CN108347946A - Additive composition for paper making and its method and purposes - Google Patents

Additive composition for paper making and its method and purposes Download PDF

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Publication number
CN108347946A
CN108347946A CN201680061816.2A CN201680061816A CN108347946A CN 108347946 A CN108347946 A CN 108347946A CN 201680061816 A CN201680061816 A CN 201680061816A CN 108347946 A CN108347946 A CN 108347946A
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weight
paper
paper pulp
additive composition
paper making
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P·戴尔
P·D·戴尔
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Neozyme International Inc
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Neozyme International Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D21C5/02—Working-up waste paper
    • D21C5/025—De-inking
    • D21C5/027—Chemicals therefor
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P1/00—Preparation of compounds or compositions, not provided for in groups C12P3/00 - C12P39/00, by using microorganisms or enzymes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
    • B08B9/02—Cleaning pipes or tubes or systems of pipes or tubes
    • B08B9/027—Cleaning the internal surfaces; Removal of blockages
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/30—Microbial fungi; Substances produced thereby or obtained therefrom
    • A01N63/32—Yeast
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/14—Fungi; Culture media therefor
    • C12N1/16—Yeasts; Culture media therefor
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/005—Microorganisms or enzymes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06—Paper forming aids
    • D21H21/08—Dispersing agents for fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/32—Bleaching agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/64—Paper recycling

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Zoology (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Mycology (AREA)
  • Organic Chemistry (AREA)
  • Biotechnology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Virology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Genetics & Genomics (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Biomedical Technology (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Medicinal Chemistry (AREA)
  • Botany (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Paper (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Detergent Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Wrappers (AREA)

Abstract

Subject description discloses additive composition for paper making, the article of manufacture, the container comprising such composition or kit and increase cellulose fibre from the separation of paper pulp, from removing one or more of impurity and/or one or more of pollutants in paper pulp and/or paper material and remove the method and purposes of removal ink from paper pulp and/or paper material.

Description

Additive composition for paper making and its method and purposes
This application claims the priority for the U.S. Provisional Patent Application 62/208,662 submitted for 22nd in August in 2015 and Shens Please day equity, the content of the temporary patent application is integrally incorporated accordingly by reference with it.
Paper is very important, practical and multiduty substance, wherein generating every year ten hundreds of different based on paper Product.Paper can it is impregnated, apply glaze, crease, waterproof, waxing, glazing, it is photosensitive, bending, fold, corrugation, cutting, dissolving, leaching Soft, molding or embossing.Similarly, paper can be together with fabric, plastics and metal laminate.It, can be by paper in order to organize Manufactured many products can be divided into five major class：1) newsprint and magazine；2) printing and writing paper；3) toilet paper and home-use Paper；4) packaging material and product；And 5) dedicated paper.Because being the natural part of our daily lifes, we forget sometimes We have relies on this important, reproducible and continuous development resource more.
The serviceability of paper product generates significant impact to global economy.In 2015, the full generation of the product based on paper Boundary's production is 5 $ 100 billions more than 300,000,000 tons and by valuation.Corrugated and cardboard container accounts for about the 30% of industrial income. Other major products include board product (15%), bag and coating and processing paper product (10%) and hygiene paper product (5%).Global pulp and paper-making industry are that the industry of leading multi-million dollar is mainly accounted for by the U.S. and China, and two countries account for generation Always raw amount is more than 40% on boundary.However Japan, Germany, Canada, South Korea, Sweden, Finland, Brazil and Indonesia also have There are many paper pulp and paper enterprise.Main export and import country includes the U.S. and Germany.
Other than being one of leading force in industry, the U.S. is also consumed by bases more more than any other country in the world In the product of paper, the third of the product based on paper of production in 2015, or about 100,000,000 tons are used.This height of product based on paper Degree, which is used and consumed, is important America's economy.In the U.S., 450 manufacturing works' productions are close to 2,000,000,000 dollars by valuation Product.About 150,000 people is directly employed by the industry, creates the emolument close to 10,000,000,000 dollars.It is estimated that paper pulp and making Paper industry is the tenth-largest employer in the U.S..
The manufacture of paper is the industry of maturation.Current paper pulp and paper industry basic component currently in use and technique are appropriate Ground continue for an almost century.In addition, paper pulp processing and papermaking are a kind of high-throughputs, a large amount of natural resources is also used Such as water and timber, chemicals and energy produce paper pulp and paper.Therefore, industrial maturity, high output, material and Energy resource be widely used and environmental legislation causes manufacturer stringent economic restriction.However, improving or optimizing paper The innovation of the productivity and/or efficiency of production be still important with it is valuable.For example, due to high paper output, so It increases productivity and/or the innovation of efficiency is converted into tens million of dollars in terms of saving and/or increased profit, if not Tens billion of dollars.In addition, reducing the innovation of a large amount of energy expenditure and a large amount of wastewater effluents and waste by-product will solve The important environmental problem that the environment reduced influences and economy is relieved will also be caused.Therefore, exist for the technique for improving papermaking Great demand.
Therefore, to it is nontoxic, biodegradable and be efficiently modified or optimize paper production productivity and/or efficiency papermaking There are great demands for additive.
It summarizes
Additive composition for paper making is disclosed in terms of this specification.Disclosed additive composition for paper making includes through processing Fermentation microorganism supernatant and one or more of nonionic surface active agent.Disclosed additive composition for paper making is also Can include one or more of anionic surfactant.In addition, disclosed additive composition for paper making can also be optional Ground includes cellulose digestion enzyme.Disclosed additive composition for paper making is biodegradable and to the mankind, mammal, plant Object and environment are generally nontoxic.
Additive for paper making kit (papermaking additive kit) is disclosed in terms of this specification.It is disclosed Additive for paper making kit is comprising additive composition for paper making disclosed herein and how to be improved using the composition or excellent Change the productivity of paper production and/or the specification of efficiency.
The method for detaching fiber from pulp is disclosed in terms of this specification.Disclosed method be included in slurrying and/ Or during the paper production phase, a effective amount of compositions disclosed herein is applied to pulp.The application causes fiber from paper Starch the increased separation of raw material present in slurry.
The method that impurity and/or pollutant are removed from paper pulp and/or paper material is disclosed in terms of this specification.Institute is public The method opened includes that a effective amount of additive composition for paper making disclosed herein is applied to slurrying and/or paper production phase.It should Using causing to remove impurity and/or pollutant from paper pulp and/or paper material.
The method by paper pulp and/or paper material deinking is disclosed in terms of this specification.Disclosed method includes will have The compositions disclosed herein of effect amount is applied to slurrying and/or paper production phase.The application causes from paper pulp and/or paper material Except removal ink.
It is fine for being detached from pulp that additive composition for paper making disclosed herein is disclosed in terms of this specification The purposes of dimension.Disclosed purposes includes answering a effective amount of additive composition for paper making in slurrying and/or during the paper production phase With to pulp, to increase fiber from the separation in raw material present in pulp.
Additive composition for paper making disclosed herein is disclosed in terms of this specification for from paper pulp and/or paper material Remove the purposes of impurity and/or pollutant.Disclosed purposes include in slurrying and/or during the paper production phase, will be a effective amount of Additive composition for paper making is applied to pulp, to remove removal ink from paper pulp and/or paper material.
Additive composition for paper making disclosed herein is disclosed in terms of this specification for taking off paper pulp and/or paper material The purposes of ink.Disclosed purposes includes answering a effective amount of additive composition for paper making in slurrying and/or during the paper production phase With to pulp, to remove removal ink from paper pulp and/or paper material.
Brief description
Figure 1A-Fig. 1 C show the equal of the fiber handled with additive composition for paper making disclosed herein in pulping process The time dependence of matter improves, and wherein Figure 1A shows freedom (freeness) of the fiber at 10 minutes；Figure 1B is shown Freedom of the fiber at 20 minutes；And Fig. 1 C show the freedom of fiber at 30 minutes.
Fig. 2 shows with additive composition for paper making disclosed herein treated refined fiber (refined fiber)。
It is described in detail
Paper is made of the cellulose fibre being obtained from vegetable material, and the vegetable material for example such as comes from palohierror and soft Timber, rag, flax, cotton linter and/or the bagasse of ebon.Recycled writing paper (reclaimed paper) can be recovered with life New paper product is produced, wherein being often blended has protofibre (virgin fiber).Synthetic material can be used for specialty goods Matter assigns finished product paper product.Other products made of cellulose fibre include diaper, artificial silk, cellulose acetate and for knitting The cellulose esters of object, packaging film and explosive.
Typical timber include the cellulose of about 40%-50%, the hemicellulose of 25%-35%, 15%-30% it is wooden The extract of element and 2%-10%.In papermaking, one has main steps that from the residue of other components extraction cellulose.It is logical Often, the amount of hemicellulose present in paper product, lignin and extract is higher, and quality is lower.
The paper mill in many modern times is roughly divided into five different operational phases：1) pulp stage；2) formative stage； 3) stage is pressed；3) drying stage；And 5) calendering stage (calendering phase).Four-stage can be common afterwards Ground is known as the paper production phase.Raw material can be processed in pulp stage and refined with from lignin, extract and other are former Cellulose fibre is detached in impurities of materials, and generates the wet slurry or paper pulp with about 99% water content for being referred to as dispensing. Formative stage is also known as green end (wet end), dispensing is distributed to the shifting for being referred to as fourdrinier wire (fourdrinier wire) Water to be discharged from dispensing (by gravity or under vacuum) to form continuous fiber on dynamic sieve (moving screen) Sieve.In the pressing stage, make fiber screen then between the big roller that loads under high pressure by as much as possible to squeeze out Water, to form the sheet material of pressing.Then, the sheet material of pressing enters drying stage, wherein the sheet material of pressing is made to pass through a series of steamings The drying cylinder (cylinder) of vapour heating, water content is reduced to about 6% level by this.Finally, it in calendering stage, will dry Paper it is smooth using steel rider under high load and pressure and flatten, to produce the untrained paper product of finished product.By untouched edge Paper roll at reel, for being used on web press (web-fed press) such as newspaper printing press, or tearing and cut Length is cut into so that the sheet material of the paper for sheet-fed press is made.
In pulp stage, using chemistry and/or Mechanically programm, (such as oil is set for useful fiber and lignin, extract Fat and wax) it is detached with other raw material waste products.For example, in chemical program, raw material are processed to smaller particle, even Same chemicals (white liquor) and water are placed in the referred to as autoclave of boiling vessel, and with steam boiling together under high pressure.Boiling makes Lignin bond material decomposes, this makes cellulose fibre be detached with the rest part of raw material.Then, the raw material and use of separation The boiling chemicals crossed is sent to recovery process, and wherein pulping chemical and energy is recovered via multiple evaporation steps, is used for Pulping waste liquor (black liquor) is concentrated, it is burned that the pulping waste liquor may then act as fuel.
In Mechanically programm, raw material are by grinder, the rotation stone that raw material are soaked relative to water in the grinder It is ground or heat produced by grinding softens the lignin of binding fiber, and mechanical force makes fiber separation be ground to be formed The timber of mill.Selectively, raw material make raw material be subjected to rotation steel disk and fixed plate by refiner in the refiner Between strong shearing force.Disk on its face raised stick and with narrow gap make each other by.This action makes Fiber is detached with the rest part of raw material.Shear action also makes fiber loose, and the fibrinogen of fiber is caused to be partially separated simultaneously It blooms outward (bloom).Before entering boiling vessel or refiner, raw material can also be softened by heating (heat-machinery) Or impregnated with chemical treatment, to contribute to fibrillation (chemithermo-mechanical).
No matter whether fiber separation is occurred by the combination of chemical program, Mechanically programm or two kinds of programs, by the paper of processing Slurry is pumped by a series of holding tank of commonly known as casees (chest), for further processing.For example, paper pulp can be with It is washed to clean fiber and remove remaining lignin and other impurities and screening to remove any remaining fibre bundle simultaneously Realize quality and consistency evenly.The paper pulp of processing can also be from the paper product from different raw material sources or recycling The paper pulp of other processing obtained mixes the paper pulp of the processing to generate blending in case (blending chest) is blended.It takes Certainly in the type of made final paper product, the paper pulp of processing can also be by a series of casees, wherein various fillers are added To in the paper pulp of processing to improve such as opacity, brightness, mechanical strength, smoothness, absorbency and other properties.Example Such as, bleaching agent or other brightening agents can be added so that fiber bleaches and increases brightness, dyestuff and pigment can be added to generate Chromatics paper, opacifying agent such as calcium carbonate, clay and titanium dioxide increase opacity can be printed on both sides, can add Sizing agent is to increase moisture-proof.The paper pulp of processing can also be treated to remove ink (deinking) and other pollutants, if former Material is the recycled paper products being recycled, then what this was typically required.Finally, the paper pulp of processing can so that its pH is adjusted It saves and dilutes the dispensing to form consistent with water, be used for subsequent processing.
The main purpose of pulp stage is that lignin, extract and other waste materials as much as possible are removed from paper pulp Material, to increase the amount of the cellulose fibre detached present in paper pulp, the integrality and intensity without sacrificial fiber are so as to reality Existing high fiber fineness and quality.Another main purpose of pulp stage is to increase the surface area of fiber with for example, by causing The fibrinogen of fiber is partially separated and is bloomed outward to promote to combine.In addition, especially for the paper of recycling, another mesh Be remove removal ink and adhesive pollutant, they can influence the purity and quality of final paper product.
It is not intended to be limited by its theory, the additive composition for paper making dissolving of the disclosure disperses or breaks in another manner The bad one or more of pollutants being used to prepare in the raw material of paper pulp.This mechanism of action seem partly be disclosed herein Additive composition for paper making decompose lignin and/or promote to detach the ability of individual cellulose and hemicellulose from fibre bundle It is associated.Final result is that cellulose and hemicellulose fibers are detached with the improved of fibre bundle, this eventually leads to more effective And cost-efficient mode produce the paper product of higher quality.This mechanism of action also appear to partly with it is disclosed herein Additive composition for paper making decomposition is considered as that the ink of the impurity in the raw material obtained by recycled paper products is organic with other The ability of compound is associated.
Do not consider that theory of operation, disclosed additive composition for paper making, method and purposes are provided independent of to the mankind Or the selectable papermaking means of the chemicals of environmental toxic.In addition, disclosed additive composition for paper making, method and purposes are led The better decomposition of lignin and other impurities is caused, this helps more easily to recycle waste water to be reused for slurrying or paper life In the production stage, this is additionally beneficial to the mankind and environment.In addition, disclosed additive composition for paper making, method and purposes need not be wide General energy input, so as to reduce gross energy dosage, this is further beneficial to man and environment.And it disclosed herein makes Paper additive composition, method and purposes seem increase cellulose fibre separation, increase fiber surface area and except removal ink, Adhesive and other pollutants, without sacrificial fiber integrality and intensity to realize high fiber fineness and quality.In addition, public The additive composition for paper making opened, which has been demonstrated, to be generally nontoxic to people and domestic animal and has to wild animal and environment Minimum side effect.
The aspect of this specification partly discloses additive composition for paper making.Additive composition for paper making disclosed herein Including the microorganism supernatant of processed fermentation and one or more of nonionic surface active agent.Processed fermentation Microorganism supernatant does not have the microorganism such as yeast or bacterium of any work, and in addition without any organized enzyme, activable Proenzyme (pro-enzyme) or any enzymatic activity.In addition, microorganism example of the additive composition for paper making without any work itself Such as yeast or bacterium, and in addition without any organized enzyme, activable proenzyme or any enzymatic activity.Papermaking disclosed herein Compositions of additives can be used for any personal or business paper technology.
In in terms of this embodiment, additive composition for paper making disclosed herein includes for example, about 75% to about 99% Processed fermentation microorganism supernatant and about 1%-25% one or more of nonionic surface active agent.Herein In the other side of embodiment, additive composition for paper making disclosed herein includes for example, about 80% to about 97% through place The microorganism supernatant of the fermentation of reason and one or more of nonionic surface active agent of about 3%-20%.Embodiment party herein In the another aspect of case, additive composition for paper making disclosed herein includes for example, about 85% to about 95% processed fermentation Microorganism supernatant and about 5%-15% one or more of nonionic surface active agent.This embodiment in addition In one side, additive composition for paper making disclosed herein includes the micro- of for example, about 87% to about 93% processed fermentation One or more of nonionic surface active agent of biological supernatant and about 7%-13%.In another side of this embodiment In face, additive composition for paper making disclosed herein includes on the microorganism of for example, about 88% to about 92% processed fermentation One or more of nonionic surface active agent of clear liquid and about 8%-12%.In the other side of this embodiment, Additive composition for paper making disclosed herein includes the microorganism supernatant of for example, about 89% to about 91% processed fermentation One or more of nonionic surface active agent of about 9%-11%.
The aspect of this specification partly discloses the microorganism supernatant of fermentation.On the microorganism of fermentation disclosed herein Clear liquid can pass through culture yeasts bacterial strain, bacterium bacterial strain or yeast in the fermentation medium comprising sugared source, malt and magnesium salts It is prepared by the combination of both bacterial strain and bacterium bacterial strain.In in terms of this embodiment, only single yeast strain is in fermented and cultured It is used in base.In the other side of this embodiment, two or more different yeast strains are in the fermentation medium It uses.In the another aspect of this embodiment, only single bacterium bacterial strain uses in the fermentation medium.In this embodiment In addition in other side, two or more different bacterium bacterial strains use in the fermentation medium.In this embodiment In other side, one or more of different yeast strains are together with one or more of different bacteriums in fermentation medium Middle use.In the another aspect of this embodiment, two kinds, three kinds, four kinds, five kinds or more different yeast strains together with Two kinds, three kinds, four kinds, five kinds or more different bacteriums use in the fermentation medium.
Sugared source includes but not limited to the sucrose from or mixtures thereof molasses, raw sugar, soybean.For example in addition to reduced sugar Except glucose and maltose and ash content, organic non-saccharide and some water, molasses usually also include up to about 50% sucrose. The presence of the sugar of the type found in molasses is important in terms of promoting their enzymes of generation and the activity of saccharomycete.Although Untreated sugarcane blackstrap molasses molasses (cane blackstrap molasses) are preferred, but can also use other sugar Sweet such as beet molasses, bucket molasses (barrel molasses) and the like are as the natural next of the material needed for enzymatic fermentation Source.In the amount for preparing molasses useful in fermentation medium disclosed herein between by weight 40% and about 80%, and Preferably between by weight about 55% and about 75%.It will be appreciated that the molasses used it is specific amount can change with Generate desired optimum combination object.
Raw sugar is not to be refined and includes the sugar product of remaining molasses and other natural impuritys.Although no It is clearly understood, it has however been found that with the residue chemistry used included in decoloration and final purifying and in refining is used The use of the refined sugar of product is compared, and the chemicals of the remnants may have some harmful works to saccharomycete and maltase With the property that the presence generation of raw sugar significantly improves in fermentation reaction.It has been found that fermented material existing in the mixture A part include raw sugar in the case of, the optimal biological property and enzymatic property of disclosed fermentation medium is modified. Can be by weight about 10% and about 40% in the amount for preparing raw sugar useful in fermentation medium disclosed herein, and Preferably between by weight about 10% and about 30%.It will be appreciated that the specific amount of the raw sugar used can change To generate desired optimum combination object.
The key enzyme for advantageously contributing to fermentation reaction is provided by malt and yeast and/or bacterium.What is used is specific Malt is preferably diastatic malt, and the diastatic malt includes enzyme, and the enzyme includes carbohydrase, maltose and amylase.It removes Contribute to except the total effect and activity of enzymatic composition in final products mixture, malt is also believed to improve saccharomycete And/or the activity of bacterium.The amount for preparing malt useful in fermentation medium disclosed herein can be by weight about 3% Between about 15%, and preferably between by weight about 7% and about 12%.It will be appreciated that the tool of the malt used The amount of body can change to generate desired optimum combination object.
Fermentation is to cause carbohydrate and other complicated organic material decompositions into such as sugar, sour, gas and alcohol more The metabolic process of simple substance.Fermentation can carry out in yeast, bacterium and mould.Fermentation includes alcohol fermentation and lactic acid hair Ferment.Lactic fermentation includes homofermentative lactic and heterolactic fermentation.
Yeast, which refers to generate, to be caused for example by carbohydrate-modifying at the fermentation reaction of carbon dioxide and alcohol institute Any fermented fungal of the enzyme needed.During fermentation reaction, many enzymes are generated by active dry yeasr, and include hydrolase and Both oxidizing ferment, for example, invertase, catalyzing enzyme, lactase, maltose, carboxylase and other.Yeast is included in following food Useful yeast strain in processing and fermentation：Such as the fermentation such as based on beans, the fermentation based on flour, the hair based on cereal Ferment, the fermentation based on vegetables, the fermentation based on fruit, the fermentation based on honey, the fermentation based on dairy products, the hair based on fish Ferment, the fermentation based on meat and the fermentation based on tea.The useful special Blastocystis in fermentation reaction disclosed herein Non-exhaustive inventory includes but not limited to brettanomyce Pseudomonas, Candida, quasi- Weir Blastocystis (Cyberlindnera), the black powder Blastocystis (Cystofilobasidium) of sporangiocyst line, Debaryomyces Pseudomonas (Debaryomyces), moral carat saccharomycete (Dekkera), Fusarium, geotrichum sp category, her Sa Blastocystis (Issatchenkia), Kazakhstan's Blastocystis (Kazachstania), Ke Leke Blastocystis (Kloeckera), gram Shandong tie up Blastocystis, lecanium Pseudomonas (Lecanicillium), Mucor, Neurospora, Pediococcus (Pediococcus), Penicillium, Pichia pastoris Pseudomonas, Rhizopus (Rhizopus), rhodosporidium toruloides Pseudomonas (Rhodosporidium), red ferment Female Pseudomonas (Rhodotorula), Schizosccharomyces, hair spore Blastocystis (Thrichosporon), has spore at Blastocystis Torula (Torulaspora), Torulopsis, Verticillium dahliae category (Verticillium), Ye Luoweiya Blastocystis (Yarrowia), Zygosaccharomyces Pseudomonas (Zygosaccharomyces) and Zygotorulaspora.Fermentation disclosed herein is anti- Useful yeast species belong to but are not limited in answering, and useful special yeast species is non-detailed in fermentation reaction disclosed herein Most inventory includes but not limited to abnormal British mold (B.anomalus), Brussels British mold (B.bruxellensis), gram Lawson British mold (B.claussenii), Ban Tute British molds (B.custersianus), Na Shi British molds (B.naardenensis), this southern brettanomyce (B.nanus), mound shape are false Silk yeast (C.colliculosa), small Candida (C.exiguous), Candida humicola (C.humicola), koumiss Candidiasis (C.kefyr), candida krusei (C.krusei), Miller Candida (C.milleri), Candida Bacterium (C.mycoderma), candida pelliculosa bacterium (C.pelliculosa), corrugated candidiasis (C.rugose), star Candidiasis (C.stellate), Candida tropicalis (C.tropicalis), candida albicans bacterium of laying eggs (C.utilis), Candida valida bacterium (C.valida), sour wine candidiasis (C.vini), candida zeylanoides bacterium (C.zeylanoides), it is inferior to intend Weir killer yeast bacterium (Cb.mrakii), Cryptococcus (Cs, infirmominiatum), the Chinese Dbaly yeast bacterium (D.hansenii), Ke Leke saccharomyces pastorianus bacterium (D.kloeckeri), abnormal moral carat saccharomycete (Dk.anomala), Brussels moral gram yeast (Dk.bruxellensis), F.domesticum, Geotrichum (G.candidum), Issatchenkia orientalis bacterium (I.orientalis), marine yeast (K.exigua), monospore saccharomyces cerevisiae (K.unispora), Africa Ke Leke yeast (KI.africana), K. apiculata bacterium (KI.apis), Java gram Strangle gram yeast (KI.javanica), lactic acid yeast kluyveromyces (Ku.lactis), Kluyveromyces marxianus bacterium (Ku.marxianus), Kluyveromyces marxianus bacterium (Ku.marxianus), Verticillium lecanii (L.lecanii), frozen soil hair Mould (M.hiemalis), thicket Mucor (M.plumbeus), Mucor racemosus (M.racemosus), Mucor racemosus, type arteries and veins Born of the same parents bacterium (N.intermedia), pediococcus cerevisiae (P.cerevisiae), white Penicillium notatum (Pn.album), sramana cypress cheese are green It is mould (Pn.camemberti), cheese Penicillium notatum (Pn.caseifulvum), penicillium chrysogenum (Pn.chrysogenum), general Logical Penicillium notatum (Pn.commune) receives ground mould (Pn.nalgiovense), penicillium roqueforti (Pn.roqueforti), chlorine nitrogen Tall and erect Penicillium notatum (Pn.solitum), fermentation Pichia yeast (Pi.fermentans), Rhizopus microsporus (R.microspores), Rs.infirmominiatum, sticky red rhodotorula (Rt.glutinis), small Rhodotorula sp (Rt.minuta), deep red saccarom ycete (Rt.rubra), saccharomyces bayanus bacterium (S.bayanus), Bu Ladi saccharomycete (S.boulardii), saccharomyces carlsbergensis bacterium (S.carlsbergensis), S. cervisiae (S.cerevisiae), true saccharomyces bayanus bacterium (S.eubayanus), unusual wine brewing Saccharomycete (S.paradoxus), saccharomyces pastorianus bacterium (S.pastorianus), methamidophos (S.rouzii), saccharomyces uvarum There are spore circle in bacterium (S.uvarum), schizosaccharomyces pombe bacterium (Sc.pombe), Fructus Atriplicis Sibiricae trichosporon bacteria (Th.beigelii), Dell Saccharomycete (T.delbrueckii), T.franciscae, ball have spore torula bacterium (T.pretoriensis), small ellipse to have spore Torula bacterium (T.microellipsoides), spherical shape have spore torula bacterium (T.globosa), India's Tilletia foetida (T.indica), Mary has spore torula bacterium (T.maleeae), T.quercuum, variable quasi- ball saccharomycete (To.versatilis), Verticillium lecanii (V.lecanii), Yarrowialipolytica bacterium (Y.lipolytica), Bayer connect Close saccharomycete (Z.bailii), two spore Zygosaccharomyces bacterium (Z.bisporus), aroma-producing yeast bacterium (Z.cidri), fermentation engagement ferment Female bacterium (Z.fermentati), Florence Zygosaccharomyces bacterium (Z.florentinus), engagement sugar yeast bacterium (Z.kombuchaensis), adhesive bond saccharomycete (Z.lentus), honey Zygosaccharomyces bacterium (Z.mellis), small ellipse connect Close saccharomycete (Z.microellipsoides), Mu Lake Zygosaccharomyces bacterium (Z.mrakii), vacation Lu Shi combining yeast bacterium (Z.pseudorouxii) and Lu Shi Zygosaccharomyces bacterium (Z.rouxii) and Zt.florentina.Preferred yeast is usual It can be used as the saccharomyces cerevisiae (Saccharomyces cerevisiae) of Saccharomyces cerevisiae acquisition.
Bacterium, which refers to generate, to cause for example to generate alcohol such as ethyl alcohol or acid such as acetic acid, the hair of lactic acid and/or succinic acid Any zymogenous bacteria of enzyme needed for ferment reaction.What useful specific bacterium belonged in fermentation reaction disclosed herein is non-exhaustive Inventory include but not limited to acetobacter (Acetobacter), Arthrobacter, Aerococcus (Aerococcus), Bacillus, Bifidobacterium, short shape Bacillus (Brachybacterium), brevibacterium, Barnobacterium, meat Bacillus (Carnobacterium), rodlike Pseudomonas, enterococcus spp, Colibacter, glucose acetobacter (Gluconacetobacter), Gluconobacter, Hafnia (Hafnia), Halomonas (Halomonas), Cook Pseudomonas (Kocuria), Lactobacillus, lactococcus, Leuconostoc, megacoccus category (Macrococcus), Microbacterium, Micrococcus, neisseria, wine Coccus (Oenococcus), Pediococcus, Propionibacterium, Proteus, false monospore Pseudomonas, Psychrobacter (Psychrobacter), Salmonella, gemma Bacillus acidi lactici (Sporolactobacillus), grape Coccus, streptococcus, streptomyces, Tetracoccus (Tetragenococcus), Vagococcus (Vagococcus), Wei Si Bordetella (Weissella) and zymomonas.Useful specific thin species in fermentation reaction disclosed herein Non-exhaustive inventory include but not limited to acetify acetobacter (A.aceti), aphid parasite acetobacter (A.fabarum), sieve Prosperous acetobacter (A.lovaniensis), apple acetobacter (A.malorum), east acetobacter (A.orientalis), Acetobacter pasteurianus (A.pasteurianus), Acetobacter pasteurianus (A.pasteurianus), A.pomorum, Portugal acetic acid Bacillus (A.syzygii), tropical acetobacter (A.tropicalis), A Shi arthrobacteriums (Ar.arilaitensis), Bei Reer It is family name's arthrobacterium (Ar.Bergerei), Arthrobacter globiformis (Ar.Globiformis), nicotianae (Ar.nicotianae), more Become arthrobacterium (Ar.variabilis), Bacillus cercus (B.cereus, bacillus coagulans (B.coagulans), lichens Bacillus (B.licheniformis), bacillus pumilus (B.pumilus), Bacillus sphaericus (B.sphaericus), Bacillus stearothermophilus (B.stearothermophilus), bacillus subtilis (B.subtilis), bifidobacterium adolescentis (B.adolescentis), animal bifidobacteria (B.animalis), bifidobacterium bifidum (B.bifidum), bifidobacterium breve (B.breve), bifidobacterium infantis (B.infantis), lactic acid Bifidobacterium (B.lactis), bifidobacterium longum (B.longum), bifidobacterium pseudolongum (B.pseudolongum), bifidobacterium thermophilum (B.thermophilum), food are small short Bacillus (Br.alimentarium), the small brevibacterium of food (Br.alimentarium), the small brevibacterium of cheese fermentation (Br.tyrofermentans), the small brevibacterium (Br.tyrofermentans) of cheese fermentation, Bv.aurantiacum, cheese are short Bacillus (Bv.casei), Brevibacterium linens (Bv.linens) blazon meat bacillus (C.divergens), maltose meat bacillus (C.maltaromaticum), it dwells flesh of fish bacillus (C.piscicola), brevibacterium ammoniagene (C.ammoniagenes), cheese stick Shape bacterium (Co.casei), micro- yellow corynebacteria (Co.flavescens), the corynebacteria (Co.mooreparkense) of isolation, change Different corynebacteria (Co.variabile), enterococcus faecalis (E.faecalis), enterococcus faecium (E.faecium), fixed nitrogen glucose acetic acid Bacillus (G.azotocaptans), acetobacter diazotrophicus acidfast bacilli (G.diazotrophicus), circus glucose acetobacter (G.entanii), European glucose acetobacter (G.europaeus), Chinese Xun Shi glucose acetobacter (G.hansenii), John Na glucose acetobacter (G.johannae), the wooden glucose acetobacter (G.oboediens), the wooden grape vinegar acidfast bacilli (G.xylinus), Gluconobacter oxvdans (Gl.oxydans), hafnia alvei (H.alvei), elongation Halomonas (Hl.elongate), thermophilic cock Salmonella (K.rhizophila), thermophilic cock Salmonella (K.rhizophila), variation Cook Bacterium (K.varians), variation Kocuria kristinae ad (K.varians), acidproof Bacillus acidi lactici (L.acidifarinae), sour powder Bacillus acidi lactici (L.acidifarinae), Lactobacillus acidophilus (L.acidipiscis), digestion Bacillus acidi lactici (L.alimentarius), short Bacillus acidi lactici (L.brevis), Bu Shi Bacillus acidi lacticis (L.bucheri), cocoa Bacillus acidi lactici (L.cacaonum), cheese lactic acid Bacillus (L.casei), cellobiose Bacillus acidi lactici (L.cellobiosus), mound shape bacterium colony Bacillus acidi lactici (L.collinoides), compound Bacillus acidi lactici (L.composti), rod-shaped lactobacillus (L.coryniformis), curling breast Acidfast bacilli (L.crispatus), lactobacillus curvatus (L.curvatus), lactobacillus delbrueckii, dextrin Bacillus acidi lactici (L.dextrinicus), Di Shi Bacillus acidi lacticis (L.diolivorans), double enzyme fusiform Bacillus acidi lacticis (L.fabifermentans), sausage Bacillus acidi lactici (L.farciminis), fermentation lactobacillus (L.fermentum), grignard Bacillus acidi lactici (L.gasseri), Ghana's Bacillus acidi lactici (L.ghanensis), Kazakhstan Bacillus acidi lactici (L.hammesii), Harbin Bacillus acidi lactici (L.harbinensis), Lactobacillus helveticus (L.helveticus), Xi Shi Bacillus acidi lacticis (L.hilgardii), Homotype corruption wine Bacillus acidi lactici (L.homohiochii), Zhan Shi Bacillus acidi lacticis (L.jensenii), Yue Shi Bacillus acidi lacticis (L.johnsonii), koumiss sample Bacillus acidi lactici (L.kefiranofaciens), Kefir grains Bacillus acidi lactici (L.kefiri), bubble Dish Bacillus acidi lactici (L.kimchi), L.kisonensis, Kun Shi Bacillus acidi lactici (L.kunkeei), Malian Bacillus acidi lactici (L.mali), food cassava Bacillus acidi lactici (L.manihotivorans), bright step on Bacillus acidi lactici (L.mindensis), mucous membrane lactic acid Bacillus (L.mucosae), Na Shi Bacillus acidi lacticis (L.nagelii), south Mu Shi (L.namuresis), the special Bacillus acidi lactici in south (L.nantesis), Deng Shi Bacillus acidi lacticis (L.nodensis), L.oeni, L.otakiensis, bread Bacillus acidi lactici are exerted (L.panis), the short Bacillus acidi lactici of class (L.parabrevis), class Bu Shi Bacillus acidi lacticis (L.parabuchneri), class cheese breast Acidfast bacilli (L.paracasei), class kefir Bacillus acidi lactici (L.parakefiri), class digest Bacillus acidi lactici (L.paralimentarius), class lactobacillus plantarum (L.paraplantarum), pentose Bacillus acidi lactici (L.pentosus), L.perolens, lactobacillus plantarum (L.plantarum), the sub- Bacillus acidi lactici of rag (L.pobuzihii), bridge Bacillus acidi lactici (L.pontis), L.rapi, reuteri (L.reuteri), rhamnose lactic acid bacteria (L.rhamnosus), red breast Acidfast bacilli (L.rossiae), picogram Bacillus acidi lactici (L.sakei), saliva Bacillus acidi lactici (L.salivarius), San Francisco lactic acid Bacillus (L.sanfranciscensis), Sa rub Bacillus acidi lactici (L.satsumensis), L.secaliphilus, L.senmaizukei, L.siliginis, nematode Bacillus acidi lactici (L.similis), lactobacillus reuteri (L.spicheri), The double mortar Bacillus acidi lactici (L.suebicus) of pig, L.sunkii, L.tucceti, cowpox Bacillus acidi lactici (L.vaccinostercus), Wen's Bacillus acidi lactici (L.versmoldesis), Witter not La Lishi Bacillus acidi lacticis (L.yamanashiensis, Lactococcus lactis (Lc.lactis), lactococcus raffinolactis (Lc.raffinolactis), leukonid (Le.carnosum), the bright string of thermophilic citric acid Pearl bacterium (Le.citreum), bright string coccus (Le.fallax), leuconostoc lactis (Le.holzapfelii), Le.inhae, pickles Leukonid (Le.kimchi), lactic acid leukonid (Le.lactis), Leuconostoc mesenteroides (Le.mesenteroides), palm fibre Palmitic acid leukonid (Le.palmae), leuconostoc pseudomesenteroides (Le.Pseudomesenteroides), the big coccus of molten junket (M.caseolyticus), blade microbacterium (Mb.foliorum), Mb gubbeenense, micrococcus luteus (Mc.luteus), Micrococcus lylae (Mc.lylae), Pediococcus acidilactici (P.acidilactici), Pediococcus pentosaceus (P.pentosaceus), sour propionibacterium acide-propionici (P.acidipropionici), Fei Shi propionic acid bars are produced (P.freudenreichii), propionibacterium jensenii (P.jensenii), Te Shi Propionibacteriums (P.thoenii), common variation Coccus (Pr.vulgaris), Pseudomonas fluorescens (Ps.fluorescens), Py.celer, meat streptomycete (S.carnosus), condiment staphylococcus (S.condiment), Staphylococcus equorum (S.equorum), Fu Shi staphylococcuses (S.fleurettii), fish fermented grape coccus (S.piscifermentans), staphylococcus saprophyticus (S.saphrophyticus), Staphylococcus sciuri (S.sciuri), simulation staphylococcus (S.simulans), amber grape ball Bacterium (S.succinus), calf staphylococcus (S.vitulinus), Warner staphylococcus (S.warneri), staphylococcus xylosus (S.xylosus), streptococcus cremoris (St.cremoris), gallic acid streptococcus (St.gallolyticus), saliva hammer Bacterium (St.salivarius), streptococcus thermophilus (St.thermophiles) detest color streptomycete (St.griseus), thermophilic salt tetrad Coccus (T.halophilus), South Korea's tetrads (T.koreensis), Benin Wei Si Salmonellas (W.beninensis), cibarium Wei Si Salmonellas (W.cibaria), W.fabaria, W.ghanesis, South Korea Wei Si Salmonellas (W.koreensis), class goldbeater's skin Wei Si Salmonella (W.paramesenteroides), Thailand Wei Si Salmonellas (W.thailandensis) and zymomonas mobilis (Z.mobilis)。
Mould, which refers to generate, to cause for example to generate alcohol such as ethyl alcohol or acid such as acetic acid, the hair of lactic acid and/or succinic acid Any fermentation mould of enzyme needed for ferment reaction.What useful specific mould belonged in fermentation reaction disclosed herein is non-exhaustive Inventory includes but not limited to aspergillus.The non-exhaustive inventory of useful specific mould species in fermentation reaction disclosed herein Including but not limited to A.acidus, aspergillus fumigatus, black-koji mould, aspergillus oryzae and soy sauce koji mould (A.sojae).
