MX2014004462A - Métodos para preparar precursores de complejos de carbeno de rutenio y complejos de carbeno de rutenio. - Google Patents
Métodos para preparar precursores de complejos de carbeno de rutenio y complejos de carbeno de rutenio.Info
- Publication number
- MX2014004462A MX2014004462A MX2014004462A MX2014004462A MX2014004462A MX 2014004462 A MX2014004462 A MX 2014004462A MX 2014004462 A MX2014004462 A MX 2014004462A MX 2014004462 A MX2014004462 A MX 2014004462A MX 2014004462 A MX2014004462 A MX 2014004462A
- Authority
- MX
- Mexico
- Prior art keywords
- ruthenium
- ruthenium carbene
- carbene complex
- preparing
- complex
- Prior art date
Links
- 229910052707 ruthenium Inorganic materials 0.000 title abstract 15
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 title abstract 11
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 title abstract 8
- 239000002243 precursor Substances 0.000 title abstract 5
- -1 ruthenium carbene complexes Chemical class 0.000 title abstract 5
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un método para preparar un precursor del complejo de carbeno de rutenio, incluye hacer reaccionar una sal de refinería con un halogenuro de hidrógeno para formar un intermediario de rutenio, y hacer reaccionar el intermediario de rutenio con un ligando tipo L para formar el precursor del complejo de carbeno de rutenio; un método para preparar un complejo de vinilcarbeno de rutenio incluye convertir un precursor del complejo de carbeno de rutenio en un complejo halogenuro de hidruro de rutenio, y hacer reaccionar el complejo halogenuro de hidruro de rutenio con un halogenuro de propargilo para formar el complejo de carbeno de rutenio; un método para preparar un complejo de carbeno de rutenio incluye convertir un precursor de complejo de carbeno de rutenio en un complejo de carbeno de rutenio que tiene la estructura (PR1 R2R3)2CI2Ru=CH-R4, en donde R1, R2 , R3 y R4 son iguales o diferentes, y en donde enlaces covalentes pueden existir entre dos o más de R1, R2 y R3 y/o dos de R1, R2 y R3 considerados en conjunto pueden formar opcionalmente un anillo con fósforo.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/272,788 US8779152B2 (en) | 2011-10-13 | 2011-10-13 | Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes |
| US13/606,640 US8975414B2 (en) | 2011-10-13 | 2012-09-07 | Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes |
| PCT/US2012/059280 WO2013055644A2 (en) | 2011-10-13 | 2012-10-09 | Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014004462A true MX2014004462A (es) | 2015-04-09 |
| MX349199B MX349199B (es) | 2017-07-17 |
Family
ID=47116392
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014004462A MX349199B (es) | 2011-10-13 | 2012-10-09 | Métodos para preparar precursores de complejos de carbeno de rutenio y complejos de carbeno de rutenio. |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US8975414B2 (es) |
| EP (1) | EP2766378B1 (es) |
| JP (1) | JP2015502333A (es) |
| CN (1) | CN104302652B (es) |
| AU (1) | AU2012323398B2 (es) |
| BR (1) | BR112014008924A2 (es) |
| CA (1) | CA2851899A1 (es) |
| IN (1) | IN2014DN03420A (es) |
| MX (1) | MX349199B (es) |
| MY (1) | MY185097A (es) |
| RU (1) | RU2619112C2 (es) |
| SG (1) | SG11201401419UA (es) |
| WO (1) | WO2013055644A2 (es) |
| ZA (1) | ZA201402630B (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8779152B2 (en) * | 2011-10-13 | 2014-07-15 | Elevance Renewable Sciences, Inc. | Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes |
| US9512157B2 (en) | 2012-11-30 | 2016-12-06 | Elevance Renewable Sciences, Inc. | Methods for preparing ruthenium carbene complexes and precursors thereto |
