RU2299231C2 - Флуоресцирующие изделия, имеющие множество пленочных слоев - Google Patents
Флуоресцирующие изделия, имеющие множество пленочных слоев Download PDFInfo
- Publication number
- RU2299231C2 RU2299231C2 RU2004134736A RU2004134736A RU2299231C2 RU 2299231 C2 RU2299231 C2 RU 2299231C2 RU 2004134736 A RU2004134736 A RU 2004134736A RU 2004134736 A RU2004134736 A RU 2004134736A RU 2299231 C2 RU2299231 C2 RU 2299231C2
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Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
- G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/422—Luminescent, fluorescent, phosphorescent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2590/00—Signboards, advertising panels, road signs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31507—Of polycarbonate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/135,537 US7264880B2 (en) | 2002-04-30 | 2002-04-30 | Fluorescent articles having multiple film layers |
| US10/135,537 | 2002-04-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2004134736A RU2004134736A (ru) | 2005-05-10 |
| RU2299231C2 true RU2299231C2 (ru) | 2007-05-20 |
Family
ID=29249473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2004134736A RU2299231C2 (ru) | 2002-04-30 | 2003-04-09 | Флуоресцирующие изделия, имеющие множество пленочных слоев |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US7264880B2 (cg-RX-API-DMAC10.html) |
| EP (1) | EP1503897B1 (cg-RX-API-DMAC10.html) |
| JP (1) | JP4610330B2 (cg-RX-API-DMAC10.html) |
| KR (1) | KR100972524B1 (cg-RX-API-DMAC10.html) |
| CN (1) | CN1649732B (cg-RX-API-DMAC10.html) |
| AU (1) | AU2003230842B2 (cg-RX-API-DMAC10.html) |
| BR (2) | BR0309588A (cg-RX-API-DMAC10.html) |
| CA (1) | CA2480519C (cg-RX-API-DMAC10.html) |
| ES (1) | ES2607803T3 (cg-RX-API-DMAC10.html) |
| MX (1) | MXPA04009570A (cg-RX-API-DMAC10.html) |
| RU (1) | RU2299231C2 (cg-RX-API-DMAC10.html) |
| WO (1) | WO2003093006A1 (cg-RX-API-DMAC10.html) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2569672C2 (ru) * | 2009-05-12 | 2015-11-27 | Авери Деннисон Корпорейшн | Прочные флуоресцентные изделия, имеющие многочисленные пленочные слои |
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| RU210231U9 (ru) * | 2021-10-20 | 2022-05-17 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ КАЗЕННОЕ ВОЕННОЕ ОБРАЗОВАТЕЛЬНОЕ УЧРЕЖДЕНИЕ ВЫСШЕГО ОБРАЗОВАНИЯ "ТЮМЕНСКОЕ ВЫСШЕЕ ВОЕННО-ИНЖЕНЕРНОЕ КОМАНДНОЕ УЧИЛИЩЕ ИМЕНИ МАРШАЛА ИНЖЕНЕРНЫХ ВОЙСК А.И. ПРОШЛЯКОВА" Министерства обороны Российской Федерации | Светоотражающий указатель прохода в минном поле |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6110566A (en) * | 1997-10-23 | 2000-08-29 | 3M Innovative Properties Company | Stabilization of fluorescent dyes in vinyl articles using hindered amine light stabilizers |
| US7264880B2 (en) * | 2002-04-30 | 2007-09-04 | Avery Dennison Corporation | Fluorescent articles having multiple film layers |
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| DE102006011436A1 (de) * | 2006-03-07 | 2007-09-13 | Sibylle Wagner-Quinte | Kunststoffverbund |