It will be appreciated that the actual amount of the various types of enzymes generated will depend on many factors, it is included in preparation fermentation The type of the molasses and sugar that are used in mixture.However, again, it is believed that in using molasses and raw sugar, obtain optimal enzyme and receive Rate and activity.In embodiments, the amount for preparing yeast useful in fermentation medium disclosed herein can be by weight Between meter about 0.2% and about 5%, and preferably between by weight about 1% and about 3%.It will be appreciated that the ferment used Female Specific amounts can change to generate desired optimum combination object.
The presence of a small amount of organic catalyst such as magnesium salts is not only during fermentation reaction but also hereafter in product composition In trap and decompose organic waste materials in improve enzyme activity.Preferred magnesium salts is magnesium sulfate.It is disclosed herein preparing The amount of useful magnesium salts can be between by weight about 0.1% and about 5%, and preferably by weight in fermentation medium Between meter about 1% and about 3%.It will be appreciated that the Specific amounts of the magnesium salts used can change to generate desired optimum combination Object.
In order to prepare the microorganism supernatant of fermentation, molasses, sucrose and magnesium salts are added into the warm water suitably measured.To the greatest extent The Specific amounts for the water that pipe uses is not especially important, but the water typically suitably measured is the hair used from fermentation reaction About the 2 of the total weight of the other compositions of ferment culture medium are again to about 20 times.The water of this amount is enough to promote easily to mix and foot To activate yeast, bacterium and/or mould and dissolve other materials.In addition, the temperature of water cannot be too hot, so that heat inactivation hair Maltase needed for ferment and yeast enzyme.Thus, for example greater than about 65 DEG C of coolant-temperature gage must be avoided by and preferred temperature exists Between about 25 DEG C to about 45 DEG C.The use of cold water may lead to excessively slow fermentation reaction rate, and therefore it is expected to increase In the case of the reaction rate added, the use of cold water should be also avoided.Molasses, sugar and magnesium salts are effectively being mixed and dissolving it Afterwards, malt and yeast are added, mixture is stirred and allows to cure, it is substantially complete until fermenting.At about 20 DEG C and about 45 Temperature between DEG C, reaction time can be between about 2 days and about 5 days.The effervesce of attentive response mixture can be passed through (effervescence) generally subside and completed to be readily determined.At the end of fermentation reaction, by the microorganism of fermentation Culture is centrifuged to remove " sludge (sludge) " that is formed during fermentation.The fermented supernatant fluid generated is collected (typically to press Weight meter about 90% is to about 98%) for subsequent processing.
The microorganism supernatant of fermentation includes biological nutrients, minerals and amino acid.Biological nutrients typically with from The amount of about 0.01% to about 1% of the total weight of the microorganism supernatant of fermentation exists.Each individual biological nutrients is typical Ground from the amount of about 0.00001% to about 0.01% of the total weight of the microorganism supernatant of fermentation to exist.Biological nutrients Example includes but not limited to biotin, folic acid, glucan such as alpha-glucans and beta glucan, niacin, inositol (insotil), general Acid, pyridoxol, riboflavin and thiamine.In in terms of this embodiment, the microorganism supernatant of fermentation disclosed herein Including the biotin of for example, about 0.00001% to about 0.0011%, the folic acid of about 0.0006% to about 0.016%, about 0.005% To about 15% niacin, the inositol of about 0.01% to about 1%, the pantothenic acid of about 0.00017% to about 0.017%, about 0.0006% To about 0.016% pyridoxol, the riboflavin of about 0.002% to about 0.023% and the thiamines of about 0.001% to about 0.02% Element.In in terms of other of this embodiment, the microorganism supernatant of fermentation disclosed herein include for example, about 0.00006% to About 0.0006% biotin, the folic acid of about 0.001% to about 0.011%, the niacin of about 0.01% to about 0.1%, about The inositol of 0.08% to about 0.18%, the pantothenic acid of about 0.002% to about 0.012%, about 0.001% to about 0.011% pyrrole tremble The thiamine of alcohol, the riboflavin of about 0.007% to about 0.017%, about 0.003% to about 0.013%.This embodiment again In other aspects, the microorganism supernatant of fermentation disclosed herein includes the biology of for example, about 0.00012% to about 0.0006% The flesh of element, the folic acid of about 0.001% to about 0.011%, the niacin of about 0.01% to about 0.1%, about 0.08% to about 0.18% Alcohol, the pantothenic acid of about 0.003% to about 0.013%, the pyridoxol of about 0.001% to about 0.011%, about 0.008% are to about The thiamine of 0.017% riboflavin, about 0.003% to about 0.013%.This embodiment it is other in terms of other in, this The literary disclosed microorganism supernatant to ferment include the biotin of for example, about 0.00009% to about 0.0003%, about 0.004% to About 0.008% folic acid, the niacin of about 0.03% to about 0.07%, the inositol of about 0.11% to about 0.15%, about 0.006% to About 0.01% pantothenic acid, the pyridoxol of about 0.004% to about 0.008%, the riboflavin of about 0.01% to about 0.014%, about The thiamine of 0.006% to about 0.010%.
Minerals from the amount of about 0.1% to about 20% of the total weight of the microorganism supernatant of fermentation typically to exist. Each individual minerals from the amount of about 0.0001% to about 5% of the total weight of the microorganism supernatant of fermentation typically to deposit .The example of minerals includes but not limited to calcium, chromium, copper, iron, magnesium, phosphate, potassium, sodium and zinc.In the side of this embodiment In face, the microorganism supernatant of fermentation disclosed herein include the calcium of for example, about 0.02% to about 0.3%, about 0.000002% to About 0.0016% chromium, the copper of about 0.000009% to about 0.0014%, the iron of about 0.00005% to about 0.02%, about The magnesium of 0.001% to about 1.3%, the phosphate of about 0.2% to about 14%, the potassium of about 0.4% to about 16%, about 0.2% are to about The zinc of 15% sodium and about 0.08% to about 13%.In in terms of other of this embodiment, fermentation disclosed herein it is micro- Biological supernatant includes the calcium of for example, about 0.07% to about 0.21%, the chromium of about 0.000007% to about 0.0011%, about The copper of 0.00004% to about 0.0009%, the iron of about 0.0001% to about 0.015%, the magnesium of about 0.005% to about 0.9%, about The phosphate of 0.7% to about 9%, the potassium of about 0.9% to about 11%, the sodium of about 0.7% to about 10% and about 0.3% are to about 8% zinc.This embodiment again in terms of other in, the microorganism supernatant of fermentation disclosed herein includes for example, about The calcium of 0.05% to about 1%, the chromium of about 0.0001% to about 0.0009%, the copper of about 0.00006% to about 0.0007%, about The iron of 0.0001% to about 0.013%, the magnesium of about 0.005% to about 1%, the phosphate of about 0.1% to about 7%, about 0.5% to The zinc of about 9% potassium, the sodium of about 0.5% to about 8% and about 0.5% to about 6%.In the other in terms of other of this embodiment In, calcium of the microorganism supernatant comprising for example, about 0.12% to about 0.16% of fermentation disclosed herein, about 0.0002% are to about 0.0006% chromium, the copper of about 0.00009% to about 0.0004%, the iron of about 0.0006% to about 0.01%, about 0.01% to About 0.4% magnesium, the phosphate of about 1% to about 4%, the potassium of about 2% to about 6%, the sodium of about 1% to about 5% and about 0.8% To about 3% zinc.
Amino acid from the amount of about 20% to about 60% of the total weight of the microorganism supernatant of fermentation typically to exist.Often The individual amino acid of kind from the amount of about 0.1% to about 15% of the total weight of the microorganism supernatant of fermentation typically to exist. The example of minerals include but not limited to alanine, arginine, aspartic acid, cysteine, glutamic acid, glycine, lysine, Methionine, phenylalanine, proline, serine and threonine.In in terms of this embodiment, fermentation disclosed herein Microorganism supernatant include the alanine of for example, about 0.2% to about 16%, the arginine of about 0.09% to about 15%, about The aspartic acid of 0.4% to about 18%, the cysteine of about 0.003% to about 5%, the glutamic acid of about 0.5% to about 20%, about The glycine of 0.09% to about 15%, the lysine of about 0.09% to about 15%, the methionine of about 0.002% to about 5%, about The phenylalanine of 0.09% to about 15%, the proline of about 0.09% to about 15%, about 0.09% to about 15% serine with And the threonine of about 0.09% to about 15%.In in terms of other of this embodiment, on the microorganism of fermentation disclosed herein Clear liquid includes the alanine of for example, about 0.7% to about 11%, the arginine of about 0.5% to about 10%, about 0.9% to about 13% Aspartic acid, the cysteine of about 0.008% to about 1.2%, the glutamic acid of about 1% to about 15%, about 0.5% to about 10% The benzene of glycine, the lysine of about 0.8% to about 12%, the methionine of about 0.2% to about 1.6%, about 0.5% to about 10% The Soviet Union of alanine, the proline of about 0.5% to about 10%, the serine of about 0.5% to about 10% and about 0.5% to about 10% Propylhomoserin.This embodiment again in terms of other in, the microorganism supernatant of fermentation disclosed herein include for example, about 0.5% to About 9% alanine, the arginine of about 0.5% to about 8%, the aspartic acid of about 1% to about 11%, about 0.01% to about 2% Cysteine, the glutamic acid of about 3% to about 13%, the glycine of about 0.5% to about 8%, about 1% to about 10% bad ammonia Acid, the methionine of about 0.3% to about 3%, the phenylalanine of about 0.5% to about 7%, about 0.5% to about 7% proline, The threonine of the serine of about 0.5% to about 7% and about 0.5% to about 7%.In the other in terms of other of this embodiment In, the microorganism supernatant of fermentation disclosed herein includes the essence of the alanine of for example, about 2% to about 6%, about 1% to about 5% The paddy ammonia of propylhomoserin, the aspartic acid of about 4% to about 8%, the cysteine of about 0.03% to about 0.7%, about 6% to about 10% Acid, the glycine of about 1% to about 5%, the lysine of about 3% to about 7%, the methionine of about 0.7% to about 1.1%, about 1% To about 5% phenylalanine, the proline of about 1% to about 5%, the serine of about 1% to about 5% and about 1% to about 5% Threonine.
The aspect of this specification partly discloses the microorganism supernatant of processed fermentation.Processed fermentation it is micro- Biological supernatant is with denaturation, kills or otherwise destroy the yeast of any remaining work, contributed by yeast and malt Another any other micro- life come source contribution present in organized enzyme and microorganism supernatant by fermentation disclosed herein The supernatant that the mode of object or enzyme is handled.The non-limiting examples of useful processing routine include boiling work using high temperature Skill；High-pressure treatment process using high temperature and high pressure or the irradiation technique by the way that supernatant to be exposed to ionising radiation；Or denaturation, The yeast for killing or otherwise destroying any remaining work, the organized enzyme contributed by yeast and malt and by being disclosed herein Fermentation microorganism supernatant present in it is another come any other microorganism of source contribution or any other sterilizing of enzyme Technique.In addition, treatment process above can be used alone, it is in combination with one another or with pasteurization technique, chemical sterilization work Skill and sterilising filtration process combination use, and with denaturation, kill or otherwise destroy in fermented supernatant fluid disclosed herein and deposit Protein such as enzyme and microorganism such as yeast, bacterium and/or mould.All methods discussed above are that this field is common Technique known to technical staff, the field because they prepare and/or sterilize commonly used in food.
Then the microorganism supernatant of processed fermentation can be stored for subsequent use in liquid form.It may be selected The microorganism supernatant on ground, processed fermentation can be spray-dried by methods known in the art to generate xeraphium End.Dry powder form can also be stored for subsequent use.
The microorganism supernatant of the processed fermentation disclosed herein of any amount can be used for disclosed additive for paper making In composition, condition is that the amount is useful to putting into practice method disclosed herein and purposes.For determining proper amount of factor packet The microorganism supernatant of for example processed fermentation is included whether in liquid or the microorganism supernatant of powder type, processed fermentation The particular business source of liquid, the ad hoc approach of microorganism supernatant for producing processed fermentation, additive for paper making combination Whether object is used as concentrate or is produced as off-the-shelf and it is expected when preparing additive composition for paper making by concentrate Dilution factor.In general, relative to dry powder form, it would be desirable on the microorganism of the processed fermentation of larger amount of liquid form Clear liquid.
In in terms of this embodiment, the amount of the microorganism supernatant of the processed fermentation used is for example by weight Meter about 0.5%, by weight about 1.0%, by weight about 1.5%, by weight about 2.0%, by weight about 2.5%, press Weight meter about 3.0%, by weight about 3.5%, by weight about 4.0%, by weight about 4.5%, by weight about 5.0%, by weight about 6.0%, by weight about 7.0%, by weight about 7.5%, by weight about 8.0%, by weight Meter about 9.0% or by weight about 10.0%.In in terms of other of this embodiment, micro- life of the processed fermentation used The amount of object supernatant is such as by weight at least 0.5%, by weight at least 1.0%, by weight at least 1.5%, by weight Gauge at least 2.0%, by weight at least 2.5%, by weight at least 3.0%, by weight at least 3.5%, by weight At least 4.0%, by weight at least 4.5%, by weight at least 5.0%, by weight at least 6.0%, by weight at least 7.0%, by weight at least 7.5%, by weight at least 8.0%, by weight at least 9.0% or by weight at least 10.0%.This embodiment again in terms of other in, the amount of the microorganism supernatant of the processed fermentation used is for example By weight at most 0.5%, by weight at most 1.0%, by weight at most 1.5%, by weight at most 2.0%, by weight Gauge at most 2.5%, by weight at most 3.0%, by weight at most 3.5%, by weight at most 4.0%, by weight At most 4.5%, by weight at most 5.0%, by weight at most 6.0%, by weight at most 7.0%, by weight at most 7.5%, by weight at most 8.0%, by weight at most 9.0% or by weight at most 10.0%.In this embodiment In addition in other aspects, the amount of the microorganism supernatant of the processed fermentation used for example by weight about 0.1% to by Between weight meter about 2.5%, between by weight about 0.1% to by weight about 3.0%, by weight about 0.1% to Between by weight about 3.5%, between by weight about 0.1% to by weight about 4.0%, by weight about 0.1% Between to by weight about 5.0%, between by weight about 0.5% to by weight about 2.5%, by weight about Between 0.5% to by weight about 3.0%, between by weight about 0.5% to by weight about 3.5%, by weight Between about 0.5% to by weight about 4.0%, between by weight about 0.5% to by weight about 5.0%, by weight Meter about 1% to by weight about 2.5% between, between by weight about 1% to by weight about 3.0%, by weight Between about 1% to by weight about 3.5%, between by weight about 1% to by weight about 4.0%, by weight about Between 1% to by weight about 5.0%, between by weight about 1% to by weight about 6.0%, by weight about 1% Between to by weight about 7.0%, between by weight about 1% to by weight about 8.0%, by weight about 1% to Between by weight about 9.0% or between by weight about 1% to by weight about 10.0%.
In in terms of other of this embodiment, the amount of the microorganism supernatant of the processed fermentation used be for example by Weight meter about 15.0%, by weight about 20.0%, by weight about 25.0%, by weight about 30.0%, by weight about 35.0%, by weight about 40.0% it, by weight about 45.0%, by weight about 50.0%, by weight about 55.0%, presses Weight meter about 60.0%, by weight about 65.0%, by weight about 70.0%, by weight about 75.0%, by weight about 80.0%, by weight about 85.0% or by weight about 90.0%.This embodiment again in terms of other in, the warp that uses The amount of the microorganism supernatant of the fermentation of processing is such as by weight at least 15.0%, by weight at least 20.0%, by weight Gauge at least 25.0%, by weight at least 30.0%, by weight at least 35.0%, by weight at least 40.0%, by weight Gauge at least 45.0%, by weight at least 50.0%, by weight at least 55.0%, by weight at least 60.0%, by weight Gauge at least 65.0%, by weight at least 70.0%, by weight at least 75.0%, by weight at least 80.0%, by weight Gauge at least 85.0% or by weight at least 90.0%.This embodiment it is other in terms of other in, use through processing Fermentation microorganism supernatant amount be such as by weight at most 15.0%, by weight at most 20.0%, by weight At most 25.0%, by weight at most 30.0%, by weight at most 35.0%, by weight at most 40.0%, by weight At most 45.0%, by weight at most 50.0%, by weight at most 55.0%, by weight at most 60.0%, by weight At most 65.0%, by weight at most 70.0%, by weight at most 75.0%, by weight at most 80.0%, by weight At most 85.0% or by weight at most 90.0%.
In in terms of other of this embodiment, the amount of the microorganism supernatant of the processed fermentation used for example by Between weight meter about 5% to by weight about 7.5%, between by weight about 5% to by weight about 10%, by weight Meter about 5% to by weight about 15% between, between by weight about 5% to by weight about 20%, by weight about Between 5% to by weight about 25%, between by weight about 5% to by weight about 30%, by weight about 5% to Between by weight about 35%, between by weight about 5% to by weight about 40%, by weight about 5% to by weight Between gauge about 45%, between by weight about 5% to by weight about 50%, by weight about 5% to by weight Between about 55%, between by weight about 5% to by weight about 60%, by weight about 5% to by weight about Between 65%, between by weight about 5% to by weight about 70%, by weight about 5% to by weight about 75% Between, between by weight about 5% to by weight about 80%, between by weight about 5% to by weight about 85%, Between by weight about 5% to by weight about 90%, between by weight about 5% to by weight about 95%, by Between weight meter about 10% to by weight about 15%, between by weight about 10% to by weight about 20%, by weight Between gauge about 10% to by weight about 25%, between by weight about 10% to by weight about 30%, by weight Meter about 10% to by weight about 35% between, between by weight about 10% to by weight about 40%, by weight Between about 10% to by weight about 45%, between by weight about 10% to by weight about 50%, by weight about Between 10% to by weight about 55%, between by weight about 10% to by weight about 60%, by weight about Between 10% to by weight about 65%, between by weight about 10% to by weight about 70%, by weight about Between 10% to by weight about 75%, between by weight about 10% to by weight about 80%, by weight about Between 10% to by weight about 85%, between by weight about 10% to by weight about 90%, by weight about Between 10% to by weight about 95%, between by weight about 15% to by weight about 20%, by weight about Between 15% to by weight about 25%, between by weight about 15% to by weight about 30%, by weight about Between 15% to by weight about 35%, between by weight about 15% to by weight about 40%, by weight about Between 15% to by weight about 45%, between by weight about 15% to by weight about 50%, by weight about Between 15% to by weight about 55%, between by weight about 15% to by weight about 60%, by weight about Between 15% to by weight about 65%, between by weight about 15% to by weight about 70%, by weight about Between 15% to by weight about 75%, between by weight about 15% to by weight about 80%, by weight about Between 15% to by weight about 85%, between by weight about 15% to by weight about 90%, by weight about Between 15% to by weight about 95%, between by weight about 25% to by weight about 25%, by weight about Between 25% to by weight about 30%, between by weight about 25% to by weight about 35%, by weight about Between 25% to by weight about 40%, between by weight about 25% to by weight about 45%, by weight about Between 25% to by weight about 50%, between by weight about 25% to by weight about 55%, by weight about Between 25% to by weight about 60%, between by weight about 25% to by weight about 65%, by weight about Between 25% to by weight about 70%, between by weight about 25% to by weight about 75%, by weight about Between 25% to by weight about 80%, between by weight about 25% to by weight about 85%, by weight about Between 25% to by weight about 90%, between by weight about 25% to by weight about 95%, by weight about Between 25% to by weight about 30%, between by weight about 25% to by weight about 35%, by weight about Between 25% to by weight about 40%, between by weight about 25% to by weight about 45%, by weight about Between 25% to by weight about 50%, between by weight about 25% to by weight about 55%, by weight about Between 25% to by weight about 60%, between by weight about 25% to by weight about 65%, by weight about Between 25% to by weight about 70%, between by weight about 25% to by weight about 75%, by weight about Between 25% to by weight about 80%, between by weight about 25% to by weight about 85%, by weight about Between 25% to by weight about 90%, between by weight about 25% to by weight about 95%, by weight about Between 30% to by weight about 35%, between by weight about 30% to by weight about 40%, by weight about Between 30% to by weight about 45%, between by weight about 30% to by weight about 50%, by weight about Between 30% to by weight about 55%, between by weight about 30% to by weight about 60%, by weight about Between 30% to by weight about 65%, between by weight about 30% to by weight about 70%, by weight about Between 30% to by weight about 75%, between by weight about 30% to by weight about 80%, by weight about Between 30% to by weight about 85%, between by weight about 30% to by weight about 90%, by weight about Between 30% to by weight about 95%, between by weight about 35% to by weight about 40%, by weight about Between 35% to by weight about 45%, between by weight about 35% to by weight about 50%, by weight about Between 35% to by weight about 55%, between by weight about 35% to by weight about 60%, by weight about Between 35% to by weight about 65%, between by weight about 35% to by weight about 70%, by weight about Between 35% to by weight about 75%, between by weight about 35% to by weight about 80%, by weight about Between 35% to by weight about 85%, between by weight about 35% to by weight about 90%, by weight about Between 35% to by weight about 95%, between by weight about 40% to by weight about 45%, by weight about Between 40% to by weight about 50%, between by weight about 40% to by weight about 55%, by weight about Between 40% to by weight about 60%, between by weight about 40% to by weight about 65%, by weight about Between 40% to by weight about 70%, between by weight about 40% to by weight about 75%, by weight about Between 40% to by weight about 80%, between by weight about 40% to by weight about 85%, by weight about Between 40% to by weight about 90%, between by weight about 40% to by weight about 95%, by weight about Between 45% to by weight about 50%, between by weight about 45% to by weight about 55%, by weight about Between 45% to by weight about 60%, between by weight about 45% to by weight about 65%, by weight about Between 45% to by weight about 70%, between by weight about 45% to by weight about 75%, by weight about Between 45% to by weight about 80%, between by weight about 45% to by weight about 85%, by weight about Between 45% to by weight about 90%, between by weight about 45% to by weight about 95%, by weight about Between 50% to by weight about 55%, between by weight about 50% to by weight about 60%, by weight about Between 50% to by weight about 65%, between by weight about 50% to by weight about 70%, by weight about Between 50% to by weight about 75%, between by weight about 50% to by weight about 80%, by weight about Between 50% to by weight about 85%, between by weight about 50% to by weight about 90%, by weight about Between 50% to by weight about 95%, between by weight about 55% to by weight about 60%, by weight about Between 55% to by weight about 65%, between by weight about 55% to by weight about 70%, by weight about Between 55% to by weight about 75%, between by weight about 55% to by weight about 80%, by weight about Between 55% to by weight about 85%, between by weight about 55% to by weight about 90%, by weight about Between 55% to by weight about 95%, between by weight about 60% to by weight about 65%, by weight about Between 60% to by weight about 70%, between by weight about 60% to by weight about 75%, by weight about Between 60% to by weight about 80%, between by weight about 60% to by weight about 85%, by weight about Between 60% to by weight about 90%, between by weight about 60% to by weight about 95%, by weight about Between 65% to by weight about 70%, between by weight about 65% to by weight about 75%, by weight about Between 65% to by weight about 80%, between by weight about 65% to by weight about 85%, by weight about Between 65% to by weight about 90%, between by weight about 65% to by weight about 95%, by weight about Between 70% to by weight about 75%, between by weight about 70% to by weight about 80%, by weight about Between 70% to by weight about 85%, between by weight about 70% to by weight about 90%, by weight about Between 70% to by weight about 95%, between by weight about 75% to by weight about 80%, by weight about Between 75% to by weight about 85%, between by weight about 75% to by weight about 90%, by weight about Between 75% to by weight about 95%, between by weight about 80% to by weight about 85%, by weight about Between 80% to by weight about 90%, between by weight about 80% to by weight about 95%, by weight about Between 85% to by weight about 90%, between by weight about 85% to by weight about 95% or by weight about Between 90% to by weight about 95%.
The aspect of this specification partly discloses surfactant.Surfactant is the surface tension for reducing liquid Compound, allows more easily to spread and reduce between two kinds of liquid or the interfacial tension between liquid and solid.Single table Face activating agent can be mixed with buffer solution disclosed herein or a variety of surfactants can be molten with buffering disclosed herein Liquid mixes.Useful surfactant include but not limited to ionic surfactant, amphoteric ion (both sexes) surfactant, Nonionic surface active agent or in which any combinations.The surfactant used in method disclosed herein can change, As understood by a person skilled in the art, and normally partially depend on the special buffer used, diluted protein and The conductivity value of use.
Ionic surfactant includes anionic surfactant.Anionic surfactant includes based on attached Be connected to the anionic surfactants of the permanent functional group on head (head) as such as sulfate, sulfonate, phosphate, Carboxylate or pH dependence anion type surfactants.Anionic surfactant include but not limited to alkyl sulfate such as Ammonium lauryl sulfate and lauryl sodium sulfate (SDS)；Alkyl ether sulfate such as sodium laureth sulfate (sodium laureth sulfate) and myristyl alcohol polyethers sodium sulphate (sodium myreth sulfate)；More library esters (docusate) such as dioctyl sodium sulphosuccinate (dioctyl sodium sulfosuccinate)；Sulfonate fluorochemical surface Activating agent such as perfluoro octane sulfonate (PFOS) and perflurobutane sulfonate；Alkyl diphenyl ether dithionate such as DOWFAXTM 2A1 (two disodium sulfate of lauryl phenyl ether), DOWFAXTM3B2 (two disodium sulfate of decyl phenyl ether), DOWFAXTMC10L (decyls Two disodium sulfate of phenyl ether), DOWFAXTM2EP and DOWFAXTM8390 (two disodium sulfates of palmityl phenyl ether)；Potassium phosphate Polyether ester such as TRITONTMH-55 and TRITONTMH-66；Alkylbenzene sulfonate；Alkylaryl ether phosphate；Alkyl ether phosphates Salt；Alkyl carboxylate such as fatty acid salt and odium stearate；Sodium N-lauroyl sarcosinate；Carboxylate fluorine-containing surfactant such as perfluor Pelargonate and per-fluoro octanoate and hexyl diphenyl ether sodium sulphate (DOWFAXTM C6L)。
Ionic surfactant further includes cationic surface active agent.Cationic surface active agent includes based on forever The surfactant of long property cationic surfactant or pH dependence cationic surfactants, such as such as primary amine, secondary amine Or tertiary amine.Cationic surface active agent includes but not limited to alkyl trimethyl ammonium salt such as cetyltrimethylammonium bromide (CTAB) With cetyltrimethyl ammonium chloride (CTAC)；Chlorination palmityl pyridine (CPC)；The beef tallow amine (POEA) of polyethoxylated；Benzene Prick oronain (BAC)；Benzethonium chloride (BAC)；The bromo- 5- nitros -1,3- dioxanes of 5-；Dimethyldioctadecylammonium ammonium chloride；With it is double Primary amine, secondary amine or the tertiary amine of octadecyldimethyl ammonium bromide (DODAB) and pH dependences, such as wherein primary amine is more than 10 PH become the surfactant that positively charged or secondary amine becomes electrically charged lotus in the pH less than 4, such as dichloride Octenidine.Its His useful anionic surfactant includes the anionic surfactant based on biology, including but not limited toAM 30-KE, Texapon Special andEHS, sodium 2-ethylhexyl sulfate.It is such The molecule that surfactant based on biology does not synthesize, the anionic surface derived from organic substance such as plant are lived Property agent.
Zwitterionic surfactant is based on primary amine, secondary amine or tertiary amine or quaternary ammonium cation and sulfate, carboxylate or phosphorus Hydrochlorate.Zwitterionic surfactant includes but not limited to 3- [(3- courages amidopropyl) dimethylammonio] -1- propane sulfonic acids Salt (CHAPS)；Sulfobetaines (sultaine) such as cocamidopropyl propyl amide hydroxyl sulfo betaine (cocamidopropyl hydroxysultaine)；Glycine betaine such as cocamidopropyl betaine；Or lecithin.
