application disclosed herein provides for the production of processed pulp with a low beta cellulose content. In aspects of this embodiment of the present invention, the method or use disclosed herein provides for treated pulp with a beta cellulose content of, for example, about 5%, about 10%, about 15%, about 20%, about 25%, about 30 % or approximately 35%. In aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated pulp with a beta cellulose content of, for example, not more than 5%, not more than 10%, not more than 15%, not more than 20%, not more 25%, not more than 30% or not more than 35%. In aspects of this embodiment of the present invention, a method or application disclosed herein provides for the production of treated pulp with a beta cellulose content of, for example, from about 5% to about 10%, from about 5% to about 15%, from about 5 % to about 20%, from about 5% to about 25%, from about 5% to about 30%, from about 5% to about 35%, from about 10% to about 15%, from about 10% to about specifically 20%, from about 10% to about 25%, from about 10% to about 30%, from about 10% to about 35%, from about 15% to about 20%, from about 15% to about 25%, from about 15% to about 30%, from about 15% to about 35%, from about 20% to about 25%, from about 20% to about 30%, from about 20% to about 35%, from about 25% to about 30%, from about 25% to about 35%, or from about 30% to about an impressive 35%.

[094] In one embodiment of the present invention, the method or use disclosed herein provides for the production of treated gamma cellulose-treated pulp pulp. In aspects of this embodiment of the present invention, the method or application disclosed in the present application provides treated pulp with a gamma cellulose content of, for example, about 5%, about 10%, about 15%, about 20%, about 25%, about 30 % or approximately 35%. In aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated cellulose pulp with a gamma cellulose content of, for example, not more than 5%, not more than 10%, not more than 15%, not more than 20%, not more 25%, not more than 30% or not more than 35%. In aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated cellulose pulp with a gamma cellulose content of, for example, from about 5% to about 10%, from about 5% to about 15%, from about 5% up to about 20%, from about 5% to about 25%, from about 5% to about 30%, from about 5% to about 35%, from about 10% to about 15%, from about 10% to about 20%, from about 10% to about 25%, from about 10% to about 30%, from about 10% to about 35%, from about 15% to about 20%, from about 15% to about 25%, from about 15% to about 30%, from about 15% to about 35%, from about 20% to about 25%, from about 20% to about 30%, from about 20% to about 35%, from about 25% to about 30%, from about 25% to about 35%, or from about 30% to about 35%.

[095] In one embodiment of the present invention, the method or application disclosed herein provides for the preparation of high viscosity treated pulp. In aspects of this embodiment of the present invention, the method or application disclosed herein provides treated pulp with a viscosity of, for example, 5 mPa⋅s, about 10 mPa⋅s, about 15 mPa⋅s, about 20 mPa⋅s, about 25 mPa⋅s, approximately 30 mPa⋅s, approximately 35 mPa⋅s, approximately 40 mPa⋅s, approximately 45 mPa⋅s, or approximately 50 mPa⋅s. In aspects of this embodiment of the present invention, the method or application disclosed in the present application provides treated pulp with a viscosity of, for example, at least 5 mPa⋅s, at least 10 mPa⋅s, at least 15 mPa⋅s, at least 20 mPa⋅s, at least 25 mPa⋅s, at least 30 mPa⋅s, at least 35 mPa⋅s, at least 40 mPa⋅s, at least 45 mPa⋅s, or at least 50 mPa⋅s. In other aspects of this embodiment of the present invention, the method or application disclosed in the present application provides treated pulp with a viscosity of, for example, not more than 5 mPa⋅s, not more than 10 mPa⋅s, not more than 15 mPa⋅s, not more than 20 mPa⋅s, no more than 25 mPa⋅s, no more than 30 mPa⋅s, no more than 35 mPa⋅s, no more than 40 mPa⋅s, no more than 45 mPa⋅s or no more than 50 mPa⋅s. In other aspects of this embodiment of the present invention, the method or application disclosed herein provides treated pulp with a viscosity of, for example, from about 5 mPa⋅s to about 10 mPa ,s, from about 5 mPa⋅s to about 15 mPa⋅ s, from about 5 mPa⋅s to about 20 mPa⋅s, from about 5 mPa⋅s to about 25 mPa⋅s, from about 5 mPa⋅s to about 30 mPa⋅s, from about 5 mPa⋅s to about 35 mPa⋅s, from about 5 mPa⋅s to about 40 mPa⋅s, from about 5 mPa⋅s to about 45 mPa⋅s, from about 5 mPa⋅s to about 50 mPa⋅s, from about 10 mPa⋅s to about 15 mPa⋅s, from about 10 mPa⋅s to about 20 mPa⋅s, from about 10 mPa⋅s to about 25 mPa⋅s, from about 10 mPa⋅s to about 30 mPa⋅s, from about 10 mPa⋅ s to about 35 mPa⋅s, from about 10 mPa⋅s to about 40 mPa⋅s, from about 10 mPa⋅s to about 45 mPa⋅s, from about 10 mPa⋅s to about 50 mPa⋅s, from about 15 mPa⋅s to about 20 mPa⋅s, from about 15 mPa⋅ s to about 25 mPa⋅s, from about 15 mPa⋅s to about 30 mPa⋅s, from about 15 mPa⋅s to about 35 mPa⋅s, from about 15 mPa⋅s to about 40 mPa⋅s, from about 15 mPa⋅s to about 45 mPa⋅s, from about 15 mPa⋅s to about 50 mPa⋅s, from about 20 mPa⋅s to about 25 mPa⋅s, from about 20 mPa⋅s to about 30 mPa⋅s, from about 20 mPa⋅s to about 35 mPa⋅s, from about 20 mPa⋅s to about 40 mPa⋅s, from about 20 mPa⋅s to about 45 mPa⋅s, from about 20 mPa⋅s to about 50 mPa⋅s , from about 25 mPa⋅s to about 30 mPa⋅s, from about 25 mPa⋅s to about 35 mPa⋅s, from about 25 mPa⋅s to about about 40 mPa⋅s, from about 25 mPa⋅s to about 45 mPa⋅s, from about 25 mPa⋅s to about 50 mPa⋅s, from about 30 mPa⋅s to about 35 mPa⋅s, from about 30 mPa⋅ s to about 40 mPa⋅s, from about 30 mPa⋅s to about 45 mPa⋅s, from about 30 mPa⋅s to about 50 mPa⋅s, from about 35 mPa⋅s to about 40 mPa⋅s, from about 35 mPa⋅s to about 45 mPa⋅s, from about 35 mPa⋅s to about 50 mPa⋅s, from about 40 mPa⋅s to about 45 mPa⋅s, from about 40 mPa⋅s to about 50 mPa⋅s, or approximately 45 mPa⋅s to approximately 50 mPa⋅s.

[096] Another aspect of high purity and quality of the fiber is the amount of lignin, extractables and other contaminants present in the treated cellulose or in the resulting paper product. Generally, the smaller the amount of lignin, extractables and other contaminants, the higher the purity and quality of the cellulosic material in the treated cellulosic pulp. Typically, wood consists of 15% -30% of lignin and 2% -10% of extractables. There is more research to measure the lignin content in treated pulp.

[097] In determining the Kappa number (permanganate number), the Kappa number is an indicator of the hardness, whiteness, and delignification of the treated pulp pulp. The Kappa number is defined as the volume (in milliliters) of 0.1 N potassium permanganate (KMnO ₄ ) consumed per gram of anhydrous cellulose in an acidic medium for a certain time and under certain temperature conditions. The Kappa number can be in the range from 1 to 100 and allows you to estimate how much lignin is contained in the pulp, which determines the amount of bleach to be added if the goal is to obtain a product from white paper. A high Kappa number requires more bleach, while a low Kappa number requires less lignin, which requires less bleach. To determine the Kappa number, a reaction is carried out with a known amount of treated cellulose pulp and an equivalent amount of 4 N sulfuric acid and 0.1 N potassium permanganate solution for a predetermined time. The amount of cellulose pulp is selected so that at the end of the reaction time approximately 50% of the total oxidative activity of permanganate is retained. A solution of potassium iodide is added to the test solution, and then sodium thiosulfate is used to titrate the excess of iodide and the spent amount of potassium permanganate is used to calculate the lignin equivalent. The Kappa number (K) is determined using the following formula: K = p × f / w and p = (b - a) N / 0.1, where K is the Kappa number, f is the correction factor for the consumption of 50% permanganate, depending on p, w is the weight (in grams) of anhydrous cellulose in the sample, p is the amount (in milliliters) of 0.1 N permanganate that actually reacted with the test sample, b is the amount (in milliliters) of thiosulfate that reacted in the control determination, a is the amount (in milliliters) of thiosulfate that has reacted with the test subject aztsom, and N is the normality value thiosulfate. The Kappa number of bleached pulp is in the range of 25-30, pulp for paper bags is in the range of 45-55, and pulp for corrugated cardboard is in the range of 60-90. The Kappa number can also monitor the efficiency of extraction of lignin from the treated cellulose pulp, since this number is approximately proportional to the residual lignin content in the cellulose pulp. The following formula can be applied: K = cI, where K is the Kappa number, c is a constant with a value of approximately 6.57, which depends on the process and raw materials used, and I is the percentage of lignin. The standard definition of Kappa number is described, for example, in TAPPI Standard T 236 cm-99 “Pulp Kappa Number”, in ISO 302: 2015 Standard “Kappa Number Determination” and in Chai and Zhu, Rapid Pulp Kappa Number Determination Using Spectrophotometry, J. Pulp Paper Sci. 25 (11): 387-394 (1999), the contents of each of which is fully incorporated into this application by reference.

[098] When determining the copper number, the copper number is an indicator of the reducing groups of the cellulosic material and impurities having the reducing properties that are present in the treated cellulose. Hydrolyzed or oxidized cellulose is capable of reducing certain metal ions to lower valence states, and reactions of this type are used to detect cellulose degradation and to estimate the number of reducing groups. Thus, the copper number can be considered as an indicator of such impurities in cellulose as hydroxycellulose, hydrocellulose, lignin and sugars, which have reducing properties. Thus, this analysis is valuable for detecting changes that accompany decomposition, and therefore it can be considered as a test for assessing the durability of paper. The copper number is defined as the number of grams of metallic copper (as Cu ₂ O) resulting from the reduction of CuSO ₄ by reaction with 100.00 g of cellulose fibers. To determine the copper number, the kiln-dried cellulose of known mass is treated with a solution of CuSO ₄ and a solution of carbonate-bicarbonate, heated to 100 ° C for 3 hours, periodically shaking, and then washed with 5% Na ₂ CO ₃ and then hot water. The treated cellulosic material is then incubated with phosphomolybdenum acid, macerated, washed with water until the blue color of the fibers is removed, then the filtrate is diluted to the desired volume and titrated with 0.05 N KMnO ₄ until pale pink at the end of the titration. The copper number (C) is calculated using the following formula: C = 6.357 × (V - B) × N / W, where C is the copper number, V is the volume (in milliliters) of the KMnO ₄ solution for titration of the filtrate from the sample, B is the volume (in milliliters) of a KMnO ₄ solution for titration of a control filtrate, N is a normality value of 0.05 N KMnO ₄ , W is the weight (in grams) of kiln dried pulp. A standard alkali solubility study is described, for example, in TAPPI Standard T 430 cm-09 “Copper Number of Pulp, Paper and Cardboard”, the entire contents of which are incorporated herein by reference.

[099] In one embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce low lignin treated pulp. In aspects of this embodiment of the present invention, an effective amount of the papermaking additive composition disclosed herein is an amount sufficient to produce a treated pulp with a low lignin content with a Kappa number of, for example, about 5, about 10, about 15, about 20, approximately 25, approximately 30, approximately 35, approximately 40, approximately or approximately 50. In aspects of this embodiment of the present invention, an effective amount of the paper additive composition disclosed herein is an amount sufficient to produce a low lignin treated pulp with a number Kappa equal to, for example, at least 5, at least 10, at least 15, at least 20, at least 25, at least 30, at least 35, at least 40, at least 45, or at least 50. In others aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce processed pulp with a low lignin content with a Kappa number of, for example, not more than 5, not more than 10, not more than 15, not more more than 20, not more than 25, not more than 30, not more than 35, not more than 40, not more than 45 or not more than 50. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to obtain processed pulp with a low lignin content with a Kappa number of, for example, from about 5 to about 10, from about 5 to about 15, from about 5 to about 20, from about 5 to about 25, from about 5 to about 30 , from about 5 to about 35, from about specifically 5 to about 40, from about 5 to about 45, from about 5 to about 50, from about 10 to about 15, from about 10 to about 20, from about 10 to about 25, from about 10 to about 30, from about 10 to about 35, from about 10 to about 40, from about 10 to about 45, from about 10 to about 50, from about 15 to about 20, from about 15 to about 25, from about 15 to about 30, from about 15 to about 35, from about 15 to about 40, from about 15 to about 45, from about 15 to about 50, from about 20 to about 25, from about 20 to about 30, from about 20 to about 35, from about 20 to about 40, from about 20 to about 45, from about 20 to p about 50, from about 25 to about 30, from about 25 to about 35, from about 25 to about 40, from about 25 to about 45, from about 25 to about 50, from about 30 to about 35, from about 30 to about 40, from about 30 to about 45, from about 30 to about 50, from about 35 to about 40, from about 35 to about 45, from about 35 to about 50, from about 40 to about 45, from about 40 to about 50 or from about 45 to about 50.

[0100] In one embodiment of the present invention, the method or application disclosed in the present application provides a treated cellulose pulp with a low lignin content. In aspects of this embodiment of the present invention, the method or application disclosed in the present application provides for the production of treated pulp with a low lignin content with a Kappa number of, for example, approximately 5, approximately 10, approximately 15, approximately 20, approximately 25, approximately 30, approximately 35 , approximately 40, approximately or approximately 50. In aspects of this embodiment of the present invention, the method or application disclosed herein provides for preparing treated pulp with a low lignin content with a Kappa number of, for example, at least 5, at least 10, at least 15, at least 20, at least 25, at least 30, at least 35, at least 40, at least 45, or at least 50. In other aspects of this embodiment of the present invention, disclosed herein the application, the method or application provides Work pulp with a low lignin content with a Kappa number of, for example, not more than 5, not more than 10, not more than 15, not more than 20, not more than 25, not more than 30, not more than 35, not more than 40, not more than 45 not more than 50. In other aspects of this embodiment of the present invention, the method or application disclosed in the present application provides for the production of treated pulp with a low lignin content with a Kappa number of, for example, from about 5 to about 10, from about 5 to about 15, from about 5 to about 20, from about 5 to about 25, from about 5 to about 30, from about 5 to about 35, from about 5 to about 40, from about 5 to about 45, from about 5 to about 50, from about 10 to about 15, from about 10 to about 20, from about 10 to about 25, from about 10 to about specifically 30, from about 10 to about 35, from about 10 to about 40, from about 10 to about 45, from about 10 to about 50, from about 15 to about 20, from about 15 to about 25, from about 15 to about 30, from about 15 to about 35, from about 15 to about 40, from about 15 to about 45, from about 15 to about 50, from about 20 to about 25, from about 20 to about 30, from about 20 to about 35 from about 20 to about 40, from about 20 to about 45, from about 20 to about 50, from about 25 to about 30, from about 25 to about 35, from about 25 to about 40, from about 25 to about 45, from about 25 to about 50, from about 30 to about 35, from about 30 to about 40, from about 30 to about 45, from about 30 to about 50, from about 35 to about 40, from about 35 to about 45, from about 35 to about 50, from about 40 to about 45, from about 40 to about 50; or from about 45 to about 50.

[0101] In one embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce a low impurity treated pulp. In aspects of this embodiment of the present invention, an effective amount of the paper additive additive composition disclosed herein is an amount sufficient to produce a low impurity treated cellulose pulp with a copper number of, for example, about 0.5, about 0.75, about 1 0, approximately 1.25, approximately 1.5, approximately 1.75, approximately 2.0, approximately 2.25, approximately 2.5, approximately 2.75, approximately 3.0, approximately 3.25, approximately 3 5, approximately 3.75, approximately 4.0, approximately 4.25, approximately 4.5, approximately 4.75, approximately 5.0, approximately 5.25, approximately 5.5, approximately 5.75, approximately 6 0, about 6.25, about 6.5, about 6.75, or about 7.0. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce a low impurity treated cellulose pulp with a copper number of, for example, at least 0.5, at least 0 , 75, at least 1.0, at least 1.25, at least 1.5, at least 1.75, at least 2.0, at least 2.25, at least 2, 5, at least 2.75, at least 3.0, at least 3.25, at least 3.5, at least 3.75, at least 4.0, at least 4.25 at least 4.5, at least 4.75, at least 5.0, at least 5.25, at least 5.5, at least 5.75, at least 6.0, at least 6.25, at least 6.5, at least 6.75, or at least 7.0. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce processed pulp with a low impurity content with a copper number of, for example, not more than 0.5, not more than 0.75 , no more than 1.0, no more than 1.25, no more than 1.5, no more than 1.75, no more than 2.0, no more than 2.25, no more than 2.5, no more than 2.75, not more than 3.0, no more than 3.25, no more than 3.5, no more than 3.75, no more than 4.0, no more than 4.25, no more than 4.5, no more than 4.75, no more than 5 0, not more than 5.25, not more than 5.5, not more than 5.75, not more than 6.0, not more than 6.25, not more than 6.5, not more than 6.75 or not more than 7.0 . In other aspects of this embodiment, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce a low impurity treated cellulose pulp with a copper number of, for example, from about 0.5 to about 1.0, from from about 0.5 to about 2.0; from about 0.5 to about 3.0; from about 0.5 to about 4.0; from about 0.5 to about 5.0; from about 0.5 to about 6.0, from about 0.5 to about 7.0, from about 0.75 to about 1.0, from about 0.75 to about 2.0, from about 0.75 to about 3.0, from about 0.75 to about 4.0, from about 0.75 to about 5.0, from about 0.75 to about 6.0, from about 0.75 to about 7.0, from about 1.0 to about 2 , 0, from approximate specifically 1.0 to about 3.0, from about 1.0 to about 4.0, from about 1.0 to about 5.0, from about 1.0 to about 6.0, from about 1.0 to about 7.0, from about 1.25 to about 2.0, from about 1.25 to about 3.0, from about 1.25 to about 4.0, from about 1.25 to about 5.0, from about 1.25 to about 6.0, from about 1.25 to about 7.0, from about 1.5 to about 2.0, from about 1.5 to about 3.0, from about 1.5 to about 4 , 0, from about 1.5 to about 5.0, from about 1.5 to about 6.0, from about 1.5 to about 7.0, from about 1.75 to about 2.0, from about 1 , 75 to about 3.0, from about 1.75 to about 4.0, from about 1.75 to about 5.0, from about 1.75 to about 6.0, from about especially 1.75 to about 7.0, from about 2 to about 3.0, from about 2 to about 4.0, from about 2 to about 5.0, from about 2 to about 6.0, or from about 2 to approximately 7.0.

