RU2594157C1 - Способ регенерации и необязательного возвращения на рецикл катализатора в способе гидрокрекинга с взвешенным слоем - Google Patents
Способ регенерации и необязательного возвращения на рецикл катализатора в способе гидрокрекинга с взвешенным слоем Download PDFInfo
- Publication number
- RU2594157C1 RU2594157C1 RU2015108034/04A RU2015108034A RU2594157C1 RU 2594157 C1 RU2594157 C1 RU 2594157C1 RU 2015108034/04 A RU2015108034/04 A RU 2015108034/04A RU 2015108034 A RU2015108034 A RU 2015108034A RU 2594157 C1 RU2594157 C1 RU 2594157C1
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- resin
- aqueous solution
- paragraphs
- insoluble salt
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000004517 catalytic hydrocracking Methods 0.000 title claims abstract description 18
- 238000004064 recycling Methods 0.000 title claims description 8
- 238000011069 regeneration method Methods 0.000 title claims description 6
- 230000008929 regeneration Effects 0.000 title claims description 5
- 239000011347 resin Substances 0.000 claims abstract description 27
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 239000007864 aqueous solution Substances 0.000 claims abstract description 22
- 150000003839 salts Chemical class 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 11
- 150000001450 anions Chemical class 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 230000003472 neutralizing effect Effects 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 2
- 230000001172 regenerating effect Effects 0.000 abstract description 4
- 238000002386 leaching Methods 0.000 abstract description 3
- 238000000926 separation method Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 10
- 239000003921 oil Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- -1 naphtha 80 Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005367 electrostatic precipitation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012053 oil suspension Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007320 rich medium Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/043—Sulfides with iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/68—Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/568,473 | 2012-08-07 | ||
| US13/568,473 US8912111B2 (en) | 2012-08-07 | 2012-08-07 | Process for catalyst recovery and optional recycle in a slurry hydrocracking process |
| PCT/US2013/052448 WO2014025561A1 (en) | 2012-08-07 | 2013-07-29 | Process for catalyst recovery and optional recycle in a slurry hydrocracking process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2594157C1 true RU2594157C1 (ru) | 2016-08-10 |
Family
ID=50066638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015108034/04A RU2594157C1 (ru) | 2012-08-07 | 2013-07-29 | Способ регенерации и необязательного возвращения на рецикл катализатора в способе гидрокрекинга с взвешенным слоем |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8912111B2 (enExample) |
| EP (1) | EP2882531A4 (enExample) |
| CN (1) | CN104520000B (enExample) |
| IN (1) | IN2015DN00459A (enExample) |
| RU (1) | RU2594157C1 (enExample) |
| WO (1) | WO2014025561A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2794324C2 (ru) * | 2018-09-25 | 2023-04-17 | Эни С.П.А. | Способ гидропереработки тяжелых нефтепродуктов с повторной переработкой |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9777226B2 (en) | 2014-09-08 | 2017-10-03 | Uop Llc | Methods and systems for slurry hydrocracking with reduced feed bypass |
| CN106731833B (zh) * | 2016-12-28 | 2019-03-29 | 北京三聚环保新材料股份有限公司 | 一种湿法脱硫富液的再生工艺 |
| RS63555B1 (sr) | 2018-09-25 | 2022-09-30 | Eni Spa | Proces za hidrokonverziju teških naftnih proizvoda sa reciklažom |