Nonionic surface active agent be less denaturation and therefore to dissolving memebrane protein and lipid be it is useful, together When retaining protein-protein interaction.Nonionic surface active agent includes polyethers nonionic surface active agent, poly- hydroxyl Base nonionic surface active agent and biosurfactant.Nonionic surface active agent includes alcohol ethoxylate, alkyl Phenol elhoxylate, phenol elhoxylate, acid amide ethoxylates, glycerol ethoxylate, fatty acid ethoxylate And amine ethoxylates.Nonionic surface active agent disclosed herein can have H (OCH2CH2)xOC6H4R1、 (OCH2CH2)xOR2Or H (OCH2CH2)xOC(O)R2General formula, wherein x representative be added to alkylphenol and/or fatty alcohol or fat The molal quantity of ethylene oxide (ethylene oxide) in acid, R1Represent long chain alkyl group and R2Represent long-chain fat race Group.In in terms of this embodiment, R1It is C7-C10Alkyl group and/or R2It is C12-C20Aliphatic group.Other are useful Nonionic surface active agent include based on biology nonionic surface active agent, including but not limited toNonionic surface active agent derived from MET-10U molasses is undersaturated short-chain amides.It is such The molecule that surfactant based on biology does not synthesize, the non-ionic surface derived from organic substance such as plant are lived Property agent.
The non-limiting examples of surfactant include polyethylene glycol anhydrous sorbitol Arrcostab (or the sorb of ethoxylation Alcohol ester) such as Polysorbate 20 dehydrating sorbitol monooleate (20), Polysorbate 40 anhydrosorbitol list Oleate (40), Polysorbate 60 dehydrating sorbitol monooleate (60), polysorbate 61 loses Water sorbitol monooleate (61), Polysorbate 65 dehydrating sorbitol monooleate (65)、 Polysorbate 80 dehydrating sorbitol monooleate (80), 81 dehydrating sorbitol monooleate of polysorbate (81) and Polysorbate 85 dehydrating sorbitol monooleate (85)；Sorbitol ester such as dehydration Sorbitol monooleate, sorbitan monolaurate, sorbitan-monopalmityl ester, anhydrosorbitol list Stearate and anhydrosorbitol tristearate；Polyglycerol ester such as glyceryl monooleate, glyceryl monolaurate, Dan Zong Palmitic acid acid glyceride, glycerin monostearate, olein, castor-oil plant acid glyceride, glyceryl tristearate, single two glyceride And glyceryl triacetate；The polyglycerol ester of ethoxylation；Alkyl-glucoside such as peanut base glucoside (arachidyl glucoside)、C12-20Alkyl-glucoside, caprylyl/Octyl glucoside, cetearyl glucoside (cetearyl Glucoside), cocoyl glucoside, Ethyl-glucoside and lauryl glucoside, decyl glucoside；Ethyoxyl The alkyl-glucoside of change；Such as single sucrose oleate ester of sucrose ester, mono laurate sucrose ester, single palmitic acid sucrose ester, monostearate Sucrose ester, three sucrose oleate esters, ricinoleic acid sucrose ester, three stearic acid sucrose esters, two glyceride of sucrose and triacetic acid sucrose ester； The sucrose ester of ethoxylation；Amine oxide；The alcohol of ethoxylation；The aliphatic alcohol of ethoxylation；Alkylamine；The alkane of ethoxylation Base amine；The octyl phenol of the nonyl phenol and ethoxylation of such as ethoxylation of the alkylphenol of ethoxylation；Alkyl polysaccharide；Ethoxy The alkyl polysaccharide of base；The castor oil of the aliphatic acid of ethoxylation such as ethoxylation；Such as ethoxylation of the fatty alcohol of ethoxylation Cetyl oleyl alcohol, the cetyl stearyl alcohol of ethoxylation, the decyl alcohol of ethoxylation, ethoxylation lauryl alcohol and ethyoxyl The tridecanol of change；The fatty amine of ethoxylation；Pa network sand nurse class (polyethylene-polypropylene copolymer), as pa network sand nurse 124 (L44), pa network sand nurse 181 (L61), pa network sand nurse 182 ( L62), pa network sand nurse 184 (L64), pa network sand nurse 188 (F68), pa network sand nurse 237 (F87), pa network sand nurse 338 (L108) and pa network sand nurse 407 ( F127)；Linear secondary alcohol ethoxylate such as TERGITOLTM 15-S-5、TERGITOLTM 15-S-7、TERGITOLTM 15-S- 9、TERGITOLTM 15-S-12、TERGITOLTM 15-S-15、TERGITOLTM 15-S-20、TERGITOLTM15-S-30 with And TERGITOLTM15-S-40；Alkylphenol polyol ethers；Alkyl aryl polyethyleneglycol ether；Polyethylene glycol alkyl ether, such as eight second Glycol list dodecyl ether, five ethylene glycol list dodecyl ether,30 and35；12 ethoxy-ethanols of 2- (-PX)；Polyethylene glycol octyl phenol ether such as polyethylene glycol (4-5) to tert-octyl phenol (X-45) And Triton X-100X-100)；Polyethylene glycol alkyl phenols ether such as Nonoxynol-9；Phenoxy group is poly- Ethoxy ethanol such as nonylphenoxy polyethoxy ethyl alcohol and octylphenoxy polyethoxy ethanol (CA-630 or NONIDETTMP-40)；Glucoside alkyl ether such as octylglucopyranoside glycosides；Maltoside alkyl ether such as dodecyl pyrans wheat Bud glucosides；Thioglucoside alkyl ether such as heptyl pyrans thioglucoside；Cardigin, alkyl esters of glycerol such as lauric acid Ester；Alkyl aryl polyether sulfuric ester；Sulfonic acid alcohol ester；Anhydrosorbitol Arrcostab；Coconut oleoyl amine ethanol amine such as coconut oleoyl amine one Ethanol amine and cocamide diethanolamine；Mono laurate sucrose ester；Dodecyl dimethylamine oxide and sodium taurocholate.Herein In disclosed method other non-limiting examples of useful surfactant can in such as Winslow, et al., Methods and Compositions for Simultaneously Isolating Hemoglobin from Red Blood Cells and Inactivating Viruses,U.S.2008/0138790；Pharmaceutical Dosage Forms and Drug Delivery Systems (Howard C.Ansel, et al., editor, Lippincott Williams＆Wilkins Publishers, the 7th edition, 1999)；Remington:The Science and Practice of Pharmacy(Alfonso R.Gennaro is edited, Lippincott, Williams＆Wilkins, the 20th edition, 2000)；Goodman&Gilman's The Pharmacological Basis of Therapeutics (Joel G.Hardman et al., editor, McGraw-Hill Professional, the 10th edition, 2001) and Handbook of Pharmaceutical Excipients (Raymond C.Rowe, et al., APhA Publications, the 4th edition, 2003) in be found, each of these bibliography lead to accordingly Reference is crossed to be integrally incorporated with it.
Nonionic surface active agent synergistically acts on the effect of the microorganism supernatant to enhance fermentation.In addition, It is well established that the nonionic surface active agent used in additive composition for paper making disclosed herein and enhancing chemical action It is compatible.Therefore, in embodiments, additive composition for paper making disclosed herein only includes one or more of nonionics Type surfactant.In another embodiment, additive composition for paper making disclosed herein only includes one or more Nonionic surface active agent and one or more of anionic surfactant.In another embodiment, public herein The additive composition for paper making opened does not include any cationic surface active agent.In another embodiment, it is disclosed herein Additive composition for paper making do not include any cationic surface active agent or zwitterionic surfactant.In another reality It applies in scheme, additive composition for paper making disclosed herein does not include any ionic surfactant.In another embodiment party In case, additive composition for paper making disclosed herein does not include any ionic surfactant or amphoteric ion surface-active Agent.
Can use the surfactant disclosed herein of any amount, condition be the amount to put into practice method disclosed herein and Purposes is useful.In in terms of this embodiment, the amount of the surfactant used is such as by weight about 0.01%, By weight about 0.05%, by weight about 0.075%, by weight about 0.1%, by weight about 0.2%, by weight about 0.3%, by weight about 0.4%, by weight about 0.5%, by weight about 0.6%, by weight about 0.7%, by weight Meter about 0.8%, by weight about 0.9%, by weight about 1.0%, by weight about 1.5%, by weight about 2.0%, press Weight meter about 2.5%, by weight about 3.0%, by weight about 4.0%, by weight about 5.0%, by weight about 6.0%, by weight about 7.0%, by weight about 7.5%, by weight about 8.0%, by weight about 9.0% or by weight Meter about 10.0%.In in terms of other of this embodiment, the amount of the surfactant used is for example by weight at least 0.01%, by weight at least 0.05%, by weight at least 0.075%, by weight at least 0.1%, by weight at least 0.25%, by weight at least 0.5%, by weight at least 0.75%, by weight at least 1.0%, by weight at least 1.5%, by weight at least 2.0%, by weight at least 2.5%, by weight at least 3.0%, by weight at least 4.0%, by weight at least 5.0%, by weight at least 6.0%, by weight at least 7.0%, by weight at least 7.5%, by weight at least 8.0%, by weight at least 9.0% or by weight at least 10.0%.In this embodiment Again in other aspects, the amount of the surfactant used is such as by weight at most 0.01%, by weight at most 0.05%, By weight at most 0.075%, by weight at most 0.1%, by weight at most 0.25%, by weight at most 0.5%, press Weight meter at most 0.75%, by weight at most 1.0%, by weight at most 1.5%, by weight at most 2.0%, by weight Meter at most 2.5%, by weight at most 3.0%, by weight at most 4.0%, by weight at most 5.0%, by weight extremely More 6.0%, by weight at most 7.5%, by weight at most 8.0%, by weight at most 9.0% or by weight at most 10.0%.
This embodiment it is other in terms of other in, the amount of the surfactant used is for example by weight about Between 0.1% to about by weight about 0.5%, between by weight about 0.1% to about by weight about 0.75%, by weight Gauge about 0.1% between about by weight about 1.0%, between by weight about 0.1% to about by weight about 1.5%, Between by weight about 0.1% to about by weight about 2.0%, by weight about 0.1% to about by weight about 2.5% Between, between by weight about 0.2% to about by weight about 0.5%, by weight about 0.2% to about by weight about Between 0.75%, between by weight about 0.2% to about by weight about 1.0%, by weight about 0.2% to about press weight Between gauge about 1.5%, between by weight about 0.2% to about by weight about 2.0%, by weight about 0.2% to Between about by weight about 2.5%, between by weight about 0.5% to about by weight about 1.0%, by weight about Between 0.5% to about by weight about 1.5%, between by weight about 0.5% to about by weight about 2.0%, by weight Gauge about 0.5% between about by weight about 2.5%, between by weight about 0.5% to about by weight about 3.0%, Between by weight about 0.5% to about by weight about 4.0%, by weight about 0.5% to about by weight about 5.0% Between, between by weight about 1.0% to about by weight about 2.5%, by weight about 1.0% to about by weight about Between 3.0%, between by weight about 1.0% to about by weight about 4.0%, by weight about 1.0% to about press weight Between gauge about 5.0%, between by weight about 1.0% to about by weight about 6.0%, by weight about 1.0% to Between about by weight about 7.0%, between by weight about 1.0% to about by weight about 7.5%, by weight about Between 1.0% to about by weight about 8.0%, between by weight about 1.0% to about by weight about 9.0%, by weight Gauge about 1.0% between about by weight about 10.0%, between by weight about 2.0% to about by weight about 2.5%, Between by weight about 2.0% to about by weight about 3.0%, by weight about 2.0% to about by weight about 4.0% Between, between by weight about 2.0% to about by weight about 5.0%, by weight about 2.0% to about by weight about Between 6.0%, between by weight about 2.0% to about by weight about 7.0%, by weight about 2.0% to about press weight Between gauge about 7.5%, between by weight about 2.0% to about by weight about 8.0%, by weight about 2.0% to Between about by weight about 9.0%, between by weight about 2.0% to about by weight about 10.0%, by weight about Between 5.0% to about by weight about 6.0%, between by weight about 5.0% to about by weight about 7.0%, by weight Gauge about 5.0% between about by weight about 7.5%, between by weight about 5.0% to about by weight about 8.0%, To about by weight about between by weight about 5.0% to about by weight about 9.0%, by weight about 5.0% Between 10.0%, between by weight about 5.0% to about by weight about 11.0%, by weight about 5.0% to about pressing Between weight meter about 12.0%, between by weight about 5.0% to about by weight about 13.0%, by weight about Between 5.0% to about by weight about 14.0% or between by weight about 5.0% to about by weight about 15.0%.
The aspect of this specification partly discloses the pH of additive composition for paper making disclosed herein.Additive for paper making group The final pH for closing object is typically acid, because this contributes to the longer storage period of composition.In the side of this embodiment In face, the pH of additive composition for paper making disclosed herein is for example, about 2, about 2.5, about 3, about 3.5, about 4, about 4.5, about 5, about 5.5 or about 6.In in terms of other of this embodiment, the pH of additive composition for paper making disclosed herein is for example, at least 2, At least 2.5, at least 3, at least 3.5, at least 4, at least 4.5, at least 5, at least 5.5 or at least 6.This embodiment again other In aspect, the pH of additive composition for paper making disclosed herein is such as at most 2, at most 2.5, at most 3, at most 3.5, at most 4, At most 4.5, at most 5, at most 5.5 or to how many 6.This embodiment it is other in terms of other in, papermaking disclosed herein adds Add the pH of agent composition for example between about 2 to about 3, between about 2 to about 3.5, between about 2 to about 4, about 2 to about 4.5 Between, between about 2 to about 5, between about 2 to about 5.5, between about 2 to about 6, between about 2.5 to about 3, about 2.5 Between to about 3.5, between about 2.5 to about 4, between about 2.5 to about 4.5, between about 2.5 to about 5, about 2.5 to about Between 5.5, between about 2.5 to about 6, between about 3 to about 3.5, between about 3 to about 4, between about 3 to about 4.2, Between about 3 to about 4.5, between about 3 to about 4.7, between about 3 to about 5, between about 3 to about 5.2, about 3 to about 5.5 Between, between about 3 to about 6, between about 3.5 to about 4, between about 3.5 to about 4.2, between about 3.5 to about 4.5, Between about 3.5 to about 4.7, between about 3.5 to about 5, between about 3.5 to about 5.2, between about 3.5 to about 5.5, about Between 3.5 to about 6, between about 3.7 to about 4.0, between about 3.7 to about 4.2, between about 3.7 to about 4.5, about 3.7 Between to about 5.2, between about 3.7 to about 5.5 or between about 3.7 to about 6.
The aspect of this specification partly discloses enzyme.Additive composition for paper making disclosed herein can also be wrapped optionally Containing enzyme.Useful enzyme includes promoting bleaching, increasing deinking, make fibre structure modification, increasing effluent in paper pulp and paper production Control removes deasphalting (pitch) and goo (adhesive) and the enzyme for making starch conversion, all these to cause to increase production Power reduces environmental nuisance and reduces energy requirement.For example, amylase is for cracking starch molecule to reduce viscosity.Xylan Enzyme (hemicellulase) is for cracking hemicellulose so that bleaching process is more effective and increases brightness.Fatty enzymatic lysis glycerine The key of three esters is to generate aliphatic acid and for controlling pitch in pulp stage.Cellulase and the micro- fibril of xylanase hydrolysis Dimension, causes fiber to be swollen, this makes fiber more flexible and promotes the removal of ink and adhesive.Esterase decomposes in ink particle Ester bond and toner and adhesive in the polymer that uses.The non-limiting examples of useful enzyme in paper pulp and paper production Including cellulase, zytase, lipase, esterase, amylase, pectase, catalyzing enzyme, laccase, peroxidase, paper pulp enzyme (pulpase) DI, paper pulp enzyme RF and paper pulp enzyme BL.
The aspect of this specification partly discloses additive composition for paper making, and the additive composition for paper making is can to give birth to Object degradation.Biodegradable additive composition for paper making disclosed herein be according to method disclosed herein and purposes once Made it easy to degrade, corrode, reabsorb, decompose or be broken to the additive composition for paper making of essence or obvious degree by application. In the aspect of this embodiment, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, at least 99% sheet Additive composition for paper making disclosed in text is raw in for example, about 1 day, about 2 days, about 3 days, about 4 days, about 5 days, about 6 days or about 7 days Object is degraded.In in terms of other of this embodiment, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, At least 99% additive composition for paper making disclosed herein is for example, about 1 day to about 2 days, about 1 day to about 3 days, about 1 day to about 4 days, about 1 day to about 5 days, about 1 day to about 6 days, about 1 day to about 7 days, about 2 days to about 3 days, about 2 days to about 4 days, about 2 days extremely About 5 days, about 2 days to about 6 days, about 2 days to about 7 days, about 3 days to about 4 days, about 3 days to about 5 days, about 3 days to about 6 days, about 3 days To about 7 days, about 4 days to about 5 days, about 4 days to about 6 days, about 4 days to about 7 days, about 5 days to about 6 days, about 5 days to about 7 days or about 6 It is to biodegradable in about 7 days.
In in terms of this embodiment, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, extremely Few 99% additive composition for paper making disclosed herein for example, about 7 days, about 8 days, about 9 days, about 10 days, about 11 days, about 12 It, it is biodegradable in about 13 days or about 14 days.In in terms of other of this embodiment, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, at least 99% additive composition for paper making disclosed herein was at for example, about 7 days to about 8 It, about 7 days to about 9 days, about 7 days to about 10 days, about 7 days to about 11 days, about 7 days to about 12 days, about 7 days to about 13 days, about 7 days To about 14 days, about 8 days to about 9 days, about 8 days to about 10 days, about 8 days to about 11 days, about 8 days to about 12 days, about 8 days to about 13 It, about 8 days to about 14 days, about 9 days to about 10 days, about 9 days to about 11 days, about 9 days to about 12 days, about 9 days to about 13 days, about 9 It is to about 14 days, about 9 days to about 11 days, about 9 days to about 12 days, about 9 days to about 13 days, about 9 days to about 14 days, about 10 days to about 11 days, about 10 days to about 12 days, about 10 days to about 13 days, about 10 days to about 14 days, about 11 days to about 12 days, about 11 days to about 13 It, about 11 days to about 14 days, about 12 days to about 13 days, it is biodegradable in about 12 days to about 14 days or about 13 days to about 14 days.
In in terms of this embodiment, at least 75%, at least 80%, at least 85%, at least 90%, at least 95%, extremely Few 99% additive composition for paper making disclosed herein for example, about 15 days, about 16 days, about 17 days, about 18 days, about 19 days, about It is biodegradable in 20 days or about 21 days.In in terms of other of this embodiment, at least 75%, at least 80%, at least 85%, extremely Few 90%, at least 95%, at least 99% additive composition for paper making disclosed herein for example, about 15 days to about 16 days, about 15 It was to about 17 days, about 15 days to about 18 days, about 15 days to about 19 days, about 15 days to about 20 days, about 15 days to about 21 days, about 16 days To about 17 days, about 16 days to about 18 days, about 16 days to about 19 days, about 16 days to about 20 days, about 16 days to about 21 days, about 17 days extremely About 18 days, about 17 days to about 19 days, about 17 days to about 20 days, about 17 days to about 21 days, about 18 days to about 19 days, about 18 days to about It is biodegradable in 20 days, about 18 days to about 21 days, about 19 days to about 20 days, about 19 days to about 21 days or about 20 days to about 21 days.
The aspect of this specification partly discloses kit, and the kit includes for putting into practice method disclosed herein Or one or more of components (component) that purposes is useful.Kit offer can be used for putting into practice method disclosed herein or The convenient shell (enclosure) of the component of purposes is to promote or enhance commercial distribution.For example, kit can include herein Disclosed additive composition for paper making and other the one or more of reagents that can be used for putting into practice method disclosed herein or purposes, Such as such as one or more diluents and/or one or more of carriers.
Kit typically provides suitable container, such as comprising can be used for putting into practice the one of method disclosed herein or purposes Kind or more the box of component or other closed carriers.In addition, kit disclosed herein will typically comprise individual appearance Device, such as bottle, bottle (vial), flask or other closed carriers comprising one or more of components.For example, for herein The container of disclosed additive composition for paper making and individual container for one or more of reagents are included in kit In.Kit can be portable, such as can be transported and in the remote of such as business or industrial equipment or farmland It is used in area.Other kits can have purposes in residential housing.
Kit disclosed herein may include label or insert.Label or insert include that can be used as individual material Material, packaging material (such as box) are provided or are attached or be fixed to " printed matter " of the container comprising reagent constituents.Mark Label or insert can also comprise：Computer-readable medium, such as disk (such as hard disk, flash memory)；CD such as CD or DVD-ROM/RAM, DVD, MP3, tape；Or electric storage medium such as RAM and ROM；Or these mixing, such as magnetism/optics Storage medium, FLASH media or type of memory card.Label or insert can include determining that one such or more component Information, dosage, dose frequency or timing, about the information of individual component.Label or insert can include determining that manufacture Quotient's information, article No., manufacturer position and date information.Label or insert may include about reagent constituents can by with In condition or situation information.Label or insert may include for using method as disclosed herein or with examination on the way One or more of specifications in agent box component.Specification may include dosage, frequency or duration and for putting into practice The explanation of any method or purposes or processing scheme described herein and about potential hazard or in which by it is inappropriate using try The warning of situation in the case of agent box component.
The aspect of this specification partly discloses the method for detaching fiber from pulp.It is disclosed herein to be starched from paper pulp The method of material separation fiber includes in slurrying and/or during the paper production phase, by a effective amount of additive composition for paper making application To pulp.The application leads to the increased separation of fiber raw material present in the pulp.
The aspect of this specification partly discloses the side that impurity and/or pollutant are removed from paper pulp and/or paper material Method.It is disclosed herein that the method for removing impurity and/or pollutant includes from paper pulp and/or paper material during the paper production phase A effective amount of additive composition for paper making disclosed herein is applied to slurrying and/or paper production phase.The application causes from logical Cross slurrying and/or the production of paper production phase paper pulp and/or paper material in remove impurity and/or pollutant.
The aspect of this specification partly discloses the method that removal ink is removed from paper pulp and/or paper material.It is disclosed herein Slave paper pulp and/or paper material in except the method for removal ink includes answering a effective amount of additive composition for paper making disclosed herein With to slurrying and/or paper production phase.The application causes from the paper pulp and/or paper produced by slurrying and/or paper production phase Removal ink is removed in material.
Additive composition for paper making disclosed herein is disclosed in terms of this specification for detaching fiber from pulp Purposes.The purposes that additive for paper making disclosed herein is used to detach fiber from pulp is included in slurrying and/or paper production During stage, a effective amount of additive composition for paper making is applied to pulp, is deposited from pulp to increase fiber Raw material separation.
Additive composition for paper making disclosed herein is disclosed in terms of this specification for from paper pulp and/or paper material Remove the purposes of impurity and/or pollutant.Disclosed purposes include in slurrying and/or during the paper production phase, will be a effective amount of Additive composition for paper making is applied to pulp, so as to from the paper pulp and/or paper produced by slurrying and/or paper production phase Impurity and/or pollutant are removed in material.
Additive composition for paper making disclosed herein is disclosed in terms of this specification for from paper pulp and/or paper material Except the purposes of removal ink.Disclosed purposes includes in slurrying and/or during the paper production phase, by a effective amount of additive for paper making group It closes object and is applied to pulp, deoil to be removed from the paper pulp and/or paper material produced by slurrying and/or paper production phase Ink.
Impurity and/or pollutant typically comprise resin, wax, fat, fitter acids and its ester and unsaponifiable matters matter, light Sterol (photosterol), salt and other water-soluble substances and fixed hydrocarbon and ink, adhesive, plastics and other add Add agent.Such impurity and/or pollutant are commonly known as extract.Ink is prepared by pigment, pigment carrier and additive It forms, to reduce and the relevant stain of ink, contamination (picking) and other printing issues.
Micro- life of nonionic surface active agent and processed fermentation in additive composition for paper making disclosed herein The combination of object supernatant leads to the polysaccharide component present in the raw material for being used to prepare paper pulp and paper material and based on lipid The especially chemical bond of molecular structure present in component, the especially in-situ chemical of the acceleration of chemical bond and the component based on lipid Reaction.In-situ chemical reaction dissolving disperses or otherwise destroys one or more of components in raw material.
It does not wish to be bound by any theory restrictions, using after additive composition for paper making in aqueous environment, spontaneously forms Highly reactive, unique texture, ultra-fine microbubble.These " functionalized " microbubbles include external " highly reactive " Shell and inner core, the shell include one or more of nonionic surface active agent and the microorganism from processed fermentation The component of supernatant, the inner core include air." highly reactive " shell makes it possible to realize the oxygen in aqueous environment The violent living things catalysis increased with the acceleration of the molecular structure of compound of mass transfer, provides synergistic function to a combination thereof.It closes In the mass transfer of oxygen, this functional level for increasing the delivery rate of oxygen and improve the dissolved oxygen in aqueous environment, the water Pingyuan County is more than the solubility limit expected from Henry's law and is in the level that cannot be realized simply by mechanical ventilation system. It is good to seem that the component interference nonionic surface active agent of the microorganism supernatant from processed fermentation generates assembling The ability of micella shell.The result is that the loose packing of molecules of these fermentation components and surfactant, makes shell " functionalization " with more It is ventilative, create more favorable condition to be transmitted for bulk gas.Therefore, this oxygen transfer function increases the oxygen in aqueous environment Availability.About the living things catalysis of acceleration, this functionality reacts platform to reduce needed for catalysis reaction generation by offer Energy transformation, it is described reaction platform increase reactant local concentration, enabling contribute electronics and promote electronics not The chemical reaction in good site.Therefore, this biocatalytic Activity mediates the fracture of chemical bond present in compound, the chemical bond Including glycosidic bond and ester bond.Therefore, " functionalized " shell of microbubble has catalytic activity similar with conventional enzyme system, but not Need any enzyme.Therefore, " functionalized " microbubble, " function are generated using additive composition for paper making disclosed herein Change：Microbubble increase causes the oxygen of higher dissolved oxygen levels to dissipate and accelerates the molecule phase for the catalytic decomposition for leading to compound Interaction.
When be used to prepare paper pulp starting material when, " functionalized " shell with can contribute electronics or in electronics it is bad It interacts to lignin in the mode and material reacted at site and component chemical based on lipid, the mode mediates wood The fracture of chemical bond present in quality and other extracts, the chemical bond includes glycosidic bond and ester bond.Similarly, when with it is miscellaneous When matter or pollutant include ink contact, side of " functionalized " shell can contribute electronics or be reacted at the bad site of electronics Formula interacts with impurity and pollutant chemistry, and the mode mediates the fracture of chemical bond present in impurity and pollutant, The chemical bond includes glycosidic bond and ester bond.These interaction seemingly use beta oxidation hydrolysed form, wherein in addition to according to Except the component of Lai Yu " functionalized " shell, oxygen present in the core of microbubble is also utilized.Therefore, exist in " functionalized " shell Property and the oxygen transmission capacity of core synergistically work and changed present in lignin, extract, impurity and pollutant with enhancing It learns the in situ of key to destroy, the chemical bond includes glycosidic bond and ester bond.
The application of additive composition for paper making disclosed herein can be by any method by raw material, impurity and/or Pollutant is exposed to disclosed additive composition for paper making, mode be to provide raw material, impurity and/or pollutant one kind or The suitable key of more kinds of components destroys.For example, exposure can be by during pulp stage by additive composition for paper making It is applied to the paper pulp being contained in holding tank, the dispensing being stored in holding tank is applied to or is applied to during shaping stage and matched Material.
The undiluted form of additive composition for paper making disclosed herein can be in method disclosed herein and on the way It uses.Selectively, additive composition for paper making disclosed herein can be desirably diluted, and those skilled in the art know Road can use the dilution (dilution) of such composition.The dilution of additive composition for paper making disclosed herein is typical Ground can be carried out using water, although other suitable diluents can also be used, as long as them and micro- gas as disclosed herein The formation of bubble is compatible.In in terms of this embodiment, additive composition for paper making is diluted into ratio below：Such as 1:10、1:25、1:50、1:75、1:100、1:200、1:300、1:400、1:500、1:600、1:700、1:800、1:900、1: 1000、1:2000、1:3000、1:4000、1:5000、1:6000、1:7000、1:8000、1:9000、1:10000、1:20000、 1:30000、1:4000、1:50000、1:60000、1:70000、1:80000、1:90000 or 1:100000.In this embodiment Other aspect in, additive composition for paper making is diluted into ratio below：For example, at least 1:10, at least 1:25, at least 1: 50, at least 1:75, at least 1:100, at least 1:200, at least 1:300, at least 1:400, at least 1:500, at least 1:600, at least 1:700, at least 1:800, at least 1:900, at least 1:1000, at least 1:2000, at least 1:3000, at least 1:4000, at least 1: 5000, at least 1:6000, at least 1:7000, at least 1:8000, at least 1:9000, at least 1:10000, at least 1:20000, at least 1:30000, at least 1:4000, at least 1:50000, at least 1:60000, at least 1:70000, at least 1:80000, at least 1: 90000 or at least 1:100000.This embodiment again in terms of other in, additive composition for paper making is diluted into below Ratio：Such as at most 1:10, at most 1:25, at most 1:50, at most 1:75, at most 1:100, at most 1:200, at most 1:300, extremely More 1:400, at most 1:500, at most 1:600, at most 1:700, at most 1:800, at most 1:900, at most 1:1000, at most 1: 2000, at most 1:3000, at most 1:4000, at most 1:5000, at most 1:6000, at most 1:7000, at most 1:8000, at most 1: 9000, at most 1:10000, at most 1:20000, at most 1:30000, at most 1:4000, at most 1:50000, at most 1:60000、 At most 1:70000, at most 1:80000, at most 1:90000 or at most 1:100000.
In the other in terms of other of this embodiment, additive composition for paper making is diluted into ratio below：For example, about 1:1 to about 1:10, about 1:1 to about 1:25, about 1:1 to about 1:50, about 1:1 to about 1:75, about 1:1 to about 1:100, about 1:2 to About 1:10, about 1:2 to about 1:25, about 1:2 to about 1:50, about 1:2 to about 1:75, about 1:2 to about 1:100, about 1:10 to about 1: 25, about 1:10 to about 1:50, about 1:10 to about 1:75, about 1:10 to about 1:100, about 1:10 to about 1:125, about 1:10 to about 1: 150, about 1:10 to about 1:175, about 1:10 to about 1:200, about 1:10 to about 1:225, about 1:10 to about 1:250, about 1:50 to About 1:100, about 1:50 to about 1:200, about 1:50 to about 1:300, about 1:50 to about 1:400, about 1:50 to about 1:500, about 1: 50 to about 1:600, about 1:50 to about 1:700, about 1:50 to about 1:800, about 1:50 to about 1:900, about 1:50 to about 1:1000、 About 1:100 to about 1:200, about 1:100 to about 1:300, about 1:100 to about 1:400, about 1:100 to about 1:500, about 1:100 to About 1:600, about 1:100 to about 1:700, about 1:100 to about 1:800, about 1:100 to about 1:900, about 1:100 to about 1:1000、 About 1:500 to about 1:1000, about 1:500 to about 1:2000, about 1:500 to about 1:3000, about 1:500 to about 1:4000, about 1: 500 to about 1:5000, about 1:500 to about 1:6000, about 1:500 to about 1:7000, about 1:500 to about 1:8000, about 1:500 to About 1:9000, about 1:500 to about 1:10000, about 1:1000 to about 1:2000, about 1:1000 to about 1:3000, about 1:1000 to About 1:4000, about 1:1000 to about 1:5000, about 1:1000 to about 1:6000, about 1:1000 to about 1:7000, about 1:1000 to About 1:8000, about 1:1000 to about 1:9000, about 1:1000 to about 1:10000, about 1:5000 to about 1:10000, about 1:5000 To about 1:20000, about 1:5000 to about 1:30000, about 1:5000 to about 1:40000, about 1:5000 to about 1:50000, about 1: 5000 to about 1:60000, about 1:5000 to about 1:70000, about 1:5000 to about 1:80000, about 1:5000 to about 1:90000、 About 1:5000 to about 1:100000, about 1:10000 to about 1:20000, about 1:10000 to about 1:30000, about 1:10000 to about 1:40000, about 1:10000 to about 1:50000, about 1:10000 to about 1:60000, about 1:10000 to about 1:70000, about 1: 10000 to about 1:80000, about 1:10000 to about 1:90000, about 1:10000 to about 1:100000.
The application of additive composition for paper making disclosed herein is with effective quantity.Disclosed additive composition for paper making has Effect amount can be the amount for being enough to realize high fiber fineness and quality.In in terms of this embodiment, effective quantity causes fiber Cellulose fiber separation increase, fiber increase, ink, adhesive and/or the other impurities of surface area or the removing of pollutant or Any combination thereof.Preferentially, such effective quantity will not damage fibre integrity and intensity.Disclosed additive composition for paper making Actually active amount pass through the conventional screening of control activity and efficiency for assessing additive composition for paper making disclosed herein Program determines.Such screening sequence is well known to those skilled in the art., it is expected that this paper with higher activity level Disclosed additive composition for paper making can be used with smaller amount and concentration, and the papermaking with lower activity level adds Add agent composition that may need larger quantities or concentration to realize identical control effect.