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| DE202016101032U1 (de) * | 2016-02-26 | 2016-03-17 | Büchel Industriebeteiligungen GmbH | Warndreieck |
| CN106760966A (zh) * | 2016-11-28 | 2017-05-31 | 尤晓丽 | 一种锁孔可视贴 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5005873A (en) * | 1986-04-07 | 1991-04-09 | West Michael A | Marking of articles |
| RU2063057C1 (ru) * | 1993-07-08 | 1996-06-27 | Обособленное научно-исследовательское подразделение по солнечной и точной оптике при Научно-производственном объединении "Астрофизика" | Световозвращающий экран (варианты) и способ его изготовления (варианты) |
| GB2300596A (en) * | 1995-05-10 | 1996-11-13 | Portals Ltd | Fluorescent security feature for cheques and banknotes |
| RU2101779C1 (ru) * | 1996-04-26 | 1998-01-10 | Константин Борисович Демидов | Световозвращающий материал с изображением знака |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2001A (en) * | 1841-03-12 | Sawmill | ||
| US463260A (en) * | 1891-11-17 | Valve foe steam engines | ||
| US9A (en) * | 1836-08-10 | Thomas Blanchard | Method of riveting plank or made blocks | |
| US2A (en) * | 1826-12-15 | 1836-07-29 | John Goulding | Mode of manufacturing wool or other fibrous materials |
| US812896A (en) * | 1904-07-13 | 1906-02-20 | Alvaro R Stokesbury | Rein-supporter. |
| US3830682A (en) * | 1972-11-06 | 1974-08-20 | Rowland Dev Corp | Retroreflecting signs and the like with novel day-night coloration |
| US4601861A (en) * | 1982-09-30 | 1986-07-22 | Amerace Corporation | Methods and apparatus for embossing a precision optical pattern in a resinous sheet or laminate |
| US4486363A (en) * | 1982-09-30 | 1984-12-04 | Amerace Corporation | Method and apparatus for embossing a precision optical pattern in a resinous sheet |
| JP2844339B2 (ja) * | 1988-07-05 | 1999-01-06 | 日本カーバイド工業株式会社 | 蛍光発色シート |
| CA2026161A1 (en) | 1990-06-25 | 1991-12-26 | Thomas C. Dipietro | Fluorescent pigments |
| US5117304A (en) * | 1990-09-21 | 1992-05-26 | Minnesota Mining And Manufacturing Company | Retroreflective article |
| ZA918849B (en) * | 1990-12-06 | 1992-08-26 | Minnesota Mining & Mfg | Articles exhibiting durable fluorescence |
| US5614286A (en) * | 1993-10-20 | 1997-03-25 | Minnesota Mining And Manufacturing Company | Conformable cube corner retroreflective sheeting |
| CN1071359C (zh) * | 1994-11-28 | 2001-09-19 | 美国3M公司 | 具有耐久的色彩和/或荧光性能的制品 |
| EP0812896B1 (en) | 1995-03-01 | 2001-02-07 | Morii, Toshihiro | Colored composites exhibiting long afterglow characteristics and colored articles exhibiting long afterglow characteristics |
| JP3127198B2 (ja) * | 1995-03-01 | 2001-01-22 | 森井 壽▲ひろ▼ | 有彩色残光性複合体および有彩色残光性物品 |
| US5674622A (en) * | 1995-09-29 | 1997-10-07 | Minnesota Mining And Manufacturing Company | Fluorescent dye blends |
| US5672643A (en) * | 1995-09-29 | 1997-09-30 | Minnesota Mining And Manufacturing Company | Fluorescent dye blends |
| US5920429A (en) * | 1995-09-29 | 1999-07-06 | Minnesota Mining And Manufacturing Company | Fluorescent dye blends |
