RU2656997C2 - Смеси полимеров и изготовленные из них изделия - Google Patents
Смеси полимеров и изготовленные из них изделия Download PDFInfo
- Publication number
- RU2656997C2 RU2656997C2 RU2015106313A RU2015106313A RU2656997C2 RU 2656997 C2 RU2656997 C2 RU 2656997C2 RU 2015106313 A RU2015106313 A RU 2015106313A RU 2015106313 A RU2015106313 A RU 2015106313A RU 2656997 C2 RU2656997 C2 RU 2656997C2
- Authority
- RU
- Russia
- Prior art keywords
- polymer
- ethylene
- peak
- value
- equal
- Prior art date
Links
- 229920002959 polymer blend Polymers 0.000 title description 3
- 229920000642 polymer Polymers 0.000 claims abstract description 261
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 120
- 239000005977 Ethylene Substances 0.000 claims abstract description 120
- 239000000203 mixture Substances 0.000 claims abstract description 116
- 229920000573 polyethylene Polymers 0.000 claims abstract description 73
- 238000010828 elution Methods 0.000 claims abstract description 48
- 238000009826 distribution Methods 0.000 claims abstract description 40
- 239000010410 layer Substances 0.000 claims abstract description 39
- 229920000092 linear low density polyethylene Polymers 0.000 claims abstract description 32
- 239000004707 linear low-density polyethylene Substances 0.000 claims abstract description 30
- 239000004711 α-olefin Substances 0.000 claims abstract description 24
- 238000004458 analytical method Methods 0.000 claims abstract description 13
- 238000012360 testing method Methods 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 239000002356 single layer Substances 0.000 claims abstract description 5
- 239000000155 melt Substances 0.000 claims description 43
- 229920006254 polymer film Polymers 0.000 claims description 27
- 238000006555 catalytic reaction Methods 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 3
- 238000005194 fractionation Methods 0.000 claims description 3
- 239000011342 resin composition Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 13
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 36
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 26
- -1 polyethylene Polymers 0.000 description 18
- 238000006116 polymerization reaction Methods 0.000 description 18
- 239000003054 catalyst Substances 0.000 description 17
- 229910052735 hafnium Inorganic materials 0.000 description 16
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 15
- 239000004698 Polyethylene Substances 0.000 description 14
- 238000002844 melting Methods 0.000 description 14
- 230000008018 melting Effects 0.000 description 14
- 229920001577 copolymer Polymers 0.000 description 11
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 10
- 239000000178 monomer Substances 0.000 description 10
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 8
- 229910052726 zirconium Inorganic materials 0.000 description 8
- 229920001684 low density polyethylene Polymers 0.000 description 7
- 239000004702 low-density polyethylene Substances 0.000 description 7
- 239000002609 medium Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 229920005684 linear copolymer Polymers 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 3
- 239000004708 Very-low-density polyethylene Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000000113 differential scanning calorimetry Methods 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229920001866 very low density polyethylene Polymers 0.000 description 3
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920001179 medium density polyethylene Polymers 0.000 description 2
- 239000004701 medium-density polyethylene Substances 0.000 description 2
- 239000012968 metallocene catalyst Substances 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 101000588019 Homo sapiens Shadow of prion protein Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 101100291930 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) MPE1 gene Proteins 0.000 description 1
- 102100031579 Shadow of prion protein Human genes 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000009750 centrifugal casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000012897 dilution medium Substances 0.000 description 1
- 238000007907 direct compression Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229920006300 shrink film Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920006302 stretch film Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/07—Long chain branching
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261718861P | 2012-10-26 | 2012-10-26 | |