The effective quantity of additive composition for paper making disclosed herein can by the purity of the paper pulp of production and paper product and Quality is estimated.Paper pulp and paper industrial technology association (Technical Association of Pulp and Paper Industry) (TAPPI) and International Organization for standardization (International Organization for Standardization) (ISO) has determined that the standard method of the paper pulp purity and quality of assessment processing, see, for example, Alpha fibre, β-cellulose and gamma cellulose in TAPPI standard T 203cm-99 paper pulp；TAPPI standard T 235cm-85R10 With the alkali solubility of R18；Copper number in TAPPI standard T 430cm-09 paper pulp, paper and cardboard；TAPPI standard T 236cm-99 Kappa number in paper pulp；The viscosity of TAPPI standard T 230om-99 paper pulp；TAPPI standard T 452om-08 paper pulp, paper and cardboard Brightness；TAPPI standard T 235cm-85 carboxyl-contents；The solvent extractable matter of TAPPI standard T204cm-97 timber and paper pulp； And the ash content in TAPPI standard T 211om-93 wood pulps, paper and cardboard：It burns at 525 DEG C.
High fiber fineness and quality is pulp yield on one side.In general, the cellulosic material from raw material Yield is higher, and fiber fineness and quality are better.The half of typical cellulose of the timber comprising about 40%-50% and 25%-35% Cellulose.Extraction is more than that 70% cellulosic material is typically considered high pulp yield.
In embodiments, the effective quantity of disclosed additive composition for paper making is to be enough to generate high pulp yield Amount.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough to generate paper pulp below to receive The amount of rate：For example, about 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%.In this embodiment In other aspects, the effective quantity of disclosed additive composition for paper making is the amount for being enough to generate pulp yield below：Such as extremely Few 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% Or at least 99%.This embodiment again in terms of other in, the effective quantity of disclosed additive composition for paper making is to be enough to produce The amount of raw pulp yield below：Such as at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, at most 89%, at most 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, At most 96%, at most 97%, at most 98% or at most 99%.This embodiment again in terms of other in, side disclosed herein Method or purposes lead to pulp yield below：For example, about 70% to about 80%, about 70% to about 85%, about 70% to about 90%, About 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to about 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
In another embodiment, method disclosed herein or purposes lead to high pulp yield.In this embodiment Aspect in, method disclosed herein or purposes lead to pulp yield below：For example, about 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%.In in terms of other of this embodiment, method disclosed herein or purposes cause Pulp yield below, for example, at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, At least 97%, at least 98% or at least 99%.This embodiment again in terms of other in, method disclosed herein or purposes are led Cause pulp yield below：Such as at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, extremely More 88%, at most 89%, at most 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, at most 97%, at most 98% or at most 99%.This embodiment again in terms of other in, method disclosed herein or Purposes leads to pulp yield below：For example, about 70% to about 80%, about 70% to about 85%, about 70% to about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to about 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
High fiber fineness and quality is the α-present in the paper pulp or paper product of the processing of generation on the other hand The amount of content of cellulose, β-cellulose content and gamma cellulose content.In general, alpha-cellulose is complete, higher in paper pulp The indicant (indicator) of molecular weight cellulose cellulose content, β-cellulose are the indicant of the cellulose of degradation, and γ-fibre Dimension element is the indicant of hemicellulose.There are the measuring methods of cellulosic material content in several paper pulp for measuring processing.
In content of cellulose measurement, alpha-cellulose fraction (fraction), β-are detached using alkalization caustic solution Cellulose fraction and gamma cellulose fraction, alpha-cellulose is kept insoluble in the caustic solution that alkalizes, after acid adds, β- Cellulose is precipitated out from solution, and gamma cellulose retains in the solution.For example, alpha-cellulose is resistance under conditions of test By the paper pulp fraction of 17.5% and 9.45% sodium hydroxide solution.β-cellulose is soluble fraction, the quilt when solution is acidified Reprecipitation；Gamma cellulose is kept in the fraction in solution.Soluble fraction including β-cellulose and gamma cellulose passes through It is determined in volume with potassium dichromate oxidation, and is pushed away by using the difference of following formula as the alpha-cellulose of insoluble fraction It leads：AC%=100-[6.85 (V2–V1) × N × 20]/A × W, wherein AC% is alpha-cellulose percentage, V1In terms of milliliter The titer of filtrate of paper stuff, V2It is the titer of the blank in terms of milliliter, N is that the equivalent of accurate l ferrous ammonium sulfate solution is dense Degree, A are the volumes of the filtrate of paper stuff in terms of milliliter used in oxidation, and W be paper pulp sample in gram baking oven it is dry Dry weight.GC%=[6.85 × N × 20 (V4-V3)]/(25 × W), wherein GC% is gamma cellulose percentage, V3It is with milli Rise the titer of the solution after the precipitation of the β-cellulose of meter, V4It is the titer of the blank in terms of milliliter, N is accurate sulphur The equivalent concentration of sour ferrous iron ammonium salt solution, and W is the oven-dry weight of paper pulp sample in gram.BC%=100-(AC%+ GC%), wherein BC% is β-cellulose percentage, and wherein AC% is alpha-cellulose percentage and wherein GC% is gamma fibers Plain percentage.Standardized content of cellulose measures alpha-cellulose, β-fibre in such as TAPPI standards T 203cm-99 paper pulp It is described in dimension element and gamma cellulose, the content of the measurement is integrally incorporated accordingly by reference with it.
In alkali resistance measurement, retains cellulosic material using at least two different weight percentage aqueous slkalis and provide about processing Paper pulp in high molecular weight carbohydrate (complete cellulose or alpha-cellulose) information.Alkali is typically sodium hydroxide And most common concentration is 18%, 10% and 5% (m/m).For example, 10% sodium hydroxide solution dissolving degradation cellulose and Both hemicelluloses, this provides instruction (reservation in 10% alkali or the R of the total amount about insoluble fibre cellulosic material10Value). Therefore, R10Value includes the amount of alpha-cellulose (complete cellulose).However, only hemicellulose is in 18% sodium hydroxide solution Soluble, this provides the valuation of the amount about the alpha-cellulose and both β-celluloses that are retained in insoluble fraction (18% Reservation in alkali or R18Value).In order to carry out alkali solubility measurement, paper pulp, it is known that the paper pulp of the processing of the oven drying of quality, 20 DEG C are handled with sodium hydroxide solution and continue 60 minutes, the washing and insoluble fibre cellulosic material is dry and claim in acetic acid Weight.Alkali resistance RcIt is represented as the percentage by mass using following formula：m1×100/m0, wherein RcIt is alkali resistance, m0Be with The quality in gram of the part of detecting calculated based on oven drying, and m1It is the baking of alkali-insoluble fraction in gram Case dry mass.When carrying out alkali resistance measurement using 10% aqueous slkali, RcIt is referred to as R10, resistance to when being carried out using 18% aqueous slkali When alkalinity measures, RcIt is referred to as R18.Standardized alkali solubility is measured in such as iso standard 699:2015 paper pulp-alkali resistance It is described in determination, the content of the measurement is integrally incorporated accordingly by reference with it.
In alkali solubility measurement, provided in the solubility of the cellulosic material of two kinds of different weight percentage aqueous slkalis about adding The information of low molecular weight carbohydrate (cellulose or β-cellulose of degradation) and hemicellulose in the paper pulp of work.Alkali is typical Ground is sodium hydroxide and most common concentration is 18% and 10% (m/m).For example, the dissolving degradation of 10% sodium hydroxide solution Both cellulose and hemicellulose, this provide about the Soluble Fiber cellulosic material in alkaline solution total amount instruction ( Solubility in 10% alkali or S10Value).Therefore, S10Value includes the sum of hemicellulose and β-cellulose (cellulose of degradation).So And hemicellulose is soluble in 18% sodium hydroxide solution, this is provided about the remaining hemicellulose present in paper pulp Amount valuation (solubility in 18% alkali or S18Value).Therefore, β-cellulose (cellulose of degradation) can be by from S18 Value subtracts S10Value determines (S18Subtract S10).Pass through the total amount for determining cellulosic material simultaneously furthermore, it is possible to be measured based on alkali solubility Subtract S10Value calculates alpha-cellulose content.In order to carry out alkali solubility measurement, paper pulp sodium hydroxide solution is handled and is used The organic substance of potassium dichromate oxidation dissolving.Iron ammonium sulfate (II) is used for the potassium bichromate of overtitration, and consume The amount of potassium bichromate be used to calculate cellulose equivalent.Using following formula, the soluble fraction of cellulose is represented as doing by baking oven The percentage of the quality meter of dry paper pulp：Sc=6.85 (V2–V1) × c × 100/m × V, wherein ScIt is alkali solubility, V is with milliliter The volume for the filtrate of meter used in oxidation, V1It is the iron ammonium sulfate consumed in the titration of test solution in terms of milliliter (II) volume of solution, V2The volume of iron ammonium sulfate (II) solution consumed in skip test in terms of milliliter, c be with The concentration of iron ammonium sulfate (II) solution of mol/L meter, m are the part of detecting calculated based on oven drying in gram Quality；And 6.85 be the experience factor in terms of milligram, and instruction is equivalent to the amount of the cellulose of the potassium bichromate of 1/6mol. When carrying out alkali solubility measurement using 10% aqueous slkali, ScIt is referred to as S10, alkali solubility survey is carried out when using 18% aqueous slkali Periodically, ScIt is referred to as S18.Standardized alkali solubility is measured is described in 25 DEG C of paper in such as TAPPI standards T 235cm-09 In the determination of alkali solubility and iso standard 692 paper pulp-alkali solubility of slurry, the content of each in the measurement accordingly by Reference is integrally incorporated with it.
In pulp viscosity measurement, the viscosity of the paper pulp of processing is determined.The viscosity of paper pulp is average fiber element polymerization journey The indicant of degree.Higher pulp viscosity is the indicant of longer cellulosic chain-length and less degradation.Therefore, pulp viscosity More higher, more complete, higher molecular weight cellulose (alpha-cellulose) is present in the paper pulp of processing, and on the contrary, less degradation Cellulose (β-cellulose) is present in paper pulp.Standardized pulp viscosity is measured in such as TAPPI standards T 203om-99 paper It is described in the viscosity of slurry, the content of the measurement is integrally incorporated accordingly by reference with it.
In embodiments, the effective quantity of disclosed additive composition for paper making is the height for being enough to cause in the paper pulp of processing The amount of alpha-cellulose content.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough to lead Cause the amount of the alpha-cellulose content in the paper pulp of processing below：For example, about 70%, about 75%, about 60%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough Lead to the amount of the alpha-cellulose content in the paper pulp of processing below：For example, at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91%, at least 92%, at least 93%, At least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%.In its other party again of this embodiment In face, the effective quantity of disclosed additive composition for paper making is the alpha-cellulose content for being enough to cause in the paper pulp of processing below Amount：Such as at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, at most 89%, at most 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, at most 97%, At most 98% or at most 99%.This embodiment again in terms of other in, additive composition for paper making disclosed herein has Effect amount is to be enough to cause the amount of the alpha-cellulose content in the paper pulp of processing below：For example, about 70% to about 80%, about 70% To about 85%, about 70% to about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to About 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
In embodiments, the effective quantity of disclosed additive composition for paper making is low in the paper pulp for being enough to lead to processing The amount of β-cellulose content.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough to lead Cause the amount of the β-cellulose content in the paper pulp of processing below：For example, about 5%, about 10%, about 15%, about 20%, about 25%, About 30% or about 35%.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough to cause The amount of β-cellulose content in the paper pulp of processing below：Such as at most 5%, at most 10%, at most 15%, at most 20%, At most 25%, at most 30% or at most 35%.In in terms of this embodiment, disclosed additive composition for paper making it is effective Amount is to be enough to cause the amount of the β-cellulose content in the paper pulp of processing below：For example, about 5% to about 10%, about 5% to about 15%, about 5% to about 20%, about 5% to about 25%, about 5% to about 30%, about 5% to about 35%, about 10% to about 15%, About 10% to about 20%, about 10% to about 25%, about 10% to about 30%, about 10% to about 35%, about 15% to about 20%, about 15% to about 25%, about 15% to about 30%, about 15% to about 35%, about 20% to about 25%, about 20% to about 30%, about 20% to about 35%, about 25% to about 30%, about 25% to about 35% or about 30% to about 35%.
In embodiments, the effective quantity of disclosed additive composition for paper making is low in the paper pulp for being enough to lead to processing The amount of gamma cellulose content.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough to lead Cause the amount of the gamma cellulose content in the paper pulp of processing below：For example, about 5%, about 10%, about 15%, about 20%, about 25%, about 30% or about 35%.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough Lead to the amount of the gamma cellulose content in the paper pulp of processing below：Such as at most 5%, at most 10%, at most 15%, at most 20%, at most 25%, at most 30% or at most 35%.In in terms of this embodiment, disclosed additive composition for paper making Effective quantity be the amount for being enough to cause the gamma cellulose content in the paper pulp of processing below：For example, about 5% to about 10%, about 5% to about 15%, about 5% to about 20%, about 5% to about 25%, about 5% to about 30%, about 5% to about 35%, about 10% to About 15%, about 10% to about 20%, about 10% to about 25%, about 10% to about 30%, about 10% to about 35%, about 15% to about 20%, about 15% to about 25%, about 15% to about 30%, about 15% to about 35%, about 20% to about 25%, about 20% to about 30%, about 20% to about 35%, about 25% to about 30%, about 25% to about 35% or about 30% to about 35%.
In embodiments, the effective quantity of disclosed additive composition for paper making is to be enough to cause the height of the paper pulp of processing viscous The amount of degree.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making be enough to cause it is below plus The amount of the viscosity of the paper pulp of work：For example, about 5mPas, about 10mPas, about 15mPas, about 20mPas, about 25mPas, About 30mPas, about 35mPas, about 40mPas, about 45mPas or about 50mPas.In in terms of this embodiment, The effective quantity of disclosed additive composition for paper making is the amount for being enough to cause the viscosity of the paper pulp of processing below：For example, at least 5mPas, at least 10mPas, at least 15mPas, at least 20mPas, at least 25mPas, at least 30mPas, at least 35mPas, at least 40mPas, at least 45mPas or at least 50mPas.It is public in the another aspect of this embodiment The effective quantity for the additive composition for paper making opened is the amount for being enough to cause the viscosity of the paper pulp of processing below：Such as at most 5mPas, at most 10mPas, at most 15mPas, at most 20mPas, at most 25mPas, at most 30mPas, at most 35mPas, at most 40mPas, at most 45mPas or at most 50mPas.It is public in the another aspect of this embodiment The effective quantity for the additive composition for paper making opened is the amount for being enough to cause the viscosity of the paper pulp of processing below：For example, about 5mPa S to about 10mPas, about 5mPas are to about 15mPas, about 5mPas to about 20mPas, about 5mPas to about 25mPas, about 5mPas to about 30mPas, about 5mPas to about 35mPas, about 5mPas to about 40mPas, about 5mPas to about 45mPas, about 5mPas to about 50mPas, about 10mPas to about 15mPas, about 10mPas extremely About 20mPas, about 10mPas are to about 25mPas, about 10mPas to about 30mPas, about 10mPas to about 35mPas, about 10mPas are to about 40mPas, about 10mPas to about 45mPas, about 10mPas to about 50mPa S, about 15mPas to about 20mPas, about 15mPas to about 25mPas, about 15mPas to about 30mPas, about 15mPas to about 35mPas, about 15mPas are to about 40mPas, about 15mPas to about 45mPas, about 15mPas To about 50mPas, about 20mPas to about 25mPas, about 20mPas to about 30mPas, about 20mPas to about 35mPas, about 20mPas are to about 40mPas, about 20mPas to about 45mPas, about 20mPas to about 50mPa S, about 25mPas to about 30mPas, about 25mPas to about 35mPas, about 25mPas to about 40mPas, about 25mPas to about 45mPas, about 25mPas are to about 50mPas, about 30mPas to about 35mPas, about 30mPas To about 40mPas, about 30mPas to about 45mPas, about 30mPas to about 50mPas, about 35mPas to about 40mPas, about 35mPas are to about 45mPas, about 35mPas to about 50mPas, about 40mPas to about 45mPa S, about 40mPas to about 50mPas or about 45mPas to about 50mPas.
In embodiments, method disclosed herein or purposes lead to the paper of the processing for the alpha-cellulose content for having high Slurry.In in terms of this embodiment, method disclosed herein or purposes lead to the processing with alpha-cellulose content below Paper pulp：For example, about 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%.In this embodiment In aspect, method disclosed herein or purposes lead to the paper pulp with the processing of alpha-cellulose content below：For example, at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, At least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%.This embodiment again in terms of other in, method disclosed herein or purposes lead to that there is alpha-cellulose below to contain The paper pulp of the processing of amount：Such as at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, at most 89%, at most 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, At most 97%, at most 98% or at most 99%.This embodiment again in terms of other in, method disclosed herein or purposes are led Cause the paper pulp of the processing with alpha-cellulose content below：For example, about 70% to about 80%, about 70% to about 85%, about 70% To about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to about 90%, about 75% to About 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
In embodiments, method disclosed herein or purposes lead to the paper of the processing for the β-cellulose content for having low Slurry.In in terms of this embodiment, method disclosed herein or purposes lead to the processing with β-cellulose content below Paper pulp：For example, about 5%, about 10%, about 15%, about 20%, about 25%, about 30% or about 35%.In the side of this embodiment In face, method disclosed herein or purposes lead to the paper pulp with the processing of β-cellulose content below：Such as at most 5%, At most 10%, at most 15%, at most 20%, at most 25%, at most 30% or at most 35%.In in terms of this embodiment, Method disclosed herein or purposes lead to the paper pulp with the processing of β-cellulose content below：For example, about 5% to about 10%, About 5% to about 15%, about 5% to about 20%, about 5% to about 25%, about 5% to about 30%, about 5% to about 35%, about 10% To about 15%, about 10% to about 20%, about 10% to about 25%, about 10% to about 30%, about 10% to about 35%, about 15% to About 20%, about 15% to about 25%, about 15% to about 30%, about 15% to about 35%, about 20% to about 25%, about 20% to about 30%, about 20% to about 35%, about 25% to about 30%, about 25% to about 35% or about 30% to about 35%.
In embodiments, method disclosed herein or purposes lead to the paper of the processing for the gamma cellulose content for having low Slurry.In in terms of this embodiment, method disclosed herein or purposes lead to the processing with gamma cellulose content below Paper pulp：For example, about 5%, about 10%, about 15%, about 20%, about 25%, about 30% or about 35%.In the side of this embodiment In face, method disclosed herein or purposes lead to the paper pulp with the processing of gamma cellulose content below：Such as at most 5%, At most 10%, at most 15%, at most 20%, at most 25%, at most 30% or at most 35%.In in terms of this embodiment, Method disclosed herein or purposes lead to the paper pulp with the processing of gamma cellulose content below：For example, about 5% to about 10%, about 5% to about 15%, about 5% to about 20%, about 5% to about 25%, about 5% to about 30%, about 5% to about 35%, about 10% to about 15%, about 10% to about 20%, about 10% to about 25%, about 10% to about 30%, about 10% to about 35%, about 15% to about 20%, about 15% to about 25%, about 15% to about 30%, about 15% to about 35%, about 20% to about 25%, about 20% to about 30%, about 20% to about 35%, about 25% to about 30%, about 25% to about 35% or about 30% to about 35%.
In embodiments, method disclosed herein or purposes lead to the paper pulp with highly viscous processing.Implement herein In the aspect of scheme, method disclosed herein or purposes lead to the paper pulp with the processing of viscosity below：For example, about 5mPa S, about 10mPas, about 15mPas, about 20mPas, about 25mPas, about 30mPas, about 35mPas, about 40mPa S, about 45mPas or about 50mPas.In in terms of this embodiment, method disclosed herein or purposes cause to have with Under viscosity processing paper pulp：For example, at least 5mPas, at least 10mPas, at least 15mPas, at least 20mPas, At least 25mPas, at least 30mPas, at least 35mPas, at least 40mPas, at least 45mPas or at least 50mPa s.In the another aspect of this embodiment, method disclosed herein or purposes lead to the paper with the processing of viscosity below Slurry：Such as at most 5mPas, at most 10mPas, at most 15mPas, at most 20mPas, at most 25mPas, at most 30mPas, at most 35mPas, at most 40mPas, at most 45mPas or at most 50mPas.In this embodiment In another aspect, method disclosed herein or purposes lead to the paper pulp with the processing of viscosity below：For example, about 5mPas is extremely About 10mPas, about 5mPas to about 15mPas, about 5mPas to about 20mPas, about 5mPas to about 25mPas, About 5mPas to about 30mPas, about 5mPas to about 35mPas, about 5mPas to about 40mPas, about 5mPas extremely About 45mPas, about 5mPas are to about 50mPas, about 10mPas to about 15mPas, about 10mPas to about 20mPa S, about 10mPas to about 25mPas, about 10mPas to about 30mPas, about 10mPas to about 35mPas, about 10mPas to about 40mPas, about 10mPas are to about 45mPas, about 10mPas to about 50mPas, about 15mPas To about 20mPas, about 15mPas to about 25mPas, about 15mPas to about 30mPas, about 15mPas to about 35mPas, about 15mPas are to about 40mPas, about 15mPas to about 45mPas, about 15mPas to about 50mPa S, about 20mPas to about 25mPas, about 20mPas to about 30mPas, about 20mPas to about 35mPas, about 20mPas to about 40mPas, about 20mPas are to about 45mPas, about 20mPas to about 50mPas, about 25mPas To about 30mPas, about 25mPas to about 35mPas, about 25mPas to about 40mPas, about 25mPas to about 45mPas, about 25mPas are to about 50mPas, about 30mPas to about 35mPas, about 30mPas to about 40mPa S, about 30mPas to about 45mPas, about 30mPas to about 50mPas, about 35mPas to about 40mPas, about 35mPas to about 45mPas, about 35mPas are to about 50mPas, about 40mPas to about 45mPas, about 40mPas To about 50mPas or about 45mPas to about 50mPas.
High fiber fineness and quality is wooden present in the paper pulp or paper product of the processing of generation on the other hand The amount of quality, extract and other impurities.In general, the amount of the lignin, extract and other impurities in paper pulp is lower, processing The purity and integrality (integrity) of cellulosic material in paper pulp are higher.Typical timber includes the wood of about 15%-30% The extract of quality and 2%-10%.There are the measuring methods of the content of lignin in several paper pulp for measuring processing.
In Kappa number measurement, Kappa number is the hardness of paper pulp of processing, bleachability (bleachability) and takes off wooden The indicant of element.Kappa number was defined as under the time of restriction and temperature condition, moisture free paper in 1 gram of acid medium 0.1N potassium permanganate (the KMnO in terms of milliliter that slurry (moisture-free pulp) is consumed4) volume.Kappa number has 1 To 100 range and be assessment in paper pulp there are how many lignin, if which determine the paper that target is white processing Product is required the amount for the bleaching agent for being added to paper pulp.High Kappa number needs more bleaching agents, and lower value have compared with Few lignin and need less bleaching agent.In order to carry out Kappa number measurement, allow the paper pulp and phase of the processing of known quantity The time that 4N sulfuric acid and 0.1N the liquor potassic permanganates reaction of same amount persistently give.Select the amount of paper pulp so that in the reaction time At the end of, about the 50% of total oxidation capacity of permanganate is left and does not consume.Liquor kalii iodide is added into test solution And then sodium thiosulfate is used for the amount of the iodine of overtitration and the potassium permanganate of consumption and be used to calculate lignin and work as Amount.Kappa number K is determined using following formula：K=p × f/w and p=(b-a) N/0.1, wherein K is Kappa number, and f is for correcting extremely The factor of 50% permanganate consumption, depends on the value of p, w is the weight of moisture free paper pulp in sample in gram, p It is the amount of the 0.1N permanganates in terms of milliliter of actually tested sample consumption, b is consumed in blank determination with milli The amount of the thiosulfate of meter is risen, a is the amount of the thiosulfate in terms of milliliter of tested sample consumption, and N is thio The equivalent concentration of sulfate.For the Kappa number of paper pulp for that can bleach in the range of 25-30, pocket paper paper pulp is 45-55's In range, and the paper pulp of corrugated board is used in the range of 60-90.Kappa number can also monitor the wood of the paper pulp from processing The effect of quality extraction, because the value and the residual lignin content of paper pulp are generally proportionate.Following formula can be used：K=cI, Middle K is Kappa number, and c is with the constant of about 6.57 value, and depending on the technique and raw material used, and I is with percentage The content of lignin of meter.Standardized Kappa number measurement be described in such as Kappa number of TAPPI standards T 236cm-99 paper pulp, Iso standard 302:The determination of 2015 Kappa numbers and Chai and Zhu, Rapid Pulp Kappa Number Determination Using Spectrophotometry,J.Pulp Paper Sci.25(11):387-394(1999) In, content in each of these measuring methods is integrally incorporated accordingly by reference with it.
In copper number measurement, copper number is cellulosic material and impurity with reducing property present in the paper pulp of processing Reduction group indicant.Certain metal ions can be reduced into lower valence state by hydrolysis or oxidation cellulose, and And the reaction of this type has been used to detect the damage to cellulose and the amount for assessing reduction group.Therefore, copper number can Be considered as in cellulose have those of reducing property impurity such as oxycellulose, hydrocellulose, lignin with And the index of sugar.Therefore, it is valuable that this, which is measured for the variation for detecting adjoint deterioration, and is therefore considered use In the test of the durability of instruction paper.Copper number is defined as restoring CuSO by the paper pulp fiber of 100.00g4Generated metallic copper (with Cu2O grams).In order to carry out copper number measurement, in the case where shaking once in a while, by paper pulp, it is known that the processing of the oven drying of quality Paper pulp, use CuSO4Solution and the carbonate-bicarbonate solution treatment heated at 100 DEG C continue 3 hours, and then exist 5%Na2CO3And it then washs in hot water.Then, processed cellulosic material is incubated with phosphomolybdic acid, is macerated, is washed with water Until the blue of fiber is removed, and filtrate is diluted into suitable volume and then uses 0.05N KMnO4It is titrated to weak Pink colour terminal.Copper number C is calculated using following formula：C=6.357 × (V-B) × N/W, wherein C is copper number, and V is that titration comes from sample Filtrate the KMnO in terms of milliliter4The volume of solution, B are the KMnO in terms of milliliter for titrating blank filtrate4The volume of solution, N It is 0.05N KMnO4Equivalent concentration, W is the weight of the paper pulp of oven drying in gram.Standardized alkali solubility measures It is described in such as copper number of TAPPI standards T 430cm-09 paper pulp, paper and cardboard, the content of the measurement is accordingly by reference It is integrally incorporated with it.
In embodiments, the effective quantity of disclosed additive composition for paper making is to be enough to cause to have low lignin to contain The amount of the paper pulp of the processing of amount.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough Cause the amount of the paper pulp of the processing for the content of lignin for having low, the paper pulp of the processing that there is Kappa number below：For example, about 5, about 10, about 15, about 20, about 25, about 30, about 35, about 40, about or about 50.In in terms of this embodiment, disclosed papermaking The effective quantity of compositions of additives is the amount for being enough to cause to have the paper pulp of the processing of low content of lignin, the paper of the processing Slurry has Kappa number below：For example, at least 5, at least 10, at least 15, at least 20, at least 25, at least 30, at least 35, at least 40, at least 45 or at least 50.In the another aspect of this embodiment, the effective quantity of disclosed additive composition for paper making is foot To cause the amount of the paper pulp of the processing for the content of lignin for having low, the paper pulp of the processing that there is Kappa number below：Such as At most 5, at most 10, at most 15, at most 20, at most 25, at most 30, at most 35, at most 40, at most 45 or at most 50.It is real herein In the another aspect for applying scheme, the effective quantity of disclosed additive composition for paper making is to be enough to lead to have low content of lignin Processing paper pulp amount, the paper pulp of the processing has Kappa number below：For example, about 5 to about 10, about 5 to about 15, about 5 to About 20, about 5 to about 25, about 5 to about 30, about 5 to about 35, about 5 to about 40, about 5 to about 45, about 5 to about 50, about 10 to about 15, About 10 to about 20, about 10 to about 25, about 10 to about 30, about 10 to about 35, about 10 to about 40, about 10 to about 45, about 10 to about 50, About 15 to about 20, about 15 to about 25, about 15 to about 30, about 15 to about 35, about 15 to about 40, about 15 to about 45, about 15 to about 50, About 20 to about 25, about 20 to about 30, about 20 to about 35, about 20 to about 40, about 20 to about 45, about 20 to about 50, about 25 to about 30, About 25 to about 35, about 25 to about 40, about 25 to about 45, about 25 to about 50, about 30 to about 35, about 30 to about 40, about 30 to about 45, About 30 to about 50, about 35 to about 40, about 35 to about 45, about 35 to about 50, about 40 to about 45, about 40 to about 50 or about 45 to about 50。
In embodiments, method disclosed herein or purposes lead to the paper pulp of the processing for the content of lignin for having low. In in terms of this embodiment, method disclosed herein or purposes lead to the paper pulp of the processing for the content of lignin for having low, The paper pulp of the processing has Kappa number below：For example, about 5, about 10, about 15, about 20, about 25, about 30, about 35, about 40, about Or about 50.In in terms of this embodiment, method disclosed herein or purposes lead to the processing for the content of lignin for having low Paper pulp, the paper pulp of the processing has Kappa number below：For example, at least 5, at least 10, at least 15, at least 20, at least 25, At least 30, at least 35, at least 40, at least 45 or at least 50.In the another aspect of this embodiment, method disclosed herein or Purposes causes the paper pulp of the processing for the content of lignin for having low, the paper pulp of the processing to have Kappa number below：Such as extremely More 5, at most 10, at most 15, at most 20, at most 25, at most 30, at most 35, at most 40, at most 45 or at most 50.Implement herein In the another aspect of scheme, method disclosed herein or purposes lead to the paper pulp of the processing for the content of lignin for having low, described The paper pulp of processing has Kappa number below：For example, about 5 to about 10, about 5 to about 15, about 5 to about 20, about 5 to about 25, about 5 to About 30, about 5 to about 35, about 5 to about 40, about 5 to about 45, about 5 to about 50, about 10 to about 15, about 10 to about 20, about 10 to about 25, about 10 to about 30, about 10 to about 35, about 10 to about 40, about 10 to about 45, about 10 to about 50, about 15 to about 20, about 15 to about 25, about 15 to about 30, about 15 to about 35, about 15 to about 40, about 15 to about 45, about 15 to about 50, about 20 to about 25, about 20 to about 30, about 20 to about 35, about 20 to about 40, about 20 to about 45, about 20 to about 50, about 25 to about 30, about 25 to about 35, about 25 to about 40, about 25 to about 45, about 25 to about 50, about 30 to about 35, about 30 to about 40, about 30 to about 45, about 30 to about 50, about 35 to about 40, about 35 to about 45, about 35 to about 50, about 40 to about 45, about 40 to about 50 or about 45 to about 50.
In embodiments, the effective quantity of disclosed additive composition for paper making is to be enough to lead to have adding for low impurity The amount of the paper pulp of work.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough to cause to have There are the amount of the paper pulp of the processing of low impurity content, the paper pulp of the processing that there is copper number below：For example, about 0.5, about 0.75, About 1.0, about 1.25, about 1.5, about 1.75, about 2.0, about 2.25, about 2.5, about 2.75, about 3.0, about 3.25, about 3.5, about 3.75, about 4.0, about 4.25, about 4.5, about 4.75, about 5.0, about 5.25, about 5.5, about 5.75, about 6.0, about 6.25, about 6.5, About 6.75 or about 7.0.In in terms of other of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough to lead Cause the amount of the paper pulp of the processing with low impurity content, the paper pulp of the processing that there is copper number below：For example, at least 0.5, At least 0.75, at least 1.0, at least 1.25, at least 1.5, at least 1.75, at least 2.0, at least 2.25, at least 2.5, at least 2.75, At least 3.0, at least 3.25, at least 3.5, at least 3.75, at least 4.0, at least 4.25, at least 4.5, at least 4.75, at least 5.0, At least 5.25, at least 5.5, at least 5.75, at least 6.0, at least 6.25, at least 6.5, at least 6.75 or at least 7.0.Implement herein In other aspects again of scheme, the effective quantity of disclosed additive composition for paper making is to be enough to lead to have low impurity content The paper pulp of the amount of the paper pulp of processing, the processing has copper number below：Such as at most 0.5, at most 0.75, at most 1.0, at most 1.25, at most 1.5, at most 1.75, at most 2.0, at most 2.25, at most 2.5, at most 2.75, at most 3.0, at most 3.25, at most 3.5, at most 3.75, at most 4.0, at most 4.25, at most 4.5, at most 4.75, at most 5.0, at most 5.25, at most 5.5, at most 5.75, at most 6.0, at most 6.25, at most 6.5, at most 6.75 or at most 7.0.This embodiment it is other in terms of other in, The effective quantity of disclosed additive composition for paper making is the amount for being enough to cause to have the paper pulp of the processing of low impurity content, described The paper pulp of processing has copper number below：For example, about 0.5 to about 1.0, about 0.5 to about 2.0, about 0.5 to about 3.0, about 0.5 to about 4.0, about 0.5 to about 5.0, about 0.5 to about 6.0, about 0.5 to about 7.0, about 0.75 to about 1.0, about 0.75 to about 2.0, about 0.75 To about 3.0, about 0.75 to about 4.0, about 0.75 to about 5.0, about 0.75 to about 6.0, about 0.75 to about 7.0, about 1.0 to about 2.0, About 1.0 to about 3.0, about 1.0 to about 4.0, about 1.0 to about 5.0, about 1.0 to about 6.0, about 1.0 to about 7.0, about 1.25 to about 2.0, about 1.25 to about 3.0, about 1.25 to about 4.0, about 1.25 to about 5.0, about 1.25 to about 6.0, about 1.25 to about 7.0, about 1.5 to about 2.0, about 1.5 to about 3.0, about 1.5 to about 4.0, about 1.5 to about 5.0, about 1.5 to about 6.0, about 1.5 to about 7.0, About 1.75 to about 2.0, about 1.75 to about 3.0, about 1.75 to about 4.0, about 1.75 to about 5.0, about 1.75 to about 6.0, about 1.75 To about 7.0, about 2 to about 3.0, about 2 to about 4.0, about 2 to about 5.0, about 2 to about 6.0 or about 2 to about 7.0.