[0102] In one embodiment of the present invention, the method or application disclosed herein provides for the preparation of low impurity treated pulp. In aspects of this embodiment of the present invention, the method or application disclosed in the present application provides a treated cellulosic pulp with a low impurity content with a copper number of, for example, about 0.5, about 0.75, about 1.0, about 1.25, approximately 1.5, approximately 1.75, approximately 2.0, approximately 2.25, approximately 2.5, approximately 2.75, approximately 3.0, approximately 3.25, approximately 3.5, approximately 3.75, approximately 4.0, approximately 4.25, approximately 4.5, approximately 4.75, approximately 5.0, approximately 5.25, approximately 5.5, approximately 5.75, approximately 6.0, approximately 6.25, about 6.5, about 6.75, or about 7.0. In other aspects of this embodiment of the present invention, the method or application disclosed herein provides a treated cellulosic pulp with a low impurity content with a copper number of, for example, at least 0.5, at least 0.75, at least 1, 0, at least 1.25, at least 1.5, at least 1.75, at least 2.0, at least 2.25, at least 2.5, at least 2.75 at least 3.0, at least 3.25, at least 3.5, at least 3.75, at least 4.0, at least 4.25, at least 4.5, at least 4.75, at least 5.0, at least 5.25, at least 5.5, at least 5.75, at least 6.0, at least 6.25, at at least 6.5, at least 6.75, or at least 7.0. In other aspects of this embodiment of the present invention, the method or application disclosed in the present application provides a treated pulp with a low content of impurities with a copper number of, for example, not more than 0.5, not more than 0.75, not more than 1.0, not more more than 1.25, no more than 1.5, no more than 1.75, no more than 2.0, no more than 2.25, no more than 2.5, no more than 2.75, no more than 3.0, no more than 3 , 25, no more than 3.5, no more than 3.75, no more than 4.0, no more than 4.25, no more than 4.5, no more than 4.75, no more than 5.0, no more than 5.25 , not more than 5.5, not more than 5.75, not more than 6.0, not more than 6.25, not more than 6.5, not more than 6.75 or not more than 7.0. In other aspects of this embodiment of the present invention, the method or application disclosed in the present application provides for the production of low impurity treated pulp with a copper number of, for example, from about 0.5 to about 1.0, from about 0.5 to about 2 , 0, from about 0.5 to about 3.0, from about 0.5 to about 4.0, from about 0.5 to about 5.0, from about 0.5 to about 6.0, from about 0 5 to about 7.0, from about 0.75 to about 1.0, from about 0.75 to about 2.0, from about 0.75 to about 3.0, from about 0.75 to about 4, 0, from about 0.75 to about 5.0, from about 0.75 to about 6.0, from about 0.75 to about 7.0, from about 1.0 to about 2.0, from about 1, 0 to about 3.0, from about 1.0 to about specifically 4.0, from about 1.0 to about 5.0, from about 1.0 to about 6.0, from about 1.0 to about 7.0, from about 1.25 to about 2.0, from from about 1.25 to about 3.0, from about 1.25 to about 4.0, from about 1.25 to about 5.0, from about 1.25 to about 6.0, from about 1.25 to about 7.0, from about 1.5 to about 2.0, from about 1.5 to about 3.0, from about 1.5 to about 4.0, from about 1.5 to about 5.0, from about 1.5 to about 6.0, from about 1.5 to about 7.0, from about 1.75 to about 2.0, from about 1.75 to about 3.0, from about 1.75 to about 4 , 0, from about 1.75 to about 5.0, from about 1.75 to about 6.0, from about 1.75 to about 7.0, from about 2 to about specifically 3.0, from about 2 to about 4.0, from about 2 to about 5.0, from about 2 to about 6.0, or from about 2 to about 7.0.

[0103] Another aspect of the high purity and quality of the fibers is the content of carboxyl groups in the treated cellulosic pulp. As a rule, the more carboxyl groups, the higher the purity and integrity of the cellulosic material in the treated cellulosic pulp. There is more research to measure the amount of carboxyl groups in cellulosic material from treated cellulose pulp.

[0104] In a study of carboxyl content, the amount of carboxyl is determined, which is an indicator of paper strength, delignification and the reuse of cellulose fiber. Carboxyl groups are useful in binding cellulose fibers to paper, which provides paper strength. The higher the content of carboxyl groups, the greater the strength of the paper. To analyze the carboxyl content, the dried treated cellulose is mixed with 0.1 M HCl for 60 minutes, and then filtered and washed with water. The treated cellulosic material is then added to 250 ml of a 1 mM NaCl solution, which is acidified with 1.5 ml of 0.1 M HCl and then conductometric titration of 0.05 N NaOH is carried out in 0.2 ml increments. According to titration, a graph of the conductivity versus volume is plotted to determine the milliequivalent of acid groups per kilogram of cellulose. The content of carboxyl groups C _{0 is} calculated using the following formula: C ₀ = N × V × 100 / M, where C ₀ represents the content of carboxyl groups (meq / 100 g of cellulose), N is the concentration of the titrant, V is the volume (in milliliters) ) at the equilibrium point, and M is the mass (in grams) of kiln dried pulp. Standard alkali solubility studies are described, for example, in TAPPI Standard T 237 cm-08 “Carboxyl Content in Cellulose” and Chen, et al., Fiber Properties of Eucalyptus Kraft Pulp with Different Carboxyl Group Contents, Cellulose 20: 2839-2846 (2013), in Standard Test Methods for Carboxyl Content in Cellulose ASTM D 1926-00 (Standard Test Methods for Carboxyl Content if Cellulose) and Barbosa, et al., A Rapid Method for Quantification of Carboxyl Group in Cellulose Pulp, BioResources 8 ( 1): 1043-1054 (2013), the contents of which are incorporated into this application in full by reference.

[0105] In one embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce a high carboxyl treated pulp. In aspects of this embodiment of the present invention, an effective amount of the papermaking additive composition disclosed herein is an amount sufficient to produce treated pulp with a carboxyl content of, for example, about 4 meq / 100 g cellulose, about 4.5 meq / 100 g cellulose, about 5 meq / 100 g of cellulose, about 5.5 meq / 100 g of cellulose, about 6 meq / 100 g of cellulose, about 6.5 meq / 100 g of cellulose, about 7 meq / 100 g of cellulose, about 7.5 meq / 100 g cellulose, about 8 meq / 100 g cellulose, about 8.5 meq / 100 g cellulose, about 9 meq / 100 g cellulose, about 9.5 meq / 100 g cellulose, or about 10 meq / 100 g cellulose. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce treated cellulose pulp with a carboxyl content of, for example, at least 4 meq / 100 g of cellulose, at least 4, 5 meq / 100 g cellulose, at least 5 meq / 100 g cellulose, at least 5.5 meq / 100 g cellulose, at least 6 meq / 100 g cellulose, at least 6.5 meq / 100 g cellulose at least 7 meq / 100 g cellulose, at least 7.5 meq / 100 g cellulose, at least 8 meq / 100 g cellulose, at least 8.5 meq / 100 g cellulose, at least 9 meq / 100 g cellulose, at least 9.5 meq / 100 g cellulose or at least 10 meq / 100 g cellulose. In other aspects of this embodiment of the present invention, the method disclosed herein provides for treated cellulose pulp with a carboxyl content of, for example, not more than 4 meq / 100 g of cellulose, not more than 4.5 meq / 100 g of cellulose, not more than 5 meq / 100 g of cellulose, not more than 5.5 meq / 100 g of cellulose, not more than 6 meq / 100 g of cellulose, not more than 6.5 meq / 100 g of cellulose, not more than 7 meq / 100 g of cellulose, not more than 7.5 meq / 100 g of cellulose, not more than 8 meq / 100 g of cellulose, not more than 8.5 meq / 100 g of cellulose, not more than 9 meq / 100 g of cellulose, not more than 9.5 meq / 100 g of cellulose or not more than 10 meq / 100 g of pulp. In other aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated cellulosic pulp with a carboxyl content of, for example, from about 4 meq / 100 g of cellulose to about 5 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 6 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 7 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 6 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 7 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 5 meq / 100 g cellulose up to about 9 meq / 100 g cellulose, from about 5 meq / 100 g cellulose to about 10 meq / 100 g cellulose, from about 6 meq / 100 g cellulose to about 7 meq / 100 g cellulose, from about 6 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 6 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 6 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 8 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 8 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, or from about 9 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose.

[0106] In one embodiment of the present invention, the method or application disclosed herein provides for the preparation of treated carboxylated pulp with a high content of carboxyl. In aspects of this embodiment of the present invention, the method or application disclosed herein provides treated cellulose pulp with a carboxyl content of, for example, about 4 meq / 100 g cellulose, about 4.5 meq / 100 g cellulose, about 5 meq / 100 g cellulose, approximately 5.5 meq / 100 g cellulose, approximately 6 meq / 100 g cellulose, approximately 6.5 meq / 100 g cellulose, approximately 7 meq / 100 g cellulose, approximately 7.5 meq / 100 g cellulose, approximately 8 meq / 100 g cellulose, about 8.5 meq / 100 g cellulose, about 9 meq / 100 g cellulose, about 9.5 meq / 100 g cellulose, or about 10 meq / 100 g cellulose. In other aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated cellulose pulp with a carboxyl content of, for example, at least 4 meq / 100 g cellulose, at least 4.5 meq / 100 g cellulose, according to at least 5 meq / 100 g cellulose, at least 5.5 meq / 100 g cellulose, at least 6 meq / 100 g cellulose, at least 6.5 meq / 100 g cellulose, at least 7 meq / 100 g of cellulose, at least 7.5 meq / 100 g of cellulose, at least 8 meq / 100 g of cellulose, at least 8.5 meq / 100 g of cellulose, at least 9 meq / 100 g of cellulose, at least 9.5 meq / 100 g of cellulose or at least 10 meq / 100 g of cellulose. In other aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated cellulose pulp with a carboxyl content of, for example, not more than 4 meq / 100 g of cellulose, not more than 4.5 meq / 100 g of cellulose, not more than 5 meq / 100 g cellulose, not more than 5.5 meq / 100 g cellulose, not more than 6 meq / 100 g cellulose, not more than 6.5 meq / 100 g cellulose, not more than 7 meq / 100 g cellulose, not more than 7, 5 meq / 100 g of cellulose, not more than 8 meq / 100 g of cellulose, not more than 8.5 meq / 100 g of cellulose, not more than 9 meq / 100 g of cellulose, not more than 9.5 meq / 100 g of cellulose or not more than 10 meq / 100 g of pulp. In other aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated cellulosic pulp with a carboxyl content of, for example, from about 4 meq / 100 g of cellulose to about 5 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 6 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 7 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 6 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 7 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 5 meq / 100 g cellulose up to about 9 meq / 100 g cellulose, from about 5 meq / 100 g cellulose to about 10 meq / 100 g cellulose, from about 6 meq / 100 g cellulose to about 7 meq / 100 g cellulose, from about 6 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 6 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 6 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 8 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 8 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, or from about 9 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose.

[0107] Another aspect of the high purity and quality of the fibers is the whiteness of the treated pulp or the resulting paper product. Generally, the higher the whiteness, the higher the purity and integrity of the cellulosic material in the treated cellulosic pulp or in the resulting paper product. There is more research to measure the amount of carboxyl groups in cellulosic material from treated cellulose pulp.

[0108] Whiteness is the numerical value of the reflection coefficient of a sample relative to blue light with certain spectral and geometric characteristics. Initially, blue light reflection measurements were developed to determine the amount of bleach used in pulp production. This procedure is applicable for all types of cellulose of natural color and for paper and paperboard obtained from it. Whiteness is based on a scale from zero to 100, with the higher the reflection coefficient, the whiter the paper will look. To conduct whiteness studies, a paper sample is irradiated with a laser with a wavelength of 457 nm and a width of 44 nm, and the amount of blue light reflected from the surface of the paper with a wavelength of 457 nm is measured. Standard whiteness studies are described, for example, in TAPPI Standard T 452 om-08 “Pulp, paper and paperboard whiteness (directional reflectance at 457 nm)” and ISO 2470: 2009 “Measurement of diffuse reflectance of blue light (ISO whiteness)” , the contents of which are fully incorporated into this application by reference.

[0109] In one embodiment of the present invention, an effective amount of the papermaking additive composition disclosed herein is an amount sufficient to produce treated pulp or a high whiteness paper product obtained from such pulp. In aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce treated pulp or a paper product obtained from such pulp with a whiteness value of, for example, about 70%, about 75%, about 80%, approximately 85%, approximately 86%, approximately 87%, approximately 88%, approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96% , approximately 97%, approximately 98%, or approximately 99%. In aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce a treated pulp or a paper product obtained from such pulp with a whiteness value of, for example, at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91% at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98%, or at least 99%. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce a treated pulp or a paper product obtained from such pulp with a whiteness value of, for example, not more than 70%, not more than 75 %, no more than 80%, no more than 85%, no more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91%, no more than 92%, no more than 93 %, not more than 94%, not more than 95%, not more than 96%, not more than 97%, not more than 98% or not more than 99%. In other aspects of this embodiment of the present invention, the method or use disclosed herein provides for the production of treated cellulose pulp with an alpha cellulose content of, for example, from about 70% to about 80%, from about 70% to about 85%, from about 70 % to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95% , from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about 93%, from about 85% to about 95%, from about 85% to about 97%, from about 85% to about 99%, from about 90% to about 93%, from about specifically 90% to about 95%, from about 90% to about 97%, from about 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97%, or from about 95% to about 99%.

[0110] In one embodiment of the present invention, the method or application disclosed herein provides for the production of treated pulp or a high whiteness paper product obtained from such pulp. In aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated pulp or a paper product obtained from such pulp with a whiteness value of, for example, approximately 70%, approximately 75%, approximately 80%, approximately 85%, approximately 86%, approximately 87%, approximately 88%, approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96%, approximately 97%, approximately 98% or approximately 99%. In aspects of this embodiment of the present invention, the method or application disclosed herein provides for the preparation of treated pulp or a paper product obtained from such pulp with a whiteness value of, for example, at least 70%, at least 75%, at least 80% at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91%, at least 92%, at at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98%, or at least 99%. In other aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated pulp or a paper product obtained from such pulp with a whiteness value of, for example, not more than 70%, not more than 75%, not more than 80%, not more than 85%, no more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91%, no more than 92%, no more than 93%, no more than 94%, not more than 95%, no more than 96%, no more than 97%, no more than 98% or no more than 99%. In other aspects of this embodiment of the present invention, the method or use disclosed herein provides for the production of treated cellulose pulp with an alpha cellulose content of, for example, from about 70% to about 80%, from about 70% to about 85%, from about 70 % to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95% , from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about 93%, from about 85% to about 95%, from about 85% to about 97%, from about 85% to about 99%, from about 90% to about 93%, from about specifically 90% to about 95%, from about 90% to about 97%, from about 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97%, or from about 95% to about 99%.

[0111] Another aspect of high purity and quality of fibers is the amount of impurities and / or the content of contaminants in the treated pulp or in the resulting paper product. Typically, the lower the content of impurities and / or pollutants, the higher the purity and integrity of the cellulosic material in the treated cellulosic pulp or in the resulting paper product. There is more research to measure the amount of carboxyl groups in cellulosic material from treated cellulose pulp.

[0112] Another aspect of the high purity and quality of the fibers is the content of the printing ink in the treated pulp or in the resulting paper product. Typically, the lower the ink content, the higher the purity and integrity of the cellulosic material in the treated cellulosic pulp or in the resulting paper product. There is more research to measure the ink content of the treated pulp pulp material.

[0113] Since most water-soluble and volatile compounds soluble in organic solvents are usually removed during the cooking phase, impurities and / or pollutants usually contain tar, fatty acids and their esters, waxes and unsaponifiables, as well as impurities and / or pollutants recycled paper products such as printing ink, plastics, and other additives. Such impurities and / or pollutants are commonly referred to as extractables.

[0114] In a study of solvent extractable substances, the content of extractable substances in the treated pulp is determined, which is an indicator of paper strength, delignification and the frequency of reuse of cellulose fiber. Studies of solvent-extracted substances include studies based on dichloromethane and ethanol-benzene. The content of dichloromethane extracted substances in the treated cellulose is an indicator of the content of waxes, fats, resins, phytosterols and non-volatile hydrocarbons. The content of substances extracted with ethanol-benzene in the treated cellulose includes components extracted with dichloromethane, including low molecular weight carbohydrates, salts and other water-soluble substances in addition to waxes, fats, resins, phytosterols and non-volatile hydrocarbons. To conduct a solvent extraction test, the dried treated cellulose is mixed with an appropriate solvent and the sample is heated in the extraction apparatus for at least 24 extraction cycles for about 4 to about 5 hours. The sample is removed from the apparatus, any remaining solvent is evaporated, and then the sample is dried in an oven. The content of extractables E% is calculated using the following formula: E% = [(W _e - W _b ) / W _p ] × 100, where E% is the content of extractables, W _e is the weight of the extract after drying in an oven (in grams) , W _b is the weight of the residue of the solvent after drying in the oven (in grams) and W _p is the weight of the original sample of cellulose after drying in the oven (in grams). Standard studies of solvent-extracted substances are described, for example, in TAPPI Standard T 204 cm-97 "Solvent-Extracted Wood and Cellulose Substances", the contents of which are incorporated herein by reference in their entirety.

[0115] In one embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce processed pulp with a low content of extractables. In aspects of this embodiment of the present invention, an effective amount of the papermaking additive composition disclosed herein is an amount sufficient to produce treated pulp with extractables of, for example, about 0.01%, about 0.02%, about 0.03 %, approximately 0.04%, approximately 0.05%, approximately 0.06%, approximately 0.07%, approximately 0.08%, approximately 0.09%, approximately 0.1%, approximately 0.2%, approximately 0.3%, approximately 0.4%, approximately 0.5%, approximately 0.6%, approximately 0.7%, approximately 0.8%, approximately 0.9%, approximately 1%, approximately 2%, about 3%, about 4%, or about 5%. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce treated pulp with an extractable content of, for example, not more than 0.01%, not more than 0.02%, not more than 0.03%, no more than 0.04%, no more than 0.05%, no more than 0.06%, no more than 0.07%, no more than 0.08%, no more than 0.09%, no more 0.1%, not more than 0.2%, not more than 0.3%, not more than 0.4%, not more than 0.5%, not more than 0.6%, not more than 0.7%, not more than 0 , 8%, not more than 0.9%, not more than 1%, not more than 2%, not more than 3%, not more than 4% or not more than 5%. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is an amount sufficient to produce treated pulp with extractables of, for example, from about 0.001% to about 0.005%, from about 0.001% to about 0.01%, from about 0.001% to about 0.05%, from about 0.001% to about 0.1%, from about 0.001% to about 0.5%, from about 0.001% to about 1%, from about 0.001 % to about 5%, from about 0.005% to about 0.01%, from about 0.005% to about 0.05%, from about 0.005% to about 0.1%, from about 0.005% to about 0.5%, from about 0.005% to about 1%, from about 0.005% to about 5%, from about 0.01% to about 0.05%, from about 0.01% for about 0.1%, from about 0.01% to about 0.5%, from about 0.01% to about 1%, from about 0.01% to about 5%, from about 0.05% to about 0.1%, from about 0.05% to about 0.5%, from about 0.05% to about 1%, from about 0.05% to about 5%, from about 0.1% to about 0, 5%, from about 0.1% to about 1%, from about 0.1% to about 5%, from about 0.5% to about 1%, from about 0.5% to about 5%, or from about 1 % to about 5%.

