RU2386583C2 - Способ получения обогащенного водородом газового потока - Google Patents

Способ получения обогащенного водородом газового потока Download PDF

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Publication number
RU2386583C2
RU2386583C2 RU2005133159/15A RU2005133159A RU2386583C2 RU 2386583 C2 RU2386583 C2 RU 2386583C2 RU 2005133159/15 A RU2005133159/15 A RU 2005133159/15A RU 2005133159 A RU2005133159 A RU 2005133159A RU 2386583 C2 RU2386583 C2 RU 2386583C2
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Russia
Prior art keywords
conversion
dimethyl ether
hydrogen
stage
catalyst
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RU2005133159/15A
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English (en)
Russian (ru)
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RU2005133159A (ru
Inventor
Поуль Эрик Хейлунд НИЛЬСЕН (DK)
Поуль Эрик Хейлунд НИЛЬСЕН
Джон Бегильд ХАНСЕН (DK)
Джон Бегильд ХАНСЕН
Нильс Кристиан ШЕДТ (DK)
Нильс Кристиан ШЕДТ
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Хальдор Топсеэ А/С
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/12—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/12—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
RU2005133159/15A 2003-04-01 2004-03-25 Способ получения обогащенного водородом газового потока RU2386583C2 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DKPA200300499 2003-04-01
DKPA200300499 2003-04-01
DKPA200300532 2003-04-07
DKPA200300532 2003-04-07

Publications (2)

Publication Number Publication Date
RU2005133159A RU2005133159A (ru) 2006-03-20
RU2386583C2 true RU2386583C2 (ru) 2010-04-20

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RU2005133159/15A RU2386583C2 (ru) 2003-04-01 2004-03-25 Способ получения обогащенного водородом газового потока

Country Status (12)

Country Link
US (1) US7517374B2 (https=)
EP (1) EP1613551B1 (https=)
JP (1) JP4391521B2 (https=)
KR (1) KR20060002904A (https=)
AT (1) ATE342226T1 (https=)
AU (1) AU2004226237B2 (https=)
CA (1) CA2520850C (https=)
DE (1) DE602004002769T2 (https=)
ES (1) ES2273240T3 (https=)
MX (1) MXPA05010539A (https=)
RU (1) RU2386583C2 (https=)
WO (1) WO2004087566A1 (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008195585A (ja) * 2007-02-15 2008-08-28 Toshiba Corp 水素製造装置
JP2008200656A (ja) * 2007-02-22 2008-09-04 Toshiba Corp ジメチルエーテル改質触媒およびその製造方法
CN100441294C (zh) * 2007-05-10 2008-12-10 湖北省化学研究院 一氧化碳原料气脱氧催化剂及其制备和应用
EP2336083A1 (en) * 2009-12-17 2011-06-22 Topsøe Fuel Cell A/S Gas generator and processes for the conversion of a fuel into an oxygen-depleted gas and/or hydrogen-enriched gas
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0754649A1 (en) * 1995-07-21 1997-01-22 Haldor Topsoe A/S Process for the preparation of hydrogen rich gas
US5626794A (en) * 1994-12-15 1997-05-06 Amoco Corporation Process for hydroshifting dimethyl ether
RU2165790C1 (ru) * 2000-03-13 2001-04-27 Институт катализа им. Г.К. Борескова СО РАН Катализатор и способ получения обогащенной по водороду газовой смеси из диметилового эфира

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4091086A (en) * 1976-12-20 1978-05-23 Engelhard Minerals & Chemicals Corporation Process for production of hydrogen
DK147705C (da) 1982-09-07 1985-05-13 Haldor Topsoe As Fremgangsmaade til fremstilling af carbonhydrider ud fra syntesegas
CN1502546A (zh) * 1997-10-07 2004-06-09 JFE�عɹ�˾ 制造氢或合成气体用的催化剂及制造氢或合成气体的方法
DE10010069A1 (de) * 2000-03-02 2001-09-20 Xcellsis Gmbh Verfahren zum Betreiben einer Gaserzeugungsvorrichtung bzw. eines Brennstoffzellensystems, Gaserzeugungsvorrichtung und Brennstoffzellensystem
JP2003010685A (ja) * 2001-06-27 2003-01-14 Nkk Corp 水素製造触媒およびその製造方法ならびに水素を製造する方法
JP4175452B2 (ja) * 2001-08-07 2008-11-05 三菱重工業株式会社 ジメチルエーテル改質触媒およびジメチルエーテル改質方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5626794A (en) * 1994-12-15 1997-05-06 Amoco Corporation Process for hydroshifting dimethyl ether
EP0754649A1 (en) * 1995-07-21 1997-01-22 Haldor Topsoe A/S Process for the preparation of hydrogen rich gas
US5837217A (en) * 1995-07-21 1998-11-17 Haldor Topsoe A/S Process for the preparation of hydrogen rich gas
RU2165790C1 (ru) * 2000-03-13 2001-04-27 Институт катализа им. Г.К. Борескова СО РАН Катализатор и способ получения обогащенной по водороду газовой смеси из диметилового эфира

Also Published As

Publication number Publication date
ES2273240T3 (es) 2007-05-01
CA2520850A1 (en) 2004-10-14
US7517374B2 (en) 2009-04-14
KR20060002904A (ko) 2006-01-09
US20060168888A1 (en) 2006-08-03
CA2520850C (en) 2009-08-25
JP2006521990A (ja) 2006-09-28
DE602004002769D1 (de) 2006-11-23
JP4391521B2 (ja) 2009-12-24
DE602004002769T2 (de) 2007-02-08
MXPA05010539A (es) 2005-11-23
EP1613551B1 (en) 2006-10-11
AU2004226237A1 (en) 2004-10-14
ATE342226T1 (de) 2006-11-15
WO2004087566A1 (en) 2004-10-14
RU2005133159A (ru) 2006-03-20
AU2004226237B2 (en) 2009-08-13
EP1613551A1 (en) 2006-01-11

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Effective date: 20120326