In embodiments, method disclosed herein or purposes lead to the paper pulp of the processing for the impurity for having low.It is real herein In the aspect for applying scheme, method disclosed herein or purposes lead to the paper pulp of the processing for the impurity content for having low, the processing Paper pulp have copper number below：For example, about 0.5, about 0.75, about 1.0, about 1.25, about 1.5, about 1.75, about 2.0, about 2.25, About 2.5, about 2.75, about 3.0, about 3.25, about 3.5, about 3.75, about 4.0, about 4.25, about 4.5, about 4.75, about 5.0, about 5.25, about 5.5, about 5.75, about 6.0, about 6.25, about 6.5, about 6.75 or about 7.0.In in terms of other of this embodiment, Method disclosed herein or purposes lead to the paper pulp of the processing for the impurity content for having low, and the paper pulp of the processing is with below Copper number：For example, at least 0.5, at least 0.75, at least 1.0, at least 1.25, at least 1.5, at least 1.75, at least 2.0, at least 2.25, At least 2.5, at least 2.75, at least 3.0, at least 3.25, at least 3.5, at least 3.75, at least 4.0, at least 4.25, at least 4.5, At least 4.75, at least 5.0, at least 5.25, at least 5.5, at least 5.75, at least 6.0, at least 6.25, at least 6.5, at least 6.75 Or at least 7.0.This embodiment again in terms of other in, method disclosed herein or purposes lead to the impurity content for having low Processing paper pulp, the paper pulp of the processing has copper number below：Such as at most 0.5, at most 0.75, at most 1.0, at most 1.25, at most 1.5, at most 1.75, at most 2.0, at most 2.25, at most 2.5, at most 2.75, at most 3.0, at most 3.25, at most 3.5, at most 3.75, at most 4.0, at most 4.25, at most 4.5, at most 4.75, at most 5.0, at most 5.25, at most 5.5, at most 5.75, at most 6.0, at most 6.25, at most 6.5, at most 6.75 or at most 7.0.This embodiment it is other in terms of other in, Method disclosed herein or purposes lead to the paper pulp of the processing for the impurity content for having low, and the paper pulp of the processing is with below Copper number：For example, about 0.5 to about 1.0, about 0.5 to about 2.0, about 0.5 to about 3.0, about 0.5 to about 4.0, about 0.5 to about 5.0, about 0.5 to about 6.0, about 0.5 to about 7.0, about 0.75 to about 1.0, about 0.75 to about 2.0, about 0.75 to about 3.0, about 0.75 to about 4.0, about 0.75 to about 5.0, about 0.75 to about 6.0, about 0.75 to about 7.0, about 1.0 to about 2.0, about 1.0 to about 3.0, about 1.0 To about 4.0, about 1.0 to about 5.0, about 1.0 to about 6.0, about 1.0 to about 7.0, about 1.25 to about 2.0, about 1.25 to about 3.0, about 1.25 to about 4.0, about 1.25 to about 5.0, about 1.25 to about 6.0, about 1.25 to about 7.0, about 1.5 to about 2.0, about 1.5 to about 3.0, about 1.5 to about 4.0, about 1.5 to about 5.0, about 1.5 to about 6.0, about 1.5 to about 7.0, about 1.75 to about 2.0, about 1.75 To about 3.0, about 1.75 to about 4.0, about 1.75 to about 5.0, about 1.75 to about 6.0, about 1.75 to about 7.0, about 2 to about 3.0, about 2 to about 4.0, about 2 to about 5.0, about 2 to about 6.0 or about 2 to about 7.0.
High fiber fineness and quality be on the other hand the carboxylic group present in the paper pulp of processing content.It is logical Often, the number of carboxylic group is higher, and the purity and integrality of the cellulosic material in the paper pulp of processing are higher.There are several measurements The measuring method of the number of carboxylic group in the cellulosic material of paper pulp from processing.
In carboxyl-content measurement, determines the carboxyl-content of the paper pulp of processing, be paper intensity, delignification and cellulose The indicant for the number that fiber can recycle.Carboxylic group is beneficial in terms of the paper pulp fiber in combining paper, this contributes to Paper intensity.The content of carboxylic group is higher, and paper intensity will be bigger.In order to carry out carboxyl-content measurement, by the paper of dry processing Slurry mixes lasting 60 minutes with 0.1M HCl, and then filters and be washed with water.Then, processed cellulosic material is added It adds in the 1mM NaCl solutions of the 250mL of the 0.1M HCl acidifications with 1.5mL, and then uses 0.05N NaOH with 0.2mL Increment thermal conductivity carries out quantitative titration.Titration data is plotted as conductivity relative to volume, with the milli of every kilogram of paper pulp of determination The acid groups of equivalent.Carboxyl group content C is calculated using following formula0：C0=N × V × 100/M, wherein C0It is carboxyl group content (meq/100g paper pulp), N are titrant concentrations, and V is the volume in terms of milliliter at equivalent point, and M is baking in gram The quality of the paper pulp of case drying.Standardized alkali solubility measurement is described in such as TAPPI standards T 237cm-08 paper pulp Carboxyl-content and Chen, et al., Fiber Properties of Eucalyptus Kraft Pulp with Different Carboxyl Group Contents,Cellulose 20:2839-2846 (2013), the carboxyl-content for cellulose ASTM D 1926-00 standard method of test (ASTM D 1926-00Standard Test Methods for Carboxyl Content if Cellulose) and Barbosa, et al., A Rapid Method for Quantification of Carboxyl Croups in Cellulose Pulp,BioResources 8(1):In 1043-1054 (2013), these surveys Determine content in each of method to be integrally incorporated with it accordingly by reference.
In embodiments, the effective quantity of disclosed additive composition for paper making is to be enough to lead to have high carboxyl-content Processing paper pulp amount.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough to lead Cause the amount of the paper pulp of the processing with carboxyl-content below：For example, about 4meq/100g paper pulp, about 4.5meq/100g paper pulp, about 5meq/100g paper pulp, about 5.5meq/100g paper pulp, about 6meq/100g paper pulp, about 6.5meq/100g paper pulp, about 7meq/100g Paper pulp, about 7.5meq/100g paper pulp, about 8meq/100g paper pulp, about 8.5meq/100g paper pulp, about 9meq/100g paper pulp, about 9.5meq/100g paper pulp or about 10meq/100g paper pulp.In in terms of other of this embodiment, disclosed additive for paper making group The effective quantity for closing object is the amount for being enough to cause to have the paper pulp of the processing of carboxyl-content below：For example, at least 4meq/100g paper Slurry, at least 4.5meq/100g paper pulp, at least 5meq/100g paper pulp, at least 5.5meq/100g paper pulp, at least 6meq/100g paper Slurry, at least 6.5meq/100g paper pulp, at least 7meq/100g paper pulp, at least 7.5meq/100g paper pulp, at least 8meq/100g paper Slurry, at least 8.5meq/100g paper pulp, at least 9meq/100g paper pulp, at least 9.5meq/100g paper pulp or at least 10meq/100g Paper pulp.This embodiment again in terms of other in, the effective quantity of disclosed additive composition for paper making is to be enough to cause to have The amount of the paper pulp of the processing of carboxyl-content below：Such as at most 4meq/100g paper pulp, at most 4.5meq/100g paper pulp, at most 5meq/100g paper pulp, at most 5.5meq/100g paper pulp, at most 6meq/100g paper pulp, at most 6.5meq/100g paper pulp, at most 7meq/100g paper pulp, at most 7.5meq/100g paper pulp, at most 8meq/100g paper pulp, at most 8.5meq/100g paper pulp, at most 9meq/100g paper pulp, at most 9.5meq/100g paper pulp or at most 10meq/100g paper pulp.This embodiment it is other other In aspect, method disclosed herein or purposes lead to the paper pulp with the processing of carboxyl-content below：For example, about 4meq/100g Paper pulp is to about 5meq/100g paper pulp, about 4meq/100g paper pulp to about 6meq/100g paper pulp, about 4meq/100g paper pulp to about 7meq/100g paper pulp, about 4meq/100g paper pulp to about 8meq/100g paper pulp, about 4meq/100g paper pulp to about 9meq/100g paper Slurry, about 4meq/100g paper pulp to about 10meq/100g paper pulp, about 5meq/100g paper pulp to about 6meq/100g paper pulp, about 5meq/ 100g paper pulp to about 7meq/100g paper pulp, about 5meq/100g paper pulp to about 8meq/100g paper pulp, about 5meq/100g paper pulp extremely About 9meq/100g paper pulp, about 5meq/100g paper pulp to about 10meq/100g paper pulp, about 6meq/100g paper pulp to about 7meq/ 100g paper pulp, about 6meq/100g paper pulp to about 8meq/100g paper pulp, about 6meq/100g paper pulp to about 9meq/100g paper pulp, about 6meq/100g paper pulp is to about 10meq/100g paper pulp, about 7meq/100g paper pulp to about 8meq/100g paper pulp, about 7meq/100g Paper pulp is to about 9meq/100g paper pulp, about 7meq/100g paper pulp to about 10meq/100g paper pulp, about 8meq/100g paper pulp to about 9meq/100g paper pulp, about 8meq/100g paper pulp to about 10meq/100g paper pulp or about 9meq/100g paper pulp are to about 10meq/ 100g paper pulp.
In embodiments, method disclosed herein or purposes lead to the paper pulp of the processing for the carboxyl-content for having high. In the aspect of this embodiment, method disclosed herein or purposes lead to the paper pulp with the processing of carboxyl-content below：Example Such as from about 4meq/100g paper pulp, about 4.5meq/100g paper pulp, about 5meq/100g paper pulp, about 5.5meq/100g paper pulp, about 6meq/ 100g paper pulp, about 6.5meq/100g paper pulp, about 7meq/100g paper pulp, about 7.5meq/100g paper pulp, about 8meq/100g paper pulp, About 8.5meq/100g paper pulp, about 9meq/100g paper pulp, about 9.5meq/100g paper pulp or about 10meq/100g paper pulp.It is real herein In other aspects for applying scheme, method disclosed herein or purposes lead to the paper pulp with the processing of carboxyl-content below：Example Such as at least 4meq/100g paper pulp, at least 4.5meq/100g paper pulp, at least 5meq/100g paper pulp, at least 5.5meq/100g paper Slurry, at least 6meq/100g paper pulp, at least 6.5meq/100g paper pulp, at least 7meq/100g paper pulp, at least 7.5meq/100g paper Slurry, at least 8meq/100g paper pulp, at least 8.5meq/100g paper pulp, at least 9meq/100g paper pulp, at least 9.5meq/100g paper Slurry or at least 10meq/100g paper pulp.This embodiment again in terms of other in, method disclosed herein or purposes cause to have There is the paper pulp of the processing of carboxyl-content below：Such as at most 4meq/100g paper pulp, at most 4.5meq/100g paper pulp, at most 5meq/100g paper pulp, at most 5.5meq/100g paper pulp, at most 6meq/100g paper pulp, at most 6.5meq/100g paper pulp, at most 7meq/100g paper pulp, at most 7.5meq/100g paper pulp, at most 8meq/100g paper pulp, at most 8.5meq/100g paper pulp, at most 9meq/100g paper pulp, at most 9.5meq/100g paper pulp or at most 10meq/100g paper pulp.This embodiment it is other other In aspect, method disclosed herein or purposes lead to the paper pulp with the processing of carboxyl-content below：For example, about 4meq/100g Paper pulp is to about 5meq/100g paper pulp, about 4meq/100g paper pulp to about 6meq/100g paper pulp, about 4meq/100g paper pulp to about 7meq/100g paper pulp, about 4meq/100g paper pulp to about 8meq/100g paper pulp, about 4meq/100g paper pulp to about 9meq/100g paper Slurry, about 4meq/100g paper pulp to about 10meq/100g paper pulp, about 5meq/100g paper pulp to about 6meq/100g paper pulp, about 5meq/ 100g paper pulp to about 7meq/100g paper pulp, about 5meq/100g paper pulp to about 8meq/100g paper pulp, about 5meq/100g paper pulp extremely About 9meq/100g paper pulp, about 5meq/100g paper pulp to about 10meq/100g paper pulp, about 6meq/100g paper pulp to about 7meq/ 100g paper pulp, about 6meq/100g paper pulp to about 8meq/100g paper pulp, about 6meq/100g paper pulp to about 9meq/100g paper pulp, about 6meq/100g paper pulp is to about 10meq/100g paper pulp, about 7meq/100g paper pulp to about 8meq/100g paper pulp, about 7meq/100g Paper pulp is to about 9meq/100g paper pulp, about 7meq/100g paper pulp to about 10meq/100g paper pulp, about 8meq/100g paper pulp to about 9meq/100g paper pulp, about 8meq/100g paper pulp to about 10meq/100g paper pulp or about 9meq/100g paper pulp are to about 10meq/ 100g paper pulp.
High fiber fineness and quality be on the other hand production processing paper pulp or paper product brightness.In general, Brightness is higher, and the paper pulp of the processing of production or the purity and integrality of the cellulosic material in paper product are higher.There are several surveys Measure the measuring method of the number of the carboxylic group in the cellulosic material of the paper pulp from processing.
Brightness is numerical value of the sample relative to the reflectivity of the blue light of specific spectral characteristic and geometrical property.Blue light is anti- The rate measurement of penetrating is originally designed as providing the instruction of the amount for the bleaching having occurred and that in the manufacture of paper pulp.This program is suitable for institute There are natural colorful paper pulp and paper and plate made of paper pulp.Brightness is based on zero to 100 scale, the higher finger of blu-ray reflection rate score It is whiter to show that paper product will be presented.In order to carry out brightness measuring, pattern product are exposed to the width of wavelength and 44nm with 457nm Laser, and measure the amount of the blue light from the wavelength with 457nm of the surface reflection of paper.Standardized brightness measuring is retouched It states in the brightness (directional reflectance at 457nm) of such as TAPPI standards T 452om-08 paper pulp, paper and cardboard and ISO 2470:In the measurement (ISO brightness) of 2009 blue light diffusing reflection factors, these contents measured are whole simultaneously with it accordingly by reference Enter.
In embodiments, the effective quantity of disclosed additive composition for paper making is to be enough to cause derived from such paper pulp The paper pulp or paper product of processing are with the amount with high brightness.In in terms of this embodiment, disclosed additive for paper making combination The effective quantity of object is the paper pulp for being enough to cause to process derived from such paper pulp or paper product with the amount with brightness below：Example Such as from about 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%.In in terms of this embodiment, The effective quantity of disclosed additive composition for paper making be the paper pulp for being enough to cause to process derived from such paper pulp or paper product with Amount with high brightness below：For example, at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, At least 96%, at least 97%, at least 98% or at least 99%.This embodiment again in terms of other in, disclosed papermaking adds The effective quantity of agent composition is added to be the paper pulp for being enough to cause to process derived from such paper pulp or paper product with height below The amount of brightness：Such as at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, At most 89%, at most 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, at most 97%, at most 98% or at most 99%.This embodiment again in terms of other in, method disclosed herein or purposes cause to have There is the paper pulp of the processing of alpha-cellulose content below：For example, about 70% to about 80%, about 70% to about 85%, about 70% to about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to about 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
In embodiments, method disclosed herein or purposes cause the paper pulp processed derived from such paper pulp or paper to produce Product are with high brightness.In in terms of this embodiment, method disclosed herein or purposes cause derived from such paper pulp The paper pulp or paper product of processing are with high brightness below：For example, about 70%, about 75%, about 80%, about 85%, about 86%, About 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, About 98% or about 99%.In in terms of this embodiment, method disclosed herein or purposes cause derived from such paper pulp The paper pulp or paper product of processing are with brightness below：For example, at least 70%, at least 75%, at least 80%, at least 85%, extremely Few 86%, at least 87%, at least 88%, at least 89%, at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%.In this embodiment again in terms of other In, method disclosed herein or purposes cause the paper pulp processed derived from such paper pulp or paper product with below bright Degree：Such as at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, at most 89%, at most 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, at most 97%, At most 98% or at most 99%.This embodiment again in terms of other in, method disclosed herein or purposes cause to have with Under alpha-cellulose content processing paper pulp：For example, about 70% to about 80%, about 70% to about 85%, about 70% to about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to about 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
The paper pulp for being on the other hand the processing produced of high fiber fineness and quality or the impurity content in paper product And/or the amount of pollutant load.In general, impurity content and/or pollutant load are lower, the paper pulp or paper product of the processing of production In cellulosic material purity and integrality it is higher.There are the carboxylics in several cellulosic materials for measuring the paper pulp from processing The measuring method of the number of base group.
High fiber fineness and quality is the paper pulp of the processing produced or the ink content of paper product on the other hand.It is logical Often, ink content is lower, and the paper pulp of the processing of production or the purity and integrality of the cellulosic material in paper product are higher.In the presence of The measuring method of the value of ink content in the cellulosic material of several paper pulp for measuring the processing from production or paper product.
Because pulp stage is usually removed the most of water-soluble and volatile compound dissolved in organic solvent, Impurity and/or pollutant typically comprise resin and fitter acids and its ester, wax and nonsaponifying substance and recycled paper products Impurity and/or pollutant such as ink, plastics and other additives.Such impurity and/or pollutant commonly known as carry Take object.
In solvent extractable matter measurement, determines the extractive content of the paper pulp of processing, be paper intensity, delignification and fibre The indicant for the number that cellulose fiber can recycle.Solvent extractable matter measurement includes measurement and ethyl alcohol-benzene based on dichloromethane It measures.The dichloromethane extractable content of the paper pulp of processing is the degree of wax, fat, resin, lumisterol and fixed hydrocarbon Amount.Other than wax, fat, resin, lumisterol and fixed hydrocarbon, ethyl alcohol-benzene extractable content of the paper pulp of processing Further include dichloromethane insoluble component, including low molecular weight carbohydrate, salt and other water-soluble substances.It is molten in order to carry out Agent extract measures, and the paper pulp of dry processing is mixed with suitable solvent, and sample is small about 4 in extraction equipment It is not less than 24 extraction cycles up to heating and continuous in about 5 hours periods.Sample is taken out from the device, and evaporates and appoints What remaining solvent is simultaneously then by sample oven drying.Extractive content E% is calculated using following formula：E%=[(We–Wb)/Wp] × 100, wherein E% are extractive content, WeIt is the oven-dry weight of extract in gram, WbIt is sky in gram The oven-dry weight of white residue, and WpIt is the oven-dry weight of initial pulp sample in gram.It is standardized molten Agent extract measurement is described in such as solvent extractable matter of TAPPI standards T 204cm-97 timber and paper pulp, these measurement In the content of each be integrally incorporated with it accordingly by reference.
In embodiments, the effective quantity of disclosed additive composition for paper making is to be enough to cause to have low extract to contain The amount of the paper pulp of the processing of amount.In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is to be enough Lead to the amount with the paper pulp of the processing of extractive content below：For example, about 0.01%, about 0.02%, about 0.03%, about 0.04%, about 0.05%, about 0.06%, about 0.07%, about 0.08%, about 0.09%, about 0.1%, about 0.2%, about 0.3%, About 0.4%, about 0.5%, about 0.6%, about 0.7%, about 0.8%, about 0.9%, about 1%, about 2%, about 3%, about 4% or about 5%.In in terms of other of this embodiment, the effective quantity of disclosed additive composition for paper making be enough to cause to have it is following Extractive content processing paper pulp amount：Such as at most 0.01%, at most 0.02%, at most 0.03%, at most 0.04%, At most 0.05%, at most 0.06%, at most 0.07%, at most 0.08%, at most 0.09%, at most 0.1%, at most 0.2%, extremely More 0.3%, at most 0.4%, at most 0.5%, at most 0.6%, at most 0.7%, at most 0.8%, at most 0.9%, at most 1%, At most 2%, at most 3%, at most 4% or at most 5%.In in terms of other of this embodiment, disclosed additive for paper making group The effective quantity for closing object is the amount for being enough to cause to have the paper pulp of the processing of extractive content below：For example, about 0.001% to about 0.005%, about 0.001% to about 0.01%, about 0.001% to about 0.05%, about 0.001% to about 0.1%, about 0.001% To about 0.5%, about 0.001% to about 1%, about 0.001% to about 5%, about 0.005% to about 0.01%, about 0.005% to about 0.05%, about 0.005% to about 0.1%, about 0.005% to about 0.5%, about 0.005% to about 1%, about 0.005% to about 5%, about 0.01% to about 0.05%, about 0.01% to about 0.1%, about 0.01% to about 0.5%, about 0.01% to about 1%, about 0.01% to about 5%, about 0.05% to about 0.1%, about 0.05% to about 0.5%, about 0.05% to about 1%, about 0.05% to About 5%, about 0.1% to about 0.5%, about 0.1% to about 1%, about 0.1% to about 5%, about 0.5% to about 1%, about 0.5% to About 5% or about 1% to about 5%.
In embodiments, method disclosed herein or purposes lead to the paper pulp of the processing for the extractive content for having low. In in terms of this embodiment, method disclosed herein or purposes lead to the paper with the processing of extractive content below Slurry：For example, about 0.01%, about 0.02%, about 0.03%, about 0.04%, about 0.05%, about 0.06%, about 0.07%, about 0.08%, about 0.09%, about 0.1%, about 0.2%, about 0.3%, about 0.4%, about 0.5%, about 0.6%, about 0.7%, about 0.8%, about 0.9%, about 1%, about 2%, about 3%, about 4% or about 5%.It is public herein in terms of other of this embodiment The method or purposes opened lead to the paper pulp with the processing of extractive content below：Such as at most 0.01%, at most 0.02%, At most 0.03%, at most 0.04%, at most 0.05%, at most 0.06%, at most 0.07%, at most 0.08%, at most 0.09%, At most 0.1%, at most 0.2%, at most 0.3%, at most 0.4%, at most 0.5%, at most 0.6%, at most 0.7%, at most 0.8%, at most 0.9%, at most 1%, at most 2%, at most 3%, at most 4% or at most 5%.In its other party of this embodiment In face, method disclosed herein or purposes lead to the paper pulp with the processing of extractive content below：For example, about 0.001% to About 0.005%, about 0.001% to about 0.01%, about 0.001% to about 0.05%, about 0.001% to about 0.1%, about 0.001% to about 0.5%, about 0.001% to about 1%, about 0.001% to about 5%, about 0.005% to about 0.01%, about 0.005% to about 0.05%, about 0.005% to about 0.1%, about 0.005% to about 0.5%, about 0.005% to about 1%, about 0.005% to about 5%, about 0.01% to about 0.05%, about 0.01% to about 0.1%, about 0.01% to about 0.5%, about 0.01% to about 1%, about 0.01% to about 5%, about 0.05% to about 0.1%, about 0.05% to about 0.5%, about 0.05% to About 1%, about 0.05% to about 5%, about 0.1% to about 0.5%, about 0.1% to about 1%, about 0.1% to about 5%, about 0.5% To about 1%, about 0.5% to about 5% or about 1% to about 5%.
The effective quantity of disclosed additive composition for paper making can be the dilution of additive composition for paper making disclosed herein It spends (dilution).In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is papermaking below Compositions of additives:Diluent ratio：For example, about 1:50, about 1:75, about 1:100, about 1:125, about 1:150, about 1:175, about 1:200, about 1:225, about 1:250, about 1:275, about 1:300, about 1:325, about 1:350, about 1:375, about 1:400, about 1: 425, about 1:450, about 1:475, about 1:500, about 1:525, about 1:550, about 1:575 or about 1:600.In its of this embodiment In his aspect, the effective quantity of disclosed additive composition for paper making is additive composition for paper making below:Diluent ratio：Example Such as at least 1:50, at least 1:75, at least 1:100, at least 1:125, at least 1:150, at least 1:175, at least 1:200, at least 1: 225, at least 1:250, at least 1:275, at least 1:300, at least 1:325, at least 1:350, at least 1:375, at least 1:400, extremely Few 1:425, at least 1:450, at least 1:475, at least 1:500, at least 1:525, at least 1:550, at least 1:575 or at least 1: 600.This embodiment again in terms of other in, the effective quantity of disclosed additive composition for paper making is papermaking addition below Agent composition:Diluent ratio：Such as at most 1:50, at most 1:75, at most 1:100, at most 1:125, at most 1:150, at most 1:175, at most 1:200, at most 1:225, at most 1:250, at most 1:275, at most 1:300, at most 1:325, at most 1:350、 At most 1:375, at most 1:400, at most 1:425, at most 1:450, at most 1:475, at most 1:500, at most 1:525, at most 1: 550, at most 1:575 or at most 1:600.In in terms of other of this embodiment, disclosed additive composition for paper making has Effect amount is additive composition for paper making below:Diluent ratio：For example, about 1:50 to about 1:100, about 1:50 to about 1:200、 About 1:50 to about 1:300, about 1:50 to about 1:400, about 1:50 to about 1:500, about 1:50 to about 1:600, about 1:100 to about 1: 200, about 1:100 to about 1:300, about 1:100 to about 1:400, about 1:100 to about 1:500, about 1:100 to about 1:600, about 1: 200 to about 1:300, about 1:200 to about 1:400, about 1:200 to about 1:500, about 1:200 to about 1:600, about 1:300 to about 1: 400, about 1:300 to about 1:500, about 1:300 to about 1:600, about 1:400 to about 1:500, about 1:400 to about 1:600 or about 1: 500 to about 1:600.
In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making is additive for paper making below Composition:Diluent ratio：For example, about 1:500, about 1:750, about 1:1000, about 1:1250, about 1:1500, about 1:1750, about 1:2000, about 1:2250, about 1:2500, about 1:2750, about 1:3000, about 1:3250, about 1:3500, about 1:3750, about 1: 4000, about 1:4250, about 1:4500, about 1:4750, about 1:5000, about 1:5250, about 1:5500, about 1:5750, about 1:6000、 About 1:7000, about 1:8000, about 1:9000 or about 1:10000.In in terms of other of this embodiment, disclosed papermaking addition The effective quantity of agent composition is additive composition for paper making below:Diluent ratio：For example, at least 1:500, at least 1:750、 At least 1:1000, at least 1:1250, at least 1:1500, at least 1:1750, at least 1:2000, at least 1:2250, at least 1:2500、 At least 1:2750, at least 1:3000, at least 1:3250, at least 1:3500, at least 1:3750, at least 1:4000, at least 1:4250、 At least 1:4500, at least 1:4750, at least 1:5000, at least 1:5250, at least 1:5500, at least 1:5750, at least 1:6000、 At least 1:7000, at least 1:8000, at least 1:9000 or at least 1:10000.This embodiment again in terms of other in, it is open The effective quantity of additive composition for paper making be additive composition for paper making below:Diluent ratio：Such as at most 1:500、 At most 1:750, at most 1:1000, at most 1:1250, at most 1:1500, at most 1:1750, at most 1:2000, at most 1:2250、 At most 1:2500, at most 1:2750, at most 1:3000, at most 1:3250, at most 1:3500, at most 1:3750, at most 1:4000、 At most 1:4250, at most 1:4500, at most 1:4750, at most 1:5000, at most 1:5250, at most 1:5500, at most 1:5750、 At most 1:6000, at most 1:7000, at most 1:8000, at most 1:9000 or at most 1:10000.In its other party of this embodiment In face, the effective quantity of disclosed additive composition for paper making is additive composition for paper making below:Diluent ratio：For example, about 1:500 to about 1:1000, about 1:500 to about 1:2000, about 1:500 to about 1:3000, about 1:500 to about 1:4000, about 1:500 To about 1:5000, about 1:500 to about 1:6000, about 1:500 to about 1:7000, about 1:500 to about 1:8000, about 1:500 to about 1:9000, about 1:500 to about 1:10000, about 1:1000 to about 1:2000, about 1:1000 to about 1:3000, about 1:1000 to about 1:4000, about 1:1000 to about 1:5000, about 1:1000 to about 1:6000, about 1:1000 to about 1:7000, about 1:1000 to about 1:8000, about 1:1000 to about 1:9000, about 1:1000 to about 1:10000, about 1:2000 to about 1:3000, about 1:2000 to about 1:4000, about 1:2000 to about 1:5000, about 1:2000 to about 1:6000, about 1:2000 to about 1:7000, about 1:2000 to about 1:8000, about 1:2000 to about 1:9000, about 1:2000 to about 1:10000, about 1:3000 to about 1:4000, about 1:3000 to about 1:5000, about 1:3000 to about 1:6000, about 1:3000 to about 1:7000, about 1:3000 to about 1:8000, about 1:3000 to about 1:9000, about 1:3000 to about 1:10000, about 1:4000 to about 1:5000, about 1:4000 to about 1:6000, about 1:4000 to about 1:7000, about 1:4000 to about 1:8000, about 1:4000 to about 1:9000, about 1:4000 to about 1:10000, about 1:5000 to about 1:6000, about 1:5000 to about 1:7000, about 1:5000 to about 1:8000, about 1:5000 to about 1:9000, about 1:5000 to about 1:10000, about 1:6000 to about 1:7000, about 1:6000 to about 1:8000, about 1:6000 to about 1:9000, about 1:6000 to about 1:10000, about 1:7000 to about 1:8000, about 1:7000 to about 1:9000, about 1:7000 to about 1:10000, about 1:8000 to About 1:9000, about 1:8000 to about 1:10000 or about 1:9000 to about 1:10000.
In in terms of this embodiment, the effective quantity of disclosed additive composition for paper making has below final dense Degree：For example, about 0.0001%, about 0.0002%, about 0.0003%, about 0.0004%, about 0.0005%, about 0.0006%, about 0.0007%, about 0.0008%, about 0.0009%, about 0.001%, about 0.002%, about 0.003%, about 0.004%, about 0.005%, about 0.006%, about 0.007%, about 0.008%, about 0.009%, about 0.01%, about 0.02%, about 0.03%, about 0.04%, about 0.05%, about 0.06%, about 0.07%, about 0.08%, about 0.09%, about 0.1%, about 0.2%, about 0.3%, About 0.4%, about 0.5%, about 0.6%, about 0.7%, about 0.8%, about 0.9%, about 1%, about 2%, about 3%, about 4%, about 5%, about 6%, about 7%, about 8%, about 9% or about 10%.In in terms of other of this embodiment, disclosed additive for paper making The effective quantity of composition has ultimate density below：For example, at least 0.0001%, at least 0.0002%, at least 0.0003%, At least 0.0004%, at least 0.0005%, at least 0.0006%, at least 0.0007%, at least 0.0008%, at least 0.0009%, at least 0.001%, at least 0.002%, at least 0.003%, at least 0.004%, at least 0.005%, at least 0.006%, at least 0.007%, at least 0.008%, at least 0.009%, at least 0.01%, at least 0.02%, at least 0.03%, At least 0.04%, at least 0.05%, at least 0.06%, at least 0.07%, at least 0.08%, at least 0.09%, at least 0.1%, At least 0.2%, at least 0.3%, at least 0.4%, at least 0.5%, at least 0.6%, at least 0.7%, at least 0.8%, at least 0.9%, at least 1%, at least 2%, at least 3%, at least 4%, at least 5%, at least 6%, at least 7%, at least 8%, at least 9% Or at least 10%.This embodiment again in terms of other in, the effective quantity of disclosed additive composition for paper making has following Ultimate density：Such as at most 0.0001%, at most 0.0002%, at most 0.0003%, at most 0.0004%, at most 0.0005%, at most 0.0006%, at most 0.0007%, at most 0.0008%, at most 0.0009%, at most 0.001%, at most 0.002%, at most 0.003%, at most 0.004%, at most 0.005%, at most 0.006%, at most 0.007%, at most 0.008%, at most 0.009%, at most 0.01%, at most 0.02%, at most 0.03%, at most 0.04%, at most 0.05%, extremely More 0.06%, at most 0.07%, at most 0.08%, at most 0.09%, at most 0.1%, at most 0.2%, at most 0.3%, at most 0.4%, at most 0.5%, at most 0.6%, at most 0.7%, at most 0.8%, at most 0.9%, at most 1%, at most 2%, at most 3%, at most 4%, at most 5%, at most 6%, at most 7%, at most 8%, at most 9% or at most 10%.In this embodiment In addition in other aspects, the effective quantity of disclosed additive composition for paper making has ultimate density below：For example, about 0.0001% to about 0.0005%, about 0.0001% to about 0.001%, about 0.0001% to about 0.005%, about 0.0001% to About 0.01%, about 0.0001% to about 0.05%, about 0.0001% to about 0.1%, about 0.0001% to about 0.5%, about 0.0001% to about 1%, about 0.0001% to about 5%, about 0.0001% to about 10%, about 0.0005% to about 0.001%, about 0.0005% to about 0.005%, about 0.0005% to about 0.01%, about 0.0005% to about 0.05%, about 0.0005% to about 0.1%, about 0.0005% to about 0.5%, about 0.0005% to about 1%, about 0.0005% to about 5%, about 0.0005% to about 10%, about 0.001% to about 0.005%, about 0.001% to about 0.01%, about 0.001% to about 0.05%, about 0.001% to About 0.1%, about 0.001% to about 0.5%, about 0.001% to about 1%, about 0.001% to about 5%, about 0.001% to about 10%, about 0.005% to about 0.01%, about 0.005% to about 0.05%, about 0.005% to about 0.1%, about 0.005% to about 0.5%, about 0.005% to about 1%, about 0.005% to about 5%, about 0.005% to about 10%, about 0.01% to about 0.05%, About 0.01% to about 0.1%, about 0.01% to about 0.5%, about 0.01% to about 1%, about 0.01% to about 5%, about 0.01% To about 10%, about 0.05% to about 0.1%, about 0.05% to about 0.5%, about 0.05% to about 1%, about 0.05% to about 5%, About 0.05% to about 10%, about 0.1% to about 0.5%, about 0.1% to about 1%, about 0.1% to about 5%, about 0.1% to about 10%, about 0.5% to about 1%, about 0.5% to about 5%, about 0.5% to about 10%, about 1% to about 5%, about 1% to about 10% Or about 5% to about 10%.