[0116] In one embodiment of the present invention, the method or application disclosed in the present application provides for the production of processed pulp with a low extractable content. In aspects of this embodiment of the present invention, the method or application disclosed in the present application provides for the production of treated pulp with an extractable content of, for example, about 0.01%, about 0.02%, about 0.03%, about 0.04%, approximately 0.05%, approximately 0.06%, approximately 0.07%, approximately 0.08%, approximately 0.09%, approximately 0.1%, approximately 0.2%, approximately 0.3%, approximately 0 , 4%, approximately 0.5%, approximately 0.6%, approximately 0.7%, approximately 0.8%, approximately 0.9%, approximately 1%, approximately 2%, approximately 3%, approximately 4%, or approximately 5%. In other aspects of this embodiment of the present invention, the method or application disclosed in this application provides for the production of treated cellulose with an extractable content of, for example, not more than 0.01%, not more than 0.02%, not more than 0.03%, not more than 0.04%, not more than 0.05%, not more than 0.06%, not more than 0.07%, not more than 0.08%, not more than 0.09%, not more than 0.1%, not more than 0 , 2%, not more than 0.3%, not more than 0.4%, not more than 0.5%, not more than 0.6%, not more than 0.7%, not more than 0.8%, not more than 0, 9%, not more than 1%, not more than 2%, not more than 3%, not more than 4% or not more than 5%. In other aspects of this embodiment of the present invention, the method or application disclosed herein provides for the production of treated pulp with extractable contents of, for example, from about 0.001% to about 0.005%, from about 0.001% to about 0.01%, from about 0.001 % to about 0.05%, from about 0.001% to about 0.1%, from about 0.001% to about 0.5%, from about 0.001% to about 1%, from about 0.001% to about 5%, from about 0.005% to about 0.01%, from about 0.005% to about 0.05%, from about 0.005% to about 0.1%, from about 0.005% to about 0.5%, from about 0.005% to about 1% from about 0.005% to about 5%, from about 0.01% to about 0.05%, from about 0.01% to about 0.1%, from about 0.01% to about 0.5% from about 0.01% to about 1%, from about 0.01% to about 5%, from about 0.05% to about 0.1%, from about 0.05% to about 0.5%, from from about 0.05% to about 1%, from about 0.05% to about 5%, from about 0.1% to about 0.5%, from about 0.1% to about 1%, from about 0.1 % to about 5%, from about 0.5% to about 1%, from about 0.5% to about 5%, or from about 1% to about 5%.

[0117] An effective amount of the paper manufacture additive composition disclosed herein may be a dilution of the paper manufacture additive composition disclosed herein. In aspects of this embodiment of the present invention, an effective amount of the papermaking additive composition disclosed herein is a dilution with the ratio of the composition of the papermaking additive: diluent equal to, for example, approximately 1:50, approximately 1:75, approximately 1: 100, approximately 1 : 125, approximately 1: 150, approximately 1: 175, approximately 1: 200, approximately 1: 225, approximately 1: 250, approximately 1: 275, approximately 1: 300, approximately 1: 325, approximately 1: 350, approximately 1 : 375, approximately 1: 400, approximately 1: 425, approximately 1: 450, approximately 1: 475, approximately 1: 500, approximately 1: 525, approximately 1: 550, approximately 1: 575, or approximately 1: 600. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is a dilution with a ratio of the composition of the paper manufacture additive: diluent equal to, for example, at least 1:50, at least 1:75, at least at least 1: 100, at least 1: 125, at least 1: 150, at least 1: 175, at least 1: 200, at least 1: 225, at least 1: 250, at least 1: 275, at least 1: 300, at least 1: 325, at least 1: 350, at least 1: 375, at least 1: 400, at least 1: 425, at least 1 : 450, at least 1: 475, at least 1: 500, at least 1: 525, at least 1: 550, at least 1: 575, or at least 1: 600. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is a dilution with a ratio of the paper manufacture additive: diluent composition equal to, for example, not more than 1:50, not more than 1:75, not more than 1: 100, no more than 1: 125, no more than 1: 150, no more than 1: 175, no more than 1: 200, no more than 1: 225, no more than 1: 250, no more than 1: 275, no more than 1: 300 no more than 1: 325, no more than 1: 350, no more than 1: 375, no more than 1: 400, no more than 1: 425, no more than 1: 450, no more than 1: 475, no more than 1: 500, no more 1: 525, not more than 1: 550, not more than 1: 575 or not more than 1: 600. In other aspects of this embodiment of the present invention, an effective amount of the papermaking additive composition disclosed herein is a dilution with a papermaking: diluting additive composition ratio of, for example, about 1:50 to about 1: 100, about 1:50 to about 1: 200, approximately 1:50 to approximately 1: 300, approximately 1:50 to approximately 1: 400, approximately 1:50 to approximately 1: 500, approximately 1:50 to approximately 1: 600, approximately 1: 100 to approximately 1: 200, approximately 1: 100 to approximately 1: 300, approximately 1: 100 to approximately 1: 400, approximately 1: 100 to approximately 1: 500, approximately 1: 100 to approximately 1: 600, approximately 1: 200 to approximately 1: 300, about 1: 200 to about 1: 400, about 1: 200 to about 1: 500, about 1: 200 to about 1: 600, about 1: 300 to about 1: 400, approximately 1: 300 to approximately 1: 500, approximately 1: 300 to approximately 1: 600, approximately 1: 400 to approximately 1: 500, approximately 1: 400 to approximately 1: 600, or approximately 1: 500 to approximately 1: 600.

[0118] In aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is a dilution with the ratio of the paper manufacture: diluent additive composition equal to, for example, about 1: 500, about 1: 750, about 1: 1000 , approximately 1: 1250, approximately 1: 1500, approximately 1: 1750, approximately 1: 2000, approximately 1: 2250, approximately 1: 2500, approximately 1: 2750, approximately 1: 3000, approximately 1: 3250, approximately 1: 3500 , approximately 1: 3750, approximately 1: 4000, approximately 1: 4250, approximately 1: 4500, approximately 1: 4750, approximately 1: 5000, approximately 1: 5250, approximately 1: 5500, approximately 1: 5750, approximately 1: 6000 about 1: 7000, about 1: 8000, about 1: 9000, or about 1: 10000. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is a dilution with a ratio of the composition of the paper manufacture additive: diluent equal to, for example, at least 1: 500, at least 1: 750, at least at least 1: 1000, at least 1: 1250, at least 1: 1500, at least 1: 1750, at least 1: 2000, at least 1: 2250, at least 1: 2500, at least 1: 2750, at least 1: 3000, at least 1: 3250, at least 1: 3500, at least 1: 3750, at least 1: 4000, at least 1: 4250, at least 1 : 4500, at least 1: 4750, at least 1: 5000, at least 1: 5250, at least 1: 5500, at least 1: 5750, at least 1: 6000, at least 1: 7000, at least 1: 8000, at least 1: 9000, or at least 1: 10000. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is a dilution with a ratio of the paper manufacture additive: diluent composition equal to, for example, not more than 1: 500, not more than 1: 750, not more than 1: 1000, no more than 1: 1250, no more than 1: 1500, no more than 1: 1750, no more than 1: 2000, no more than 1: 2250, no more than 1: 2500, no more than 1: 2750, no more than 1: 3000, no more than 1: 3250, no more than 1: 3500, no more than 1: 3750, no more than 1: 4000, no more than 1: 4250, no more than 1: 4500, no more than 1: 4750, no more than 1: 5000, no more 1: 5250, no more than 1: 5500, no more than 1: 5750, no more than 1: 6000 no more than 1: 7000, no more than 1: 8000, no more than 1: 9000 or no more than 1: 10000. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein is a dilution with a ratio of the composition of the paper manufacture: diluent additive, for example, from about 1: 500 to about 1: 1000, from about 1: 500 to about 1: 2000, from about 1: 500 to about 1: 3000, from about 1: 500 to about 1: 4000, from about 1: 500 to about 1: 5000, from about 1: 500 to about 1: 6000, from about 1: 500 to about 1: 7000, from about 1: 500 to about 1: 8000, from about 1: 500 to about 1: 9000, from about 1: 500 to about 1: 10000, from about 1: 1000 to about 1: 2000, from about 1: 1000 to about 1: 3000, from about 1: 1000 to about 1: 4000, from about 1: 1000 to about 1: 5000, from about 1: 1000 to about 1: 6000, from about 1: 1000 to about 1: 7000, from about 1: 1000 to about 1: 8000, from about 1: 1000 to about 1: 9000, from about 1: 1000 to about 1: 10000 , from about 1: 2000 to about 1: 3000, from about 1: 2000 to about 1: 4000, from about 1: 2000 to about 1: 5000, from about 1: 2000 to about 1: 6000, from about 1: 2000 to about 1: 7000, from about 1: 2000 to about 1: 8000, from about 1: 2000 to about 1: 9000, from about 1: 2000 to about 1: 10000, from about 1: 3000 to about 1: 4000, from about 1: 3000 to about 1: 5000, from about 1: 3000 to about 1: 6000, from about 1: 3000 to about 1: 7000, from about 1: 3000 to about 1: 8000, from about 1: 3000 to about 1: 9000, from about 1: 3000 to about 1: 1000 0, from about 1: 4000 to about 1: 5000, from about 1: 4000 to about 1: 6000, from about 1: 4000 to about 1: 7000, from about 1: 4000 to about 1: 8000, from about 1: 4000 to about 1: 9000, from about 1: 4000 to about 1: 10000, from about 1: 5000 to about 1: 6000, from about 1: 5000 to about 1: 7000, from about 1: 5000 to about 1: 8000 , from about 1: 5000 to about 1: 9000, from about 1: 5000 to about 1: 10000, from about 1: 6000 to about 1: 7000, from about 1: 6000 to about 1: 8000, from about 1: 6000 to about 1: 9000, from about 1: 6000 to about 1: 10000, from about 1: 7000 to about 1: 8000, from about 1: 7000 to about 1: 9000, from about 1: 7000 to about 1: 10000, from about 1: 8000 to about 1: 9000, from about 1: 8000 to about 1: 10000; or from about 1: 9000 to about 1: 10000.

[0119] In aspects of this embodiment, an effective amount of the paper manufacture additive composition disclosed herein has a final concentration of, for example, about 0.0001%, about 0.0002%, about 0.0003%, about 0.0004 %, approximately 0.0005%, approximately 0.0006%, approximately 0.0007%, approximately 0.0008%, approximately 0.0009%, approximately 0.001%, approximately 0.002%, approximately 0.003%, approximately 0.004%, approximately 0.005 %, approximately 0.006%, approximately 0.007%, approximately 0.008%, approximately 0.009%, approximately 0.01%, approximately 0.02%, approximately 0.03%, approximately 0.04%, approximately 0.05%, approximately 0 , 06%, approximately 0.07%, approximately 0.08%, approximately 0.09%, approximately 0.1%, approximately 0.2%, approximately 0.3%, approximately 0.4%, approximately 0.5 %, approximately 0.6%, approximately 0.7%, approximately 0.8%, approximately 0.9%, approximately 1%, approximately 2%, approximately 3%, approximately 4%, approximately 5%, approximately 6%, approximately 7%, approximately 8%, approximately 9%, or approximately 10%. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein has a final concentration of, for example, at least 0.0001%, at least 0.0002%, at least 0.0003%, at least 0.0004%, at least 0.0005%, at least 0.0006%, at least 0.0007%, at least 0.0008%, at least 0.0009%, at least at least 0.001%, at least 0.002%, at least 0.003%, at least 0.004%, at least 0.005%, at least 0.006%, at least 0.007%, at least 0.008%, at least 0.009 %, at least 0.01%, at least 0.02%, at least 0.03%, at least 0.04%, at least 0.05%, at least 0.06%, at least 0.07%, at least 0.08%, at least 0.09%, at least 0.1%, at least 0.2%, at least 0.3%, at least at least 0.4%, at least 0.5%, at least 0.6%, at least at least 0.7%, at least 0.8%, at least 0.9%, at least 1%, at least 2%, at least 3%, at least 4%, at least 5%, at least 6%, at least 7%, at least 8%, at least 9%, or at least 10%. In other aspects of this embodiment of the present invention, an effective amount of the paper manufacture additive composition disclosed herein has a final concentration of, for example, not more than 0.0001%, not more than 0.0002%, not more than 0.0003%, not more than 0 , 0004%, not more than 0.0005%, not more than 0.0006%, not more than 0.0007%, not more than 0.0008%, not more than 0.0009%, not more than 0.001%, not more than 0.002%, not more than 0.003%, not more than 0.004%, not more than 0.005%, not more than 0.006%, not more than 0.007%, not more than 0.008%, not more than 0.009%, not more than 0.01%, not more than 0.02%, not more 0.03%, not more than 0.04%, not more than 0.05%, not more than 0.06%, not more than 0.07%, not more than 0.08%, not more than 0.09%, not more than 0 , 1%, not more than 0.2%, not more than 0.3%, not more than 0.4%, not more than 0.5%, not more than 0.6%, not more than 0.7%, not more than 0, 8%, not more than 0.9%, not more than 1%, not more than 2%, not more than 3%, not more than 4%, not more than 5%, not more than 6%, not more than 7%, not more than 8%, no more than 9% or no more than 10%. In other aspects of this embodiment, an effective amount of the paper manufacture additive composition disclosed herein has a final concentration of, for example, from about 0.0001% to about 0.0005%, from about 0.0001% to about 0.001%, from about 0.0001% to about 0.005%, from about 0.0001% to about 0.01%, from about 0.0001% to about 0.05%, from about 0.0001% to about 0.1%, from about 0.0001% to about 0.5%, from about 0.0001% to about 1%, from about 0.0001% to about 5%, from about 0.0001% to about 10%, from about 0, 0005% to about 0.001%, from about 0.0005% to about 0.005%, from about 0.0005% to about 0.01%, from about 0.0005% to about 0.05%, from about 0.0005% up to about 0.1%, from about 0.0005% to about 0.5%, from about 0.0005% to about 1%, from about 0.0005% to about 5%, from about 0.0005% to about 10%, from about 0.001% to about 0.005%, from about 0.001% to about 0.01%, 0.001% to about 0.05%, from about 0.001% to about 0.1%, 0.001% to about 0.5%, 0.001% to about 1%, 0.001% to about 5 %, from about 0.001% to about 10%, from about 0.005% to about 0.01%, from about 0.005% to about 0.05%, from about 0.005% to about 0.1%, from about 0.005% to about 0.5%, from about 0.005% to about 1%, from about 0.005% to about 5%, from about 0.005% to about 10%, from about 0.01% to about 0.05%, from about 0.01 % to about 0.1%, from about 0.01% to about 0.5%, from about 0.01% to at about 1%, from about 0.01% to about 5%, from about 0.01% to about 10%, from about 0.05% to about 0.1%, from about 0.05% to about 0.5 %, from about 0.05% to about 1%, from about 0.05% to about 5%, from about 0.05% to about 10%, from about 0.1% to about 0.5%, from about 0.1% to about 1%, from about 0.1% to about 5%, from about 0.1% to about 10%, from about 0.5% to about 1%, from about 0.5% to about 5%, from about 0.5% to about 10%, from about 1% to about 5%, from about 1% to about 10%, or from about 5% to about 10%.

[0120] The use of the paper additive composition disclosed in this application can be accomplished by any process in which efficient microbubble formation occurs, as disclosed in this application. The microbubbles formed by the paper manufacturing additive composition disclosed in this application appear to increase the mass transfer of oxygen in liquids. Not limited to scientific theory, the inventors believe that there are more possible explanations for this difference. First, surfactants that are part of the paper additive formulation disclosed in this application include nonionic surfactants and / or biosurfactants that significantly alter the behavior of the bubbles. Secondly, the paper additive composition disclosed in this application requires a much lower concentration of surfactants to form microbubbles. It has been suggested that surfactant concentrations should approach the critical micelle concentration of the surfactant system. In the paper composition disclosed herein, microbubbles are formed when the concentration of surfactants used is lower than the calculated critical micelle concentration for surfactants. This suggests that microbubbles are formed as a result of aggregation of surfactant molecules with loose packing of molecules, which is more favorable in terms of the characteristics of mass gas transfer. A surface containing fewer surfactant molecules will be more permeable to gas than a well-organized micelle containing gas. Regardless of the mechanism, the tendency of the paper additive composition disclosed in this application to organize into clusters, aggregates, or gas-filled bubbles provides a platform for reactions to occur by increasing local reagent concentrations, lowering the transition energy necessary for the catalytic reaction to occur, or due to which or any other mechanism that has not yet been described.

[0121] In aspects of this embodiment of the present invention, the microbubbles disclosed herein have an average diameter of, for example, about 5 microns, about 10 microns, about 15 microns, about 20 microns, about 25 microns, about 30 microns, about 40 microns, approximately 50 μm, approximately 75 μm, approximately 100 μm, approximately 150 μm, approximately 200 μm, approximately 250 μm, approximately 300 μm, approximately 350 μm, approximately 400 μm, approximately 450 μm, approximately 500 μm, approximately 550 μm, approximately 600 μm, approximately 650 μm, approximately 700 μm, approximately 750 μm, approximately 800 μm, approximately 850 μm, approximately 900 μm, approximately 950 μm, or approximately 1000 μm. In other aspects of this embodiment, the microbubbles disclosed herein have an average diameter of, for example, at least 5 μm, at least 10 μm, at least 15 μm, at least 20 μm, at least 25 μm, at least 30 microns, at least 50 microns, at least 100 microns, at least 150 microns, at least 200 microns, at least 250 microns, at least 300 microns, at least at least 350 microns, at least 400 microns, at least 450 microns, at least 550 microns, at least 550 microns, at least 650 microns, at least 650 microns, at least 700 microns, at least 750 microns microns, at least 800 microns, at least 850 microns, at least 900 microns, at least 950 microns, or at least 1000 microns. In other aspects of this embodiment of the present invention, the microbubbles disclosed herein have an average diameter of, for example, not more than 5 μm, not more than 10 μm, not more than 15 μm, not more than 20 μm, not more than 25 μm, not more than 30 μm, not more than 40 microns, not more than 50 microns, not more than 100 microns, not more than 150 microns, not more than 250 microns, not more than 300 microns, not more than 350 microns, not more than 400 microns, not more than 450 microns, not more than 500 microns, not more than 550 microns, not more than 600 microns, not more than 650 microns, not more than 700 microns, not more than 750 microns, not more than 800 microns, not more than 850 microns, not more than 900 microns, not more than 950 microns or no more than 1000 microns.

