RU2161164C2 - Способ получения винилароматических сополимеров, усиленных каучуком, винилароматические сополимеры - Google Patents
Способ получения винилароматических сополимеров, усиленных каучуком, винилароматические сополимеры Download PDFInfo
- Publication number
- RU2161164C2 RU2161164C2 RU96102853/04A RU96102853A RU2161164C2 RU 2161164 C2 RU2161164 C2 RU 2161164C2 RU 96102853/04 A RU96102853/04 A RU 96102853/04A RU 96102853 A RU96102853 A RU 96102853A RU 2161164 C2 RU2161164 C2 RU 2161164C2
- Authority
- RU
- Russia
- Prior art keywords
- vinyl aromatic
- rubber
- copolymers
- polar solvent
- diene
- Prior art date
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- 229920002554 vinyl polymer Polymers 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 36
- 229920001577 copolymer Polymers 0.000 title claims abstract description 34
- 229920001971 elastomer Polymers 0.000 claims abstract description 59
- 239000000178 monomer Substances 0.000 claims abstract description 49
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 239000003999 initiator Substances 0.000 claims abstract description 15
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 229920003244 diene elastomer Polymers 0.000 claims abstract description 12
- 239000002798 polar solvent Substances 0.000 claims abstract description 8
- 239000000806 elastomer Substances 0.000 claims abstract description 7
- 239000012454 non-polar solvent Substances 0.000 claims abstract description 7
- LLVWLCAZSOLOTF-UHFFFAOYSA-N 1-methyl-4-[1,4,4-tris(4-methylphenyl)buta-1,3-dienyl]benzene Chemical compound C1=CC(C)=CC=C1C(C=1C=CC(C)=CC=1)=CC=C(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 LLVWLCAZSOLOTF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 5
- 239000005060 rubber Substances 0.000 claims description 51
- 238000006116 polymerization reaction Methods 0.000 claims description 24
- 239000011541 reaction mixture Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 150000004945 aromatic hydrocarbons Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 239000011877 solvent mixture Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 abstract description 27
- 239000000126 substance Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 22
- 239000000243 solution Substances 0.000 description 21
- 229920001400 block copolymer Polymers 0.000 description 16
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 15
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 15
- 239000002245 particle Substances 0.000 description 15
- 229920002857 polybutadiene Polymers 0.000 description 15
- 239000005062 Polybutadiene Substances 0.000 description 14
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 10
- 150000001993 dienes Chemical class 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 7
- -1 for example Substances 0.000 description 7
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000008364 bulk solution Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000003039 volatile agent Substances 0.000 description 3
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical class CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 230000002902 bimodal effect Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000003701 inert diluent Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- SVHAMPNLOLKSFU-UHFFFAOYSA-N 1,2,2-trichloroethenylbenzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC=C1 SVHAMPNLOLKSFU-UHFFFAOYSA-N 0.000 description 1
- AUHKVLIZXLBQSR-UHFFFAOYSA-N 1,2-dichloro-3-(1,2,2-trichloroethenyl)benzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC(Cl)=C1Cl AUHKVLIZXLBQSR-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- XPXMCUKPGZUFGR-UHFFFAOYSA-N 1-chloro-2-(1,2,2-trichloroethenyl)benzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC=C1Cl XPXMCUKPGZUFGR-UHFFFAOYSA-N 0.000 description 1
