RU2619112C2 - Способы приготовления предшественника рутений-карбенового комплекса и рутений-карбеновых комплексов - Google Patents

Способы приготовления предшественника рутений-карбенового комплекса и рутений-карбеновых комплексов Download PDF

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RU2619112C2
RU2619112C2 RU2014117297A RU2014117297A RU2619112C2 RU 2619112 C2 RU2619112 C2 RU 2619112C2 RU 2014117297 A RU2014117297 A RU 2014117297A RU 2014117297 A RU2014117297 A RU 2014117297A RU 2619112 C2 RU2619112 C2 RU 2619112C2
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ruthenium
rucl
salt
product
purified
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RU2014117297A
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Russian (ru)
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RU2014117297A (ru
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Линда А. КУНЗ
Стевен А. ЦОХЕН
Мелвин Л. ЛУЕТКЕНС
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Елевансе Реневабле Сайенсез, Инк.
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046Ruthenium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046Ruthenium compounds
    • C07F15/0053Ruthenium compounds without a metal-carbon linkage

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
RU2014117297A 2011-10-13 2012-10-09 Способы приготовления предшественника рутений-карбенового комплекса и рутений-карбеновых комплексов RU2619112C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US13/272,788 2011-10-13
US13/272,788 US8779152B2 (en) 2011-10-13 2011-10-13 Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes
US13/606,640 2012-09-07
US13/606,640 US8975414B2 (en) 2011-10-13 2012-09-07 Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes
PCT/US2012/059280 WO2013055644A2 (en) 2011-10-13 2012-10-09 Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes

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RU2014117297A RU2014117297A (ru) 2015-11-20
RU2619112C2 true RU2619112C2 (ru) 2017-05-12

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US (2) US8975414B2 (cg-RX-API-DMAC7.html)
EP (1) EP2766378B1 (cg-RX-API-DMAC7.html)
JP (1) JP2015502333A (cg-RX-API-DMAC7.html)
CN (1) CN104302652B (cg-RX-API-DMAC7.html)
AU (1) AU2012323398B2 (cg-RX-API-DMAC7.html)
BR (1) BR112014008924A2 (cg-RX-API-DMAC7.html)
CA (1) CA2851899A1 (cg-RX-API-DMAC7.html)
IN (1) IN2014DN03420A (cg-RX-API-DMAC7.html)
MX (1) MX349199B (cg-RX-API-DMAC7.html)
MY (1) MY185097A (cg-RX-API-DMAC7.html)
RU (1) RU2619112C2 (cg-RX-API-DMAC7.html)
SG (1) SG11201401419UA (cg-RX-API-DMAC7.html)
WO (1) WO2013055644A2 (cg-RX-API-DMAC7.html)
ZA (1) ZA201402630B (cg-RX-API-DMAC7.html)

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Publication number Priority date Publication date Assignee Title
US8779152B2 (en) * 2011-10-13 2014-07-15 Elevance Renewable Sciences, Inc. Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes
US9512157B2 (en) 2012-11-30 2016-12-06 Elevance Renewable Sciences, Inc. Methods for preparing ruthenium carbene complexes and precursors thereto
EP3063592B1 (en) 2013-10-30 2021-04-07 California Institute of Technology Direct photopatterning of robust and diverse materials
CN112705268B (zh) * 2019-10-25 2024-02-13 香港中文大学 用于催化有氧氧化反应的两性离子-钌络合物
KR102666413B1 (ko) * 2020-12-14 2024-05-17 한화솔루션 주식회사 사이클로도데카트리엔의 선택수첨 반응을 위한 촉매 제조 방법 및 이의 제조방법으로 제조된 촉매

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA200500607A1 (ru) * 2002-10-15 2005-10-27 Бёрингер Ингельхайм Интернациональ Гмбх Рутениевые комплексы в качестве (пред)катализаторов для реакций метатезиса