[0122] In aspects of this embodiment, the microbubbles disclosed herein have an average diameter of, for example, about 5 microns to about 10 microns, about 5 microns to about 15 microns, about 5 microns to about 20 microns, about 5 microns to about 25 microns, about 5 microns to about 30 microns, about 5 microns to about 40 microns, about 5 microns to about 50 microns, about 5 microns to about 75 microns, about 5 microns to about 100 microns, about 10 microns to about 15 μm, approximately 10 μm to approximately 20 μm, approximately 10 μm to approximately 25 μm, approximately 10 μm to approximately 30 μm, approximately 10 μm to approximately 40 μm, approximately 10 μm to approximately 50 μm, approximately 10 μm to approximately 75 μm, about 10 microns to about 100 microns, about 15 microns to about about 20 microns, about 15 microns to about 25 microns, about 15 microns to about 30 microns, about 15 microns to about 40 microns, about 15 microns to about 50 microns, about 15 microns to about 75 microns, about 15 microns to about 100 microns, about 20 microns to about 25 microns, about 20 microns to about 30 microns, about 20 microns to about 40 microns, about 20 microns to about 50 microns, about 20 microns to about 75 microns, about 20 microns to about 100 microns, about 25 microns to about 30 microns, about 25 microns to about 40 microns, about 25 microns to about 50 microns, about 25 microns to about 75 microns, about 25 microns to about 100 microns, about 30 microns to about 40 microns, about 30 microns to about 50 microns, about 30 microns to about 75 microns, about 30 microns to pr about 100 microns, about 40 microns to about 50 microns, about 40 microns to about 75 microns, about 40 microns to about 100 microns, about 50 microns to about 75 microns, about 50 microns to about 100 microns, about 50 microns to about 150 μm, approximately 50 μm to approximately 200 μm, approximately 50 μm to approximately 250 μm, approximately 50 μm to approximately 300 μm, approximately 50 μm to approximately 350 μm, approximately 50 μm to approximately 400 μm, approximately 50 μm to approximately 450 μm, about 50 microns to about 500 microns, about 50 microns to about 550 microns, about 50 microns to about 600 microns, about 50 microns to about 650 microns, about 50 microns to about 700 microns, about 50 microns to about 750 microns, about 50 microns to about 800 microns, about 50 microns to about 850 microns, p about 50 microns to about 900 microns, about 50 microns to about 950 microns, about 50 microns to about 1000 microns, about 100 microns to about 150 microns, about 100 microns to about 200 microns, about 100 microns to about 250 microns, about 100 μm to approximately 300 μm, approximately 100 μm to approximately 350 μm, approximately 100 μm to approximately 450 μm, approximately 100 μm to approximately 450 μm, approximately 100 μm to approximately 500 μm, approximately 100 μm to approximately 550 μm, approximately 100 μm to approximately 600 μm, approximately 100 μm to approximately 650 μm, approximately 100 μm to approximately 750 μm, approximately 100 μm to approximately 750 μm, approximately 100 μm to approximately 800 μm, approximately 100 μm to approximately 850 μm, approximately 100 μm to approximately 900 μm, approximately 100 μm to approximately 950 μm, with about 100 microns to about 1000 microns, about 150 microns to about 200 microns, about 150 microns to about 250 microns, about 150 microns to about 300 microns, about 150 microns to about 350 microns, about 150 microns to about 400 microns, about 150 μm to approximately 450 μm, approximately 150 μm to approximately 500 μm, approximately 150 μm to approximately 600 μm, approximately 150 μm to approximately 650 μm, approximately 150 μm to approximately 700 μm, approximately 150 μm to about 750 microns, about 150 microns to about 800 microns, about 150 microns to about 850 microns, about 150 microns to about 900 microns, about 150 microns to about 950 microns, about 150 microns to about 1000 microns, about 200 microns to about 250 microns, about 200 microns to about 300 microns, p about 200 microns to about 350 microns, about 200 microns to about 400 microns, about 200 microns to about 450 microns, about 200 microns to about 500 microns, about 200 microns to about 550 microns, about 200 microns to about 600 microns, about 200 μm to approximately 650 μm, approximately 200 μm to approximately 700 μm, approximately 200 μm to approximately 750 μm, approximately 200 μm to approximately 800 μm, approximately 200 μm to approximately 850 μm, approximately 200 μm to approximately 900 μm, approximately 200 μm to about 950 microns, about 200 microns to about 1000 microns, about 250 microns to about 300 microns, about 250 microns to about 350 microns, about 250 microns to about 400 microns, about 250 microns to about 450 microns, about 250 microns to about 500 μm, approximately 250 μm to approximately 550 μm, about 250 microns to about 600 microns, about 250 microns to about 650 microns, about 250 microns to about 700 microns, about 250 microns to about 750 microns, about 250 microns to about 800 microns, about 250 microns to about 850 microns, about 250 μm to approximately 900 μm, approximately 250 μm to approximately 950 μm, approximately 250 μm to approximately 1000 μm, approximately 300 μm to approximately 350 μm, approximately 300 μm to approximately 400 μm, approximately 300 μm to approximately 450 μm, approximately 300 μm to about 500 microns, about 300 microns to about 550 microns, about 300 microns to about 600 microns, about 300 microns to about 650 microns, about 300 microns to about 700 microns, about 300 microns to about 750 microns, about 300 microns to about 800 microns, about 300 microns to about 850 microns, about 300 microns to about 900 microns, about 300 microns to about 950 microns, about 300 microns to about 1000 microns, about 350 microns to about 400 microns, about 350 microns to about 450 microns, about 350 microns to about 500 microns, about 350 microns to about 550 microns, about 350 microns to about 600 microns, about 350 microns to about 650 microns, about 350 microns to about 700 microns, about 350 microns to about 750 microns, about 350 microns to about 800 microns, about 350 microns to about 850 microns, about 350 microns to about 900 microns, about 350 microns to about 950 microns, about 350 microns to about 1000 microns, about 400 microns to about 450 microns, about 400 microns to about 500 microns, about 400 microns to about 550 μm, approximately 400 μm to approximately 600 μm m, about 400 microns to about 650 microns, about 400 microns to about 700 microns, about 400 microns to about 750 microns, about 400 microns to about 800 microns, about 400 microns to about 850 microns, about 400 microns to about 900 microns, about 400 microns to about 950 microns, about 400 microns to about 1000 microns, about 450 microns to about 500 microns, about 450 microns to about 550 microns, about 450 microns to about 600 microns, about 450 microns to about 650 microns, about 450 μm to approximately 700 μm, approximately 450 μm to approximately 750 μm, approximately 450 μm to approximately 850 μm, approximately 450 μm to approximately 900 μm, approximately 450 μm to approximately 950 μm, approximately 450 μm to approximately 1000 microns, approximately 500 microns to approximately 550 μm, approximately 500 μm to approximately 600 μm, approximately 500 μm to approximately 650 μm, approximately 500 μm to approximately 700 μm, approximately 500 μm to approximately 750 μm, approximately 500 μm to approximately 800 μm, approximately 500 μm to approximately 850 μm, about 500 microns to about 900 microns, about 500 microns to about 950 microns, about 500 microns to about 1000 microns, about 550 microns to about 600 microns, about 550 microns to about 650 microns, about 550 microns to about 700 microns, about 550 microns to about 750 microns, about 550 microns to about 800 microns, about 550 microns to about 850 microns, about 550 microns to about 900 microns, about 550 microns to about 950 microns, about 550 microns to about 1000 microns, about 600 microns to about 650 microns, about 600 microns to about 70 0 μm, approximately 600 μm to approximately 750 μm, approximately 600 μm to approximately 800 μm, approximately 600 μm to approximately 850 μm, approximately 600 μm to approximately 900 μm, approximately 600 μm to approximately 950 μm, approximately 600 μm to approximately 1000 μm about 650 microns to about 700 microns, about 650 microns to about 750 microns, about 650 microns to about 800 microns, about 650 microns to about 850 microns, about 650 microns to about 900 microns, about 650 microns to about 950 microns, 650 microns to about 1000 microns, about 700 microns to about 750 microns, about 700 microns to about 800 microns, about 700 microns to about 850 microns, about 700 microns to about 900 microns, about 700 microns to about 950 microns, about 700 microns up to about 1000 microns, about 750 microns to about 800 μm, approximately 750 μm to approximately 850 μm, approximately 750 μm to approximately 900 μm, approximately 750 μm to approximately 950 μm, approximately 750 μm to approximately 1000 μm, approximately 800 μm to approximately 850 μm, approximately 800 μm to approximately 900 μm approximately 800 microns to approximately 950 microns, approximately 800 microns to approximately 1000 microns, approximately 850 microns to approximately 900 microns, approximately 850 microns to approximately 950 microns, approximately 850 microns to approximately 1000 microns, approximately 900 microns to approximately 950 microns, approximately 900 microns to about 1000 microns or about 950 microns to about 1000 microns.

[0123] The paper additive compositions, method and uses disclosed herein are not likely to harm mammals or the environment, are phytotoxic, and can be safely used in a paper manufacturing method. In addition, the paper additive compositions, method, and applications disclosed herein can be used indoors and outdoors and will not soften, dissolve, or otherwise adversely affect the treated surfaces.

[0124] Aspects of the present description of the invention can also be described as follows:

1. A method of separating fibers from cellulosic pulp, the method comprising adding an effective amount of a paper additive composition to the cellulosic pulp during the cooking phase and / or the paper production phase, the application providing an improved separation of cellulosic fibers from the raw materials present in the cellulosic pulp, while the composition contains the processed fermented microbial supernatant and one or more nonionic surfactants, while the composition does not contain any active enzymes or living bacteria and the pH of the composition is not more than 5.0.

2. A method of removing one or more impurities and / or one or more contaminants from cellulosic pulp and / or paper material, the method comprising adding an effective amount of a paper additive composition to the cellulosic pulp during the cooking phase and / or paper preparation phase wherein the application removes one or more impurities and / or one or more contaminants from the cellulosic pulp and / or paper material, wherein the composition contains processed fermented microbial supernatant and one or more nonionic surfactants, wherein the composition does not contain any either active enzymes or living bacteria and the pH of the composition is not more than 5.0.

3. A method of removing ink from cellulosic pulp and / or paper material, the method comprising adding an effective amount of an additive composition for paper production during the cooking phase and / or the paper receiving phase, the application removing the ink from cellulose pulp and / or paper material, wherein the composition contains a processed fermented microbial supernatant and one or more non-ionic surfactants, the composition does not contain any active enzymes or living bacteria, and the pH of the composition is not more than 5.0.

4. The use of an effective amount of a paper additive composition for separating the fibers from the pulp, the composition containing the processed fermented microbial supernatant and one or more non-ionic surfactants, the composition not containing any active enzymes or living bacteria and the pH of the composition is not more than 5.0.

5. The use of an effective amount of a paper additive composition to remove one or more impurities and / or one or more contaminants from cellulosic pulp and / or paper material, the composition comprising a treated fermented microbial supernatant and one or more nonionic surfactants, wherein the composition does not contain any active enzymes or living bacteria and the pH of the composition is not more than 5.0.

6. The use of an effective amount of a paper additive composition for removing ink from cellulose pulp and / or paper material, the composition comprising a processed fermented microbial supernatant and one or more nonionic surfactants, wherein the composition does not contain any active enzymes or living bacteria and the pH of the composition is not more than 5.0.

7. The method according to PP. 1-3 or use according to paragraphs. 4-6, wherein the treated fermented microbial supernatant is obtained from a fermented yeast supernatant, from a fermented bacterial supernatant, from a fermented mold supernatant, or from any combination thereof.

8. The method or application according to claim 6. in which the fermented yeast supernatant is obtained from yeast species that belong to the genera Brettanomyces, Candida, Cyberlindnera, Cystofilobasidium, Debaryomyces, Dekkera, Fusarium, Geotrichum, Issatchenkia, Kazachstania, Kloeckera, Kluyillomy, Kluyillomy, Kluyillomy, Kluyillomy, Kluyillomy, Kluyillomy, Kluyillomy, Kluyillomy, Mucor, Neurospora, Pediococcus, Penicillium, Pichia, Rhizopus, Rhodosporidium, Rhodotorula, Saccharomyces, Schizosaccharomyces, Thrichosporon, Torulaspora, Torulopsis, Verticillium, Yarrowia, Zygosaccharomyces or

9. The method or application of claim 6. wherein the fermented yeast supernatant is obtained from Saccharomyces cerevisiae yeast.

10. The method or use according to claim 6. in which the fermented bacterial supernatant is obtained from bacterial species that belong to the genera Acetobacter, Arthrobacter, Aerococcus, Bacillus, Bifidobacterium, Brachybacterium, Brevibacterium, Barnobacterium, Carnobacterium, Corynebacterium, Enterococium, Erocococium, Enterococum, Gluconobacter, Hafnia, Halomonas, Kocuria, Lactobacillus, Lactococcus, Leuconostoc, Macrococcus, Microbacterium, Micrococcus, Neisseria, Oenococcus, Pediococcus, Propionibacterium, Proteus, Pocudoconococococcus, Strobococcus, Strobocompocactocompocactocompocactum, Strobocompocococcus strain, Strobococcus strain Zymomonas.

11. The method or application of claim 6. in which the fermented bacterial supernatant is obtained from bacterial species that belong to the genus Aspergillus.

12. The method according to PP. 1-3 or 7-11 or the use of PP. 4-11, wherein the papermaking additive composition contains at least 35% by weight of the treated fermented microbial supernatant.

13. The method according to PP. 1-3 or 7-12 or the use of PP. 4-12, in which the additive composition for paper production contains not more than 50% by weight of the processed fermented microbial supernatant.

14. The method according to PP. 1-3 or 7-13 or use according to paragraphs. 4-13, in which the non-ionic surfactant includes a polyester non-ionic surfactant, a polyhydroxyl nonionic surfactant and / or a nonionic biosurfactant.

15. The method or application of claim 14, wherein the polyhydroxy non-ionic surfactant comprises sucrose ester, ethoxylated sucrose ester, sorbitan ester, ethoxylated sorbitan ester, alkyl glucoside, ethoxylated alkyl glucoside, polyglycerol ester or ethoxylated polyglycerol.

16. The method according to PP. 1-3 or 7-15 or the use of PP. 4-15, wherein the nonionic surfactant includes amine oxide, ethoxylated alcohol, ethoxylated aliphatic alcohol, alkylamine, ethoxylated alkylamine, ethoxylated alkylphenol, alkyl polysaccharide, ethoxylated alkyl polysaccharide, ethoxylated ethoxylated fatty acid or ethoxylated fatty acid or OCH ₂ CH ₂ ) _x OC ₆ H ₄ R ¹ , (OCH ₂ CH ₂ ) _x OR ² or H (OCH ₂ CH ₂ ) _x OC (O) R ² , where x represents the number of moles of ethylene oxide added to the alkyl phenol and / or fatty alcohol or fatty acid, R ¹ represents a long chain alkyl group and R ² represents a long chain aliphatic group.

17. The method or application of claim 16, wherein R ¹ is a C ₇ -C ₁₀ normal alkyl group and / or R ² is a C ₁₂ -C ₂₀ aliphatic group.

18. The method according to PP. 1-3 or 7-17 or use according to paragraphs. 4-17, in which the non-ionic surfactant is ethoxylated nonylphenol, ethoxylated octylphenol, ethoxylated cetyl oleyl alcohol, ethoxylated cetyl stearyl alcohol, ethoxylated decyl alcohol, ethoxylated dodecyl alcohol, ethoxylated trideoxy alcohol or

19. The method according to PP. 1-3 or 7-18 or the use of PP. 4-18, in which the composition of the additive for the manufacture of paper contains from about 1% to about 15% by weight of one or more non-ionic surfactants.

20. The method according to p. 19, in which the composition of the additives for paper production contains from about 5% to about 13% by weight of one or more non-ionic surfactants.

21. The method according to p. 20, in which the composition of the additives for paper production contains from about 7% to about 11% by weight of one or more non-ionic surfactants.

22. The method according to PP. 1-3 or 7-21 or the use of PP. 4-21, wherein the papermaking additive composition also contains one or more anionic surfactants.

23. The method or application of claim 22, wherein the paper manufacture additive composition comprises from about 0.5% to about 10% by weight of one or more anionic surfactants.

24. The method or application of claim 23, wherein the additive composition for paper production contains from about 1% to about 8% by weight of one or more anionic surfactants.

25. The method or application according to p. 24, in which the composition of the additives for paper production contains from about 2% to about 6% by weight of one or more anionic surfactants.

26. The method according to PP. 1-3 or 7-25 or the use of PP. 4-25, in which the pH value is not more than 4.5.

27. The method or application of claim 26, wherein the pH is from about 3.7 to about 4.2.

28. The method according to PP. 1-3 or 7-27 or the use of PP. 4-27, in which the composition of the additive for paper production is mainly non-toxic to humans, mammals, plants and the environment.

29. The method according to PP. 1-3 or 7-28 or the use of PP. 4-28, wherein the paper additive composition is biodegradable.

30. The method according to PP. 1-3 or 7-29 or the use of PP. 4-29, which also includes the introduction of an enzyme composition containing an enzyme that breaks down lignin, promotes bleaching, enhances bleaching, modifies the structure of cellulose fibers, improves control of pollution by wastewater, removes tar and sticky substances (adhesives) and modifies starch.

31. The method or application of claim 30, wherein the enzyme is cellulase, xylanase, lipase, esterase, amylase, pectinase, catalase, laccase, peroxidase, pulpase DI, pulpase RF and pulpase BL.

32. The method according to PP. 1-3 or 7-31 or the use of PP. 4-31, wherein an effective amount of the paper additive composition provides a high pulp yield.

33. The method or application according to p, in which an effective amount of the composition of the additives for paper production provides a yield of cellulose equal to approximately 70%, approximately 75%, approximately 80%, approximately 85%, approximately 86%, approximately 87%, approximately 88% approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96%, approximately 97%, approximately 98%, or approximately 99%; or at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%; or no more than 70%, no more than 75%, no more than 80%, no more than 85%, no more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91% , not more than 92%, not more than 93%, not more than 94%, not more than 95%, not more than 96%, not more than 97%, not more than 98% or not more than 99%; or from about 70% to about 80%, from about 70% to about 85%, from about 70% to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95%, from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about about 93%, from about 85% to about 95%, from about 85% to about 97%, from about 85% to about 99%, from about 90% to about 93%, from about 90% to about 95%, from about 90% to about 97%, from about 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97% or from about 95% to about 99%.

34. The method according to PP. 1-3 or 7-33 or use according to paragraphs. 4-33, which provides a high yield of pulp.

35. The method or application according to clause 34, which provides a yield of cellulose equal to approximately 70%, approximately 75%, approximately 80%, approximately 85%, approximately 86%, approximately 87%, approximately 88%, approximately 89%, approximately 90% approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96%, approximately 97%, approximately 98%, or approximately 99%; or at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%; or no more than 70%, no more than 75%, no more than 80%, no more than 85%, no more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91% , not more than 92%, not more than 93%, not more than 94%, not more than 95%, not more than 96%, not more than 97%, not more than 98% or not more than 99%; or from about 70% to about 80%, from about 70% to about 85%, from about 70% to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95%, from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about about 93%, from about 85% to about 95%, from about 85% to about 97%, from about 85% to about 99%, from about 90% to about 93%, from about 90% to about 95%, from about 90% to about 97%, from about 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97% or from about 95% to about 99%.

36. The method according to PP. 1-3 or 7-35 or use according to paragraphs. 4-35, wherein an effective amount of the paper additive composition provides a high alpha cellulose content in the treated cellulosic pulp.

37. The method or application according to clause 36, in which an effective amount of the composition of the additive for paper production provides an alpha cellulose content in the treated pulp pulp equal to approximately 70%, approximately 75%, approximately 80%, approximately 85%, approximately 86%, approximately 87%, approximately 88%, approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96%, approximately 97%, approximately 98% or approximately 99% ; or at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%; or no more than 70%, no more than 75%, no more than 80%, no more than 85%, no more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91% , not more than 92%, not more than 93%, not more than 94%, not more than 95%, not more than 96%, not more than 97%, not more than 98% or not more than 99%; or from about 70% to about 80%, from about 70% to about 85%, from about 70% to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95%, from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about 93%, from about 85% to about 95%, from about 85% to about 97%, from about 85% to about 99%, from about 90% to approximately 93%, approximately 90% to approximately 95%, approximately 90% to approximately 97%, approximately 90% to approximately 99%, approximately 93% to approximately 95%, approximately 93% to approximately 97%, at about 93% to about 99%, from about 95% to about 97%, or from about 95% to about 99%.

38. The method according to PP. 1-3 or 7-37 or the use of PP. 4-37, wherein an effective amount of the papermaking additive composition provides a low beta cellulose content in the treated cellulosic pulp.

39. The method or application of claim 38, wherein the effective amount of the paper additive composition provides beta cellulose content in the treated pulp pulp equal to about 5%, about 10%, about 15%, about 20%, about 25%, about 30% or approximately 35%; or not more than 5%, not more than 10%, not more than 15%, not more than 20%, not more than 25%, not more than 30% or not more than 35%; or from about 5% to about 10%, from about 5% to about 15%, from about 5% to about 20%, from about 5% to about 25%, from about 5% to about 30%, from about 5% to about 35%, from about 10% to about 15%, from about 10% to about 20%, from about 10% to about 25%, from about 10% to about 30%, from about 10% to about 35%, from about 15% to about 20%, from about 15% to about 25% , from about 15% to about 30%, from about 15% to about 35%, from about 20% to about 25%, from about 20% to about 30%, from about 20% to about 35%, from about 25% to about 30%, from about 25% to about 35%, or from about 30% to about 35%.

40. The method according to PP. 1-3 or 7-39 or the use of PP. 4-39, wherein an effective amount of the paper additive composition provides a low gamma cellulose content in the treated cellulosic pulp.