The application of additive composition for paper making disclosed herein can be by effectively generating microbubble as disclosed herein Any technique realize.The microbubble formed with additive composition for paper making disclosed herein seems to increase the oxygen in liquid Mass transfer.It is not intended to be fettered by scientific theory, for this species diversity, there are several possible explanations.First, it is formulated into Surfactant in additive composition for paper making disclosed herein includes the nonionic for the property for significantly changing bubbling behaviour Type surfactant and/or biosurfactant.Secondly, additive for paper making combination disclosed herein needs much lower surface Surfactant concentration is formed for microbubble.It has been shown that surfactant concentration must be close to the critical of surfactant system Micellar concentration (CMS).In additive composition for paper making disclosed herein, for used surfactant, microbubble exists CMC less than estimation is formed.This shows that microbubble is surfactant molecule and is more advantageous to the pine of gaseous mass transmission characteristic The result of the aggregation of scattered packing of molecules.Including the surface of less surfactant molecule will be better than the tissue comprising gas Micella be more ventilative.Do not consider that mechanism, additive composition for paper making tissue cluster, aggregation or gas disclosed herein are filled out The trend of the bubble filled provide by the local concentration that increases reactant, reduce catalysis reaction occur needed for energy conversion or still Old other certain mechanism not described and the platform to react.
In in terms of this embodiment, microbubble disclosed herein has average diameter below：For example, about 5 μm, about 10 μm, about 15 μm, about 20 μm, about 25 μm, about 30 μm, about 40 μm, about 50 μm, about 75 μm, about 100 μm, about 150 μm, about 200 μ M, about 250 μm, about 300 μm, about 350 μm, about 400 μm, about 450 μm, about 500 μm, about 550 μm, about 600 μm, about 650 μm, about 700 μm, about 750 μm, about 800 μm, about 850 μm, about 900 μm, about 950 μm or about 1000 μm.In its other party of this embodiment In face, microbubble disclosed herein has average diameter below：For example, at least 5 μm, at least 10 μm, at least 15 μm, at least 20 μ M, at least 25 μm, at least 30 μm, at least 40 μm, at least 50 μm, at least 100 μm, at least 150 μm, at least 200 μm, at least 250 μ M, at least 300 μm, at least 350 μm, at least 400 μm, at least 450 μm, at least 500 μm, at least 550 μm, at least 600 μm, at least 650 μm, at least 700 μm, at least 750 μm, at least 800 μm, at least 850 μm, at least 900 μm, at least 950 μm or at least 1000 μ m.In in terms of other of this embodiment, microbubble disclosed herein has average diameter below：Such as at most 5 μm, extremely More 10 μm, at most 15 μm, at most 20 μm, at most 25 μm, at most 30 μm, at most 40 μm, at most 50 μm, at most 100 μm, at most 150 μm, at most 200 μm, at most 250 μm, at most 300 μm, at most 350 μm, at most 400 μm, at most 450 μm, at most 500 μm, At most 550 μm, at most 600 μm, at most 650 μm, at most 700 μm, at most 750 μm, at most 800 μm, at most 850 μm, at most 900 μm, at most 950 μm or at most 1000 μm.
In in terms of this embodiment, microbubble disclosed herein has average diameter below：For example, about 5 μm to about 10 μm, about 5 μm to about 15 μm, about 5 μm to about 20 μm, about 5 μm to about 25 μm, about 5 μm to about 310 μm, about 5 μm to about 40 μm, About 5 μm to about 50 μm, about 5 μm to about 75 μm, about 5 μm to about 100 μm, about 10 μm to about 15 μm, about 10 μm to about 20 μm, about 10 μm to about 25 μm, about 10 μm to about 30 μm, about 10 μm to about 40 μm, about 10 μm to about 50 μm, about 10 μm to about 75 μm, about 10 μm To about 100 μm, about 15 μm to about 20 μm, about 15 μm to about 25 μm, about 15 μm to about 30 μm, about 15 μm to about 40 μm, about 15 μm To about 50 μm, about 15 μm to about 75 μm, about 15 μm to about 100 μm, about 20 μm to about 25 μm, about 20 μm to about 30 μm, about 20 μm To about 40 μm, about 20 μm to about 50 μm, about 20 μm to about 75 μm, about 20 μm to about 100 μm, about 25 μm to about 30 μm, about 25 μm To about 40 μm, about 25 μm to about 50 μm, about 25 μm to about 75 μm, about 25 μm to about 100 μm, about 30 μm to about 40 μm, about 30 μm To about 50 μm, about 30 μm to about 75 μm, about 30 μm to about 100 μm, about 40 μm to about 50 μm, about 40 μm to about 75 μm, about 40 μm To about 100 μm, about 50 μm to about 75 μm, about 50 μm to about 100 μm, about 50 μm to about 150 μm, about 50 μm to about 200 μm, about 50 μm to about 250 μm, about 50 μm to about 300 μm, about 50 μm to about 350 μm, about 50 μm to about 400 μm, about 50 μm to about 450 μm, About 50 μm to about 500 μm, about 50 μm to about 550 μm, about 50 μm to about 600 μm, about 50 μm to about 650 μm, about 50 μm to about 700 μm, about 50 μm to about 750 μm, about 50 μm to about 800 μm, about 50 μm to about 850 μm, about 50 μm to about 900 μm, about 50 μm to about 950 μm, about 50 μm to about 1000 μm, about 100 μm to about 150 μm, about 100 μm to about 200 μm, about 100 μm to about 250 μm, about 100 μm to about 300 μm, about 100 μm to about 350 μm, about 100 μm to about 400 μm, about 100 μm to about 450 μm, about 100 μm to about 500 μm, about 100 μm to about 550 μm, about 100 μm to about 600 μm, about 100 μm to about 650 μm, about 100 μm to about 700 μm, about 100 μm to about 750 μm, about 100 μm to about 800 μm, about 100 μm to about 850 μm, about 100 μm to about 900 μm, about 100 μm to about 950 μm, about 100 μm to about 1000 μm, about 150 μm to about 200 μm, about 150 μm to about 250 μm, about 150 μm to about 300 μm, about 150 μm to about 350 μm, about 150 μm to about 400 μm, about 150 μm to about 450 μm, about 150 μm to about 500 μm, about 150 μm to about 550 μm, about 150 μm to about 600 μm, about 150 μm to about 650 μm, about 150 μm to about 700 μm, about 150 μm to about 750 μm, about 150 μm to about 800 μm, about 150 μm to about 850 μm, about 150 μm to about 900 μm, about 150 μm to about 950 μm, about 150 μm to about 1000 μm, about 200 μm to about 250 μm, about 200 μm to about 300 μm, about 200 μm to about 350 μm, about 200 μm to about 400 μm, about 200 μm to about 450 μm, about 200 μm to about 500 μm, about 200 μm to about 550 μm, about 200 μm to about 600 μm, about 200 μm to about 650 μm, about 200 μm to about 700 μm, about 200 μm to about 750 μm, about 200 μm to about 800 μm, about 200 μm to about 850 μm, about 200 μm to about 900 μm, about 200 μm to about 950 μm, about 200 μm to about 1000 μm, about 250 μm to about 300 μm, about 250 μm extremely About 350 μm, about 250 μm to about 400 μm, about 250 μm to about 450 μm, about 250 μm to about 500 μm, about 250 μm to about 550 μm, About 250 μm to about 600 μm, about 250 μm to about 650 μm, about 250 μm to about 700 μm, about 250 μm to about 750 μm, about 250 μm extremely About 800 μm, about 250 μm to about 850 μm, about 250 μm to about 900 μm, about 250 μm to about 950 μm, about 250 μm to about 1000 μm, About 300 μm to about 350 μm, about 300 μm to about 400 μm, about 300 μm to about 450 μm, about 300 μm to about 500 μm, about 300 μm extremely About 550 μm, about 300 μm to about 600 μm, about 300 μm to about 650 μm, about 300 μm to about 700 μm, about 300 μm to about 750 μm, About 300 μm to about 800 μm, about 300 μm to about 850 μm, about 300 μm to about 900 μm, about 300 μm to about 950 μm, about 300 μm extremely About 1000 μm, about 350 μm to about 400 μm, about 350 μm to about 450 μm, about 350 μm to about 500 μm, about 350 μm to about 550 μm, About 350 μm to about 600 μm, about 350 μm to about 650 μm, about 350 μm to about 700 μm, about 350 μm to about 750 μm, about 350 μm extremely About 800 μm, about 350 μm to about 850 μm, about 350 μm to about 900 μm, about 350 μm to about 950 μm, about 350 μm to about 1000 μm, About 400 μm to about 450 μm, about 400 μm to about 500 μm, about 400 μm to about 550 μm, about 400 μm to about 600 μm, about 400 μm extremely About 650 μm, about 400 μm to about 700 μm, about 400 μm to about 750 μm, about 400 μm to about 800 μm, about 400 μm to about 850 μm, About 400 μm to about 900 μm, about 400 μm to about 950 μm, about 400 μm to about 1000 μm, about 450 μm to about 500 μm, about 450 μm To about 550 μm, about 450 μm to about 600 μm, about 450 μm to about 650 μm, about 450 μm to about 700 μm, about 450 μm to about 750 μ M, about 450 μm to about 800 μm, about 450 μm to about 850 μm, about 450 μm to about 900 μm, about 450 μm to about 950 μm, about 450 μm To about 1000 μm, about 500 μm to about 550 μm, about 500 μm to about 600 μm, about 500 μm to about 650 μm, about 500 μm to about 700 μ M, about 500 μm to about 750 μm, about 500 μm to about 800 μm, about 500 μm to about 850 μm, about 500 μm to about 900 μm, about 500 μm To about 950 μm, about 500 μm to about 1000 μm, about 550 μm to about 600 μm, about 550 μm to about 650 μm, about 550 μm to about 700 μ M, about 550 μm to about 750 μm, about 550 μm to about 800 μm, about 550 μm to about 850 μm, about 550 μm to about 900 μm, about 550 μm To about 950 μm, about 550 μm to about 1000 μm, about 600 μm to about 650 μm, about 600 μm to about 700 μm, about 600 μm to about 750 μ M, about 600 μm to about 800 μm, about 600 μm to about 850 μm, about 600 μm to about 900 μm, about 600 μm to about 950 μm, about 600 μm To about 1000 μm, about 650 μm to about 700 μm, about 650 μm to about 750 μm, about 650 μm to about 800 μm, about 650 μm to about 850 μ M, about 650 μm to about 900 μm, about 650 μm to about 950 μm, about 650 μm to about 1000 μm, about 700 μm to about 750 μm, about 700 μ M to about 800 μm, about 700 μm to about 850 μm, about 700 μm to about 900 μm, about 700 μm to about 950 μm, about 700 μm to about 1000 μm, about 750 μm to about 800 μm, about 750 μm to about 850 μm, about 750 μm to about 900 μm, about 750 μm to about 950 μm, about 750 μ M to about 1000 μm, about 800 μm to about 850 μm, about 800 μm to about 900 μm, about 800 μm to about 950 μm, about 800 μm to about 1000 μm, about 850 μm to about 900 μm, about 850 μm to about 950 μm, about 850 μm to about 1000 μm, about 900 μm to about 950 μm, About 900 μm to about 1000 μm or about 950 μm to about 1000 μm.
Additive composition for paper making, method and purposes described herein will most unlikely damage mammal or environment, and And it is non-phytotoxic and can be safely applied to paper technology.In addition, additive for paper making combination described herein Object, method and purposes can indoors with outdoor application and will not soften, dissolve or otherwise negatively affect through place The surface of reason.
The aspect of this specification can also be described as follows：
1. a kind of method detaching fiber from paper pulp, the method includes in slurrying and/or during the paper production phase, having The additive composition for paper making of effect amount is applied to the paper pulp, wherein the application causes cellulose fibre to be deposited from the paper pulp Raw material increased separation, the composition includes the microorganism supernatant and one or more of processed fermentation Nonionic surface active agent, wherein the composition does not have the bacterium of any organized enzyme or work, and the wherein described composition With at most 5.0 pH.
2. one kind removing one or more of impurity and/or one or more of pollutants from paper pulp and/or paper material Method, the method includes in slurrying and/or during the paper production phase, a effective amount of additive composition for paper making is applied to The paper pulp, wherein the application cause to remove from the paper pulp and/or paper material one or more of impurity and/or The one or more pollutant, the composition include the microorganism supernatant and one or more of processed fermentation Nonionic surface active agent, wherein the composition does not have the bacterium of any organized enzyme or work, and the wherein described composition With at most 5.0 pH.
3. a kind of method for removing removal ink from paper pulp and/or paper material, the method includes in slurrying and/or paper production During stage, a effective amount of additive composition for paper making is applied to the paper pulp, wherein the application causes from the paper pulp And/or the ink is removed in paper material, the composition includes the microorganism supernatant of processed fermentation and a kind of or more A variety of nonionic surface active agent, wherein the composition does not have the bacterium of any organized enzyme or work, and wherein described group Closing object has at most 5.0 pH.
4. a effective amount of additive composition for paper making is used to detach the purposes of fiber from pulp, wherein the composition Including the microorganism supernatant of processed fermentation and one or more of nonionic surface active agent, wherein the composition There is no the bacterium of any organized enzyme or work, and the wherein described composition has at most 5.0 pH.
5. a effective amount of additive composition for paper making is used to remove one or more of impurity from paper pulp and/or paper material And/or the purposes of one or more of pollutants, wherein the composition include processed fermentation microorganism supernatant and One or more of nonionic surface active agent, wherein the composition does not have the bacterium of any organized enzyme or work, and its Described in composition have at most 5.0 pH.
6. purposes of a effective amount of additive composition for paper making for removing removal ink from paper pulp and/or paper material, wherein The composition includes the microorganism supernatant and one or more nonionic surface active agent of processed fermentation, wherein The composition does not have the bacterium of any organized enzyme or work, and the wherein described composition has at most 5.0 pH.
7. the method according to embodiment 1-3 or the purposes according to embodiment 4-6, wherein described through processing Yeast supernatants of the microorganism supernatant from fermentation of fermentation, the bacterial supernatant of fermentation, the mould supernatant of fermentation or Any combination thereof.
8. the method according to embodiment 6 or purposes, wherein the yeast supernatants of the fermentation are by belonging to below The yeast species of category generate：Brettanomyce Pseudomonas, Candida, quasi- Weir Blastocystis, the black powder Blastocystis of sporangiocyst line, Dbaly yeast Pseudomonas, moral carat Blastocystis, Fusarium, geotrichum sp category, her Sa Blastocystis, Kazakhstan's saccharomycete Category, Ke Leke Blastocystis, Kluyveromyces, lecanium Pseudomonas, Mucor, Neurospora, Pediococcus, Penicillium notatum Category, Pichia pastoris Pseudomonas, Rhizopus, rhodosporidium toruloides Pseudomonas, rhodotorula Pseudomonas, Blastocystis, Schizosccharomyces, hair spore Sub- Blastocystis has spore Torula, Torulopsis, Verticillium dahliae category, Ye Luoweiya Blastocystis, Zygosaccharomyces Pseudomonas Or Zygotorulaspora.
9. the method according to embodiment 6 or purposes, wherein the yeast supernatants of the fermentation are made wine ferment by yeast Female (Saccharomyces cerevisiae) is generated.
10. the method according to embodiment 6 or purposes, wherein the bacterial supernatant of the fermentation is by belonging to below The bacterial species of category generate：It is acetobacter, Arthrobacter, Aerococcus, Bacillus, Bifidobacterium, short shape Bacillus, short Bacillus, Barnobacterium, meat Bacillus, rodlike Pseudomonas, enterococcus spp, Colibacter, glucose acetobacter, Portugal Saccharobacillus category, Hafnia (Hafnia), Halomonas (Halomonas), Cook Pseudomonas, Lactobacillus, galactococcus Category, Leuconostoc, megacoccus category, Microbacterium, Micrococcus, neisseria, wine Coccus, Pediococcus, Propionibacterium Category, Proteus, Pseudomonas, Psychrobacter, Salmonella, lactobacillus, staphylococcus, streptococcus, Streptomyces, Tetracoccus (Tetragenococcus), Vagococcus (Vagococcus), Wei Si Bordetella or fermentation Zygosaccharomyces.
11. the method according to embodiment 6 or purposes, wherein the bacterial supernatant of the fermentation is by belonging to Aspergillus The bacterial species of category generate.
12. the method according to embodiment 1-3 or 7-11 or the purposes according to embodiment 4-11, wherein institute State the microorganism supernatant that additive composition for paper making includes the by weight at least 35% processed fermentation.
13. the method according to embodiment 1-3 or 7-12 or the purposes according to embodiment 4-12, wherein institute State the microorganism supernatant that additive composition for paper making includes the by weight at most 50% processed fermentation.
14. the method according to embodiment 1-3 or 7-13 or the purposes according to embodiment 4-13, wherein institute State nonionic surface active agent include polyethers nonionic surface active agent, polyhydroxy nonionic surface active agent and/or Nonionic biosurfactant.
15. the method according to embodiment 14 or purposes, wherein the polyhydroxy nonionic surface active agent packet Include sucrose ester, the sucrose ester of ethoxylation, sorbitol ester, the sorbitol ester of ethoxylation, alkyl-glucoside, ethyoxyl Alkyl-glucoside, polyglycerol ester or the polyglycerol ester of ethoxylation of change.
16. the method according to embodiment 1-3 or 7-15 or the purposes according to embodiment 4-15, wherein institute It includes amine oxide, the alcohol of ethoxylation, the aliphatic alcohol of ethoxylation, alkylamine, ethoxy to state nonionic surface active agent The alkylamine of base, the alkylphenol of ethoxylation, alkyl polysaccharide, the alkyl polysaccharide of ethoxylation, ethoxylation aliphatic acid, The fatty alcohol of ethoxylation or the fatty amine of ethoxylation have H (OCH2CH2)xOC6H4R1、(OCH2CH2)xOR2Or H (OCH2CH2)xOC(O)R2General formula nonionic surface active agent, wherein x expression be added into alkylphenol and/or fat The molal quantity of the ethylene oxide of alcohol or aliphatic acid, R1Indicate long chain alkyl group and R2Indicate long aliphatic radicals.
17. the method according to embodiment 16 or purposes, wherein R1It is C7-C10Alkyl group (the normal- of positive structure Alkyl group) and/or wherein R2It is C12-C20Aliphatic group.
18. the method according to embodiment 1-3 or 7-17 or the purposes according to embodiment 4-17, wherein institute State nonionic surface active agent be the nonyl phenol of ethoxylation, the octyl phenol of ethoxylation, ethoxylation cetyl Oleyl alcohol, the cetyl stearyl alcohol of ethoxylation, the decyl alcohol of ethoxylation, the lauryl alcohol of ethoxylation, ethoxylation tridecanol, Or the castor oil of ethoxylation.
19. the method according to embodiment 1-3 or 7-18 or the purposes according to embodiment 4-18, wherein institute One or more of non-ionic surfaces that additive composition for paper making includes by weight from about 1% to about 15% are stated to live Property agent.
20. according to the method described in embodiment 19, wherein the additive composition for paper making includes by weight from about 5% to about 13% one or more of nonionic surface active agent.
21. according to the method described in embodiment 20, wherein the additive composition for paper making includes by weight from about 7% to about 11% one or more of nonionic surface active agent.
22. the method according to embodiment 1-3 or 7-21 or the purposes according to embodiment 4-21, wherein institute It includes one or more of anionic surfactant to state additive composition for paper making also.
23. the method according to embodiment 22 or purposes, wherein the additive composition for paper making includes by weight One or more of anionic surfactant of meter from about 0.5% to about 10%.
24. the method according to embodiment 23 or purposes, wherein the additive composition for paper making includes by weight One or more of anionic surfactant of meter from about 1% to about 8%.
25. the method according to embodiment 24 or purposes, wherein the additive composition for paper making includes by weight One or more of anionic surfactant of meter from about 2% to about 6%.
26. the method according to embodiment 1-3 or 7-25 or the purposes according to embodiment 4-25, wherein institute It is at most 4.5 to state pH.
27. the method according to embodiment 26 or purposes, wherein the pH is about 3.7 to about 4.2.
28. the method according to embodiment 1-3 or 7-27 or the purposes according to embodiment 4-27, wherein institute It is generally nontoxic to the mankind, mammal, plant and environment to state additive composition for paper making.
29. the method according to embodiment 1-3 or 7-28 or the purposes according to embodiment 4-28, wherein institute It is biodegradable to state additive composition for paper making.
30. the method according to embodiment 1-3 or 7-29 or the purposes according to embodiment 4-29, further include Using enzymatic composition, the enzymatic composition includes digestion lignin, promotes bleaching, increase deinking, make cellulose fibre knot Structure is modified, increases effluent control, except deasphalting and goo (adhesive) and the enzyme for making starch conversion.
31. the method according to embodiment 30 or purposes, wherein the enzyme is cellulase, zytase, fat Enzyme, esterase, amylase, pectase, catalyzing enzyme, laccase, peroxidase, paper pulp enzyme DI, paper pulp enzyme RF and paper pulp enzyme BL.
32. the method according to embodiment 1-3 or 7-31 or the purposes according to embodiment 4-31, wherein institute Stating the effective quantity of additive composition for paper making leads to high pulp yield.
33. the method according to embodiment 32 or purposes, wherein the effective quantity of the additive composition for paper making Lead to pulp yield below：About 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%；Or at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least about 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% Or at least 99%；Or at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, At most 89%, at least more 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, extremely More 97%, at most 98% or at most 99%；Or about 70% to about 80%, about 70% to about 85%, about 70% to about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to about 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
34. the method according to embodiment 1-3 or 7-33 or the purposes according to embodiment 4-33, lead to height Pulp yield.
35. the method according to embodiment 34 or purposes lead to pulp yield below：About 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%；Or at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least about 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%；Or at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, at most 89%, at least more 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, at most 97%, at most 98% or at most 99%；Or about 70% To about 80%, about 70% to about 85%, about 70% to about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to About 85%, about 75% to about 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%
36. the method according to embodiment 1-3 or 7-35 or the purposes according to embodiment 4-35, wherein institute State additive composition for paper making the effective quantity cause the processing paper pulp high alpha-cellulose content.
37. the method according to embodiment 36 or purposes, wherein the effective quantity of the additive composition for paper making Lead to the alpha-cellulose content of the paper pulp of the processing below：About 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%；Or at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least about 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%；Or at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, at most 89%, at least more 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, at most 97%, at most 98% or at most 99%；Or about 70% to about 80%, about 70% to About 85%, about 70% to about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to about 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
38. the method according to embodiment 1-3 or 7-37 or the purposes according to embodiment 4-37, wherein institute State additive composition for paper making the effective quantity cause the processing paper pulp low β-cellulose content.
39. the method according to embodiment 38 or purposes, wherein the effective quantity of the additive composition for paper making Lead to the β-cellulose content of the paper pulp of the processing below：About 5%, about 10%, about 15%, about 20%, about 25%, about 30% or about 35%；Or at most 5%, at most 10%, at most 15%, at most 20%, at most 25%, at most 30% or at most 35%；Or about 5% to about 10%, about 5% to about 15%, about 5% to about 20%, about 5% to about 25%, about 5% to about 30%, About 5% to about 35%, about 10% to about 15%, about 10% to about 20%, about 10% to about 25%, about 10% to about 30%, about 10% to about 35%, about 15% to about 20%, about 15% to about 25%, about 15% to about 30%, about 15% to about 35%, about 20% to about 25%, about 20% to about 30%, about 20% to about 35%, about 25% to about 30%, about 25% to about 35% or about 30% to about 35%.
40. the method according to embodiment 1-3 or 7-39 or the purposes according to embodiment 4-39, wherein institute State additive composition for paper making the effective quantity cause the processing paper pulp low gamma cellulose content.
41. the method according to embodiment 40 or purposes, wherein the effective quantity of the additive composition for paper making Lead to the gamma cellulose content of the paper pulp of the processing below：About 5%, about 10%, about 15%, about 20%, about 25%, about 30% or about 35%；Or at most 5%, at most 10%, at most 15%, at most 20%, at most 25%, at most 30% or at most 35%；Or about 5% to about 10%, about 5% to about 15%, about 5% to about 20%, about 5% to about 25%, about 5% to about 30%, About 5% to about 35%, about 10% to about 15%, about 10% to about 20%, about 10% to about 25%, about 10% to about 30%, about 10% to about 35%, about 15% to about 20%, about 15% to about 25%, about 15% to about 30%, about 15% to about 35%, about 20% to about 25%, about 20% to about 30%, about 20% to about 35%, about 25% to about 30%, about 25% to about 35% or about 30% to about 35%.
42. the method according to embodiment 1-3 or 7-41 or the purposes according to embodiment 4-41, wherein institute State additive composition for paper making the effective quantity cause the processing paper pulp high viscosity.
43. the method according to embodiment 42 or purposes, wherein the effective quantity of the additive composition for paper making Lead to the viscosity of the paper pulp of the processing below：About 5mPas, about 10mPas, about 15mPas, about 20mPas, about 25mPas, about 30mPas, about 35mPas, about 40mPas, about 45mPas or about 50mPas；Or at least 5mPa S, at least 10mPas, at least 15mPas, at least 20mPas, at least 25mPas, at least 30mPas, at least 35mPas, at least 40mPas, at least 45mPas or at least 50mPas；Or at most 5mPas, at most 10mPas, At most 15mPas, at most 20mPas, at most 25mPas, at most 30mPas, at most 35mPas, at most 40mPa S, at most 45mPas or at most 50mPas；Or about 5mPas to about 10mPas, about 5mPas to about 15mPas, about 5mPas to about 20mPas, about 5mPas are to about 25mPas, about 5mPas to about 30mPas, about 5mPas to about 35mPas, about 5mPas to about 40mPas, about 5mPas to about 45mPas, about 5mPas to about 50mPas, about 10mPas to about 15mPas, about 10mPas are to about 20mPas, about 10mPas to about 25mPas, about 10mPas To about 30mPas, about 10mPas to about 35mPas, about 10mPas to about 40mPas, about 10mPas to about 45mPas, about 10mPas are to about 50mPas, about 15mPas to about 20mPas, about 15mPas to about 25mPa S, about 15mPas to about 30mPas, about 15mPas to about 35mPas, about 15mPas to about 40mPas, about 15mPas to about 45mPas, about 15mPas are to about 50mPas, about 20mPas to about 25mPas, about 20mPas To about 30mPas, about 20mPas to about 35mPas, about 20mPas to about 40mPas, about 20mPas to about 45mPas, about 20mPas are to about 50mPas, about 25mPas to about 30mPas, about 25mPas to about 35mPa S, about 25mPas to about 40mPas, about 25mPas to about 45mPas, about 25mPas to about 50mPas, about 30mPas to about 35mPas, about 30mPas are to about 40mPas, about 30mPas to about 45mPas, about 30mPas To about 50mPas, about 35mPas to about 40mPas, about 35mPas to about 45mPas, about 35mPas to about 50mPas, about 40mPas are to about 45mPas, about 40mPas to about 50mPas or about 45mPas to about 50mPa s。
44. the method according to embodiment 1-3 or 7-43 or the purposes according to embodiment 4-43, lead to institute State the high alpha-cellulose content of the paper pulp of processing.
45. the method according to embodiment 44 or purposes lead to the alpha-cellulose of the paper pulp of the processing below Content：About 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%；Or at least 70%, at least 75%, extremely Few 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least about 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%；Or at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, at most 89%, at least more 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, at most 97%, at most 98% Or at most 99%；Or about 70% to about 80%, about 70% to about 85%, about 70% to about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to about 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
46. the method according to embodiment 1-3 or 7-45 or the purposes according to embodiment 4-45, lead to institute State the low β-cellulose content of the paper pulp of processing.
47. the method according to embodiment 46 or purposes lead to the β-cellulose of the paper pulp of the processing below Content：About 5%, about 10%, about 15%, about 20%, about 25%, about 30% or about 35%；Or at most 5%, at most 10%, at most 15%, at most 20%, at most 25%, at most 30% or at most 35%；Or about 5% to about 10%, about 5% to about 15%, about 5% To about 20%, about 5% to about 25%, about 5% to about 30%, about 5% to about 35%, about 10% to about 15%, about 10% to about 20%, about 10% to about 25%, about 10% to about 30%, about 10% to about 35%, about 15% to about 20%, about 15% to about 25%, about 15% to about 30%, about 15% to about 35%, about 20% to about 25%, about 20% to about 30%, about 20% to about 35%, about 25% to about 30%, about 25% to about 35% or about 30% to about 35%.
48. the method according to embodiment 1-3 or 7-47 or the purposes according to embodiment 4-47, lead to institute State the low gamma cellulose content of the paper pulp of processing.
49. the method according to embodiment 48 or purposes lead to the gamma cellulose of the paper pulp of the processing below Content：About 5%, about 10%, about 15%, about 20%, about 25%, about 30% or about 35%；Or at most 5%, at most 10%, at most 15%, at most 20%, at most 25%, at most 30% or at most 35%；Or about 5% to about 10%, about 5% to about 15%, about 5% To about 20%, about 5% to about 25%, about 5% to about 30%, about 5% to about 35%, about 10% to about 15%, about 10% to about 20%, about 10% to about 25%, about 10% to about 30%, about 10% to about 35%, about 15% to about 20%, about 15% to about 25%, about 15% to about 30%, about 15% to about 35%, about 20% to about 25%, about 20% to about 30%, about 20% to about 35%, about 25% to about 30%, about 25% to about 35% or about 30% to about 35%.
50. the method according to embodiment 1-3 or 7-49 or the purposes according to embodiment 4-49, lead to institute State the high viscosity of the paper pulp of processing.
51. the method according to embodiment 50 or purposes lead to the viscosity of the paper pulp of the processing below：About 5mPas, about 10mPas, about 15mPas, about 20mPas, about 25mPas, about 30mPas, about 35mPas, about 40mPas, about 45mPas or about 50mPas；Or at least 5mPas, at least 10mPas, at least 15mPas, at least 20mPas, at least 25mPas, at least 30mPas, at least 35mPas, at least 40mPas, at least 45mPas or extremely Few 50mPas；Or at most 5mPas, at most 10mPas, at most 15mPas, at most 20mPas, at most 25mPas, At most 30mPas, at most 35mPas, at most 40mPas, at most 45mPas or at most 50mPas；Or about 5mPas To about 10mPas, about 5mPas to about 15mPas, about 5mPas to about 20mPas, about 5mPas to about 25mPa S, about 5mPas to about 30mPas, about 5mPas are to about 35mPas, about 5mPas to about 40mPas, about 5mPas To about 45mPas, about 5mPas to about 50mPas, about 10mPas to about 15mPas, about 10mPas to about 20mPas, about 10mPas are to about 25mPas, about 10mPas to about 30mPas, about 10mPas to about 35mPa S, about 10mPas to about 40mPas, about 10mPas to about 45mPas, about 10mPas to about 50mPas, about 15mPas to about 20mPas, about 15mPas are to about 25mPas, about 15mPas to about 30mPas, about 15mPas To about 35mPas, about 15mPas to about 40mPas, about 15mPas to about 45mPas, about 15mPas to about 50mPas, about 20mPas are to about 25mPas, about 20mPas to about 30mPas, about 20mPas to about 35mPa S, about 20mPas to about 40mPas, about 20mPas to about 45mPas, about 20mPas to about 50mPas, about 25mPas to about 30mPas, about 25mPas are to about 35mPas, about 25mPas to about 40mPas, about 25mPas To about 45mPas, about 25mPas to about 50mPas, about 30mPas to about 35mPas, about 30mPas to about 40mPas, about 30mPas are to about 45mPas, about 30mPas to about 50mPas, about 35mPas to about 40mPa S, about 35mPas to about 45mPas, about 35mPas to about 50mPas, about 40mPas to about 45mPas, about 40mPas to about 50mPas or about 45mPas to about 50mPas.