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3130805A1 (de) * 1981-08-04 1983-02-24 Basf Ag, 6700 Ludwigshafen Neue ruthenium/kohle-hydrierkatalysatoren, deren herstellung und verwendung zur selektiven hydrierung von ungesaettigten carbonylverbindungen
FR2651152B1 (fr) 1989-08-23 1991-11-29 Elf Aquitaine Perfectionnement a la preparation de catalyseurs chiraux a base de complexes du ruthenium et du phosphore.
US5831108A (en) 1995-08-03 1998-11-03 California Institute Of Technology High metathesis activity ruthenium and osmium metal carbene complexes
US7329758B1 (en) 1999-05-24 2008-02-12 California Institute Of Technology Imidazolidine-based metal carbene metathesis catalysts
KR100601984B1 (ko) * 2005-01-20 2006-07-18 삼성에스디아이 주식회사 담지 촉매 및 그 제조방법
JP4347857B2 (ja) * 2006-02-28 2009-10-21 日鉱金属株式会社 :ヘキサクロロルテニウム酸アンモニウムを製造する方法
JP2007302498A (ja) * 2006-05-10 2007-11-22 Sumitomo Metal Mining Co Ltd 酸化ルテニウム粉とその製造方法
US8779152B2 (en) * 2011-10-13 2014-07-15 Elevance Renewable Sciences, Inc. Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA200500607A1 (ru) * 2002-10-15 2005-10-27 Бёрингер Ингельхайм Интернациональ Гмбх Рутениевые комплексы в качестве (пред)катализаторов для реакций метатезиса

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
BELLALOUI A. et al., Preparation and characterization of RuS2 and its catalytic properties in biphenyl hydrogenation, Comptes Rendus de l'Academie des Sciences, Serie II, 1988, v. 307, p. 1171-1176. *
SCHLEITZER-STEINKOPF E. et al., GMELINS HANDBUCH DER ANORGANISCHEN CHEMIE, RUTHENIUM, SYSTEM-NUMBER 63, 1970, VERLAG CHEMIE, GMBH, WEINHEIM, p. 82, 284-294, 302-304, 426. ALBERS M.O. et al., ( η 4 -1,5-Cyclooctadiene)ruthenium(II) complexes, Inorganic Syntheses, 1989, v. 26, p.68-77. *
WILHELM T.E. et al., Reactivity of Ru(H)(H2)Cl(PCy3)2 with Propargyl and Vinyl Chlorides: New Methodology To Give Metathesis-Active Ruthenium Carbenes, Organometallics, 1997, v. 16, No. 18, p. 3867-3869. *
WILHELM T.E. et al., Reactivity of Ru(H)(H2)Cl(PCy3)2 with Propargyl and Vinyl Chlorides: New Methodology To Give Metathesis-Active Ruthenium Carbenes, Organometallics, 1997, v. 16, No. 18, p. 3867-3869. SCHLEITZER-STEINKOPF E. et al., GMELINS HANDBUCH DER ANORGANISCHEN CHEMIE, RUTHENIUM, SYSTEM-NUMBER 63, 1970, VERLAG CHEMIE, GMBH, WEINHEIM, p. 82, 284-294, 302-304, 426. ALBERS M.O. et al., ( η 4 -1,5-Cyclooctadiene)ruthenium(II) complexes, Inorganic Syntheses, 1989, v. 26, p.68-77. BELLALOUI A. et al., Preparation and characterization of RuS2 and its catalytic properties in biphenyl hydrogenation, Comptes Rendus de l'Academie des Sciences, Serie II, 1988, v. 307, p. 1171-1176. *

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BR112014008924A2 (pt) 2017-04-25
US9637510B2 (en) 2017-05-02
US20130096314A1 (en) 2013-04-18
RU2014117297A (ru) 2015-11-20
EP2766378B1 (en) 2017-07-26
AU2012323398B2 (en) 2017-06-01
WO2013055644A2 (en) 2013-04-18
MY185097A (en) 2021-04-30
AU2012323398A1 (en) 2014-04-24
US20150210726A1 (en) 2015-07-30
IN2014DN03420A (cg-RX-API-DMAC7.html) 2015-06-05
US8975414B2 (en) 2015-03-10
MX2014004462A (es) 2015-04-09
CN104302652B (zh) 2017-02-15
EP2766378A2 (en) 2014-08-20
WO2013055644A3 (en) 2013-07-25
CN104302652A (zh) 2015-01-21
ZA201402630B (en) 2016-06-29
MX349199B (es) 2017-07-17
CA2851899A1 (en) 2013-04-18
JP2015502333A (ja) 2015-01-22
SG11201401419UA (en) 2014-05-29

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