41. The method or application of claim 40, wherein the effective amount of the paper additive composition provides a gamma cellulose content in the treated pulp pulp of about 5%, about 10%, about 15%, about 20%, about 25%, about 30% or approximately 35%; or not more than 5%, not more than 10%, not more than 15%, not more than 20%, not more than 25%, not more than 30% or not more than 35%; or from about 5% to about 10%, from about 5% to about 15%, from about 5% to about 20%, from about 5% to about 25%, from about 5% to about 30%, from about 5% to about 35%, from about 10% to about 15%, from about 10% to about 20%, from about 10% to about 25%, from about 10% to about 30%, from about 10% to about 35%, from about 15% to about 20%, from about 15% to about 25% , from about 15% to about 30%, from about 15% to about 35%, from about 20% to about 25%, from about 20% to about 30%, from about 20% to about 35%, from about 25% to about 30%, from about 25% to about 35%, or from about 30% to about 35%.

42. The method according to PP. 1-3 or 7-41 or the use of PP. 4-41, in which an effective amount of the additive composition for papermaking provides the high viscosity of the treated pulp.

43. The method or application according to § 42, in which an effective amount of the additive composition for papermaking provides a viscosity of the treated cellulosic pulp of approximately 5 mPa⋅s, approximately 10 mPa⋅s, approximately 15 mPa⋅s, approximately 20 mPa ,s, approximately 25 mPa⋅s, approximately 30 mPa⋅s, approximately 35 mPa⋅s, approximately 40 mPa⋅s, approximately 45 mPa⋅s, or approximately 50 mPa⋅s; or at least 5 mPa⋅s, at least 10 mPa⋅s, at least 15 mPa⋅s, at least 20 mPa⋅s, at least 25 mPa⋅s, at least 30 mPa⋅s, at least 35 mPa⋅s, at least 40 mPa⋅s, at least 45 mPa⋅s, or at least 50 mPa⋅s; or no more than 5 mPa⋅s, no more than 10 mPa⋅s, no more than 15 mPa⋅s, no more than 20 mPa⋅s, no more than 25 mPa⋅s, no more than 30 mPa⋅s, no more than 35 mPa⋅s, not more than 40 mPa⋅s, not more than 45 mPa⋅s or not more than 50 mPa⋅s; or from about 5 mPa⋅s to about 10 mPa⋅s, from about 5 mPa⋅s to about 15 mPa⋅s, from about 5 mPa⋅s to about 20 mPa⋅s, from about 5 mPa⋅s to about 25 mPa⋅ ⋅ s, from about 5 mPa⋅s to about 30 mPa⋅s, from about 5 mPa⋅s to about 35 mPa⋅s, from about 5 mPa⋅s to about 40 mPa⋅s, from about 5 mPa⋅s to about 45 mPa⋅s, from about 5 mPa⋅s to about 50 mPa⋅s, from about 10 mPa⋅s to about 15 mPa⋅s, from at Relatively 10 mPa⋅s to about 20 mPa⋅s, from about 10 mPa⋅s to about 25 mPa⋅s, from about 10 mPa⋅s to about 30 mPa⋅s, from about 10 mPa⋅s to about 35 mPa⋅s , from about 10 mPa⋅s to about 40 mPa⋅s, from about 10 mPa⋅s to about 45 mPa⋅s, from about 10 mPa⋅s to about 50 mPa⋅s, from about 15 mPa⋅s to about 20 mPa⋅ ⋅ s, from approximately 15 mPa⋅s to approximately 25 mPa⋅s, from approximately 15 mPa⋅s to approximately 30 mPa⋅s, from approximately specifically 15 mPa⋅s to about 35 mPa⋅s, from about 15 mPa⋅s to about 40 mPa⋅s, from about 15 mPa⋅s to about 45 mPa⋅s, from about 15 mPa⋅s to about 50 mPa⋅s , from about 20 mPa⋅s to about 25 mPa⋅s, from about 20 mPa⋅s to about 30 mPa⋅s, from about 20 mPa⋅s to about 35 mPa⋅s, from about 20 mPa⋅s to about 40 mPa⋅ ⋅ s, from about 20 mPa⋅s to about 45 mPa⋅s, from about 20 mPa⋅s to about 50 mPa⋅s, from approximately 25 mPa⋅s to about 30 mPa⋅s, from about 25 mPa⋅s to about 35 mPa⋅s, from about 25 mPa⋅s to about 40 mPa⋅s, from about 25 mPa⋅s to about 45 mPa⋅s, from about 25 mPa⋅s to about 50 mPa⋅s, from about 30 mPa⋅s to about 35 mPa⋅s, from about 30 mPa⋅s to about 40 mPa⋅s, from about 30 mPa⋅s to about 45 mPa⋅ s, from about 30 mPa⋅s to about 50 mPa⋅s, from about 35 mPa⋅s to about 40 mPa⋅s, from about 35 mPa⋅s ⋅ s to about 45 mPa⋅s, from about 35 mPa⋅s to about 50 mPa⋅s, from about 40 mPa⋅s to about 45 mPa⋅s, from about 40 mPa⋅s to about 50 mPa⋅s, or from about 45 mPa⋅s to approximately 50 mPa⋅s.

44. The method according to PP. 1-3 or 7-43 or the use of PP. 4-43, which provides a high alpha cellulose content in the treated pulp pulp.

45. The method or application according to item 44, which provides an alpha cellulose content in the treated pulp pulp equal to approximately 70%, approximately 75%, approximately 80%, approximately 85%, approximately 86%, approximately 87%, approximately 88%, approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96%, approximately 97%, approximately 98%, or approximately 99%; or at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%; or no more than 70%, no more than 75%, no more than 80%, no more than 85%, no more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91% , not more than 92%, not more than 93%, not more than 94%, not more than 95%, not more than 96%, not more than 97%, not more than 98% or not more than 99%; or from about 70% to about 80%, from about 70% to about 85%, from about 70% to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95%, from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about about 93%, from about 85% to about 95%, from about 85% to about 97%, from about 85% to about 99%, from about 90% to about 93%, from about 90% to about 95%, from about 90% to about 97%, from about 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97% or from about 95% to about 99%.

46. The method according to PP. 1-3 or 7-45 or the use of PP. 4-45, which provides a low beta cellulose content in the treated pulp pulp.

47. The method or application according to item 46, which provides a content of beta-cellulose in the treated pulp pulp equal to approximately 5%, approximately 10%, approximately 15%, approximately 20%, approximately 25%, approximately 30% or approximately 35%; or not more than 5%, not more than 10%, not more than 15%, not more than 20%, not more than 25%, not more than 30% or not more than 35%; or from about 5% to about 10%, from about 5% to about 15%, from about 5% to about 20%, from about 5% to about 25%, from about 5% to about 30%, from about 5% to about 35%, from about 10% to about 15%, from about 10% to about 20%, from about 10% to about 25%, from about 10% to about 30%, from about 10% to about 35%, from about 15% to about 20%, from about 15% to about 25% , from about 15% to about 30%, from about 15% to about 35%, from about 20% to about 25%, from about 20% to about 30%, from about 20% to about 35%, from about 25% to about 30%, from about 25% to about 35%, or from about 30% to about 35%.

48. The method according to PP. 1-3 or 7-47 or the use of PP. 4-47, which provides a low gamma cellulose content in the treated pulp pulp.

49. The method or application of claim 48, which provides a gamma cellulose content in the treated cellulose pulp of approximately 5%, approximately 10%, approximately 15%, approximately 20%, approximately 25%, approximately 30%, or approximately 35%; or not more than 5%, not more than 10%, not more than 15%, not more than 20%, not more than 25%, not more than 30% or not more than 35%; or from about 5% to about 10%, from about 5% to about 15%, from about 5% to about 20%, from about 5% to about 25%, from about 5% to about 30%, from about 5% to about 35%, from about 10% to about 15%, from about 10% to about 20%, from about 10% to about 25%, from about 10% to about 30%, from about 10% to about 35%, from about 15% to about 20%, from about 15% to about 25% , from about 15% to about 30%, from about 15% to about 35%, from about 20% to about 25%, from about 20% to about 30%, from about 20% to about 35%, from about 25% to about 30%, from about 25% to about 35%, or from about 30% to about 35%.

50. The method according to PP. 1-3 or 7-49 or the use of PP. 4-49, which provides high viscosity treated pulp.

51. The method or application according to p. 50, which provides a viscosity of the treated cellulosic pulp equal to about 5 mPa⋅s, about 10 mPa⋅s, about 15 mPa⋅s, about 20 mPa⋅s, about 25 mPa⋅s, about 30 mPa ⋅s, approximately 35 mPa⋅s, approximately 40 mPa⋅s, approximately 45 mPa⋅s, or approximately 50 mPa⋅s; or at least 5 mPa⋅s, at least 10 mPa⋅s, at least 15 mPa⋅s, at least 20 mPa⋅s, at least 25 mPa⋅s, at least 30 mPa⋅s, at least 35 mPa⋅s, at least 40 mPa⋅s, at least 45 mPa⋅s, or at least 50 mPa⋅s; or no more than 5 mPa⋅s, no more than 10 mPa⋅s, no more than 15 mPa⋅s, no more than 20 mPa⋅s, no more than 25 mPa⋅s, no more than 30 mPa⋅s, no more than 35 mPa⋅s, not more than 40 mPa⋅s, not more than 45 mPa⋅s or not more than 50 mPa⋅s; or from about 5 mPa⋅s to about 10 mPa⋅s, from about 5 mPa⋅s to about 15 mPa⋅s, from about 5 mPa⋅s to about 20 mPa⋅s, from about 5 mPa⋅s to about 25 mPa⋅ ⋅ s, from about 5 mPa⋅s to about 30 mPa⋅s, from about 5 mPa⋅s to about 35 mPa⋅s, from about 5 mPa⋅s to about 40 mPa⋅s, from about 5 mPa⋅s to about 45 mPa⋅s, from about 5 mPa⋅s to about 50 mPa⋅s, from about 10 mPa⋅s to about 15 mPa⋅s, from at Relatively 10 mPa⋅s to about 20 mPa⋅s, from about 10 mPa⋅s to about 25 mPa⋅s, from about 10 mPa⋅s to about 30 mPa⋅s, from about 10 mPa⋅s to about 35 mPa⋅s , from about 10 mPa⋅s to about 40 mPa⋅s, from about 10 mPa⋅s to about 45 mPa⋅s, from about 10 mPa⋅s to about 50 mPa⋅s, from about 15 mPa⋅s to about 20 mPa⋅ ⋅ s, from approximately 15 mPa⋅s to approximately 25 mPa⋅s, from approximately 15 mPa⋅s to approximately 30 mPa⋅s, from approximately specifically 15 mPa⋅s to about 35 mPa⋅s, from about 15 mPa⋅s to about 40 mPa⋅s, from about 15 mPa⋅s to about 45 mPa⋅s, from about 15 mPa⋅s to about 50 mPa⋅s , from about 20 mPa⋅s to about 25 mPa⋅s, from about 20 mPa⋅s to about 30 mPa⋅s, from about 20 mPa⋅s to about 35 mPa⋅s, from about 20 mPa⋅s to about 40 mPa⋅ ⋅ s, from about 20 mPa⋅s to about 45 mPa⋅s, from about 20 mPa⋅s to about 50 mPa⋅s, from approximately 25 mPa⋅s to about 30 mPa⋅s, from about 25 mPa⋅s to about 35 mPa⋅s, from about 25 mPa⋅s to about 40 mPa⋅s, from about 25 mPa⋅s to about 45 mPa⋅s, from about 25 mPa⋅s to about 50 mPa⋅s, from about 30 mPa⋅s to about 35 mPa⋅s, from about 30 mPa⋅s to about 40 mPa⋅s, from about 30 mPa⋅s to about 45 mPa⋅ s, from about 30 mPa⋅s to about 50 mPa⋅s, from about 35 mPa⋅s to about 40 mPa⋅s, from about 35 mPa⋅s ⋅ s to about 45 mPa⋅s, from about 35 mPa⋅s to about 50 mPa⋅s, from about 40 mPa⋅s to about 45 mPa⋅s, from about 40 mPa⋅s to about 50 mPa⋅s, or from about 45 mPa⋅s to approximately 50 mPa⋅s.

52. The method according to PP. 1-3 or 7-51 or the use of PP. 4-51, wherein an effective amount of the paper additive composition provides a low lignin content in the treated cellulosic pulp.

53. The method or application of claim 52, wherein the effective amount of the paper additive composition provides a lignin content in the treated pulp with a Kappa number of about 5, about 10, about 15, about 20, about 25, about 30, about 35 approximately 40, approximately or approximately 50; or at least 5, at least 10, at least 15, at least 20, at least 25, at least 30, at least 35, at least 40, at least 45, or at least 50 ; or no more than 5, no more than 10, no more than 15, no more than 20, no more than 25, no more than 30, no more than 35, no more than 40, no more than 45 or no more than 50; or from about 5 to about 10, from about 5 to about 15, from about 5 to about 20, from about 5 to about 25, from about 5 to about 30, from about 5 to about 35, from about 5 to about 40, from about 5 to about 45, from about 5 to about 50, from about 10 to about 15, from about 10 to about 20, from about 10 to about 25, from about 10 to about 30, from But 10 to about 35, from about 10 to about 40, from about 10 to about 45, from about 10 to about 50, from about 15 to about 20, from about 15 to about 25, from about 15 to about 30, from about 15 to about 35, from about 15 to about 40, from about 15 to about 45, from about 15 to about 50, from about 20 to about 25, from about 20 to about 30, from about 20 to about about 35, from about 20 to about 40, from about 20 to about 45, from about 20 to about 50, from about 25 to about 30, from about 25 to about 35, from about 25 to about 40, from about 25 to about 45, from about 25 to about 50, from about 30 to about 35, from about 30 to about 40, from about 30 to about 45, from about 30 to about 50, from about 35 to about 40, about t from about 35 to about 45, from about 35 to about 50, from about 40 to about 45, from about 40 to about 50, or from about 45 to about 50.

54. The method according to PP. 1-3 or 7-53 or use according to claims 4-53, which provides a low lignin content in the treated cellulose pulp.

55. The method or application according to item 54, which provides a lignin content in the treated cellulose pulp with a Kappa number of approximately 5, approximately 10, approximately 15, approximately 20, approximately 25, approximately 30, approximately 35, approximately 40, approximately or approximately 50 ; or at least 5, at least 10, at least 15, at least 20, at least 25, at least 30, at least 35, at least 40, at least 45, or at least 50 ; or no more than 5, no more than 10, no more than 15, no more than 20, no more than 25, no more than 30, no more than 35, no more than 40, no more than 45 or no more than 50; or from about 5 to about 10, from about 5 to about 15, from about 5 to about 20, from about 5 to about 25, from about 5 to about 30, from about 5 to about 35, from about 5 to about 40, from about 5 to about 45, from about 5 to about 50, from about 10 to about 15, from about 10 to about 20, from about 10 to about 25, from about 10 to about 30, from But 10 to about 35, from about 10 to about 40, from about 10 to about 45, from about 10 to about 50, from about 15 to about 20, from about 15 to about 25, from about 15 to about 30, from about 15 to about 35, from about 15 to about 40, from about 15 to about 45, from about 15 to about 50, from about 20 to about 25, from about 20 to about 30, from about 20 to about about 35, from about 20 to about 40, from about 20 to about 45, from about 20 to about 50, from about 25 to about 30, from about 25 to about 35, from about 25 to about 40, from about 25 to about 45, from about 25 to about 50, from about 30 to about 35, from about 30 to about 40, from about 30 to about 45, from about 30 to about 50, from about 35 to about 40, about t from about 35 to about 45, from about 35 to about 50, from about 40 to about 45, from about 40 to about 50, or from about 45 to about 50.

56. The method according to PP. 1-3 or 7-55 or the use of PP. 4-55, in which an effective amount of the additive composition for papermaking provides a low content of impurities in the treated cellulosic pulp.

57. The method or application of claim 56, wherein the effective amount of the paper additive composition provides a low impurity content in the treated cellulosic pulp with a copper number of about 0.5, about 0.75, about 1.0, about 1.25 approximately 1.5, approximately 1.75, approximately 2.0, approximately 2.25, approximately 2.5, approximately 2.75, approximately 3.0, approximately 3.25, approximately 3.5, approximately 3.75 approximately 4.0, approximately 4.25, approximately 4.5, approximately 4, 75, approximately 5.0, approximately 5.25, approximately 5.5, approximately 5.75, approximately 6.0, approximately 6.25, approximately 6.5, approximately 6.75 or approximately 7.0; or at least 0.5, at least 0.75, at least 1.0, at least 1.25, at least 1.5, at least 1.75, at least 2.0, at least 2.25, at least 2.5, at least 2.75, at least 3.0, at least 3.25, at least 3.5, at least 3.75, at least 4.0, at least 4.25, at least 4.5, at least 4.75, at least 5.0, at least 5.25, at least 5.5, at least at least 5.75, at least 6.0, at least 6.25, at least 6.5, at least 6.75, or at least 7.0; or not more than 0.5, not more than 0.75, not more than 1.0, not more than 1.25, not more than 1.5, not more than 1.75, not more than 2.0, not more than 2.25, not more than 2.5, no more than 2.75, no more than 3.0, no more than 3.25, no more than 3.5, no more than 3.75, no more than 4.0, no more than 4.25, no more than 4 5, not more than 4.75, not more than 5.0, not more than 5.25, not more than 5.5, not more than 5.75, not more than 6.0, not more than 6.25, not more than 6.5 not more than 6.75 or not more than 7.0; or from about 0.5 to about 1.0, from about 0.5 to about 2.0, from about 0.5 to about 3.0, from about 0.5 to about 4.0, from about 0.5 to about 5.0, from about 0.5 to about 6.0, from about 0.5 to about 7.0, from about 0.75 to about 1.0, from about 0.75 to about 2.0, from about 0.75 to about 3.0, from about 0.75 to about 4.0, from about 0.75 to about 5.0, from about 0.75 to about flax 6.0, from about 0.75 to about 7.0, from about 1.0 to about 2.0, from about 1.0 to about 3.0, from about 1.0 to about 4.0, from from about 1.0 to about 5.0, from about 1.0 to about 6.0, from about 1.0 to about 7.0, from about 1.25 to about 2.0, from about 1.25 to about 3.0, from about 1.25 to about 4.0, from about 1.25 to about 5.0, from about 1.25 to about 6.0, from about 1.25 to about 7.0, from about 1.5 to about 2.0, from about 1.5 to about 3.0, from about 1.5 to about 4.0, from about 1.5 to about 5.0, from from about 1.5 to about 6.0, from about 1.5 to about 7.0, from about 1.75 to about 2.0, from about 1.75 to about 3.0, from about 1.75 to about 4.0, from about 1.75 to about 5.0, from about 1.75 to about 6.0, from about 1.75 to about 7.0, from about 2 to at lizitelno 3.0, from about 2 to about 4.0, from about 2 to about 5.0, from about 2 to about 6.0, or from about 2 to about 7.0.

58. The method according to PP. 1-3 or 7-57 or the use of PP. 4-57, which provides a low content of impurities in the treated cellulosic pulp.