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QROGIFZRVHSFLM-UHFFFAOYSA-N prop-1-enylbenzene Chemical class CC=CC1=CC=CC=C1 QROGIFZRVHSFLM-UHFFFAOYSA-N 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- BWSZXUOMATYHHI-UHFFFAOYSA-N tert-butyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(C)(C)C BWSZXUOMATYHHI-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- 238000002255 vaccination Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI950280A IT1274361B (it) | 1995-02-16 | 1995-02-16 | Procedimento per la preparazione di copolimeri vinilaromatici rinforzati con gomma |
| ITMI95/A000280 | 1995-02-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU96102853A RU96102853A (ru) | 1998-05-10 |
| RU2161164C2 true RU2161164C2 (ru) | 2000-12-27 |
Family
ID=11370562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU96102853/04A RU2161164C2 (ru) | 1995-02-16 | 1996-02-15 | Способ получения винилароматических сополимеров, усиленных каучуком, винилароматические сополимеры |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6114461A (enExample) |
| EP (1) | EP0727449B1 (enExample) |
| JP (1) | JP3691149B2 (enExample) |
| KR (1) | KR100415447B1 (enExample) |
| CN (1) | CN1064975C (enExample) |
| AT (1) | ATE203550T1 (enExample) |
| CA (1) | CA2169610C (enExample) |
| DE (1) | DE69614012T2 (enExample) |
| DK (1) | DK0727449T3 (enExample) |
| ES (1) | ES2159654T3 (enExample) |
| GR (1) | GR3036509T3 (enExample) |
| IT (1) | IT1274361B (enExample) |
| PT (1) | PT727449E (enExample) |
| RU (1) | RU2161164C2 (enExample) |
| SI (1) | SI0727449T1 (enExample) |
| TW (1) | TW322485B (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2352591C2 (ru) * | 2004-04-16 | 2009-04-20 | Полимери Эуропа С.П.А. | Способ получения винилароматических (со)полимеров, привитых на эластомере регулируемым путем |
| RU2470952C2 (ru) * | 2007-12-12 | 2012-12-27 | Полимери Эуропа С.П.А. | Полунепрерывный объединенный способ производства ударостойких винилароматических (со)полимеров путем последовательной анионной/радикальной полимеризации |
| RU2493174C2 (ru) * | 2008-08-20 | 2013-09-20 | Полимери Эуропа С.П.А. | Способ синтеза функционализированных поли(1,3-алкадиенов) и их применение в получении ударопрочных винилароматических полимеров |
| RU2506278C2 (ru) * | 2008-12-16 | 2014-02-10 | Полимери Эуропа С.П.А. | Усиленный каучуком винилароматический (со) полимер, обладающий оптимальным сочетанием физико-механических свойств и высокого блеска |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19632556A1 (de) * | 1996-08-13 | 1998-02-19 | Bayer Ag | Verfahren zur Herstellung von hochkautschukhaltigen ABS-Formmassen |
| IT1284599B1 (it) * | 1996-09-27 | 1998-05-21 | Enichem Spa | Procedimento per la preparazione di polimeri vinilaromatici rinforzati con gomma |
| KR100384385B1 (ko) * | 1998-03-23 | 2003-08-27 | 주식회사 엘지화학 | 고광택성및고충격성고무변성스티렌계수지의제조방법 |
| US6323282B1 (en) * | 1999-05-17 | 2001-11-27 | The Dow Chemical Company | Bimodal rubbers and rubber modified high impact monovinylidene aromatic polymers produced therefrom |
| US6306962B1 (en) | 1999-09-30 | 2001-10-23 | The Dow Chemical Company | Flow carbonate polymer blends |
| EP1246857B1 (en) * | 1999-12-28 | 2006-08-23 | Bayer Corporation | Process for the preparation of an extrusion-grade abs polymer having improved properties |
| KR100425244B1 (ko) * | 2001-11-14 | 2004-03-30 | 주식회사 엘지화학 | 가공성이 우수한 블록 공중합체와 그의 제조방법, 및 이를포함하는 수지 조성물 |
| US6716935B1 (en) * | 2002-12-19 | 2004-04-06 | 3M Innovative Properties Company | Continuous process for the production of controlled architecture materials under high solids loading conditions |
| US20050267261A1 (en) * | 2004-05-14 | 2005-12-01 | Dow Global Technologies, Inc. | Low gloss thermoplastic polyolefin composition |
| US20110054123A1 (en) * | 2009-08-26 | 2011-03-03 | Fina Technology, Inc. | High Impact Polymers and Methods of Making and Using Same |
| DE102017004563A1 (de) | 2017-03-05 | 2018-09-06 | Entex Rust & Mitschke Gmbh | Entgasen beim Extrudieren von Polymeren |
| DE102018001412A1 (de) | 2017-12-11 | 2019-06-13 | Entex Rust & Mitschke Gmbh | Entgasen beim Extrudieren von Stoffen, vorzugsweise von Kunststoffen |
| KR102450643B1 (ko) | 2020-10-14 | 2022-10-04 | 이종구 | 심미감 및 장식미 향상의 조형경관 조명등 |