| US61/718,861 | 2012-10-26 | ||
| PCT/US2013/062589 WO2014065989A1 (en) | 2012-10-26 | 2013-09-30 | Polymer blends and articles made therefrom |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015106313A RU2015106313A (ru) | 2016-12-20 |
| RU2656997C2 true RU2656997C2 (ru) | 2018-06-08 |
Family
ID=49447804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015106313A RU2656997C2 (ru) | 2012-10-26 | 2013-09-30 | Смеси полимеров и изготовленные из них изделия |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US11214659B2 (enExample) |
| EP (1) | EP2912114B1 (enExample) |
| CN (1) | CN104736625B (enExample) |
| BR (1) | BR112015005875A2 (enExample) |
| IN (1) | IN2015DN01430A (enExample) |
| MX (1) | MX2015002702A (enExample) |
| MY (1) | MY173844A (enExample) |
| RU (1) | RU2656997C2 (enExample) |
| WO (1) | WO2014065989A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2912114B1 (en) * | 2012-10-26 | 2017-12-13 | ExxonMobil Chemical Patents Inc. | Polymer blends and articles made therefrom |
| CN108699269B (zh) * | 2016-03-25 | 2021-05-14 | 埃克森美孚化学专利公司 | 聚乙烯膜 |
| WO2018102091A1 (en) * | 2016-12-02 | 2018-06-07 | Exxonmobil Chemical Patents Inc. | Polyethylene films |
| WO2019027524A1 (en) | 2017-08-02 | 2019-02-07 | Exxonmobil Chemical Patents Inc. | MULTILAYER FILMS AND METHODS OF MANUFACTURE |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2158280C2 (ru) * | 1993-04-28 | 2000-10-27 | Дзе Дау Кемикал Компани | Изделия, полученные из смесей полиэтилена |
| WO2002004556A2 (en) * | 2000-07-12 | 2002-01-17 | Univation Technologies, Llc | Ethylene inter-polymer blends |
| US6423420B1 (en) * | 1997-08-11 | 2002-07-23 | Exxonmobil Chemical Patents Inc. | Oriented coextruded films |
| US20030096128A1 (en) * | 2001-07-19 | 2003-05-22 | Farley James Mcleod | Polyethylene films with improved physical properties |
| US20090192270A1 (en) * | 2008-01-28 | 2009-07-30 | Malakoff Alan M | Ethylene-Based Polymers And Articles Made Therefrom |
| RU2011116177A (ru) * | 2008-09-25 | 2012-10-27 | Базелль Полиолефине Гмбх (De) | Стойкая к ударным нагрузкам композиция линейного полиэтилена низкой плотности и пленки, изготовленные из нее |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3248179A (en) | 1962-02-26 | 1966-04-26 | Phillips Petroleum Co | Method and apparatus for the production of solid polymers of olefins |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4613484A (en) | 1984-11-30 | 1986-09-23 | Phillips Petroleum Company | Loop reactor settling leg system for separation of solid polymers and liquid diluent |
| US4989802A (en) * | 1987-11-06 | 1991-02-05 | Fuji Photo Film Co., Ltd. | Core for web material |
| US5008204A (en) | 1988-02-02 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for determining the compositional distribution of a crystalline copolymer |
| FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5382631A (en) | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| JPH06509528A (ja) | 1991-07-18 | 1994-10-27 | エクソン・ケミカル・パテンツ・インク | ヒートシール製品 |
| US6316549B1 (en) * | 1991-10-15 | 2001-11-13 | The Dow Chemical Company | Ethylene polymer fiber made from ethylene polymer blends |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5378764A (en) * | 1992-10-08 | 1995-01-03 | Phillips Petroleum Company | Polyethylene blends |
| US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
| EP1623999A1 (en) | 1993-04-26 | 2006-02-08 | ExxonMobil Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5804678A (en) | 1993-07-13 | 1998-09-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
| US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
| US5763543A (en) | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
| US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
| US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
| US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
| US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
| WO1998021276A1 (en) | 1996-11-13 | 1998-05-22 | The Dow Chemical Company | Shrink film having balanced properties or improved toughness and methods of making the same |
| ATE356169T1 (de) | 1996-12-12 | 2007-03-15 | Dow Global Technologies Inc | Interpolymerzusammensezungen und davon hergestellte gegossene streckfolie |
| WO1998037140A1 (en) * | 1997-02-25 | 1998-08-27 | Exxon Chemical Patents Inc. | Oriented coextruded films |
| US6242545B1 (en) | 1997-12-08 | 2001-06-05 | Univation Technologies | Polymerization catalyst systems comprising substituted hafinocenes |