| IT201800020818A1 (it) | 2018-12-21 | 2020-06-21 | Eni Spa | Procedimento di idroconversione di miscele di polimeri |
| CA3119127A1 (en) * | 2020-05-20 | 2021-11-20 | Cenovus Energy Inc. | System and method for solid catalyst separation in slurry reactors |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6056935A (en) * | 1995-05-25 | 2000-05-02 | Asahi Kasei Kogyo Kabushiki Kaisha | Iron sulfide and process for producing the same |
| WO2011128519A2 (fr) * | 2010-04-13 | 2011-10-20 | IFP Energies Nouvelles | Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape de lixiviation |
| RU2010123818A (ru) * | 2010-01-21 | 2011-12-20 | Интевеп, С.А. (Ve) | Способ регенерации металлов из тяжелых продуктов гидропереработки |
| EP2404981A1 (en) * | 2010-07-06 | 2012-01-11 | Total Raffinage Marketing | Slurry catalyst and slurry flakes valorization |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU882596A1 (ru) * | 1979-12-14 | 1981-11-23 | За витель | Способ регенерации алюмо-молибденового катализатора дл гидрокрекинга жидких углеводородов |
| CA1159385A (en) | 1980-02-21 | 1983-12-27 | Ralph J. Bertolacini | Process for hydrodemetallization of hydrocarbon streams |
| US4818373A (en) | 1984-10-19 | 1989-04-04 | Engelhard Corporation | Process for upgrading tar and bitumen |
| DK170019B1 (da) | 1993-03-12 | 1995-05-01 | Topsoe Haldor As | Fremgangsmåde til genvinding af brugt fluoreret sulfonsyrekatalysator fra en alkyleringsproces |
| US7771584B2 (en) * | 2006-12-06 | 2010-08-10 | Chevron U.S.A. Inc. | Integrated unsupported slurry catalyst preconditioning process |
| CN101918132A (zh) * | 2007-11-28 | 2010-12-15 | 雪佛龙美国公司 | 从用过的加氢处理催化剂中回收贱金属的方法 |
| US8114802B2 (en) | 2008-12-30 | 2012-02-14 | Chevron U.S.A. Inc. | Heavy oil upgrade process including recovery of spent catalyst |
| FR2958656B1 (fr) * | 2010-04-13 | 2012-05-11 | Inst Francais Du Petrole | Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape d'extraction. |
-
2012
- 2012-08-07 US US13/568,473 patent/US8912111B2/en active Active
-
2013
- 2013-07-29 EP EP13828389.0A patent/EP2882531A4/en not_active Withdrawn
- 2013-07-29 RU RU2015108034/04A patent/RU2594157C1/ru not_active IP Right Cessation
- 2013-07-29 IN IN459DEN2015 patent/IN2015DN00459A/en unknown
- 2013-07-29 CN CN201380041418.0A patent/CN104520000B/zh not_active Expired - Fee Related
- 2013-07-29 WO PCT/US2013/052448 patent/WO2014025561A1/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6056935A (en) * | 1995-05-25 | 2000-05-02 | Asahi Kasei Kogyo Kabushiki Kaisha | Iron sulfide and process for producing the same |
| RU2010123818A (ru) * | 2010-01-21 | 2011-12-20 | Интевеп, С.А. (Ve) | Способ регенерации металлов из тяжелых продуктов гидропереработки |
| WO2011128519A2 (fr) * | 2010-04-13 | 2011-10-20 | IFP Energies Nouvelles | Procede d'hydroconversion de charges petrolieres via une technologie en slurry permettant la recuperation des metaux du catalyseur et de la charge mettant en oeuvre une etape de lixiviation |
| EP2404981A1 (en) * | 2010-07-06 | 2012-01-11 | Total Raffinage Marketing | Slurry catalyst and slurry flakes valorization |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2794324C2 (ru) * | 2018-09-25 | 2023-04-17 | Эни С.П.А. | Способ гидропереработки тяжелых нефтепродуктов с повторной переработкой |
Also Published As
| Publication number | Publication date |
|---|---|
| IN2015DN00459A (enExample) | 2015-06-26 |
| CN104520000A (zh) | 2015-04-15 |
| EP2882531A1 (en) | 2015-06-17 |
| CN104520000B (zh) | 2017-02-08 |
| EP2882531A4 (en) | 2016-03-23 |
| US8912111B2 (en) | 2014-12-16 |
| WO2014025561A1 (en) | 2014-02-13 |
| US20140045679A1 (en) | 2014-02-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20190730 |