59. The method or application according to § 58, which provides a low content of impurities in the treated cellulose pulp with a copper number of approximately 0.5, approximately 0.75, approximately 1.0, approximately 1.25, approximately 1.5, approximately 1 , 75, approximately 2.0, approximately 2.25, approximately 2.5, approximately 2.75, approximately 3.0, approximately 3.25, approximately 3.5, approximately 3.75, approximately 4.0, approximately 4 , 25, approximately 4.5, approximately 4.75, approximately 5.0, approximately 5.25, approximately 5.5, approximate but 5.75, about 6.0, about 6.25, about 6.5, about 6.75, or about 7.0; or at least 0.5, at least 0.75, at least 1.0, at least 1.25, at least 1.5, at least 1.75, at least 2.0, at least 2.25, at least 2.5, at least 2.75, at least 3.0, at least 3.25, at least 3.5, at least 3.75, according to at least 4.0, at least 4.25, at least 4.5, at least 4.75, at least 5.0, at least 5.25, at least 5.5, at least at least 5.75, at least 6.0, at least 6.25, at least 6.5, at least 6.75, or at least 7.0; or not more than 0.5, not more than 0.75, not more than 1.0, not more than 1.25, not more than 1.5, not more than 1.75, not more than 2.0, not more than 2.25, not more than 2.5, no more than 2.75, no more than 3.0, no more than 3.25, no more than 3.5, no more than 3.75, no more than 4.0, no more than 4.25, no more than 4 5, not more than 4.75, not more than 5.0, not more than 5.25, not more than 5.5, not more than 5.75, not more than 6.0, not more than 6.25, not more than 6.5 not more than 6.75 or not more than 7.0; or from about 0.5 to about 1.0, from about 0.5 to about 2.0, from about 0.5 to about 3.0, from about 0.5 to about 4.0, from about 0.5 to about 5.0, from about 0.5 to about 6.0, from about 0.5 to about 7.0, from about 0.75 to about 1.0, from about 0.75 to about 2.0, from about 0.75 to about 3.0, from about 0.75 to about 4.0, from about 0.75 to about 5.0, from about 0.75 to about flax 6.0, from about 0.75 to about 7.0, from about 1.0 to about 2.0, from about 1.0 to about 3.0, from about 1.0 to about 4.0, from from about 1.0 to about 5.0, from about 1.0 to about 6.0, from about 1.0 to about 7.0, from about 1.25 to about 2.0, from about 1.25 to about 3.0, from about 1.25 to about 4.0, from about 1.25 to about 5.0, from about 1.25 to about 6.0, from about 1.25 to about 7.0, from about 1.5 to about 2.0, from about 1.5 to about 3.0, from about 1.5 to about 4.0, from about 1.5 to about 5.0, from from about 1.5 to about 6.0, from about 1.5 to about 7.0, from about 1.75 to about 2.0, from about 1.75 to about 3.0, from about 1.75 to about 4.0, from about 1.75 to about 5.0, from about 1.75 to about 6.0, from about 1.75 to about 7.0, from about 2 to at lizitelno 3.0, from about 2 to about 4.0, from about 2 to about 5.0, from about 2 to about 6.0, or from about 2 to about 7.0.

60. The method according to PP. 1-3 or 7-59 or the use of PP. 4-59, wherein an effective amount of the paper additive composition provides a high carboxyl content in the treated cellulosic pulp.

61. The method or application of claim 60, wherein an effective amount of the paper additive composition provides a carboxyl content in the treated cellulosic pulp of about 4 meq / 100 g of cellulose, about 4.5 meq / 100 g of cellulose, about 5 meq / 100 g of cellulose, approximately 5.5 meq / 100 g of cellulose, approximately 6 meq / 100 g of cellulose, approximately 6.5 meq / 100 g of cellulose, approximately 7 meq / 100 g of cellulose, approximately 7.5 meq / 100 g of cellulose, approximately 8 meq / 100 g of pulp, approximately 8.5 meq / 10 0 g of cellulose, about 9 meq / 100 g of cellulose, about 9.5 meq / 100 g of cellulose, or about 10 meq / 100 g of cellulose; or at least 4 meq / 100 g cellulose, at least 4.5 meq / 100 g cellulose, at least 5 meq / 100 g cellulose, at least 5.5 meq / 100 g cellulose, at least 6 meq / 100 g cellulose, at least 6.5 meq / 100 g cellulose, at least 7 meq / 100 g cellulose, at least 7.5 meq / 100 g cellulose, at least 8 meq / 100 g cellulose, at least 8.5 meq / 100 g of cellulose, at least 9 meq / 100 g of cellulose, at least 9.5 meq / 100 g of cellulose, or at least 10 meq / 100 g of cellulose; or not more than 4 meq / 100 g of cellulose, not more than 4.5 meq / 100 g of cellulose, not more than 5 meq / 100 g of cellulose, not more than 5.5 meq / 100 g of cellulose, not more than 6 meq / 100 g of cellulose, not more than 6.5 meq / 100 g of cellulose, not more than 7 meq / 100 g of cellulose, not more than 7.5 meq / 100 g of cellulose, not more than 8 meq / 100 g of cellulose, not more than 8.5 meq / 100 g of cellulose not more than 9 meq / 100 g of cellulose, not more than 9.5 meq / 100 g of cellulose or not more than 10 meq / 100 g of cellulose; or from about 4 meq / 100 g of cellulose to about 5 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 6 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 7 meq / 100 g cellulose, from about 4 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 6 meq / 100 g of cellulose ozy, from about 5 meq / 100 g of cellulose to about 7 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 6 meq / 100 g of cellulose to about 7 meq / 100 g of cellulose, from about 6 meq / 100 g of cellulose to about 8 meq / 100 g cellulose, from about 6 meq / 100 g cellulose to about 9 meq / 100 g cell vines, from about 6 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 8 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 8 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose or from about 9 meq / 100 g of cellulose to about 10 meq / 100 cellulose.

62. The method according to PP. 1-3 or 7-61 or the use of PP. 4-61, which provides a high carboxyl content in the treated cellulosic pulp.

63. The method or application according to claim 62, which provides a carboxyl content in the treated cellulosic pulp of approximately 4 meq / 100 g of cellulose, approximately 4.5 meq / 100 g of cellulose, approximately 5 meq / 100 g of cellulose, approximately 5.5 meq / 100 g cellulose, approximately 6 meq / 100 g cellulose, approximately 6.5 meq / 100 g cellulose, approximately 7 meq / 100 g cellulose, approximately 7.5 meq / 100 g cellulose, approximately 8 meq / 100 g cellulose, approximately 8.5 meq / 100 g cellulose, approximately 9 meq / 100 g cellulose, approximately 9.5 me q / 100 g of cellulose or about 10 meq / 100 g of cellulose; or at least 4 meq / 100 g cellulose, at least 4.5 meq / 100 g cellulose, at least 5 meq / 100 g cellulose, at least 5.5 meq / 100 g cellulose, at least 6 meq / 100 g cellulose, at least 6.5 meq / 100 g cellulose, at least 7 meq / 100 g cellulose, at least 7.5 meq / 100 g cellulose, at least 8 meq / 100 g cellulose, at least 8.5 meq / 100 g of cellulose, at least 9 meq / 100 g of cellulose, at least 9.5 meq / 100 g of cellulose, or at least 10 meq / 100 g of cellulose; or not more than 4 meq / 100 g of cellulose, not more than 4.5 meq / 100 g of cellulose, not more than 5 meq / 100 g of cellulose, not more than 5.5 meq / 100 g of cellulose, not more than 6 meq / 100 g of cellulose, not more than 6.5 meq / 100 g of cellulose, not more than 7 meq / 100 g of cellulose, not more than 7.5 meq / 100 g of cellulose, not more than 8 meq / 100 g of cellulose, not more than 8.5 meq / 100 g of cellulose not more than 9 meq / 100 g of cellulose, not more than 9.5 meq / 100 g of cellulose or not more than 10 meq / 100 g of cellulose; or from about 4 meq / 100 g of cellulose to about 5 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 6 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 7 meq / 100 g cellulose, from about 4 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 4 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 6 meq / 100 g of cellulose ozy, from about 5 meq / 100 g of cellulose to about 7 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 5 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 6 meq / 100 g of cellulose to about 7 meq / 100 g of cellulose, from about 6 meq / 100 g of cellulose to about 8 meq / 100 g cellulose, from about 6 meq / 100 g cellulose to about 9 meq / 100 g cell vines, from about 6 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 8 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 7 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose, from about 8 meq / 100 g of cellulose to about 9 meq / 100 g of cellulose, from about 8 meq / 100 g of cellulose to about 10 meq / 100 g of cellulose or from about 9 meq / 100 g of cellulose to about 10 meq / 100 cellulose.

64. The method according to PP. 1-3 or 7-63 or the use of PP. 4-63, in which an effective amount of the paper additive composition provides a high brightness level of the treated pulp or paper material.

65. The method or application according to item 64, in which an effective amount of the composition of the additive for paper production provides a brightness level of the treated pulp or paper material equal to approximately 70%, approximately 75%, approximately 80%, approximately 85%, approximately 86%, approximately 87%, approximately 88%, approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96%, approximately 97%, approximately 98% or approximately 99% ; or at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%; or no more than 70%, no more than 75%, no more than 80%, no more than 85%, no more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91% , not more than 92%, not more than 93%, not more than 94%, not more than 95%, not more than 96%, not more than 97%, not more than 98% or not more than 99%; or from about 70% to about 80%, from about 70% to about 85%, from about 70% to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95%, from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about about 93%, from about 85% to about 95%, from about 85% to about 97%, from about 85% to about 99%, from about 90% to about 93%, from about 90% to about 95%, from about 90% to about 97%, from about 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97% or from about 95% to about 99%.

66. The method according to PP. 1-3 or 7-65 or use according to paragraphs. 4-65, which provides a high level of brightness of the treated pulp or paper material.

67. The method or application according to p. 66, which provides a brightness level of the treated pulp or paper material equal to approximately 70%, approximately 75%, approximately 80%, approximately 85%, approximately 86%, approximately 87%, approximately 88%, approximately 89%, approximately 90%, approximately 91%, approximately 92%, approximately 93%, approximately 94%, approximately 95%, approximately 96%, approximately 97%, approximately 98%, or approximately 99%; or at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%; or no more than 70%, no more than 75%, no more than 80%, no more than 85%, no more than 86%, no more than 87%, no more than 88%, no more than 89%, no more than 90%, no more than 91% , not more than 92%, not more than 93%, not more than 94%, not more than 95%, not more than 96%, not more than 97%, not more than 98% or not more than 99%; or from about 70% to about 80%, from about 70% to about 85%, from about 70% to about 90%, from about 70% to about 95%, from about 70% to about 99%, from about 75% to about 85%, from about 75% to about 90%, from about 75% to about 95%, from about 75% to about 99%, from about 80% to about 90%, from about 80% to about 95%, from about 80% to about 99%, from about 85% to about about 93%, from about 85% to about 95%, from about 85% to about 97%, from about 85% to about 99%, from about 90% to about 93%, from about 90% to about 95%, from about 90% to about 97%, from about 90% to about 99%, from about 93% to about 95%, from about 93% to about 97%, from about 93% to about 99%, from about 95% to about 97% or from about 95% to about 99%.

68. The method according to PP. 1-3 or 7-67 or the use of PP. 4-67, in which an effective amount of the paper additive composition provides a low content of extractables in the treated cellulosic pulp or paper material.

69. The method or application according to p, in which an effective amount of the composition of the additive for paper production provides an extractable content in the treated cellulosic pulp or paper material equal to approximately 0.01%, approximately 0.02%, approximately 0.03%, approximately 0.04%, approximately 0.05%, approximately 0.06%, approximately 0.07%, approximately 0.08%, approximately 0.09%, approximately 0.1%, approximately 0.2%, approximately 0, 3%, approximately 0.4%, approximately 0.5%, approximately 0.6%, approximately 0.7%, approximate no 0.8%, about 0.9%, about 1%, about 2%, about 3%, about 4% or about 5%; or not more than 0.01%, not more than 0.02%, not more than 0.03%, not more than 0.04%, not more than 0.05%, not more than 0.06%, not more than 0.07%, not more than 0.08%, not more than 0.09%, not more than 0.1%, not more than 0.2%, not more than 0.3%, not more than 0.4%, not more than 0.5%, not more than 0.6%, not more than 0.7%, not more than 0.8%, not more than 0.9%, not more than 1%, not more than 2%, not more than 3%, not more than 4% or not more than 5 %; or from about 0.001% to about 0.005%, from about 0.001% to about 0.01%, from about 0.001% to about 0.05%, from about 0.001% to about 0.1%, from about 0.001% to about 0 , 5%, from about 0.001% to about 1%, from about 0.001% to about 5%, from about 0.005% to about 0.01%, from about 0.005% to about 0.05%, from about 0.005% to about 0.1%, from approximately 0.005% to approximately 0.5%, from approximately 0.005% to approximately 1%, from approximately especially 0.005% to about 5%, from about 0.01% to about 0.05%, from about 0.01% to about 0.1%, from about 0.01% to about 0.5%, from about 0 , 01% to about 1%, from about 0.01% to about 5%, from about 0.05% to about 0.1%, from about 0.05% to about 0.5%, from about 0.05 % to about 1%, from about 0.05% to about 5%, from about 0.1% to about 0.5%, from about 0.1% to about 1%, from about 0.1% to about 5%, from about 0.5% to about 1%, from about 0.5% to about 5%, or from about 1% to about 5%.

70. The method according to PP. 1-3 or 7-69 or the use of PP. 4-69, which provides a low content of extractables in the treated cellulosic pulp or paper material.

71. The method or application according to p. 70, which provides a low content of extractable substances in the treated cellulosic pulp or paper material equal to approximately 0.01%, approximately 0.02%, approximately 0.03%, approximately 0.04%, approximately 0 , 05%, approximately 0.06%, approximately 0.07%, approximately 0.08%, approximately 0.09%, approximately 0.1%, approximately 0.2%, approximately 0.3%, approximately 0.4 %, approximately 0.5%, approximately 0.6%, approximately 0.7%, approximately 0.8%, approximately 0.9%, approximately 1%, approximately 2%, about 3%, about 4%, or about 5%; or not more than 0.01%, not more than 0.02%, not more than 0.03%, not more than 0.04%, not more than 0.05%, not more than 0.06%, not more than 0.07%, not more than 0.08%, not more than 0.09%, not more than 0.1%, not more than 0.2%, not more than 0.3%, not more than 0.4%, not more than 0.5%, not more than 0.6%, not more than 0.7%, not more than 0.8%, not more than 0.9%, not more than 1%, not more than 2%, not more than 3%, not more than 4% or not more than 5 %; or from about 0.001% to about 0.005%, from about 0.001% to about 0.01%, from about 0.001% to about 0.05%, from about 0.001% to about 0.1%, from about 0.001% to about 0 , 5%, from about 0.001% to about 1%, from about 0.001% to about 5%, from about 0.005% to about 0.01%, from about 0.005% to about 0.05%, from about 0.005% to about 0.1%, from about 0.005% to about 0.5%, from about 0.005% to about 1%, from approx. specifically 0.005% to about 5%, from about 0.01% to about 0.05%, from about 0.01% to about 0.1%, from about 0.01% to about 0.5%, from about 0 , 01% to about 1%, from about 0.01% to about 5%, from about 0.05% to about 0.1%, from about 0.05% to about 0.5%, from about 0.05 % to about 1%, from about 0.05% to about 5%, from about 0.1% to about 0.5%, from about 0.1% to about 1%, from about 0.1% to about 5%, from about 0.5% to about 1%, from about 0.5% to about 5%, or from about 1% to about 5%.

72. The method according to PP. 1-3 or 7-71 or the use of PP. 4-71, in which an effective amount of the additive composition for paper production is a dilution with a ratio of the composition of the additive for paper production: diluent equal to approximately 1:50, approximately 1:75, approximately 1: 100, approximately 1: 125, approximately 1: 150, approximately 1: 175, approximately 1: 200, approximately 1: 225, approximately 1: 250, approximately 1: 275, approximately 1: 300, approximately 1: 325, approximately 1: 350, approximately 1: 375, approximately 1: 400, approximately 1: 425, approximately 1: 450, approximately 1: 475, approximately flax 1: 500, about 1: 525, about 1: 550, about 1: 575 or about 1: 600; or at least 1:50, at least 1:75, at least 1: 100, at least 1: 125, at least 1: 150, at least 1: 175, at least 1: 200, at least 1: 225, at least 1: 250, at least 1: 275, at least 1: 300, at least 1: 325, at least 1: 350, at least 1: 375, at at least 1: 400, at least 1: 425, at least 1: 450, at least 1: 475, at least 1: 500, at least 1: 525, at least 1: 550, at least at least 1: 575 or at least 1: 600; or not more than 1:50, not more than 1:75, not more than 1: 100, not more than 1: 125, not more than 1: 150, not more than 1: 175, not more than 1: 200, not more than 1: 225, not more than 1: 250, no more than 1: 275, no more than 1: 300, no more than 1: 325, no more than 1: 350, no more than 1: 375, no more than 1: 400, no more than 1: 425, no more than 1 : 450, not more than 1: 475, not more than 1: 500, not more than 1: 525, not more than 1: 550, not more than 1: 575 or not more than 1: 600; or from about 1:50 to about 1: 100, from about 1:50 to about 1: 200, from about 1:50 to about 1: 300, from about 1:50 to about 1: 400, from about 1:50 to about 1: 500, from about 1:50 to about 1: 600, from about 1: 100 to about 1: 200, from about 1: 100 to about 1: 300, from about 1: 100 to about 1: 400, from about 1: 100 to about 1: 500, from about 1: 100 to about 1: 600, from about 1: 200 to about 1: 300, from approx. But 1: 200 to about 1: 400, from about 1: 200 to about 1: 500, from about 1: 200 to about 1: 600, from about 1: 300 to about 1: 400, from about 1: 300 to about 1: 500, from about 1: 300 to about 1: 600, from about 1: 400 to about 1: 500, from about 1: 400 to about 1: 600, or from about 1: 500 to about 1: 600.

73. The method according to PP. 1-3 or 7-71 or the use of PP. 4-71, in which an effective amount of the additive composition for paper production is a dilution with the ratio of the composition of the additive for paper production: diluent equal to approximately 1: 500, approximately 1: 750, approximately 1: 1000, approximately 1: 1250, approximately 1: 1500, approximately 1: 1750, approximately 1: 2000, approximately 1: 2250, approximately 1: 2500, approximately 1: 2750, approximately 1: 3000, approximately 1: 3250, approximately 1: 3500, approximately 1: 3750, approximately 1: 4000, approximately 1: 4250, approximately 1: 4500, approximately 1: 4750, riblizitelno 1: 5000, about 1: 5250, about 1: 5500, about 1: 5750, about 1: 6000 about 1: 7000, about 1: 8000, about 1: 9000 or about 1: 10,000; or at least 1: 500, at least 1: 750, at least 1: 1000, at least 1: 1250, at least 1: 1500, at least 1: 1750, at least 1: 2000, at least 1: 2250, at least 1: 2500, at least 1: 2750, at least 1: 3000, at least 1: 3250, at least 1: 3500, at least 1: 3750, at at least 1: 4000, at least 1: 4250, at least 1: 4500, at least 1: 4750, at least 1: 5000, at least 1: 5250, at least 1: 5500, at least at least 1: 5750, at least 1: 6000, at least 1: 7000, at least 1: 8000, at least 1: 9000, or at least 1: 10,000; or no more than 1: 500, no more than 1: 750, no more than 1: 1000, no more than 1: 1250, no more than 1: 1500, no more than 1: 1750, no more than 1: 2000, no more than 1: 2250, not more than 1: 2500, no more than 1: 2750, no more than 1: 3000, no more than 1: 3250, no more than 1: 3500, no more than 1: 3750, no more than 1: 4000, no more than 1: 4250, no more than 1 : 4500, no more than 1: 4750, no more than 1: 5000, no more than 1: 5250, no more than 1: 5500, no more than 1: 5750, no more than 1: 6000 no more than 1: 7000, no more than 1: 8000, no more than 1: 9000 or no more than 1: 10000; or from about 1: 500 to about 1: 1000, from about 1: 500 to about 1: 2000, from about 1: 500 to about 1: 3000, from about 1: 500 to about 1: 4000, from about 1: 500 to about 1: 5000, from about 1: 500 to about 1: 6000, from about 1: 500 to about 1: 7000, from about 1: 500 to about 1: 8000, from about 1: 500 to about 1: 9000, from about 1: 500 to about 1: 10000, from about 1: 1000 to about 1: 2000, from about 1: 1000 to about 1: 3000, from from about 1: 1000 to about 1: 4000, from about 1: 1000 to about 1: 5000, from about 1: 1000 to about 1: 6000, from about 1: 1000 to about 1: 7000, from about 1: 1000 to about 1: 8000, from about 1: 1000 to about 1: 9000, from about 1: 1000 to about 1: 10000, from about 1: 2000 to about 1: 3000, from about 1: 2000 to about 1: 4000, from about 1: 2000 to about 1: 5000, from about 1: 2000 to about 1: 6000, from about 1: 2000 to about 1: 7000, from from about 1: 2000 to about 1: 8000, from about 1: 2000 to about 1: 9000, from about 1: 2000 to about 1: 10000, from about 1: 3000 to about 1: 4000, from about 1: 3000 to about 1: 5000, from about 1: 3000 to about 1: 6000, from about 1: 3000 to about 1: 7000, from about 1: 3000 to about 1: 8000, from about 1: 3000 to about 1: 9000, from about 1: 3000 to about 1: 10000, from about 1: 4000 to about 1: 5000, from about 1: 4000 to about 1: 6000, from when about 1: 4000 to about 1: 7000, from about 1: 4000 to about 1: 8000, from about 1: 4000 to about 1: 9000, from about 1: 4000 to about 1: 10000, from about 1: 5000 to about 1: 6000, from about 1: 5000 to about 1: 7000, from about 1: 5000 to about 1: 8000, from about 1: 5000 to about 1: 9000, from about 1: 5000 to about 1: 10000, from about 1: 6000 to about 1: 7000, from about 1: 6000 to about 1: 8000, from about 1: 6000 to about 1: 9000, from approx from 1: 6000 to about 1: 10000, from about 1: 7000 to about 1: 8000, from about 1: 7000 to about 1: 9000, from about 1: 7000 to about 1: 10000, from about 1: 8000 to about 1: 9000, from about 1: 8000 to about 1: 10000, or from about 1: 9000 to about 1: 10000.