| US8247065B2 (en) | 2006-05-31 | 2012-08-21 | Exxonmobil Chemical Patents Inc. | Linear polymers, polymer blends, and articles made therefrom |
| US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
| US7991251B2 (en) | 2008-07-02 | 2011-08-02 | Hitachi, Ltd. | Optical module mounted with WDM filter |
| BRPI0923985B1 (pt) * | 2009-03-31 | 2019-10-08 | Dow Global Technologies Llc | Película multicamada e artigo fabricado |
| US8586676B2 (en) * | 2010-03-09 | 2013-11-19 | Exxonmobil Chemical Patents Inc. | Polymer compositions and articles made therefrom |
| EP2675844B1 (en) | 2011-02-15 | 2017-10-11 | ExxonMobil Chemical Patents Inc. | Thermoplastic polyolefin blends |
| US9340664B2 (en) | 2011-09-23 | 2016-05-17 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions for blown film |
| EP2912114B1 (en) * | 2012-10-26 | 2017-12-13 | ExxonMobil Chemical Patents Inc. | Polymer blends and articles made therefrom |
| TWI522412B (zh) * | 2013-03-25 | 2016-02-21 | 羅門哈斯公司 | 包裝用途之半透明聚烯烴膜 |
| US9361937B2 (en) | 2014-08-26 | 2016-06-07 | Seagate Technology Llc | Shingled magnetic recording data store |
-
2013
- 2013-09-30 EP EP13779660.3A patent/EP2912114B1/en active Active
- 2013-09-30 CN CN201380055369.6A patent/CN104736625B/zh active Active
- 2013-09-30 BR BR112015005875A patent/BR112015005875A2/pt not_active Application Discontinuation
- 2013-09-30 MX MX2015002702A patent/MX2015002702A/es unknown
- 2013-09-30 MY MYPI2015700531A patent/MY173844A/en unknown
- 2013-09-30 IN IN1430DEN2015 patent/IN2015DN01430A/en unknown
- 2013-09-30 RU RU2015106313A patent/RU2656997C2/ru active
- 2013-09-30 WO PCT/US2013/062589 patent/WO2014065989A1/en not_active Ceased
- 2013-09-30 US US14/423,042 patent/US11214659B2/en active Active
-
2021
- 2021-11-18 US US17/455,579 patent/US11702521B2/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2158280C2 (ru) * | 1993-04-28 | 2000-10-27 | Дзе Дау Кемикал Компани | Изделия, полученные из смесей полиэтилена |
| US6423420B1 (en) * | 1997-08-11 | 2002-07-23 | Exxonmobil Chemical Patents Inc. | Oriented coextruded films |
| WO2002004556A2 (en) * | 2000-07-12 | 2002-01-17 | Univation Technologies, Llc | Ethylene inter-polymer blends |
| US20030096128A1 (en) * | 2001-07-19 | 2003-05-22 | Farley James Mcleod | Polyethylene films with improved physical properties |
| US20090192270A1 (en) * | 2008-01-28 | 2009-07-30 | Malakoff Alan M | Ethylene-Based Polymers And Articles Made Therefrom |
| RU2011116177A (ru) * | 2008-09-25 | 2012-10-27 | Базелль Полиолефине Гмбх (De) | Стойкая к ударным нагрузкам композиция линейного полиэтилена низкой плотности и пленки, изготовленные из нее |
Also Published As
| Publication number | Publication date |
|---|---|
| US11702521B2 (en) | 2023-07-18 |
| CN104736625A (zh) | 2015-06-24 |
| WO2014065989A8 (en) | 2014-08-07 |
| US11214659B2 (en) | 2022-01-04 |
| EP2912114B1 (en) | 2017-12-13 |
| BR112015005875A2 (pt) | 2017-07-04 |
| MX2015002702A (es) | 2016-02-05 |
| CN104736625B (zh) | 2018-07-20 |
| IN2015DN01430A (enExample) | 2015-07-03 |
| US20220153940A1 (en) | 2022-05-19 |
| RU2015106313A (ru) | 2016-12-20 |
| US20150225521A1 (en) | 2015-08-13 |
| EP2912114A1 (en) | 2015-09-02 |
| WO2014065989A1 (en) | 2014-05-01 |
| MY173844A (en) | 2020-02-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RU2638261C2 (ru) | Полимеры на основе этилена и изготовленные из них изделия | |
| RU2296775C2 (ru) | Полимерная пленка | |
| US7812094B2 (en) | Polymer blend | |
| US9695290B2 (en) | Films comprising ethylene-based polymers and methods of making same | |
| CN103068574B (zh) | 多层膜 | |
| US11702521B2 (en) | Polymer blends and articles made therefrom | |
| CN110573538A (zh) | 多反应器溶液聚合 | |
| EP1994091A1 (en) | High density polyethylene | |
| WO2015075081A1 (en) | Films | |
| CN108290966A (zh) | 多峰聚乙烯组合物以及包含其的膜 | |
| EP1796902A1 (en) | Film | |
| WO2014099356A2 (en) | Polyethylene films and method of making same | |
| WO2009071323A1 (en) | Multi-modal linear low density polyethylene polymer | |
| AU2006286761A1 (en) | Film | |
| WO2018071250A1 (en) | Oriented films comprising ethylene-based and methods of making same | |
| WO2022034168A1 (en) | Multilayer film with low seal initiation temperature | |
| US11718719B2 (en) | Oriented films comprising ethlyene-based polymers and methods of making same | |
| AU2003248954B2 (en) | Schrink film | |
| CN107849270A (zh) | 收缩膜 | |
| WO2007065644A1 (en) | Polymer | |
| EP4413063A1 (en) | Polyethylene blends, films thereof, and methods thereof |