| US6015214A (en) * | 1996-05-30 | 2000-01-18 | Stimsonite Corporation | Retroreflective articles having microcubes, and tools and methods for forming microcubes |
| JP3974959B2 (ja) | 1996-09-30 | 2007-09-12 | スリーエム カンパニー | 再帰反射性情報表示シートの製造方法 |
| US6110566A (en) * | 1997-10-23 | 2000-08-29 | 3M Innovative Properties Company | Stabilization of fluorescent dyes in vinyl articles using hindered amine light stabilizers |
| US6001936A (en) * | 1997-10-24 | 1999-12-14 | 3M Innovative Properties Company | Dye enhanced durability through controlled dye environment |
| EP1049578B1 (en) | 1998-01-21 | 2002-12-04 | Reflexite Corporation | Extended life fluorescence polyvinyl chloride sheeting |
| JP2000212554A (ja) * | 1998-11-20 | 2000-08-02 | Idemitsu Kosan Co Ltd | 蛍光変換媒体及びそれを用いた表示装置 |
| SE9904080D0 (sv) * | 1998-12-03 | 1999-11-11 | Ciba Sc Holding Ag | Fotoinitiatorberedning |
| JP3430094B2 (ja) | 1998-12-10 | 2003-07-28 | 日産自動車株式会社 | 塗装構造 |
| WO2000047407A1 (en) | 1999-02-12 | 2000-08-17 | Reflexite Corporation | Extended life fluorescence polyvinyl chloride sheeting |
| JP2001092393A (ja) * | 1999-09-24 | 2001-04-06 | Shiina:Kk | 発光シート |
| JP2001174809A (ja) * | 1999-12-15 | 2001-06-29 | Asahi Kasei Corp | 面状偏光発光体 |
| US6375776B1 (en) * | 2000-01-24 | 2002-04-23 | Avery Dennison Corporation | Method for forming multi-layer laminates with microstructures |
| US6312132B1 (en) * | 2000-09-12 | 2001-11-06 | 3M Innovative Properties Company | Fluorescent red article and retroreflective article made therefrom |
| US6514594B1 (en) | 2000-11-09 | 2003-02-04 | Avery Dennison Corporation | Fluorescent polymeric articles having screening layer formed from U.V. light absorbing polymer |
| US6972147B1 (en) | 2000-11-09 | 2005-12-06 | Avery Dennison Corporation | Fluorescent polymeric articles fabricated from U.V. light absorbing polymer |
| US6531205B1 (en) | 2001-02-14 | 2003-03-11 | Avery Dennison Corporation | Fluorescent yellow retroreflective sheeting |
| US7618709B2 (en) * | 2002-04-30 | 2009-11-17 | Avery Dennison Corporation | Fluorescent articles having multiple film layers |
| US7264880B2 (en) * | 2002-04-30 | 2007-09-04 | Avery Dennison Corporation | Fluorescent articles having multiple film layers |
| US8034436B2 (en) * | 2002-04-30 | 2011-10-11 | Avery Dennison Corporation | Fluorescent article having multiple layers |
| DE10332650A1 (de) * | 2003-07-18 | 2005-02-10 | Kronos International, Inc. | Verfahren zur Oberflächenbehandlung eines Titandioxid-Pigments |
-
2002
- 2002-04-30 US US10/135,537 patent/US7264880B2/en not_active Expired - Lifetime
-
2003
- 2003-04-09 BR BRPI0309588-6A patent/BR0309588A/pt active IP Right Grant
- 2003-04-09 ES ES03723946.4T patent/ES2607803T3/es not_active Expired - Lifetime
- 2003-04-09 WO PCT/US2003/010841 patent/WO2003093006A1/en not_active Ceased
- 2003-04-09 EP EP03723946.4A patent/EP1503897B1/en not_active Expired - Lifetime
- 2003-04-09 BR BRPI0309588-6A patent/BRPI0309588B1/pt unknown