52. the method according to embodiment 1-3 or 7-51 or the purposes according to embodiment 4-51, wherein institute State additive composition for paper making the effective quantity cause the processing paper pulp low content of lignin.
53. the method according to embodiment 52 or purposes, wherein the effective quantity of the additive composition for paper making Lead to the content of lignin of the paper pulp of the processing with Kappa number below：About 5, about 10, about 15, about 20, about 25, about 30, about 35, about 40, about or about 50；Or at least 5, at least 10, at least 15, at least 20, at least 25, at least 30, at least 35, at least 40, at least 45 or at least 50；Or at most 5, at most 10, at most 15, at most 20, at most 25, at most 30, at most 35, at most 40, extremely More 45 or at most 50；Or about 5 to about 10, about 5 to about 15, about 5 to about 20, about 5 to about 25, about 5 to about 30, about 5 to about 35, about 5 to about 40, about 5 to about 45, about 5 to about 50, about 10 to about 15, about 10 to about 20, about 10 to about 25, about 10 to about 30, about 10 To about 35, about 10 to about 40, about 10 to about 45, about 10 to about 50, about 15 to about 20, about 15 to about 25, about 15 to about 30, about 15 To about 35, about 15 to about 40, about 15 to about 45, about 15 to about 50, about 20 to about 25, about 20 to about 30, about 20 to about 35, about 20 To about 40, about 20 to about 45, about 20 to about 50, about 25 to about 30, about 25 to about 35, about 25 to about 40, about 25 to about 45, about 25 To about 50, about 30 to about 35, about 30 to about 40, about 30 to about 45, about 30 to about 50, about 35 to about 40, about 35 to about 45, about 35 To about 50, about 40 to about 45, about 40 to about 50 or about 45 to about 50.
54. the method according to embodiment 1-3 or 7-53 or the purposes according to embodiment 4-53, lead to institute State the low content of lignin of the paper pulp of processing.
55. the method according to embodiment 54 or purposes lead to the paper of the processing with Kappa number below The content of lignin of slurry：About 5, about 10, about 15, about 20, about 25, about 30, about 35, about 40, about or about 50；Or at least 5, at least 10, at least 15, at least 20, at least 25, at least 30, at least 35, at least 40, at least 45 or at least 50；Or at most 5, at most 10, extremely More 15, at most 20, at most 25, at most 30, at most 35, at most 40, at most 45 or at most 50；Or about 5 to about 10, about 5 to about 15, About 5 to about 20, about 5 to about 25, about 5 to about 30, about 5 to about 35, about 5 to about 40, about 5 to about 45, about 5 to about 50, about 10 to About 15, about 10 to about 20, about 10 to about 25, about 10 to about 30, about 10 to about 35, about 10 to about 40, about 10 to about 45, about 10 to About 50, about 15 to about 20, about 15 to about 25, about 15 to about 30, about 15 to about 35, about 15 to about 40, about 15 to about 45, about 15 to About 50, about 20 to about 25, about 20 to about 30, about 20 to about 35, about 20 to about 40, about 20 to about 45, about 20 to about 50, about 25 to About 30, about 25 to about 35, about 25 to about 40, about 25 to about 45, about 25 to about 50, about 30 to about 35, about 30 to about 40, about 30 to About 45, about 30 to about 50, about 35 to about 40, about 35 to about 45, about 35 to about 50, about 40 to about 45, about 40 to about 50 or about 45 To about 50.
56. the method according to embodiment 1-3 or 7-55 or the purposes according to embodiment 4-55, wherein institute State additive composition for paper making the effective quantity cause the processing paper pulp low impurity content.
57. the method according to embodiment 56 or purposes, wherein the effective quantity of the additive composition for paper making Lead to the low impurity content of the paper pulp of the processing with copper number below：About 0.5, about 0.75, about 1.0, about 1.25, about 1.5, about 1.75, about 2.0, about 2.25, about 2.5, about 2.75, about 3.0, about 3.25, about 3.5, about 3.75, about 4.0, about 4.25, About 4.5, about 4.75, about 5.0, about 5.25, about 5.5, about 5.75, about 6.0, about 6.25, about 6.5, about 6.75 or about 7.0；Or extremely Few 0.5, at least 0.75, at least 1.0, at least 1.25, at least 1.5, at least 1.75, at least 2.0, at least 2.25, at least 2.5, extremely Few 2.75, at least 3.0, at least 3.25, at least 3.5, at least 3.75, at least 4.0, at least 4.25, at least 4.5, at least 4.75, extremely Few 5.0, at least 5.25, at least 5.5, at least 5.75, at least 6.0, at least 6.25, at least 6.5, at least 6.75 or at least 7.0；Or At most 0.5, at most 0.75, at most 1.0, at most 1.25, at most 1.5, at most 1.75, at most 2.0, at most 2.25, at most 2.5, At most 2.75, at most 3.0, at most 3.25, at most 3.5, at most 3.75, at most 4.0, at most 4.25, at most 4.5, at most 4.75, At most 5.0, at most 5.25, at most 5.5, at most 5.75, at most 6.0, at most 6.25, at most 6.5, at most 6.75 or at most 7.0； Or about 0.5 to about 1.0, about 0.5 to about 2.0, about 0.5 to about 3.0, about 0.5 to about 4.0, about 0.5 to about 5.0, about 0.5 to about 6.0, about 0.5 to about 7.0, about 0.75 to about 1.0, about 0.75 to about 2.0, about 0.75 to about 3.0, about 0.75 to about 4.0, about 0.75 to about 5.0, about 0.75 to about 6.0, about 0.75 to about 7.0, about 1.0 to about 2.0, about 1.0 to about 3.0, about 1.0 to about 4.0, about 1.0 to about 5.0, about 1.0 to about 6.0, about 1.0 to about 7.0, about 1.25 to about 2.0, about 1.25 to about 3.0, about 1.25 To about 4.0, about 1.25 to about 5.0, about 1.25 to about 6.0, about 1.25 to about 7.0, about 1.5 to about 2.0, about 1.5 to about 3.0, About 1.5 to about 4.0, about 1.5 to about 5.0, about 1.5 to about 6.0, about 1.5 to about 7.0, about 1.75 to about 2.0, about 1.75 to about 3.0, about 1.75 to about 4.0, about 1.75 to about 5.0, about 1.75 to about 6.0, about 1.75 to about 7.0, about 2 to about 3.0, about 2 to About 4.0, about 2 to about 5.0, about 2 to about 6.0 or about 2 to about 7.0.
58. the method according to embodiment 1-3 or 7-57 or the purposes according to embodiment 4-57, lead to institute State the low impurity content of the paper pulp of processing.
59. the method according to embodiment 58 or purposes lead to the paper pulp of the processing with copper number below Low impurity content：About 0.5, about 0.75, about 1.0, about 1.25, about 1.5, about 1.75, about 2.0, about 2.25, about 2.5, about 2.75, about 3.0, about 3.25, about 3.5, about 3.75, about 4.0, about 4.25, about 4.5, about 4.75, about 5.0, about 5.25, about 5.5, About 5.75, about 6.0, about 6.25, about 6.5, about 6.75 or about 7.0；Or at least 0.5, at least 0.75, at least 1.0, at least 1.25, At least 1.5, at least 1.75, at least 2.0, at least 2.25, at least 2.5, at least 2.75, at least 3.0, at least 3.25, at least 3.5, At least 3.75, at least 4.0, at least 4.25, at least 4.5, at least 4.75, at least 5.0, at least 5.25, at least 5.5, at least 5.75, At least 6.0, at least 6.25, at least 6.5, at least 6.75 or at least 7.0；Or at most 0.5, at most 0.75, at most 1.0, at most 1.25, at most 1.5, at most 1.75, at most 2.0, at most 2.25, at most 2.5, at most 2.75, at most 3.0, at most 3.25, at most 3.5, at most 3.75, at most 4.0, at most 4.25, at most 4.5, at most 4.75, at most 5.0, at most 5.25, at most 5.5, at most 5.75, at most 6.0, at most 6.25, at most 6.5, at most 6.75 or at most 7.0；Or about 0.5 to about 1.0, about 0.5 to about 2.0, About 0.5 to about 3.0, about 0.5 to about 4.0, about 0.5 to about 5.0, about 0.5 to about 6.0, about 0.5 to about 7.0, about 0.75 to about 1.0, about 0.75 to about 2.0, about 0.75 to about 3.0, about 0.75 to about 4.0, about 0.75 to about 5.0, about 0.75 to about 6.0, about 0.75 to about 7.0, about 1.0 to about 2.0, about 1.0 to about 3.0, about 1.0 to about 4.0, about 1.0 to about 5.0, about 1.0 to about 6.0, About 1.0 to about 7.0, about 1.25 to about 2.0, about 1.25 to about 3.0, about 1.25 to about 4.0, about 1.25 to about 5.0, about 1.25 to About 6.0, about 1.25 to about 7.0, about 1.5 to about 2.0, about 1.5 to about 3.0, about 1.5 to about 4.0, about 1.5 to about 5.0, about 1.5 To about 6.0, about 1.5 to about 7.0, about 1.75 to about 2.0, about 1.75 to about 3.0, about 1.75 to about 4.0, about 1.75 to about 5.0, About 1.75 to about 6.0, about 1.75 to about 7.0, about 2 to about 3.0, about 2 to about 4.0, about 2 to about 5.0, about 2 to about 6.0 or about 2 To about 7.0.
60. the method according to embodiment 1-3 or 7-59 or the purposes according to embodiment 4-59, wherein institute State additive composition for paper making the effective quantity cause the processing paper pulp high-carboxyl-content.
61. the method according to embodiment 60 or purposes, wherein the effective quantity of the additive composition for paper making Lead to the carboxyl-content of the paper pulp of the processing below：About 4meq/100g paper pulp, about 4.5meq/100g paper pulp, about 5meq/ 100g paper pulp, about 5.5meq/100g paper pulp, about 6meq/100g paper pulp, about 6.5meq/100g paper pulp, about 7meq/100g paper pulp, About 7.5meq/100g paper pulp, about 8meq/100g paper pulp, about 8.5meq/100g paper pulp, about 9meq/100g paper pulp, about 9.5meq/ 100g paper pulp or about 10meq/100g paper pulp；Or at least 4meq/100g paper pulp, at least 4.5meq/100g paper pulp, at least 5meq/ 100g paper pulp, at least 5.5meq/100g paper pulp, at least 6meq/100g paper pulp, at least 6.5meq/100g paper pulp, at least 7meq/ 100g paper pulp, at least 7.5meq/100g paper pulp, at least 8meq/100g paper pulp, at least 8.5meq/100g paper pulp, at least 9meq/ 100g paper pulp, at least 9.5meq/100g paper pulp or at least 10meq/100g paper pulp；Or at most 4meq/100g paper pulp, at most 4.5meq/100g paper pulp, at most 5meq/100g paper pulp, at most 5.5meq/100g paper pulp, at most 6meq/100g paper pulp, at most 6.5meq/100g paper pulp, at most 7meq/100g paper pulp, at most 7.5meq/100g paper pulp, at most 8meq/100g paper pulp, at most 8.5meq/100g paper pulp, at most 9meq/100g paper pulp, at most 9.5meq/100g paper pulp or at most 10meq/100g paper pulp；Or About 4meq/100g paper pulp is to about 5meq/100g paper pulp, about 4meq/100g paper pulp to about 6meq/100g paper pulp, about 4meq/100g Paper pulp is to about 7meq/100g paper pulp, about 4meq/100g paper pulp to about 8meq/100g paper pulp, about 4meq/100g paper pulp to about 9meq/100g paper pulp, about 4meq/100g paper pulp to about 10meq/100g paper pulp, about 5meq/100g paper pulp to about 6meq/100g Paper pulp, about 5meq/100g paper pulp to about 7meq/100g paper pulp, about 5meq/100g paper pulp to about 8meq/100g paper pulp, about 5meq/100g paper pulp is to about 9meq/100g paper pulp, about 5meq/100g paper pulp to about 10meq/100g paper pulp, about 6meq/100g Paper pulp is to about 7meq/100g paper pulp, about 6meq/100g paper pulp to about 8meq/100g paper pulp, about 6meq/100g paper pulp to about 9meq/100g paper pulp, about 6meq/100g paper pulp to about 10meq/100g paper pulp, about 7meq/100g paper pulp to about 8meq/100g Paper pulp, about 7meq/100g paper pulp to about 9meq/100g paper pulp, about 7meq/100g paper pulp to about 10meq/100g paper pulp, about 8meq/100g paper pulp is to about 9meq/100g paper pulp, about 8meq/100g paper pulp to about 10meq/100g paper pulp or about 9meq/100g Paper pulp is to about 10meq/100g paper pulp.
62. the method according to embodiment 1-3 or 7-61 or the purposes according to embodiment 4-61, lead to institute State the high-carboxyl-content of the paper pulp of processing.
63. the method according to embodiment 62 or purposes lead to the carboxyl-content of the paper pulp of the processing below： About 4meq/100g paper pulp, about 4.5meq/100g paper pulp, about 5meq/100g paper pulp, about 5.5meq/100g paper pulp, about 6meq/ 100g paper pulp, about 6.5meq/100g paper pulp, about 7meq/100g paper pulp, about 7.5meq/100g paper pulp, about 8meq/100g paper pulp, About 8.5meq/100g paper pulp, about 9meq/100g paper pulp, about 9.5meq/100g paper pulp or about 10meq/100g paper pulp；Or at least 4meq/100g paper pulp, at least 4.5meq/100g paper pulp, at least 5meq/100g paper pulp, at least 5.5meq/100g paper pulp, at least 6meq/100g paper pulp, at least 6.5meq/100g paper pulp, at least 7meq/100g paper pulp, at least 7.5meq/100g paper pulp, at least 8meq/100g paper pulp, at least 8.5meq/100g paper pulp, at least 9meq/100g paper pulp, at least 9.5meq/100g paper pulp or at least 10meq/100g paper pulp；Or at most 4meq/100g paper pulp, at most 4.5meq/100g paper pulp, at most 5meq/100g paper pulp, at most 5.5meq/100g paper pulp, at most 6meq/100g paper pulp, at most 6.5meq/100g paper pulp, at most 7meq/100g paper pulp, at most 7.5meq/100g paper pulp, at most 8meq/100g paper pulp, at most 8.5meq/100g paper pulp, at most 9meq/100g paper pulp, at most 9.5meq/100g paper pulp or at most 10meq/100g paper pulp；Or about 4meq/100g paper pulp to about 5meq/100g paper pulp, about 4meq/100g paper pulp is to about 6meq/100g paper pulp, about 4meq/100g paper pulp to about 7meq/100g paper pulp, about 4meq/100g paper Slurry is to about 8meq/100g paper pulp, about 4meq/100g paper pulp to about 9meq/100g paper pulp, about 4meq/100g paper pulp to about 10meq/100g paper pulp, about 5meq/100g paper pulp to about 6meq/100g paper pulp, about 5meq/100g paper pulp to about 7meq/100g Paper pulp, about 5meq/100g paper pulp to about 8meq/100g paper pulp, about 5meq/100g paper pulp to about 9meq/100g paper pulp, about 5meq/100g paper pulp is to about 10meq/100g paper pulp, about 6meq/100g paper pulp to about 7meq/100g paper pulp, about 6meq/100g Paper pulp is to about 8meq/100g paper pulp, about 6meq/100g paper pulp to about 9meq/100g paper pulp, about 6meq/100g paper pulp to about 10meq/100g paper pulp, about 7meq/100g paper pulp to about 8meq/100g paper pulp, about 7meq/100g paper pulp to about 9meq/100g Paper pulp, about 7meq/100g paper pulp to about 10meq/100g paper pulp, about 8meq/100g paper pulp to about 9meq/100g paper pulp, about 8meq/100g paper pulp is to about 10meq/100g paper pulp or about 9meq/100g paper pulp to about 10meq/100g paper pulp.
64. the method according to embodiment 1-3 or 7-63 or the purposes according to embodiment 4-63, wherein institute Stating the effective quantity of additive composition for paper making leads to the paper pulp of the processing or the high brightness of paper material.
65. the method according to embodiment 64 or purposes, wherein the effective quantity of the additive composition for paper making Lead to the paper pulp of the processing below or the brightness of paper material：About 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%；Or at least 70%, at least 75%, at least 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least about 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%；Or at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, at most 89%, at least more 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, at most 97%, at most 98% or at most 99%；Or about 70% to about 80%, about 70% to About 85%, about 70% to about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to about 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
66. the method according to embodiment 1-3 or 7-65 or the purposes according to embodiment 4-65, lead to institute State the paper pulp of processing or the high brightness of paper material.
67. the method according to embodiment 66 or purposes, lead to the paper pulp or paper material of the processing below Brightness：About 70%, about 75%, about 80%, about 85%, about 86%, about 87%, about 88%, about 89%, about 90%, about 91%, about 92%, about 93%, about 94%, about 95%, about 96%, about 97%, about 98% or about 99%；Or at least 70%, at least 75%, extremely Few 80%, at least 85%, at least 86%, at least 87%, at least 88%, at least 89%, at least about 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at least 96%, at least 97%, at least 98% or at least 99%；Or at most 70%, at most 75%, at most 80%, at most 85%, at most 86%, at most 87%, at most 88%, at most 89%, at least more 90%, at most 91%, at most 92%, at most 93%, at most 94%, at most 95%, at most 96%, at most 97%, at most 98% Or at most 99%；Or about 70% to about 80%, about 70% to about 85%, about 70% to about 90%, about 70% to about 95%, about 70% to about 99%, about 75% to about 85%, about 75% to about 90%, about 75% to about 95%, about 75% to about 99%, about 80% to about 90%, about 80% to about 95%, about 80% to about 99%, about 85% to about 93%, about 85% to about 95%, about 85% to about 97%, about 85% to about 99%, about 90% to about 93%, about 90% to about 95%, about 90% to about 97%, about 90% to about 99%, about 93% to about 95%, about 93% to about 97%, about 93% to about 99%, about 95% to about 97% or about 95% to about 99%.
68. the method according to embodiment 1-3 or 7-67 or the purposes according to embodiment 4-67, wherein institute Stating the effective quantity of additive composition for paper making leads to the paper pulp of the processing or the low extractive content of paper material.
69. the method according to embodiment 68 or purposes, wherein the effective quantity of the additive composition for paper making Lead to the paper pulp of the processing below or the extractive content of paper material：About 0.01%, about 0.02%, about 0.03%, about 0.04%, about 0.05%, about 0.06%, about 0.07%, about 0.08%, about 0.09%, about 0.1%, about 0.2%, about 0.3%, About 0.4%, about 0.5%, about 0.6%, about 0.7%, about 0.8%, about 0.9%, about 1%, about 2%, about 3%, about 4% or about 5%；Or at most 0.01%, at most 0.02%, at most 0.03%, at most 0.04%, at most 0.05%, at most 0.06%, at most 0.07%, at most 0.08%, at most 0.09%, at most 0.1%, at most 0.2%, at most 0.3%, at most 0.4%, at most 0.5%, at most 0.6%, at most 0.7%, at most 0.8%, at most 0.9%, at most 1%, at most 2%, at most 3%, at most 4% Or at most 5%；Or about 0.001% to about 0.005%, about 0.001% to about 0.01%, about 0.001% to about 0.05%, about 0.001% to about 0.1%, about 0.001% to about 0.5%, about 0.001% to about 1%, about 0.001% to about 5%, about 0.005% to about 0.01%, about 0.005% to about 0.05%, about 0.005% to about 0.1%, about 0.005% to about 0.5%, About 0.005% to about 1%, about 0.005% to about 5%, about 0.01% to about 0.05%, about 0.01% to about 0.1%, about 0.01% to about 0.5%, about 0.01% to about 1%, about 0.01% to about 5%, about 0.05% to about 0.1%, about 0.05% to About 0.5%, about 0.05% to about 1%, about 0.05% to about 5%, about 0.1% to about 0.5%, about 0.1% to about 1%, about 0.1% to about 5%, about 0.5% to about 1%, about 0.5% to about 5% or about 1% to about 5%.
70. the method according to embodiment 1-3 or 7-69 or the purposes according to embodiment 4-69, lead to institute State the paper pulp of processing or the low extractive content of paper material.
71. the method according to embodiment 70 or purposes, lead to the paper pulp or paper material of the processing below Extractive content：About 0.01%, about 0.02%, about 0.03%, about 0.04%, about 0.05%, about 0.06%, about 0.07%, about 0.08%, about 0.09%, about 0.1%, about 0.2%, about 0.3%, about 0.4%, about 0.5%, about 0.6%, about 0.7%, about 0.8%, about 0.9%, about 1%, about 2%, about 3%, about 4% or about 5%；Or at most 0.01%, at most 0.02%, at most 0.03%, at most 0.04%, at most 0.05%, at most 0.06%, at most 0.07%, at most 0.08%, at most 0.09%, at most 0.1%, at most 0.2%, at most 0.3%, at most 0.4%, at most 0.5%, at most 0.6%, at most 0.7%, at most 0.8%, At most 0.9%, at most 1%, at most 2%, at most 3%, at most 4% or at most 5%；Or about 0.001% to about 0.005%, about 0.001% to about 0.01%, about 0.001% to about 0.05%, about 0.001% to about 0.1%, about 0.001% to about 0.5%, About 0.001% to about 1%, about 0.001% to about 5%, about 0.005% to about 0.01%, about 0.005% to about 0.05%, about 0.005% to about 0.1%, about 0.005% to about 0.5%, about 0.005% to about 1%, about 0.005% to about 5%, about 0.01% to about 0.05%, about 0.01% to about 0.1%, about 0.01% to about 0.5%, about 0.01% to about 1%, about 0.01% To about 5%, about 0.05% to about 0.1%, about 0.05% to about 0.5%, about 0.05% to about 1%, about 0.05% to about 5%, About 0.1% to about 0.5%, about 0.1% to about 1%, about 0.1% to about 5%, about 0.5% to about 1%, about 0.5% to about 5% Or about 1% to about 5%.
72. the method according to embodiment 1-3 or 7-71 or the purposes according to embodiment 4-71, wherein institute The effective quantity for stating additive composition for paper making is additive composition for paper making below:Diluent ratio：About 1:50, about 1: 75, about 1:100, about 1:125, about 1:150, about 1:175, about 1:200, about 1:225, about 1:250, about 1:275, about 1:300, about 1:325, about 1:350, about 1:375, about 1:400, about 1:425, about 1:450, about 1:475, about 1:500, about 1:525, about 1: 550, about 1:575 or about 1:600；Or at least 1:50, at least 1:75, at least 1:100, at least 1:125, at least 1:150, at least 1: 175, at least 1:200, at least 1:225, at least 1:250, at least 1:275, at least 1:300, at least 1:325, at least 1:350, extremely Few 1:375, at least 1:400, at least 1:425, at least 1:450, at least 1:475, at least 1:500, at least 1:525, at least 1: 550, at least 1:575 or at most 1:600；Or at most 1:50, at most 1:75, at most 1:100, at most 1:125, at most 1:150, extremely More 1:175, at most 1:200, at most 1:225, at most 1:250, at most 1:275, at most 1:300, at most 1:325, at most 1: 350, at most 1:375, at most 1:400, at most 1:425, at most 1:450, at most 1:475, at most 1:500, at most 1:525, extremely More 1:550, at most 1:575 or at most 1:600；Or about 1:50 to about 1:100, about 1:50 to about 1:200, about 1:50 to about 1: 300, about 1:50 to about 1:400, about 1:50 to about 1:500, about 1:50 to about 1:600, about 1:100 to about 1:200, about 1:100 To about 1:300, about 1:100 to about 1:400, about 1:100 to about 1:500, about 1:100 to about 1:600, about 1:200 to about 1: 300, about 1:200 to about 1:400, about 1:200 to about 1:500, about 1:200 to about 1:600, about 1:300 to about 1:400, about 1: 300 to about 1:500, about 1:300 to about 1:600, about 1:400 to about 1:500, about 1:400 to about 1:600 or about 1:500 to about 1:600。
73. the method according to embodiment 1-3 or 7-71 or the purposes according to embodiment 4-71, wherein institute The effective quantity for stating additive composition for paper making is additive composition for paper making below:Diluent ratio：About 1:500, about 1: 750, about 1:1000, about 1:1250, about 1:1500, about 1:1750, about 1:2000, about 1:2250, about 1:2500, about 1:2750、 About 1:3000, about 1:3250, about 1:3500, about 1:3750, about 1:4000, about 1:4250, about 1:4500, about 1:4750, about 1: 5000, about 1:5250, about 1:5500, about 1:5750, about 1:6000, about 1:7000, about 1:8000, about 1:9000 or about 1: 10000；Or at least 1:500, at least 1:750, at least 1:1000, at least 1:1250, at least 1:1500, at least 1:1750, at least 1:2000, at least 1:2250, at least 1:2500, at least 1:2750, at least 1:3000, at least 1:3250, at least 1:3500, at least 1:3750, at least 1:4000, at least 1:4250, at least 1:4500, at least 1:4750, at least 1:5000, at least 1:5250, at least 1:5500, at least 1:5750, at least 1:6000, at least 1:7000, at least 1:8000, at least 1:9000 or at least 1:10000；Or At most 1:500, at most 1:750, at most 1:1000, at most 1:1250, at most 1:1500, at most 1:1750, at most 1:2000, extremely More 1:2250, at most 1:2500, at most 1:2750, at most 1:3000, at most 1:3250, at most 1:3500, at most 1:3750, extremely More 1:4000, at most 1:4250, at most 1:4500, at most 1:4750, at most 1:5000, at most 1:5250, at most 1:5500, extremely More 1:5750, at most 1:6000, at most 1:7000, at most 1:8000, at most 1:9000 or at most 1:10000；Or about 1:500 to About 1:1000, about 1:500 to about 1:2000, about 1:500 to about 1:3000, about 1:500 to about 1:4000, about 1:500 to about 1: 5000, about 1:500 to about 1:6000, about 1:500 to about 1:7000, about 1:500 to about 1:8000, about 1:500 to about 1:9000、 About 1:500 to about 1:10000, about 1:1000 to about 1:2000, about 1:1000 to about 1:3000, about 1:1000 to about 1:4000、 About 1:1000 to about 1:5000, about 1:1000 to about 1:6000, about 1:1000 to about 1:7000, about 1:1000 to about 1:8000、 About 1:1000 to about 1:9000, about 1:1000 to about 1:10000, about 1:2000 to about 1:3000, about 1:2000 to about 1:4000、 About 1:2000 to about 1:5000, about 1:2000 to about 1:6000, about 1:2000 to about 1:7000, about 1:2000 to about 1:8000、 About 1:2000 to about 1:9000, about 1:2000 to about 1:10000, about 1:3000 to about 1:4000, about 1:3000 to about 1:5000、 About 1:3000 to about 1:6000, about 1:3000 to about 1:7000, about 1:3000 to about 1:8000, about 1:3000 to about 1:9000、 About 1:3000 to about 1:10000, about 1:4000 to about 1:5000, about 1:4000 to about 1:6000, about 1:4000 to about 1:7000、 About 1:4000 to about 1:8000, about 1:4000 to about 1:9000, about 1:4000 to about 1:10000, about 1:5000 to about 1:6000、 About 1:5000 to about 1:7000, about 1:5000 to about 1:8000, about 1:5000 to about 1:9000, about 1:5000 to about 1:10000、 About 1:6000 to about 1:7000, about 1:6000 to about 1:8000, about 1:6000 to about 1:9000, about 1:6000 to about 1:10000、 About 1:7000 to about 1:8000, about 1:7000 to about 1:9000, about 1:7000 to about 1:10000, about 1:8000 to about 1:9000、 About 1:8000 to about 1:10000 or about 1:9000 to about 1:10000.
74. the method according to embodiment 1-3 or 7-73 or the purposes according to embodiment 4-73, wherein institute The effective quantity for stating additive composition for paper making has ultimate density below：About 0.0001%, about 0.0002%, about 0.0003%, about 0.0004%, about 0.0005%, about 0.0006%, about 0.0007%, about 0.0008%, about 0.0009%, about 0.001%, about 0.002%, about 0.003%, about 0.004%, about 0.005%, about 0.006%, about 0.007%, about 0.008%, about 0.009%, about 0.01%, about 0.02%, about 0.03%, about 0.04%, about 0.05%, about 0.06%, about 0.07%, about 0.08%, about 0.09%, about 0.1%, about 0.2%, about 0.3%, about 0.4%, about 0.5%, about 0.6%, about 0.7%, about 0.8%, about 0.9%, about 1%, about 2%, about 3%, about 4%, about 5%, about 6%, about 7%, about 8%, about 9% or About 10%；Or at least 0.0001%, at least 0.0002%, at least 0.0003%, at least 0.0004%, at least 0.0005%, extremely Few 0.0006%, at least 0.0007%, at least 0.0008%, at least 0.0009%, at least 0.001%, at least 0.002%, extremely Few 0.003%, at least 0.004%, at least 0.005%, at least 0.006%, at least 0.007%, at least 0.008%, at least 0.009%, at least 0.01%, at least 0.02%, at least 0.03%, at least 0.04%, at least 0.05%, at least 0.06%, extremely Few 0.07%, at least 0.08%, at least 0.09%, at least 0.1%, at least 0.2%, at least 0.3%, at least 0.4%, at least 0.5%, at least 0.6%, at least 0.7%, at least 0.8%, at least 0.9%, at least 1%, at least 2%, at least 3%, at least 4%, at least 5%, at least 6%, at least 7%, at least 8%, at least 9% or at least 10%；Or at most 0.0001%, at most 0.0002%, at most 0.0003%, at most 0.0004%, at most 0.0005%, at most 0.0006%, at most 0.0007%, extremely More 0.0008%, at most 0.0009%, at most 0.001%, at most 0.002%, at most 0.003%, at most 0.004%, at most 0.005%, at most 0.006%, at most 0.007%, at most 0.008%, at most 0.009%, at most 0.01%, at most 0.02%, at most 0.03%, at most 0.04%, at most 0.05%, at most 0.06%, at most 0.07%, at most 0.08%, at most 0.09%, at most 0.1%, at most 0.2%, at most 0.3%, at most 0.4%, at most 0.5%, at most 0.6%, at most 0.7%, At most 0.8%, at most 0.9%, at most 1%, at most 2%, at most 3%, at most 4%, at most 5%, at most 6%, at most 7%, At most 8%, at most 9% or at most 10%；Or about 0.0001% to about 0.0005%, about 0.0001% to about 0.001%, about 0.0001% to about 0.005%, about 0.0001% to about 0.01%, about 0.0001% to about 0.05%, about 0.0001% to about 0.1%, about 0.0001% to about 0.5%, about 0.0001% to about 1%, about 0.0001% to about 5%, about 0.0001% to about 10%, about 0.0005% to about 0.001%, about 0.0005% to about 0.005%, about 0.0005% to about 0.01%, about 0.0005% to about 0.05%, about 0.0005% to about 0.1%, about 0.0005% to about 0.5%, about 0.0005% to about 1%, About 0.0005% to about 5%, about 0.0005% to about 10%, about 0.001% to about 0.005%, about 0.001% to about 0.01%, 0.001% to about 0.05%, about 0.001% to about 0.1%, 0.001% to about 0.5%, 0.001% to about 1%, 0.001% to about 5%, about 0.001% to about 10%, about 0.005% to about 0.01%, about 0.005% to about 0.05%, about 0.005% to about 0.1%, about 0.005% to about 0.5%, about 0.005% to about 1%, about 0.005% to about 5%, about 0.005% to about 10%, about 0.01% to about 0.05%, about 0.01% to about 0.1%, about 0.01% to about 0.5%, about 0.01% to about 1%, about 0.01% to about 5%, about 0.01% to about 10%, about 0.05% to about 0.1%, about 0.05% to about 0.5%, about 0.05% to about 1%, about 0.05% to about 5%, about 0.05% to about 10%, about 0.1% to about 0.5%, about 0.1% to about 1%, about 0.1% to about 5%, about 0.1% to about 10%, about 0.5% to about 1%, about 0.5% to about 5%, about 0.5% to about 10%, about 1% to about 5%, about 1% to about 10% or about 5% to about 10%.
75. a kind of additive composition for paper making includes the microorganism supernatant and one or more of processed fermentation Nonionic surface active agent, wherein the composition does not have the bacterium of any organized enzyme or work, and the wherein described composition With the pH less than 5.0.
76. according to the additive composition for paper making described in embodiment 75, wherein the microorganism of the processed fermentation Yeast supernatants of the supernatant from fermentation, the bacterial supernatant of fermentation, fermentation mould supernatant.
77. according to the additive composition for paper making described in embodiment 76, wherein the yeast supernatants of the fermentation are by belonging to It is generated in the yeast species of category below：Brettanomyce Pseudomonas, Candida, quasi- Weir Blastocystis, the black powder of sporangiocyst line Blastocystis, Dbaly yeast Pseudomonas, moral carat Blastocystis, Fusarium, geotrichum sp category, her Sa Blastocystis, Kazak This smooth Blastocystis, Ke Leke Blastocystis, Kluyveromyces, lecanium Pseudomonas, Mucor, Neurospora, piece coccus Category, Penicillium, Pichia pastoris Pseudomonas, Rhizopus, rhodosporidium toruloides Pseudomonas, rhodotorula Pseudomonas, Blastocystis, fission yeast Pseudomonas, hair spore Blastocystis have spore Torula, Torulopsis, Verticillium dahliae category, Ye Luoweiya Blastocystis, connect Close Blastocystis or Zygotorulaspora.