74. The method according to PP. 1-3 or 7-73 or the use of PP. 4-73, in which an effective amount of the paper additive composition has a final concentration of approximately 0.0001%, approximately 0.0002%, approximately 0.0003%, approximately 0.0004%, approximately 0.0005%, approximately 0, 0006%, approximately 0.0007%, approximately 0.0008%, approximately 0.0009%, approximately 0.001%, approximately 0.002%, approximately 0.003%, approximately 0.004%, approximately 0.005%, approximately 0.006%, approximately 0.007%, approximately 0.008%, approximately 0.009%, approximately 0.01%, approximately 0.02%, approximately 0.03%, approximately 0.04%, approximately 0.05%, approximately 0.06%, approximately 0.07%, approximately 0.08%, approximately 0.09%, approximately 0.1%, approximately 0.2%, approximately 0 , 3%, approximately 0.4%, approximately 0.5%, approximately 0.6%, approximately 0.7%, approximately 0.8%, approximately 0.9%, approximately 1%, approximately 2%, approximately 3 %, about 4%, about 5%, about 6%, about 7%, about 8%, about 9%, or about 10%; or at least 0.0001%, at least 0.0002%, at least 0.0003%, at least 0.0004%, at least 0.0005%, at least 0.0006%, at least 0.0007%, at least 0.0008%, at least 0.0009%, at least 0.001%, at least 0.002%, at least 0.003%, at least 0.004%, at least 0.005%, at least 0.006%, at least 0.007%, at least 0.008%, at least 0.009%, at least 0.01%, at least 0.02%, at least 0.03% at least 0.04%, at least 0.05%, at least 0.06%, at least 0.07%, at least 0.08%, at least 0.09%, at least 0.1%, at least 0.2%, at least 0.3%, at least 0.4%, at least 0.5%, at least 0, 6%, at least 0.7%, at least 0.8%, at least 0.9%, at least 1%, at least 2%, at least 3%, at least 4% at least 5%, at least 6%, at least 7%, at least 8%, at least 9%, or at least 10%; or not more than 0.0001%, not more than 0.0002%, not more than 0.0003%, not more than 0.0004%, not more than 0.0005%, not more than 0.0006%, not more than 0.0007%, no more than 0,0008%, no more than 0,0009%, no more than 0,001%, no more than 0,002%, no more than 0,003%, no more than 0,004%, no more than 0,005%, no more than 0,006%, no more than 0,007%, no more than 0.008%, not more than 0.009%, not more than 0.01%, not more than 0.02%, not more than 0.03%, not more than 0.04%, not more than 0.05%, not more than 0.06% , not more than 0.07%, not more than 0.08%, not more than 0.09%, not more than 0.1%, not more than 0.2%, not more than 0.3%, not more than 0.4%, not more than 0.5%, not more than 0.6%, not more than 0.7%, not more than 0.8%, not more than 0.9%, not more than 1%, not more than 2%, not more than 3%, no more than 4%, no more than 5%, no more than 6%, no more than 7%, not olee 8%, no more than 9%, or no more than 10%; or from about 0.0001% to about 0.0005%, from about 0.0001% to about 0.001%, from about 0.0001% to about 0.005%, from about 0.0001% to about 0.01%, from from about 0.0001% to about 0.05%, from about 0.0001% to about 0.1%, from about 0.0001% to about 0.5%, from about 0.0001% to about 1%, from from about 0.0001% to about 5%, from about 0.0001% to about 10%, from about 0.0005% to about 0.001%, from about 0.0005% to about 0.005%, t from about 0.0005% to about 0.01%, from about 0.0005% to about 0.05%, from about 0.0005% to about 0.1%, from about 0.0005% to about 0.5 %, from about 0.0005% to about 1%, from about 0.0005% to about 5%, from about 0.0005% to about 10%, from about 0.001% to about 0.005%, from about 0.001% to about 0.01%, 0.001% to about 0.05%, from about 0.001% to about 0.1%, 0.001% to about 0.5%, 0.001% to about 1%, 0.001% to about 5%, from about 0.001% to about 10%, from about 0.005% to about 0.01%, from about 0.005% to about 0.05%, from about 0.005% to about 0.1%, from about 0.005% to about 0, 5%, from about 0.005% to about 1%, from about 0.005% to about 5%, from about 0.005% to about 10%, from about 0.01% to about 0.05%, from about 0.01% to about 0.1%, from about 0.01% to about 0.5%, from about 0.01% to about 1%, from about 0, 01% to about 5%, from about 0.01% to about 10%, from about 0.05% to about 0.1%, from about 0.05% to about 0.5%, from about 0.05% to about 1%, from about 0.05% to about 5%, from about 0.05% to about 10%, from about 0.1% to about 0.5%, from about 0.1% to about 1% from about 0.1% to about 5%, from about 0.1% to about 10%, from about 0.5% to about 1%, from about 0.5% to about 5%, from about typically 0.5% to about 10%, from about 1% to about 5%, from about 1% to about 10%, or from about 5% to about 10%.

75. The composition of the additive for the manufacture of paper, which contains the processed fermented microbial supernatant and one or more non-ionic surfactants, the composition does not contain any active enzymes or living bacteria and the pH of the composition is less than 5.0.

76. The paper additive composition of claim 75, wherein the treated fermented microbial supernatant is obtained from a fermented yeast supernatant, from a fermented bacterial supernatant, from a fermented mold supernatant, or from any combination thereof.

77. The papermaking additive composition of claim 76, wherein the fermented yeast supernatant is obtained from yeast species that are of the genera Brettanomyces, Candida, Cyberlindnera, Cystofilobasidium, Debaryomyces, Dekkera, Fusarium, Geotrichum, Issatchenkia, Kazachstania, Kloeveromy, Kloeveromy, Kloeckomy, Kloeveromy, Lecanicillium, Mucor, Neurospora, Pediococcus, Penicillium, Pichia, Rhizopus, Rhodosporidium, Rhodotorula, Saccharomyces, Schizosaccharomyces, Thrichosporon, Torulaspora, Torulopsis, Verticillium, Yarrowia, Zomygoschoc

78. The paper additive composition of claim 77, wherein the fermented yeast supernatant is obtained from Saccharomyces cerevisiae yeast species.

79. The paper additive composition of claim 78, wherein the fermented bacterial supernatant is obtained from bacterial species that belong to the genera Acetobacter, Arthrobacter, Aerococcus, Bacillus, Bifidobacterium, Brachybacterium, Brevibacterium, Barnobacterium, Carnobacterium, Coryichocactium, Escoryococactium, Escoryococactium Gluconacetobacter, Gluconobacter, Hafnia, Halomonas, Kocuria, Lactobacillus, Lactococcus, Leuconostoc, Macrococcus, Microbacterium, Micrococcus, Neisseria, Oenococcus, Pediococcus, Propionibacterium, Proteus, Pseudomonas, Psychrobacter, Salmonella, Sporolactobacillus, Staphylococcus, Streptococcus, Streptomyces, Tetragenococcus, Vagococcus, Weissells or Zymomonas.

80. The paper additive composition of claim 79, wherein the fermented bacterial supernatant is obtained from bacterial species that belong to the genus Aspergillus.

81. The composition of the additives for paper production according to any one of paragraphs. 75-80, where the composition of the additives for paper production contains at least 35% by weight of the processed fermented microbial supernatant.

82. The composition of the additives for paper production according to any one of paragraphs. 75-81, where the additive composition for paper production contains not more than 50% by weight of the processed fermented microbial supernatant.

83. The composition of the additives for paper production according to any one of paragraphs. 75-82, wherein the nonionic surfactant comprises a polyester nonionic surfactant, a polyhydroxyl nonionic surfactant, and / or a biosurfactant.

84. The paper additive composition of claim 83, wherein the polyhydroxy non-ionic surfactant comprises sucrose ester, ethoxylated sucrose ester, sorbitan ester, ethoxylated sorbitan ester, alkyl glucoside, ethoxylated alkyl glucoside, polyglycerol ester or ethoxylated polyglycerol.

85. The composition of the additives for paper production according to any one of paragraphs. 75-84, wherein the nonionic surfactant includes amine oxide, ethoxylated alcohol, ethoxylated aliphatic alcohol, alkylamine, ethoxylated alkylamine, ethoxylated alkylphenol, alkyl polysaccharide, ethoxylated alkyl polysaccharide, ethoxylated ethoxylated fatty acid or ethoxylated ethyl fatty acid OCH ₂ CH ₂ ) _x OC ₆ H ₄ R ¹ , (OCH ₂ CH ₂ ) _x OR ² or H (OCH ₂ CH ₂ ) _x OC (O) R ² , where x represents the number of moles of ethylene oxide added to the alkyl phenol and / or fatty alcohol or fatty acid , R ¹ represents a long chain alkyl group and R ² represents a long chain aliphatic group.

86. The paper additive composition of claim 85, wherein R ¹ is a C ₇ -C ₁₀ normal alkyl group and / or R ² is a C ₁₂ -C ₂₀ aliphatic group.

87. The composition of the additives for paper production according to any one of paragraphs. 75-86, wherein the non-ionic surfactant is ethoxylated nonylphenol, ethoxylated octylphenol, ethoxylated cetyl oleyl alcohol, ethoxylated cetyl stearyl alcohol, ethoxylated decyl alcohol, ethoxylated dodecyl alcohol, ethoxylated tridecyl alcohol or

88. The composition of the additives for paper production according to any one of paragraphs. 75-87, in which the composition of the additive for the manufacture of paper contains from about 1% to about 15% by weight of one or more non-ionic surfactants.

89. The paper additive composition of claim 88, wherein the paper additive composition contains from about 5% to about 13% by weight of one or more nonionic surfactants.

90. The papermaking additive composition of claim 89, wherein the papermaking additive composition contains from about 7% to about 11% by weight of one or more non-ionic surfactants.

91. The composition of the additives for paper production according to any one of paragraphs. 75-90, wherein the paper additive composition also contains one or more anionic surfactants.

92. The paper additive composition of claim 91, wherein the paper additive composition contains from about 0.5% to about 10% by weight of one or more anionic surfactants.

93. The paper additive composition of claim 92, wherein the paper additive composition contains from about 1% to about 8% by weight of one or more anionic surfactants.

94. The papermaking additive composition of claim 93, wherein the papermaking additive composition contains from about 2% to about 6% by weight of one or more anionic surfactants.

95. The composition of the additives for paper production according to any one of paragraphs. 75-94, the pH of which is not more than 4.5.

96. The paper additive composition of claim 95, the pH of which is from about 3.7 to about 4.2.

97. The composition of the additives for paper production according to any one of paragraphs. 75-96, where the paper additive composition also contains an antimicrobial agent.

98. The composition of the additives for paper production according to any one of paragraphs. 75-97, where the composition of the additive for paper production is mainly non-toxic to humans, mammals, plants and the environment.

99. The composition of the additives for paper production according to any one of paragraphs. 75-98, where the additive composition for paper production is biodegradable.

100. The composition of the additives for paper production according to paragraphs. 75-99, where the papermaking additive composition also contains an enzyme that breaks down lignin, enhances bleaching, improves bleaching, modifies the structure of cellulose fibers, improves control of pollution by wastewater, removes tar and sticky substances (adhesives), modifies starch, or a combination of starch enzymes.

101. The paper additive composition of claim 100, wherein the enzyme is cellulase, xylanase, lipase, esterase, amylase, pectinase, catalase, laccase, peroxidase, pulpase DI, pulpase RF, pulpase BL, or a combination thereof.

102. A method for separating fibers from cellulose pulp, the method comprising introducing an effective amount of an additive composition for paper production, as defined in any one of claims 75-101, into the pulp during the cooking phase and / or the paper production phase, the application providing improved separation of the cellulosic fibers from the raw materials present in the pulp.

103. A method for removing one or more impurities and / or one or more contaminants from cellulosic pulp and / or paper material, the method comprising adding an effective amount of an additive composition for papermaking, as defined in any one of claims. 75-101, into the cellulosic pulp during the cooking phase and / or the paper production phase, the application removing one or more impurities and / or one or more contaminants from the pulp and / or paper material.

104. A method for removing ink from cellulosic pulp and / or paper material, the method comprising adding an effective amount of an additive composition for paper production, as defined in any one of claims. 75-101, into the pulp during the cooking phase and / or the paper-receiving phase, wherein the application removes the printing ink from the pulp and / or paper material.

105. The use of an effective amount of an additive composition for papermaking, as defined in any one of paragraphs. 75-101, to separate the fibers from the pulp.

106. The use of an effective amount of an additive composition for papermaking, as defined in any one of paragraphs. 75-101, to remove one or more impurities and / or one or more contaminants from cellulosic pulp and / or paper material.

107. The use of an effective amount of an additive composition for papermaking, as defined in any one of paragraphs. 75-101, for removing printing ink from cellulose pulp and / or paper material.

EXAMPLES

[0125] The following non-limiting examples are provided for illustrative purposes only, in order to provide a more complete understanding of the presently presented embodiments of the present invention. These examples should not be construed as limiting any of the embodiments of the present invention described in the present description of the invention, including those related to paper additive compositions or methods or applications of such paper manufacturing additive compositions disclosed herein.

Example 1

Getting processed fermented yeast supernatant 1

[0126] To obtain the treated fermented yeast supernatant, a fermentation reaction was carried out, for which approximately 1000 L of warm water with a temperature of from about 29 ° C to about 38 ° C was placed in a large mixing vessel with a jacket. Approximately 84.9 kg of black raw cane-sugar molasses, approximately 25.2 kg of unrefined cane sugar and approximately 1.2 kg of magnesium sulfate were added to the water. The mixture was thoroughly mixed, after which approximately 11.4 kg of malt with active diastases and approximately 1.2 kg of baking yeast were added and mixed slightly. The mixture was incubated at a temperature of from about 26 ° C to about 42 ° C for about 3 days, after which the formation of gas bubbles in the reaction mixture ceased, indicating almost complete completion of the fermentation. At the end of the fermentation reaction, the fermented yeast composition was centrifuged to remove the “precipitate” formed during fermentation. The formed fermented supernatant (approximately 98.59% by weight) was collected and sterilized by autoclaving. The treated fermented yeast supernatant can be stored in liquid form for later use. Alternatively, the treated fermented yeast supernatant can be spray dried by methods known in the art to obtain a dry powder. In the form of a dry powder, it can also be stored for later use.

Example 2

Getting processed fermented yeast supernatant 2

[0127] To obtain the treated fermented yeast supernatant, a fermentation reaction was carried out, for which approximately 1000 L of warm water with a temperature of from about 29 ° C to about 38 ° C was placed in a large mixing vessel with a jacket. Approximately 42.5 kg of black raw cane sugar molasses, approximately 12.6 kg of unrefined cane sugar and approximately 1.2 kg of magnesium sulfate were added to the water. The mixture was thoroughly mixed, after which approximately 10.3 kg of malt with active diastases and approximately 1.2 kg of baking yeast were added and mixed slightly. The mixture was incubated at a temperature of from about 26 ° C to about 42 ° C for about 3 days, after which the formation of gas bubbles in the reaction mixture ceased, indicating almost complete completion of the fermentation. At the end of the fermentation reaction, the fermented yeast culture was centrifuged to remove the “precipitate” formed during fermentation. The formed fermented yeast supernatant (approximately 98.59% by weight) was collected and autoclaved. The treated fermented supernatant can be stored in liquid form for later use. Alternatively, the treated fermented yeast supernatant can be spray dried by methods known in the art to obtain a dry powder. In the form of a dry powder, it can also be stored for later use.

Example 3

Getting processed fermented yeast supernatant 3

[0128] To obtain the treated fermented yeast supernatant, a fermentation reaction was carried out, for which approximately 1000 L of warm water with a temperature of from about 29 ° C to about 38 ° C was placed in a large mixing vessel with a jacket. Approximately 21.3 kg of black raw cane-sugar molasses, approximately 6.3 kg of unrefined cane sugar and approximately 1.2 kg of magnesium sulfate were added to the water. The mixture was thoroughly mixed, after which approximately 9.3 kg of malt with active diastases and approximately 1.2 kg of baker's yeast were added and mixed slightly. The mixture was incubated at a temperature of from about 26 ° C to about 42 ° C for about 3 days, after which the formation of gas bubbles in the reaction mixture ceased, indicating almost complete completion of the fermentation. At the end of the fermentation reaction, the fermented yeast culture was centrifuged to remove the “precipitate” formed during fermentation. The formed fermented supernatant (approximately 98.59% by weight) was collected and autoclaved. The treated fermented yeast supernatant can be stored in liquid form for later use. Alternatively, the treated fermented yeast supernatant can be spray dried by methods known in the art to obtain a dry powder. In the form of a dry powder, it can also be stored for later use.

Example 4

Obtaining a composition of additives for paper production

[0129] To obtain a paper additive composition, 1000 L of sterile hot water (from about 60 ° C to about 65 ° C) was added to 1000 L of treated fermented yeast supernatant in a large jacketed mixing vessel. Approximately 168.8 kg of TERGITOL ™ 15-S-7 (linear secondary alcohol ethoxylate), approximately 168.8 kg of TERGITOL ™ 15-S-5 (linear secondary alcohol ethoxylate), approximately 67.5 kg of DOWFAX ™ 2A1 were added to this mixture (alkyl diphenyl oxide disulfonate) and approximately 67.5 kg of TRITON ™ H-66 (phosphate polyester ether copolymer). This mixture was thoroughly mixed to ensure dissolution. Then water was added, bringing the volume to approximately 4,500 L, and mixed until completely mixed. The pH of the resulting paper additive composition was adjusted with phosphoric acid to about 3.7-4.2. The pH adjusted paper manufacturing additive composition was then sterilized by filtration to remove any microbial contamination.

[0130] It was shown that the composition does not cause skin tissue irritation, is non-toxic, and can be stored in a cool place for months without any noticeable loss of effectiveness or decomposition.