| WO2015065649A1 (en) | 2013-10-30 | 2015-05-07 | California Institute Of Technology | Direct photopatterning of robust and diverse materials |
| CN112705268B (zh) * | 2019-10-25 | 2024-02-13 | 香港中文大学 | 用于催化有氧氧化反应的两性离子-钌络合物 |
| KR102666413B1 (ko) * | 2020-12-14 | 2024-05-17 | 한화솔루션 주식회사 | 사이클로도데카트리엔의 선택수첨 반응을 위한 촉매 제조 방법 및 이의 제조방법으로 제조된 촉매 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3130805A1 (de) * | 1981-08-04 | 1983-02-24 | Basf Ag, 6700 Ludwigshafen | Neue ruthenium/kohle-hydrierkatalysatoren, deren herstellung und verwendung zur selektiven hydrierung von ungesaettigten carbonylverbindungen |
| FR2651152B1 (fr) | 1989-08-23 | 1991-11-29 | Elf Aquitaine | Perfectionnement a la preparation de catalyseurs chiraux a base de complexes du ruthenium et du phosphore. |
| US5831108A (en) | 1995-08-03 | 1998-11-03 | California Institute Of Technology | High metathesis activity ruthenium and osmium metal carbene complexes |
| US7329758B1 (en) | 1999-05-24 | 2008-02-12 | California Institute Of Technology | Imidazolidine-based metal carbene metathesis catalysts |
| PL199412B1 (pl) * | 2002-10-15 | 2008-09-30 | Boehringer Ingelheim Int | Nowe kompleksy rutenu jako (pre)katalizatory reakcji metatezy, pochodne 2-alkoksy-5-nitrostyrenu jako związki pośrednie i sposób ich wytwarzania |
| KR100601984B1 (ko) * | 2005-01-20 | 2006-07-18 | 삼성에스디아이 주식회사 | 담지 촉매 및 그 제조방법 |
| JP4347857B2 (ja) * | 2006-02-28 | 2009-10-21 | 日鉱金属株式会社 | ：ヘキサクロロルテニウム酸アンモニウムを製造する方法 |
| JP2007302498A (ja) * | 2006-05-10 | 2007-11-22 | Sumitomo Metal Mining Co Ltd | 酸化ルテニウム粉とその製造方法 |
| US8779152B2 (en) * | 2011-10-13 | 2014-07-15 | Elevance Renewable Sciences, Inc. | Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes |
-
2012
- 2012-09-07 US US13/606,640 patent/US8975414B2/en active Active
- 2012-10-09 SG SG11201401419UA patent/SG11201401419UA/en unknown
- 2012-10-09 JP JP2014535775A patent/JP2015502333A/ja not_active Ceased
- 2012-10-09 BR BR112014008924A patent/BR112014008924A2/pt not_active IP Right Cessation
- 2012-10-09 EP EP12780590.1A patent/EP2766378B1/en not_active Not-in-force
- 2012-10-09 CN CN201280050575.3A patent/CN104302652B/zh not_active Expired - Fee Related
- 2012-10-09 MX MX2014004462A patent/MX349199B/es active IP Right Grant
- 2012-10-09 CA CA2851899A patent/CA2851899A1/en not_active Abandoned
- 2012-10-09 AU AU2012323398A patent/AU2012323398B2/en not_active Ceased
- 2012-10-09 IN IN3420DEN2014 patent/IN2014DN03420A/en unknown
- 2012-10-09 RU RU2014117297A patent/RU2619112C2/ru active
- 2012-10-09 WO PCT/US2012/059280 patent/WO2013055644A2/en active Application Filing
- 2012-10-09 MY MYPI2014001042A patent/MY185097A/en unknown
-
2014
- 2014-04-10 ZA ZA2014/02630A patent/ZA201402630B/en unknown
-
2015
- 2015-01-30 US US14/610,519 patent/US9637510B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU2012323398A1 (en) | 2014-04-24 |
| SG11201401419UA (en) | 2014-05-29 |
| JP2015502333A (ja) | 2015-01-22 |
| WO2013055644A2 (en) | 2013-04-18 |
| MY185097A (en) | 2021-04-30 |
| CN104302652B (zh) | 2017-02-15 |
| CA2851899A1 (en) | 2013-04-18 |
| ZA201402630B (en) | 2016-06-29 |
| EP2766378B1 (en) | 2017-07-26 |
| US20130096314A1 (en) | 2013-04-18 |
| US8975414B2 (en) | 2015-03-10 |
| IN2014DN03420A (es) | 2015-06-05 |
| RU2619112C2 (ru) | 2017-05-12 |
| US9637510B2 (en) | 2017-05-02 |
| BR112014008924A2 (pt) | 2017-04-25 |
| US20150210726A1 (en) | 2015-07-30 |
| WO2013055644A3 (en) | 2013-07-25 |
| RU2014117297A (ru) | 2015-11-20 |
| AU2012323398B2 (en) | 2017-06-01 |
| MX349199B (es) | 2017-07-17 |
| EP2766378A2 (en) | 2014-08-20 |
| CN104302652A (zh) | 2015-01-21 |
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Legal Events
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| FG | Grant or registration |