78. according to the additive composition for paper making described in embodiment 77, wherein the yeast supernatants of the fermentation are by ferment Female saccharomyces cerevisiae generates.
79. according to the additive composition for paper making described in embodiment 78, wherein the bacterial supernatant of the fermentation is by belonging to It is generated in the bacterial species of category below：Acetobacter, Arthrobacter, Aerococcus, Bacillus, Bifidobacterium, short shape Bacillus, brevibacterium, Barnobacterium, meat Bacillus, rodlike Pseudomonas, enterococcus spp, Colibacter, glucose acetic acid Bacillus, Gluconobacter, Hafnia (Hafnia), Halomonas (Halomonas), Cook Pseudomonas, Bacillus acidi lactici Category, lactococcus, Leuconostoc, megacoccus category, Microbacterium, Micrococcus, neisseria, wine Coccus, Pediococcus, Propionibacterium, Proteus, Pseudomonas, Psychrobacter, Salmonella, lactobacillus, staphylococcus, chain Coccus, streptomyces, Tetracoccus (Tetragenococcus), Vagococcus (Vagococcus), Wei Si Bordetella Or zymomonas.
80. according to the additive composition for paper making described in embodiment 79, wherein the bacterial supernatant of the fermentation is by belonging to It is generated in the bacterial species of Eurotium.
81. according to the additive composition for paper making described in any of embodiment 75-80, wherein the additive for paper making Composition includes the microorganism supernatant of the by weight at least 35% processed fermentation.
82. according to the additive composition for paper making described in any of embodiment 75-81, wherein the additive for paper making Composition includes the microorganism supernatant of the by weight at most 50% processed fermentation.
83. according to the additive composition for paper making described in any of embodiment 75-82, wherein the nonionic table Face activating agent includes polyethers nonionic surface active agent, polyhydroxy nonionic surface active agent and/or Bio-surface active Agent.
84. according to the additive composition for paper making described in embodiment 83, wherein the polyhydroxy non-ionic surface is lived Property agent include sucrose ester, the sucrose ester of ethoxylation, sorbitol ester, the sorbitol ester of ethoxylation, alkyl-glucoside, Alkyl-glucoside, polyglycerol ester or the polyglycerol ester of ethoxylation of ethoxylation.
85. according to the additive composition for paper making described in any of embodiment 75-84, wherein the nonionic table Face activating agent include amine oxide, the alcohol of ethoxylation, the aliphatic alcohol of ethoxylation, alkylamine, ethoxylation alkylamine, The alkylphenol of ethoxylation, alkyl polysaccharide, the alkyl polysaccharide of ethoxylation, the aliphatic acid of ethoxylation, ethoxylation fat The fatty amine of fat alcohol or ethoxylation has H (OCH2CH2)xOC6H4R1、(OCH2CH2)xOR2Or H (OCH2CH2)xOC(O)R2 General formula nonionic surface active agent, wherein x indicates to be added into the oxidation of alkylphenol and/or fatty alcohol or aliphatic acid The molal quantity of ethylene, R1Indicate long chain alkyl group and R2Indicate long aliphatic radicals.
86. according to the additive composition for paper making described in embodiment 85, wherein R1It is C7-C10It is the alkyl group of positive structure And/or wherein R2It is C12-C20Aliphatic group.
87. according to the additive composition for paper making described in any of embodiment 75-86, wherein the nonionic table Face activating agent is the nonyl phenol of ethoxylation, the octyl phenol of ethoxylation, the cetyl oleyl alcohol of ethoxylation, ethoxylation Cetyl stearyl alcohol, the decyl alcohol of ethoxylation, the lauryl alcohol of ethoxylation, the tridecanol of ethoxylation or ethoxylation Castor oil.
88. according to the additive composition for paper making described in any of embodiment 75-87, wherein the additive for paper making Composition includes by weight from about 1% to about 15% one or more of nonionic surface active agent.
89. according to the additive composition for paper making described in embodiment 88, wherein the additive composition for paper making includes By weight from about 5% to about 13% one or more of nonionic surface active agent.
90. according to the additive composition for paper making described in embodiment 89, wherein the additive composition for paper making includes By weight from about 7% to about 11% one or more of nonionic surface active agent.
91. according to the additive composition for paper making described in any of embodiment 75-90, wherein the additive for paper making Composition also includes one or more of anionic surfactant.
92. according to the additive composition for paper making described in embodiment 91, wherein the additive composition for paper making includes By weight from about 0.5% to about 10% one or more of anionic surfactant.
93. according to the additive composition for paper making described in embodiment 92, wherein the additive composition for paper making includes By weight from about 1% to about 8% one or more of anionic surfactant.
94. according to the additive composition for paper making described in embodiment 93, wherein the additive composition for paper making includes By weight from about 2% to about 6% one or more of anionic surfactant.
95. according to the additive composition for paper making described in any one of embodiment 75-94, wherein the pH is at most 4.5。
96. according to the additive composition for paper making described in embodiment 95, wherein the pH is about 3.7 to about 4.2.
97. according to the additive composition for paper making described in any of embodiment 75-96, wherein the additive for paper making Composition also includes antimicrobial.
98. according to the additive composition for paper making described in any of embodiment 75-97, wherein the additive for paper making Composition is generally nontoxic to the mankind, mammal, plant and environment.
99. according to the additive composition for paper making described in any of embodiment 75-98, wherein the additive for paper making Composition is biodegradable.
100. according to the additive composition for paper making described in embodiment 75-99, wherein the additive composition for paper making Also include enzyme, the enzymic digestion lignin promotes bleaching, increases deinking, make cellulosic fibrous structure modification, increase effluent control System, except deasphalting and goo (adhesive), make starch conversion.
101. according to the additive composition for paper making described in embodiment 100, wherein the enzyme includes that cellulase, wood are poly- Carbohydrase, lipase, esterase, amylase, pectase, catalyzing enzyme, laccase, peroxidase, paper pulp enzyme DI, paper pulp enzyme RF, paper pulp Enzyme BL or any combination thereof.
102. a kind of method detaching fiber from paper pulp, the method includes in slurrying and/or during the paper production phase, inciting somebody to action A effective amount of additive composition for paper making according to defined in any of embodiment 75-101 is applied to the paper pulp, wherein The application leads to the increased separation of cellulose fibre raw material present in the paper pulp.
103. one kind removing one or more of impurity and/or one or more of pollutions from paper pulp and/or paper material The method of object will be in a effective amount of 75-101 according to embodiment the method includes in slurrying and/or during the paper production phase Additive composition for paper making defined in any one is applied to the paper pulp, wherein the application cause from the paper pulp and/or One or more of impurity and/or one or more of pollutants are removed in paper material.
104. a kind of method for removing removal ink from paper pulp and/or paper material, the method includes in slurrying and/or paper life During the production stage, a effective amount of additive composition for paper making according to defined in any of embodiment 75-101 is applied to The paper pulp, wherein the application causes to remove the ink from the paper pulp and/or paper material.
105. a effective amount of additive composition for paper making according to defined in any of embodiment 75-101 be used for from Pulp detaches the purposes of fiber.
106. a effective amount of additive composition for paper making according to defined in any of embodiment 75-101 be used for from The purposes of one or more of impurity and/or one or more of pollutants is removed in paper pulp and/or paper material.
107. a effective amount of additive composition for paper making according to defined in any of embodiment 75-101 be used for from The purposes of removal ink is removed in paper pulp and/or paper material.
Embodiment
Following non-limiting embodiment is provided for only illustrative purpose, is set now to help to be more fully understood The representative embodiment thought.These embodiments should not be construed as limited to appointing in embodiment described in this specification What one, include having with the method or purposes of additive composition for paper making disclosed herein or such additive composition for paper making Those of pass embodiment.
Embodiment 1
The preparation of the yeast supernatants 1 of processed fermentation
In order to prepare the yeast supernatants of processed fermentation, fermentation reaction is established, wherein will have at about 29 DEG C to about The warm water of the about 1,000L of temperature between 38 DEG C is placed in the mixing kettle of big jacketed.Xiang Shuizhong adds about 84.9kg's The untreated cane molasses of black, about 25.2kg raw sugar and about 1.2kg magnesium sulfate.Mixture is fully blended, later, Add the diastatic malt of about 11.4kg and the Saccharomyces cerevisiae of about 1.2kg and mild agitation.By mixture at about 26 DEG C to about 42 DEG C Incubation lasts about 3 days, and later, effervesce reaction is subsided, and instruction is substantially completely fermented.In fermentation ends, yeast is sent out Ferment composition is centrifuged to remove " sludge " that is formed during fermentation.Collect the fermented supernatant fluid generated (by weight about 98.59%) it and by high pressure sterilization sterilizes.Then the yeast supernatants of processed fermentation can be stored up in liquid form It deposits, for then using.Selectively, the yeast supernatants of processed fermentation can by method as known in the art come Spray drying is to generate dried powder.Dry powder form can also be stored for then using.
Embodiment 2
The preparation of the yeast supernatants 2 of processed fermentation
In order to prepare the yeast supernatants of processed fermentation, fermentation reaction is established, wherein will have at about 29 DEG C to about The warm water of the about 1,000L of temperature between 38 DEG C is placed in the mixing kettle of big jacketed.Xiang Shuizhong adds about 42.5kg's The untreated cane molasses of black, about 12.6kg raw sugar and about 1.2kg magnesium sulfate.Mixture is fully blended, later, Add the diastatic malt of about 10.3kg and the Saccharomyces cerevisiae of about 1.2kg and mild agitation.By mixture at about 26 DEG C to about 42 DEG C Incubation lasts about 3 days, and later, effervesce reaction is subsided, and instruction is substantially completely fermented.In fermentation ends, yeast is sent out Ferment culture is centrifuged to remove " sludge " that is formed during fermentation.Collect the fermented yeast supernatant generated (by weight about 98.59%) it and by high pressure sterilization is handled.Then the yeast supernatants of processed fermentation can be stored up in liquid form It deposits, for then using.Selectively, the yeast supernatants of processed fermentation can by method as known in the art come Spray drying is to generate dried powder.Dry powder form can also be stored for then using.
Embodiment 3
The preparation of the yeast supernatants 3 of processed fermentation
In order to prepare the yeast supernatants of processed fermentation, fermentation reaction is established, wherein will have at about 29 DEG C to about The warm water of the about 1,000L of temperature between 38 DEG C is placed in the mixing kettle of big jacketed.Xiang Shuizhong adds about 21.3kg's The untreated cane molasses of black, about 6.3kg raw sugar and about 1.2kg magnesium sulfate.Mixture is fully blended, later, Add the diastatic malt of about 9.3kg and the Saccharomyces cerevisiae of about 1.2kg and mild agitation.By mixture in about 26 DEG C to about 42 DEG C temperature It educates and lasts about 3 days, later, effervesce reaction has been weakened, and instruction is substantially completely fermented.In fermentation ends, yeast is fermented Culture is centrifuged to remove " sludge " that is formed during fermentation.Collect the fermented supernatant fluid generated (by weight about 98.59%) it and by high pressure sterilization is handled.Then the yeast supernatants of processed fermentation can be stored up in liquid form It deposits, for then using.Selectively, the yeast supernatants of processed fermentation can by method as known in the art come Spray drying is to generate dried powder.Dry powder form can also be stored for then using.
Embodiment 4
The preparation of additive composition for paper making
In order to prepare additive composition for paper making, the hot sterile water (about 60 DEG C to about 65 DEG C) of 1,000L is added to big In the yeast supernatants of the processed fermentation of 1,000L in the mixture kettle of jacketed.It is added about into the mixture The TERGITOL of 168.8kgTMThe TERGITOL of 15-S-7 linear secondary alcohols ethoxylate, about 168.8kgTM15-S-5 is linear The DOWFAX of secondary alcohol ethoxyl compound, about 67.5kgTM2A1 alkyl diphenyl ether disulfonates (alkyldiphenyloxide ) and the TRITON of about 67.5kg disulfonateTMH-66 phosphates polyether ester (phosphate polyether ester).The mixture is fully blended to generate solution.Then water is added, so that volume reaches about 4,5000L and stirs straight To being thoroughly mixed.The pH of the additive composition for paper making of generation is adjusted to about 4.2 from about 3.7 with phosphoric acid.Then, The additive composition for paper making filtration sterilization that pH is adjusted is to remove any microbial contamination.
The composition be found to skin histology be it is nonirritant, nontoxic and can within the period of several months quilt It is stored in cold position, without any perceptible loss of effectiveness or deterioration.
DOWFAXTM2A1 can be substituted with anionic biosurfactant below, such as such asAM 30-KE, Texapon Special,EHS, sodium 2-ethylhexyl sulfate or its group It closes.
Optionally, then the additive composition for paper making of generation can be mixed with preservative below or stabilizer, such as By weight about 1% sodium benzoate, by weight about 0.01% imidazolidinyl urea, by weight about 0.15% two oxazolidines Base urea, by weight about 0.25% calcium chloride.In the case of continuous agitation, addition sodium benzoate, imidazolidinyl urea, diazole Ureine and calcium chloride.Then, the temperature of mixture is slowly increased to about 40 DEG C and is continually stirred mixture.It will be warm Degree is maintained at about 40 DEG C and lasts about 1 hour to ensure that all components of mixture are dissolved.Then, mixture is cold from about 20 DEG C But to about 25 DEG C.The pH of the additive composition for paper making of generation is adjusted to about 4.2 from about 3.7 with phosphoric acid.Then, pH is adjusted Additive composition for paper making filtration sterilization to remove any microbial contamination.
Embodiment 5
The preparation of additive composition for paper making
In order to prepare additive composition for paper making, the hot sterile water (about 60 DEG C to about 65 DEG C) of 850L is placed on big band In the mixture kettle of chuck.Xiang Shuizhong adds the powder, about of the yeast supernatants drying of the processed fermentation of about 7.62g 37.5kg TERGITOLTM15-S-7 linear secondary alcohols ethoxylate), the TERGITOL of about 37.5kgTM15-S-5 is linearly secondary The DOWFAX of alcohol ethoxylate, about 15.0kgTMThe TRITON of 2A1 alkyl diphenyl ether disulfonates and about 25.0kgTM H- 66 phosphate polyether esters.The mixture is fully blended to generate solution.Then water is added, so that volume reaches about 1,0000L And it stirs until being thoroughly mixed.The pH of the additive composition for paper making of generation is adjusted to about from about 3.7 with phosphoric acid 4.2.Then, additive composition for paper making filtration sterilization pH adjusted is to remove any microbial contamination.
Optionally, then the additive composition for paper making of generation can be mixed with preservative below or stabilizer, such as By weight about 1% sodium benzoate, by weight about 0.01% imidazolidinyl urea, by weight about 0.15% two oxazolidines Base urea, by weight about 0.25% calcium chloride.In the case of continuous agitation, addition sodium benzoate, imidazolidinyl urea, diazole Ureine and calcium chloride.Then, the temperature of mixture is slowly increased to about 40 DEG C and is continually stirred mixture.It will be warm Degree is maintained at about 40 DEG C and lasts about 1 hour to ensure that all components of mixture are dissolved.Then, mixture is cold from about 20 DEG C But to about 25 DEG C.The pH of the additive composition for paper making of generation is adjusted to about 4.2 from about 3.7 with phosphoric acid.Then, pH is adjusted Additive composition for paper making filtration sterilization to remove any microbial contamination.
The composition be found to skin histology be it is nonirritant, nontoxic and can within the period of several months quilt It is stored in cold position, without any perceptible loss of effectiveness or deterioration.
DOWFAXTM2A1 can be substituted with anionic biosurfactant below, such as such asAM 30-KE, Texapon Special,EHS, sodium 2-ethylhexyl sulfate or its group It closes.
The optional object for the powder that yeast supernatants as processed fermentation disclosed in embodiment 1-3 are dried, can be with The powder dried using the yeast supernatants of commercially available processed fermentation, including for example154、210 or900。
Embodiment 6
Slurrying is tested
The implementation exemplifies the increasing of the efficiency of the pulping process by application additive composition for paper making as disclosed herein Add.
Initially, in the miniature pulper in laboratory in the case where not adding additive composition for paper making, by crude paper pulp Preparation processing continues 45 minutes.Crude paper pulp preparation includes 17% raw material.After slurrying, assessed using Canadian standard The freedom of preparation.There is no the decomposition of raw material, therefore can not possibly be sampled or carry out freedom measurement.
In subsequent experiment, 17% crude paper pulp preparation is miniature in laboratory with Paper additive composition disclosed herein It is processed in pulper.The amount of the additive composition for paper making of addition is raw material 300mL per ton.The sample of said preparation is at the 10th point Clock, the 20th minute and the 30th minute sample.After slurrying, the freedom of preparation is assessed using Canadian standard.It observes The time dependence of freedom improves.In 10 minutes pulping process, although observing bounce (tiggering), need More times of contact are wanted to realize that better fiber homogenizes (Figure 1A).In 20 minutes pulping process, it is seen that bounce Sustained improvement (Figure 1B), and in 30 minutes pulping process, observe that excellent fiber homogenizes (Fig. 1 C).These results are shown Go out, additive composition for paper making disclosed herein significantly improves pulping process, and excellent fiber is caused to homogenize.
The subsequent microphoto of the fiber handled with additive composition for paper making disclosed herein is shown on fiber surface Improved inside and outside fibrillation, this cause between increased surface area and improved formation fiber (interfiber) and The ability (Fig. 2) of the key of (intrafiber) in fiber.
These experiments are repeated using following concentration：Raw material 30mL additive composition for paper making per ton, raw material per ton 60mL additive composition for paper making and raw material 400mL additive composition for paper making per ton.All concentration are provided similar to per ton The result of starting material concentrations 300mL additive composition for paper making.
Embodiment 7
Deinking
The implementation exemplifies additive composition for paper making disclosed herein and removes effectively ink from recyclable papers and glue The effect of mixture.
Using pulverizer, three group slurrying are continued 60 minutes in 11.5 liters of clean water, every group white comprising 0.8kg 3 shredded paper of color (3 broke paper of White).Group 1 only includes white 3 paper and is used as control.Group 2 is comprising white 3 shredded papers and often The additive composition for paper making disclosed herein of ton raw material 500mL.Group 3 includes white 3 shredded papers and raw material 500mL per ton Additive composition for paper making disclosed herein and also include cellulase.With 15 minutes intervals, 3.0g is taken out from pulverizer Sample simultaneously analyzes brightness using ISO brightness measurings.The two kinds of samples handled with additive composition for paper making disclosed herein change Into white 3 shredded papers decomposition and by brightness improvement almost 2 points.Relative to 2 processing of group, at the group 3 added with cellulase Reason is in terms of improvement without generating any appreciable difference.
Finally, it will be understood that although highlighting the various aspects of this specification by reference to specific embodiment, The person skilled in the art will easily understand the principles of these disclosed embodiments only illustration presently disclosed subject matter.Therefore, It should be appreciated that unless clearly same statement, otherwise disclosed theme is never limited to specific compound described herein, group Close object, article, equipment, method, scheme and/or reagent etc..In addition, it will be appreciated by the skilled addressee that without departing from this In the case of the spirit of specification, according to the teaching of this article, certain variations can be made, modification, arrangement, changes, addition, reduce And its sub-portfolio.Accordingly, it is anticipated that claim appended below and the claim introduced from now on be interpreted as including it is all this Variation, modification, arrangement, change, addition, reduction and its sub-portfolio of sample, because in its real spirit and scope.
This document describes certain embodiments of the present invention, including known to the present inventor it is for carrying out the present invention best Pattern.Certainly, after reading foregoing description, about these description embodiments modification for this field ordinary skill It will be apparent for personnel.The inventors expect that technical staff optionally uses such modification, and the present inventor is intended to The present invention is carried out in a manner of otherwise than as specifically described herein.Therefore, the present invention include as applicable law it is permitted The all modifications and equivalent of the theme described in this appended claims.In addition, unless in addition indicating herein or with it He is apparently contradicted in the context mode, and otherwise any combinations of above-described embodiment are with its all possible modification quilt sheet Invention is covered.
The grouping of the optional embodiment, element or step of the present invention is not interpreted to limit.Each group membership can be Individually or with other group memberships disclosed herein is referred to and be claimed in combination.For convenience and/or patentability The reason of, it is contemplated that one or more members in group can be included in group or be deleted from group.When generation is any in this way When including or deleting, this specification is considered including the group of modification, to realize used in the appended claims it is all The written description of Markush (Markush) group.
Unless otherwise instructed, the expression characterization that otherwise uses in the present specification and claims, project, quantity, ginseng All numbers of number, property, term etc. are understood to be modified by term " about " in all cases.As used herein, art Language " about " mean so quantitative characteristic, project, quantity, parameter, property or term cover above and below the characteristic stated, Positive or negative 10 range of project, quantity, parameter, the value of property or term.Therefore, unless the contrary indication, otherwise The numerical parameter stated in this specification and in the appended claims is the approximation that can change.For example, given determining When the quality of analyte, mass spectroscopy device can slightly change, ion quality or ion matter/lotus than context in, Term " about " refers to +/- 0.50 atomic mass unit.At least, without being attempt to limit the doctrine of equivalents of the scope of the claims Application, each numerical value should according at least to the effective digital of report number and by application common rounding-off technology come It explains.
The use of term " may (may) " in terms of embodiment or embodiment or " can (can) " also band There is the replacement meaning of " may not (may not) " or " cannot (cannot) ".Therefore, if subject description discloses embodiments Embodiment aspect may (may) or can (can) as subject of the present invention part by including then also clearly Mean negative limitation or removing property condition, it is meant that may not be in terms of embodiment or embodiment or cannot function as this hair The part of bright theme by including.In a similar way, the term " optionally " in terms of embodiment or embodiment Using mean such embodiment or embodiment for the use of may as subject of the present invention part by including or can Can not as subject of the present invention part by including.Whether application will be born based on this for such negative limitation or removing property condition Whether face being limited or precluded property condition is enumerated in theme claimed.
Although stating that the broad range of numberical range of the present invention and value are approximation, state in a particular embodiment Numberical range and value are reported as precisely as possible.However, any numberical range or value include inherently certain errors, the error The inevitable standard deviation by being found in being measured in its respective test generates.Herein to the numberical range of value enumerate only by It is intended as individually referring to the convenient method for each of falling into the range independent numerical value.Unless in addition instruction herein, no Then each individual value of numberical range is incorporated into this specification, as it is individually enumerated herein.
Unless in addition indicating or being apparently contradicted in the context herein, otherwise in the context describing the invention (particularly In the context of the appended claims) term " one (a) " that uses, " one (an) ", " should (the) " and similar instruction Word is interpreted both covering odd number and plural number.In addition, the ordinal indicators such as " first " of element for identification, " Two ", " third " etc. is used to distinguish between these elements, and do not indicate or imply such element needs or limitation number Mesh, and unless in addition specifically state, specific position or the sequence of such element are not otherwise indicated.Institute described herein There is method that can carry out in any suitable order, unless in addition indicating or being in addition apparently contradicted in the context herein.It carries herein For any and whole embodiments or exemplary language (for example, " such as ") use be intended merely to be better described the present invention and The range of otherwise claimed invention is not caused to limit.Language in this specification is not construed as referring to Show and essential any element being not claimed is put into practice to the present invention.
When used in a claim, it either submits or adds according to amendment, open transitional term " includes (comprising) " (and its equivalent open transitional phrase is as included (including), including (containing) and tool Have) individually or with the theme not described cover all elements clearly described, limitation, step and/or feature in combination；Institute Element, limitation and/or the feature pointed out are necessary, but can add other element, limitation and/or features for not pointing out, And still form the construction in the scope of the claims.Closed transitional phrase can be used " by ... group in the claims At " or " substantially by ... form " substitute or further limited as the modification to " including (comprising) " public herein The specific embodiment opened.When in detail in the claims in use, either according to amendment submit or add, it is closed Transitional phrase " by ... form " exclude any element, limitation, step or the feature do not enumerated clearly in the claims.Envelope The scope of the claims is limited to the element clearly enumerated, limitation, step by enclosed transitional phrase " substantially by ... form " Any other element of rapid and/or feature and non-materially affect theme claimed fundamental characteristics and novel characteristics, Limitation, step and/or feature.Therefore, the meaning of open transitional phrase " including (comprising) " is defined as covering institute There are the element specifically enumerated, limitation, step and/or feature and any optional, in addition unspecified element, limitation, step Rapid and/or feature.Closed transitional phrase " by ... form " meaning be defined as only including specifically arranging in claim Those of lift element, limitation, step and/or feature, and the meaning quilt of closed transitional phrase " substantially by ... form " It is defined as only including those of specifically enumerating element, limitation, step and/or feature in claim and non-materially affect is wanted Ask those of fundamental characteristics and the novel characteristics of the theme of protection element, limitation, step and/or feature.Therefore, open transition Wording " includes (comprising) " that (and its equivalent open transitional phrase) includes as limitation implementations in its meaning By closed transitional phrase " by ... form " or " substantially by ... form " specified claimed theme.Cause This, embodiment described herein or being claimed in this way with wording " including (comprising) " is by clearly or intrinsic bright Describe in vain, can realize and support herein phrase " substantially by ... form " and " by ... form ".
The composition described in these publications that can be for example used in conjunction with the invention for descriptions and disclosures and side The purpose of the science of law, all patents, patent publications and other publications quoted and indicated in this specification are by independent and bright Really it is integrally incorporated with it by quoting.These publications are provided and are used for the purpose of its disclosure before the submitting day of the application Content.Nothing should be construed as an admission that inventor haves no right by previous invention or due to any other original in this regard Because being disclosed prior to as.The narration on all about date or statement about these literature contents are can get based on applicant Information, and any of correctness for not constituting the date or content about these documents recognizes.
Finally, terms used herein are only used for the purpose of description particular embodiment, and are not intended to limit the present invention's Range, the scope of the present invention are limited only by the appended claims.Therefore, the present invention is inaccurately limited to as shown and described Like that.

Claims (29)

1. a kind of additive composition for paper making, including the microorganism supernatant of processed fermentation and one or more of nonionics Type surfactant, wherein the composition does not have the bacterium of any organized enzyme or work, and the wherein described composition is with low In 5.0 pH.
2. additive composition for paper making according to claim 1, wherein the microorganism supernatant of the processed fermentation The bacterial supernatant of yeast supernatants, fermentation from fermentation, the mould supernatant of fermentation or any combination thereof.
3. additive composition for paper making according to claim 2, wherein the yeast supernatants of the fermentation are by belonging to following Category yeast species generate：Brettanomyce Pseudomonas, Candida, quasi- Weir Blastocystis, the black powder saccharomycete of sporangiocyst line Category, Dbaly yeast Pseudomonas, moral carat Blastocystis, Fusarium, geotrichum sp category, her Sa Blastocystis, Kazakhstan's ferment Female Pseudomonas, Ke Leke Blastocystis, Kluyveromyces, lecanium Pseudomonas, Mucor, Neurospora, Pediococcus, mould Pseudomonas, Pichia pastoris Pseudomonas, Rhizopus, rhodosporidium toruloides Pseudomonas, rhodotorula Pseudomonas, Blastocystis, Schizosccharomyces, hair Spore Blastocystis has spore Torula, Torulopsis, Verticillium dahliae category, Ye Luoweiya Blastocystis, Zygosaccharomyces bacterium Category or Zygotorulaspora.
4. additive composition for paper making according to claim 3, wherein the yeast supernatants of the fermentation are made wine by yeast Saccharomycete generates.
5. according to the additive composition for paper making described in any one of claim 1-4, wherein the additive composition for paper making Include the microorganism supernatant of the by weight at least 35% processed fermentation.
6. additive composition for paper making according to any one of claims 1-5, wherein the additive composition for paper making Include the microorganism supernatant of the by weight at most 50% processed fermentation.
7. according to the additive composition for paper making described in any one of claim 1-6, wherein the non-ionic surfactant Agent includes polyethers nonionic surface active agent, polyhydroxy nonionic surface active agent and/or biosurfactant.
8. additive composition for paper making according to claim 7, wherein the polyhydroxy nonionic surface active agent packet Include sucrose ester, the sucrose ester of ethoxylation, sorbitol ester, the sorbitol ester of ethoxylation, alkyl-glucoside, ethyoxyl Alkyl-glucoside, polyglycerol ester or the polyglycerol ester of ethoxylation of change.
9. according to the additive composition for paper making described in any one of claim 1-8, wherein the non-ionic surfactant Agent includes amine oxide, the alcohol of ethoxylation, the aliphatic alcohol of ethoxylation, alkylamine, the alkylamine of ethoxylation, ethyoxyl The alkylphenol of change, alkyl polysaccharide, the alkyl polysaccharide of ethoxylation, the aliphatic acid of ethoxylation, ethoxylation fatty alcohol or The fatty amine of ethoxylation has H (OCH2CH2)xOC6H4R1、(OCH2CH2)xOR2Or H (OCH2CH2)xOC(O)R2General formula Nonionic surface active agent, wherein x indicates the ethylene oxide for being added into alkylphenol and/or fatty alcohol or aliphatic acid Molal quantity, R1Indicate long chain alkyl group and R2Indicate long aliphatic radicals.
10. additive composition for paper making according to claim 9, wherein R1It is C7-C10The alkyl group of positive structure and/or its Middle R2It is C12-C20Aliphatic group.
11. according to the additive composition for paper making described in any one of claim 1-10, wherein the non-ionic surface is lived Property agent be the nonyl phenol of ethoxylation, the octyl phenol of ethoxylation, the cetyl oleyl alcohol of ethoxylation, ethoxylation whale Cerul stearyl alcohol, the decyl alcohol of ethoxylation, the lauryl alcohol of ethoxylation, the tridecanol of ethoxylation or the castor-oil plant of ethoxylation Oil.
12. according to the additive composition for paper making described in any one of claim 1-11, wherein the additive for paper making combines Object includes by weight from about 1% to about 15% one or more of nonionic surface active agent.
13. additive composition for paper making according to claim 12, wherein the additive composition for paper making includes by weight One or more of nonionic surface active agent of gauge from about 5% to about 13%.
14. additive composition for paper making according to claim 13, wherein the additive composition for paper making includes by weight One or more of nonionic surface active agent of gauge from about 7% to about 11%.
15. according to the additive composition for paper making described in any one of claim 1-14, wherein the additive for paper making combines Object also includes one or more of anionic surfactant.
16. additive composition for paper making according to claim 15, wherein the additive composition for paper making includes by weight One or more of anionic surfactant of gauge from about 0.5% to about 10%.
17. additive composition for paper making according to claim 16, wherein the additive composition for paper making includes by weight One or more of anionic surfactant of gauge from about 1% to about 8%.
18. additive composition for paper making according to claim 17, wherein the additive composition for paper making includes by weight One or more of anionic surfactant of gauge from about 2% to about 6%.
19. according to the additive composition for paper making described in any one of claim 1-18, wherein the pH is at most 4.5.
20. additive composition for paper making according to claim 19, wherein the pH is about 3.7 to about 4.2.
21. according to the additive composition for paper making described in any one of claim 1-20, wherein the additive for paper making combines Object also includes antimicrobial.
22. according to the additive composition for paper making described in any one of claim 1-21, wherein the additive for paper making combines Object is generally nontoxic to the mankind, mammal, plant and environment.
23. according to the additive composition for paper making described in any one of claim 1-22, wherein the additive for paper making combines Object is biodegradable.
24. a kind of method detaching fiber from paper pulp will be effective the method includes in slurrying and/or during the paper production phase Amount is applied to the paper pulp according to the additive composition for paper making defined in any one of claim 1-23, wherein described answer With the increased separation for leading to cellulose fibre raw material present in the paper pulp.
25. a kind of side removing one or more of impurity and/or one or more of pollutants from paper pulp and/or paper material Method, the method includes in slurrying and/or during the paper production phase, by a effective amount of according in any one of claim 1-23 The additive composition for paper making of definition is applied to the paper pulp, wherein the application causes from the paper pulp and/or paper material Remove one or more of impurity and/or one or more of pollutants.
26. a kind of method for removing removal ink from paper pulp and/or paper material, the method includes producing rank in slurrying and/or paper During section, a effective amount of additive composition for paper making according to defined in any one of claim 1-23 is applied to the paper Slurry, wherein the application causes to remove the ink from the paper pulp and/or paper material.
27. a effective amount of additive composition for paper making according to defined in any one of claim 1-23 is used for from pulp Detach the purposes of fiber.
28. a effective amount of additive composition for paper making according to defined in any one of claim 1-23 be used for from paper pulp and/ Or the purposes of one or more of impurity and/or one or more of pollutants is removed in paper material.
29. a effective amount of additive composition for paper making according to defined in any one of claim 1-23 be used for from paper pulp and/ Or the purposes of removal ink is removed in paper material.
CN201680061816.2A 2015-08-22 2016-08-22 Additive composition for paper making and its method and purposes Pending CN108347946A (en)

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