[0131] DOWFAX ™ 2A1 anionic biosurfactant can be replaced, such as, e.g., STEPONOL ^® AM 30-KE (ammonium lauryl sulfate), STEPONOL ^® EHS (sodium 2-ethylhexylsulphate) or a combination thereof.

[0132] If desired, the resulting paper additive composition can then be mixed with preservatives or with stabilizing agents, such as about 1% by weight sodium benzoate, about 0.01% by weight imidazolidinyl urea, about 0.15% by weight diazolidinyl urea, approximately 0.25% by weight of calcium chloride. Sodium benzoate, imidazolidinyl urea, diazolidinyl urea and calcium chloride are added with constant stirring. Then the temperature of the mixture is slowly raised to approximately 40 ° C and the mixture is constantly stirred. The temperature is maintained at approximately 40 ° C for approximately 1 hour to completely dissolve all components of the mixture. Then the temperature is lowered to approximately 20-25 ° C. The pH of the resulting paper additive composition is adjusted with phosphoric acid to about 3.7-4.2. The pH adjusted paper manufacturing additive composition is then sterilized by filtration to remove any microbial contamination.

Example 5

Obtaining a composition of additives for paper production

[0133] To prepare the paper additive composition, 850 L of sterile hot water (from about 60 ° C to about 65 ° C) was placed in a large jacketed mixing tank. Approximately 7.62 kg of dry powder of processed fermented yeast supernatant, approximately 37.5 kg of TERGITOL ™ 15-S-7 (linear secondary alcohol ethoxylate), approximately 37.5 kg of TERGITOL ™ 15-S-5 (linear secondary ethoxylate) was added to water alcohol), approximately 15.0 kg of DOWFAX ™ 2A1 (alkyl diphenyl oxide disulfonate) and approximately 25.0 kg of TRITON ™ H-66 (phosphate polyester-ether copolymer). This mixture was thoroughly mixed to ensure dissolution. Then water was added, bringing the volume to about 1000 L, and mixed until completely mixed. The pH of the resulting paper additive composition was adjusted with phosphoric acid to about 3.7-4.2. The pH adjusted paper manufacturing additive composition was then sterilized by filtration to remove any microbial contamination.

[0134] If desired, the resulting paper additive composition can then be mixed with preservatives or with stabilizing agents such as about 1% by weight sodium benzoate, about 0.01% by weight imidazolidinyl urea, about 0.15% by weight the weight of diazolidinyl urea, approximately 0.25% by weight of calcium chloride. Sodium benzoate, imidazolidinyl urea, diazolidinyl urea and calcium chloride are added with constant stirring. Then the temperature of the mixture is slowly raised to approximately 40 ° C and the mixture is constantly stirred. The temperature is maintained at approximately 40 ° C for approximately 1 hour to completely dissolve all components of the mixture. Then the temperature is lowered to approximately 20-25 ° C. The pH of the resulting paper additive composition is adjusted with phosphoric acid to about 3.7-4.2. The pH adjusted paper manufacturing additive composition is then sterilized by filtration to remove any microbial contamination.

[0135] It was shown that the composition does not cause skin tissue irritation, is non-toxic, and can be stored in a cool place for months without any noticeable loss of effectiveness or decomposition.

[0136] DOWFAX ™ 2A1 anionic biosurfactant can be replaced, such as, e.g., STEPONOL ^® AM 30-KE (ammonium lauryl sulfate), STEPONOL ^® EHS (sodium 2-ethylhexylsulphate) or a combination thereof.

[0137] Alternatively, the dry powder processed fermented yeast supernatant as disclosed in Examples 1-3, can be used commercially available dry powders of fermented yeast supernatant treated, including, e.g., TASTONE ^® 154, TASTONE ^® 210 or 900 TASTONE ^®.

Example 6

Pulp Cooking Experiment

[0138] This example shows an increase in the efficiency of the pulping process when making the paper additive composition disclosed in this application.

[0139] Initially, the crude pulp pulp was treated without adding a paper additive composition in a laboratory minifiber for 45 minutes. The crude pulp preparation contained 17% of the raw materials. After cooking, the freeness of the preparation was evaluated using the Canadian standard. Due to the lack of disintegration of raw materials, it was impossible to take a sample and measure the creep.

[0140] In the following experiment, 17% of the crude cellulose pulp preparation was treated with the paper composition of the laboratory mini-defibre as disclosed in the present application. The amount of paper additive composition added was 300 ml per tonne of raw material. Samples of this drug were taken after 10 minutes, 20 minutes and 30 minutes. After cooking, the freeness of the preparation was evaluated using the Canadian standard. A time-dependent increase in sadness was observed. After 10 minutes of cooking, a longer contact time was required to achieve better fiber homogenization, although the onset of grinding was observed (Fig. 1A). After 20 minutes, a continuing improvement in grinding was observed (FIG. 1B), while after 30 minutes of cooking, excellent fiber homogenization was observed (FIG. 1C). These results show that the paper additive composition disclosed in the present application substantially improves the pulping process and provides excellent fiber homogenization.

[0141] Subsequent micrographs of the fibers treated with the paper additive composition disclosed in this application show improved internal and external fibril formation on the surface of the fiber, which increases the surface area and enhances the ability to form interfiber and intrafiber bonds (Fig. 2).

[0142] These experiments were repeated using the following concentrations: 30 ml of an additive composition for paper production per tonne of raw materials, 60 ml of an additive composition for paper production per tonne of raw materials, and 400 ml of an additive composition for paper production per tonne of raw material. With all concentrations, results similar to those obtained for a concentration of 300 ml of a paper additive composition per tonne of raw material were obtained.

Example 7

Ink Removal Experiment

[0143] This example shows the effectiveness of the paper composition additive disclosed herein for removing printing ink and adhesive from recycled paper.

[0144] Three groups, each of which contained 0.8 kg of white shredded White 3 paper, were boiled in 11.5 L of pure water using a disintegrator for 60 minutes. Group 1 contained only White 3 paper and served as a control. Group 2 contained crushed white paper White 3 and 500 ml of the additive composition disclosed herein for producing paper per tonne of raw material. Group 3 contained crushed white paper White 3 and 500 ml of the paper composition of the additive for the production of paper per ton of raw material disclosed in this application, as well as a cellulose enzyme. At intervals of 15 minutes, 3.0 g samples were taken from the disintegrator and the brightness was analyzed using an ISO brightness test (ISO Brightness assay). In both samples treated with the paper additive formulation disclosed herein, the disintegration of shredded White 3 paper was improved and the whiteness increased by almost 2 points. In group 3, where the cellulose enzyme was added during processing, there was no noticeable difference in the improvements relative to group 2.

[0145] In conclusion, it should be noted that although aspects of the present description of the invention are highlighted by reference to specific embodiments of the invention, one skilled in the art will readily understand that these disclosed embodiments of the invention are merely illustrative of the principles of the subject disclosed in this application. Thus, it should be understood that the disclosed subject matter is not limited to the specific compound, composition, product, device, methodology, protocol and / or reagent disclosed in the present application, unless otherwise expressly indicated. In addition, it will be understood by those skilled in the art that certain changes, modifications, permutations, changes, additions, subtractions, and combinations thereof can be made in accordance with the principles given in this application without departing from the essence of the present description of the invention. Therefore, it is understood that the following appended claims and claims presented below include all such changes, modifications, permutations, changes, additions, subtractions, and combinations that are in their true nature and scope.

[0146] Certain embodiments of the present invention are described herein, including the best mode of carrying out the present invention known to the inventors. Of course, various variations of these described embodiments of the present invention will become apparent to those skilled in the art after reading the above description of the present invention. The inventors expect that qualified specialists in the art will use such options appropriately, and the inventors suggest that the present invention may be practiced differently than is specifically described in this application. Accordingly, the present invention includes all modifications and equivalents of the subject matter indicated in the claims appended to this application, in accordance with applicable law. Moreover, any combination of the above embodiments of the present invention in all possible variants of its implementation is included in the scope of the invention, unless otherwise indicated in this application or contrary to the context explicitly.

[0147] The grouping of alternative embodiments of the present invention, elements or steps of the present invention should not be construed as limiting. You can refer to each member of the group or declare each member of the group individually or in any combination with other members of the group disclosed in this application. It is contemplated that one or more members of the group may be included or removed from the group for reasons of convenience and / or patentability. When such inclusion or deletion occurs, it is believed that the description of the invention contains a modified group, which corresponds to the written description of all Markush groups used in the attached claims.

[0148] Unless otherwise indicated, all numbers expressing a characteristic, element, quantity, parameter, property, term, etc., used in the present description of the invention and in the claims, should be understood as modified in all cases by the term "approximately" . As used in this application, the term “approximately” means that a characteristic, element, quantity, parameter, property or term thus designated includes the interval from minus to plus ten percent of the value of the specified characteristic, element, quantity, parameter, property or term. Accordingly, unless otherwise indicated, the numerical parameters indicated in the description of the present invention and in the attached claims are approximate values, which may vary. For example, since mass spectrometry tools may vary slightly in determining the mass of a given analyte, the term “approximately” in the context of an ion mass or ion mass / charge ratio means +/- 0.50 atomic mass units. At least, but not in an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical reference should be considered at least as the number of indicated significant digits and using conventional rounding techniques.

[0149] The use of the terms “may” in relation to an embodiment or aspect of an embodiment of the present invention also carries an alternative meaning of “cannot”. Thus, if the present disclosure discloses that an embodiment or aspect of an embodiment of the present invention may be included as part of the subject matter, then a negative limitation or exclusion clause is also expressly implied, which means that the embodiment or aspect of the embodiment may not be included as part of the subject matter of the invention. Similarly, the use of the term “if desired” in relation to an embodiment or aspect of an embodiment of the present invention means that such an embodiment or aspect of an embodiment of the present invention may or may not be included as part of the subject matter. The application of such a negative limitation or exclusion clause will be based on whether a negative limitation or exclusion clause is indicated in the claimed subject matter.

[0150] Although the numerical ranges and values defining the broad scope of the invention are approximations, the numerical ranges and values indicated in the specific examples are given with maximum accuracy. However, any digital range or value inevitably contains certain errors, usually resulting from the standard deviation found in the corresponding test measurements. An indication of the range of numerical values in this application is intended simply to be used as an abbreviated method for individually referencing each individual numerical value within the range. Unless otherwise indicated, each individual value of a numerical range is included in the present description of the invention as if it were given an individual reference in this application.

[0151] It is implied that the references to the singular and plural and similar references used in the context of the description of the present invention (especially in the context of the following claims) cover both the singular and the plural, unless otherwise indicated in this application or not contrary to context explicitly. In addition, order indications, such as “first”, “second”, “third”, etc., of the identified elements are used to distinguish between elements and do not indicate or do not mean the required or limited number of such elements, and do not indicate a specific the position or order of such elements, unless expressly indicated otherwise. All methods described in this application can be carried out in any suitable order, unless otherwise indicated or contrary to the context explicitly. The use of any, as well as all examples or exemplary language (eg, “such as”) provided herein is intended merely to better illuminate the present invention and does not limit the scope of the invention claimed otherwise. No wording in the present description of the invention should be construed as indicating any undeclared element necessary for the implementation of the invention.

[0152] When used in the claims filed or added as part of an amendment, the non-limiting transitional term “comprising” (and equivalent non-limiting transitional phrases such as “including”, “comprising” and “having”) covers everything explicitly the specified elements, restrictions, steps and / or properties individually or in combination with an unspecified item; these elements, limitations and / or properties are important, but unnamed elements, restrictions and / or properties may be added to them and, at the same time, they form a structural component within the framework of the claims. The specific embodiments of the present invention disclosed in this application may be further limited in the claims by using the limiting transitional phrases “consisting of” or “consisting essentially of” instead of or as an amendment for “including”. When used in a claims filed or added as part of an amendment, the limiting transition phrase “consisting of” excludes any element, limitation, step or property not expressly indicated in the claims. The limiting transition phrase “consisting essentially of” limits the scope of the claim to explicitly indicate elements, limitations, steps and / or properties and any other elements, limitations, steps and / or properties that do not significantly affect the main and new characteristics of the claimed subject of the invention. Thus, the meaning of the non-limiting transitional phrase “comprising” is defined as encompassing all specifically identified elements, limitations, steps and / or properties, as well as any optional, additional unspecified. The meaning of the restrictive phrase “consisting of” is defined as including only those elements, restrictions, steps and / or properties that are specifically indicated in the claims, while the value of the restrictive transition phrase “consisting of” is defined as including only those elements, restrictions , steps and / or properties that are specifically indicated in the claims, and those elements, limitations, steps and / or properties that do not significantly affect the main and new characteristics of the claimed subject matter. Thus, in the extreme case, the value of the non-limiting transitional phrase “comprising” (and equivalent non-limiting transitional phrases) includes the declared subject defined by the limiting transitional phrases “consisting of” or “consisting mainly of”. Thus, such embodiments described in this application or stated by the phrase “comprising” are expressly or unconditionally unambiguously described, included and contained in the present applications in the phrases “consisting essentially of” and “consisting of”.

[0153] All patents, patent publications and other publications mentioned and identified in the present description of the invention, individually and explicitly incorporated into this application in full by reference for the purpose of describing and disclosing, for example, the compositions and methods described in such publications, which can be used in connection with the present invention. These publications are presented solely for their disclosure prior to the filing date of this application. Nothing in this regard should be construed as an admission that inventors are not entitled to retroactively disclose such disclosure based on a previous invention or for any other reason. All statements regarding the date or presentation of the contents of these documents are based on information available to applicants and do not constitute recognition of the correct dates or contents of these documents.

[0154] Finally, the terminology used here is intended only to describe specific embodiments of the invention and is not intended to limit the scope of the present invention, which is defined solely by the claims. Accordingly, the present invention is not limited to how it is specifically shown and described.

Claims (30)

1. The composition of the additive for the manufacture of paper, which contains the processed fermented microbial supernatant and one or more non-ionic surfactants, while the composition does not contain any active enzymes or living bacteria, and the pH value of the composition is less than 5.0. 2. The paper additive composition of claim 1, wherein the treated fermented microbial supernatant is obtained from a fermented yeast supernatant, from a fermented bacterial supernatant, from a fermented mold supernatant, or from any combination thereof. 3. The paper additive composition of claim 2, wherein the fermented yeast supernatant is obtained from yeast species that belong to the genera Brettanomyces, Candida, Cyberlindnera, Cystofilobasidium, Debaryomyces, Dekkera, Fusarium, Geotrichum, Issatchenkia, Kazachstania, Kloeckomyces, Kloeveromyra, Lecanicillium, Mucor, Neurospora, Pediococcus, Penicillium, Pichia, Rhizopus, Rhodosporidium, Rhodotorula, Saccharomyces, Schizosaccharomyces, Thrichosporon, Torulaspora, Torulopsis, Verticillium, Yarrowia, Zomygoschoc 4. The paper additive composition of claim 3, wherein the fermented yeast supernatant is obtained from Saccharomyces cerevisiae yeast. 5. The composition of the additives for paper production according to any one of paragraphs. 1-4, containing at least 35% by weight of the processed fermented microbial supernatant. 6. The composition of the additives for paper production according to any one of paragraphs. 1-5, containing not more than 50% by weight of the processed fermented microbial supernatant. 7. The composition of the additives for paper production according to any one of paragraphs. 1-6, in which the non-ionic surfactant includes a polyester non-ionic surfactant, a polyhydroxyl nonionic surfactant and / or biosurfactant. 8. The paper additive composition of claim 7, wherein the polyhydroxy non-ionic surfactant comprises sucrose ester, ethoxylated sucrose ester, sorbitan ester, ethoxylated sorbitan ester, alkyl glucoside, ethoxylated alkyl glucoside, polyglycerol ester or ethoxylated polyglycerol. 9. The composition of the additives for paper production according to any one of paragraphs. 1-8, in which the nonionic surfactant includes amine oxide, ethoxylated alcohol, ethoxylated aliphatic alcohol, alkylamine, ethoxylated alkylamine, ethoxylated alkylphenol, alkyl polysaccharide, ethoxylated alkyl polysaccharide, ethoxylated ethoxylated fatty acid or ethoxylated fatty acid or OCH ₂ CH ₂ ) _x OC ₆ H ₄ R ¹ , (OCH ₂ CH ₂ ) _x OR ² or H (OCH ₂ CH ₂ ) _x OC (O) R ² , where x represents the number of moles of ethylene oxide added to the alkyl phenol and / or fatty alcohol or fatty acid, R ¹ represents a long chain alkyl group and R ² represents a long chain aliphatic group. 10. The paper additive composition of claim 9, wherein R ¹ is a C ₇ -C ₁₀ normal alkyl group and / or R ² is a C ₁₂ -C ₂₀ aliphatic group. 11. The composition of the additives for paper production according to any one of paragraphs. 1-10, in which the nonionic surfactant is ethoxylated nonylphenol, ethoxylated octylphenol, ethoxylated cetyl oleyl alcohol, ethoxylated cetyl stearyl alcohol, ethoxylated decyl alcohol, ethoxylated dodecyl alcohol, ethoxylated trideoxy alcohol or 12. The composition of the additives for paper production according to any one of paragraphs. 1-11, containing from 1% to 15% by weight of one or more non-ionic surfactants. 13. The additive composition for paper production according to claim 12, containing from 5% to 13% by weight of one or more non-ionic surfactants. 14. The additive composition for paper production according to claim 13, containing from 7% to 11% by weight of one or more non-ionic surfactants. 15. The composition of the additives for paper production according to any one of paragraphs. 1-14, also containing one or more anionic surfactants. 16. The paper additive composition of claim 15, comprising from 0.5% to 10% by weight of one or more anionic surfactants. 17. The paper additive composition of claim 16, comprising from 1% to 8% by weight of one or more anionic surfactants. 18. The composition of the additive for the manufacture of paper according to claim 17, containing from 2% to 6% by weight of one or more anionic surfactants. 19. The composition of the additives for paper production according to any one of paragraphs. 1-18, the pH of which is not more than 4.5. 20. The composition of the additive for the manufacture of paper according to claim 19, the pH of which is from 3.7 to 4.2. 21. The composition of the additives for paper production according to any one of paragraphs. 1-20, additionally containing an antimicrobial substance. 22. The composition of the additives for paper production according to any one of paragraphs. 1-21, which is essentially non-toxic to humans, mammals, plants and the environment. 23. The composition of the additives for paper production according to any one of paragraphs. 1-22, which is biodegradable. 24. A method of separating fibers from cellulose pulp, comprising the step of: make an effective amount of the composition of the additive for paper production, as defined in any one of paragraphs. 1-23, into the cellulosic pulp during the cooking phase and / or the paper production phase, the application providing improved separation of the cellulosic fibers from the raw materials present in the cellulosic pulp. 25. A method for removing one or more impurities and / or one or more contaminants from cellulosic pulp and / or paper material, comprising the step of introducing an effective amount of an additive composition for papermaking, as defined in any one of claims. 1-23, into the cellulosic pulp during the cooking phase and / or the paper production phase, the application removing one or more impurities and / or one or more contaminants from the pulp and / or paper material. 26. A method of removing printing ink from cellulose pulp and / or paper material, comprising the step of: introducing an effective amount of the additive composition for paper production, as defined in any one of paragraphs. 1-23, into the cellulosic pulp during the cooking phase and / or the paper production phase, the application removing the printing ink from the cellulosic pulp and / or paper material. 27. The use of an effective amount of an additive composition for paper production, as defined in any one of paragraphs. 1-23, to separate the fibers from the pulp. 28. The use of an effective amount of the composition of the additive for paper production, as defined in any one of paragraphs. 1-23, to remove one or more impurities and / or one or more contaminants from cellulosic pulp and / or paper material. 29. The use of an effective amount of an additive composition for papermaking, as defined in any one of paragraphs. 1-23, to remove ink from cellulose pulp and / or paper material.

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