- 2003-04-09 RU RU2004134736A patent/RU2299231C2/ru active
- 2003-04-09 AU AU2003230842A patent/AU2003230842B2/en not_active Expired
- 2003-04-09 MX MXPA04009570A patent/MXPA04009570A/es not_active Application Discontinuation
- 2003-04-09 KR KR1020047017514A patent/KR100972524B1/ko not_active Expired - Lifetime
- 2003-04-09 CN CN038096374A patent/CN1649732B/zh not_active Expired - Lifetime
- 2003-04-09 CA CA 2480519 patent/CA2480519C/en not_active Expired - Lifetime
- 2003-04-09 JP JP2004501162A patent/JP4610330B2/ja not_active Expired - Lifetime
-
2007
- 2007-04-02 US US11/731,888 patent/US7618710B2/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5005873A (en) * | 1986-04-07 | 1991-04-09 | West Michael A | Marking of articles |
| RU2063057C1 (ru) * | 1993-07-08 | 1996-06-27 | Обособленное научно-исследовательское подразделение по солнечной и точной оптике при Научно-производственном объединении "Астрофизика" | Световозвращающий экран (варианты) и способ его изготовления (варианты) |
| GB2300596A (en) * | 1995-05-10 | 1996-11-13 | Portals Ltd | Fluorescent security feature for cheques and banknotes |
| RU2101779C1 (ru) * | 1996-04-26 | 1998-01-10 | Константин Борисович Демидов | Световозвращающий материал с изображением знака |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2569672C2 (ru) * | 2009-05-12 | 2015-11-27 | Авери Деннисон Корпорейшн | Прочные флуоресцентные изделия, имеющие многочисленные пленочные слои |
| RU210231U1 (ru) * | 2021-10-20 | 2022-04-01 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ КАЗЕННОЕ ВОЕННОЕ ОБРАЗОВАТЕЛЬНОЕ УЧРЕЖДЕНИЕ ВЫСШЕГО ОБРАЗОВАНИЯ "ТЮМЕНСКОЕ ВЫСШЕЕ ВОЕННО-ИНЖЕНЕРНОЕ КОМАНДНОЕ УЧИЛИЩЕ ИМЕНИ МАРШАЛА ИНЖЕНЕРНЫХ ВОЙСК А.И. ПРОШЛЯКОВА" Министерства обороны Российской Федерации | Светоотражающий указатель прохода в минном поле |
| RU210231U9 (ru) * | 2021-10-20 | 2022-05-17 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ КАЗЕННОЕ ВОЕННОЕ ОБРАЗОВАТЕЛЬНОЕ УЧРЕЖДЕНИЕ ВЫСШЕГО ОБРАЗОВАНИЯ "ТЮМЕНСКОЕ ВЫСШЕЕ ВОЕННО-ИНЖЕНЕРНОЕ КОМАНДНОЕ УЧИЛИЩЕ ИМЕНИ МАРШАЛА ИНЖЕНЕРНЫХ ВОЙСК А.И. ПРОШЛЯКОВА" Министерства обороны Российской Федерации | Светоотражающий указатель прохода в минном поле |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2004134736A (ru) | 2005-05-10 |
| BRPI0309588B1 (pt) | 2019-10-08 |
| US20030203211A1 (en) | 2003-10-30 |
| JP2005528248A (ja) | 2005-09-22 |
| CN1649732A (zh) | 2005-08-03 |
| CN1649732B (zh) | 2010-05-26 |
| EP1503897A1 (en) | 2005-02-09 |
| KR20050005462A (ko) | 2005-01-13 |
| AU2003230842A1 (en) | 2003-11-17 |
| US7618710B2 (en) | 2009-11-17 |
| KR100972524B1 (ko) | 2010-07-28 |
| MXPA04009570A (es) | 2005-07-14 |
| BR0309588A (pt) | 2007-03-06 |
| ES2607803T3 (es) | 2017-04-04 |
| CA2480519C (en) | 2010-10-05 |
| AU2003230842B2 (en) | 2008-08-28 |
| US7264880B2 (en) | 2007-09-04 |
| JP4610330B2 (ja) | 2011-01-12 |
| WO2003093006A1 (en) | 2003-11-13 |
| CA2480519A1 (en) | 2003-11-13 |
| EP1503897B1 (en) | 2016-11-02 |
| US20070184278A1 (en) | 2007-08-09 |
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