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| DE3018643A1 (de) * | 1980-05-16 | 1981-11-26 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von schlagfest modifizierten styrolpolymerisaten |
| DE3023721A1 (de) * | 1980-06-25 | 1982-01-21 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen herstellung von mit kautschuk modifizierten polymerisaten von vinylaromaten |
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| IT1063217B (it) * | 1976-04-22 | 1985-02-11 | Snam Progetti | Processo per la preparazione di materiali termoplastici e materiali cosi ottenuti |
| DE3137418A1 (de) * | 1981-09-19 | 1983-03-31 | Basf Ag, 6700 Ludwigshafen | Blockcopolymerisat |
| JPS6295312A (ja) * | 1985-10-22 | 1987-05-01 | Asahi Chem Ind Co Ltd | 良好な成形品外観を与えるゴム補強芳香族モノビニル系樹脂の連続的製造方法 |
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- 1995-02-16 IT ITMI950280A patent/IT1274361B/it active IP Right Grant
-
1996
- 1996-02-02 PT PT96101503T patent/PT727449E/pt unknown
- 1996-02-02 SI SI9630320T patent/SI0727449T1/xx unknown
- 1996-02-02 DE DE69614012T patent/DE69614012T2/de not_active Revoked
- 1996-02-02 DK DK96101503T patent/DK0727449T3/da active
- 1996-02-02 EP EP96101503A patent/EP0727449B1/en not_active Revoked
- 1996-02-02 AT AT96101503T patent/ATE203550T1/de not_active IP Right Cessation
- 1996-02-02 ES ES96101503T patent/ES2159654T3/es not_active Expired - Lifetime
- 1996-02-07 TW TW085101521A patent/TW322485B/zh not_active IP Right Cessation
- 1996-02-15 CA CA002169610A patent/CA2169610C/en not_active Expired - Fee Related
- 1996-02-15 CN CN961057041A patent/CN1064975C/zh not_active Expired - Fee Related
- 1996-02-15 RU RU96102853/04A patent/RU2161164C2/ru active
- 1996-02-15 KR KR1019960003756A patent/KR100415447B1/ko not_active Expired - Fee Related
- 1996-02-16 JP JP02962296A patent/JP3691149B2/ja not_active Expired - Fee Related
-
1997
- 1997-02-21 US US08/805,077 patent/US6114461A/en not_active Expired - Lifetime
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2001
- 2001-08-31 GR GR20010401369T patent/GR3036509T3/el not_active IP Right Cessation
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE3018643A1 (de) * | 1980-05-16 | 1981-11-26 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von schlagfest modifizierten styrolpolymerisaten |
| DE3023721A1 (de) * | 1980-06-25 | 1982-01-21 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen herstellung von mit kautschuk modifizierten polymerisaten von vinylaromaten |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2352591C2 (ru) * | 2004-04-16 | 2009-04-20 | Полимери Эуропа С.П.А. | Способ получения винилароматических (со)полимеров, привитых на эластомере регулируемым путем |
| RU2470952C2 (ru) * | 2007-12-12 | 2012-12-27 | Полимери Эуропа С.П.А. | Полунепрерывный объединенный способ производства ударостойких винилароматических (со)полимеров путем последовательной анионной/радикальной полимеризации |
| RU2493174C2 (ru) * | 2008-08-20 | 2013-09-20 | Полимери Эуропа С.П.А. | Способ синтеза функционализированных поли(1,3-алкадиенов) и их применение в получении ударопрочных винилароматических полимеров |
| RU2506278C2 (ru) * | 2008-12-16 | 2014-02-10 | Полимери Эуропа С.П.А. | Усиленный каучуком винилароматический (со) полимер, обладающий оптимальным сочетанием физико-механических свойств и высокого блеска |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69614012T2 (de) | 2002-03-14 |
| DE69614012D1 (de) | 2001-08-30 |
| ATE203550T1 (de) | 2001-08-15 |
| US6114461A (en) | 2000-09-05 |
| CN1134428A (zh) | 1996-10-30 |
| KR100415447B1 (ko) | 2004-05-20 |
| ITMI950280A1 (it) | 1996-08-16 |
| IT1274361B (it) | 1997-07-17 |
| SI0727449T1 (en) | 2001-10-31 |
| PT727449E (pt) | 2001-11-30 |
| EP0727449B1 (en) | 2001-07-25 |
| DK0727449T3 (da) | 2001-10-01 |
| ES2159654T3 (es) | 2001-10-16 |
| CA2169610A1 (en) | 1996-08-17 |
| TW322485B (enExample) | 1997-12-11 |
| CN1064975C (zh) | 2001-04-25 |
| EP0727449A2 (en) | 1996-08-21 |
| CA2169610C (en) | 2006-10-03 |
| ITMI950280A0 (it) | 1995-02-16 |
| JP3691149B2 (ja) | 2005-08-31 |
| EP0727449A3 (en) | 1999-01-13 |
| KR960031499A (ko) | 1996-09-17 |
| GR3036509T3 (en) | 2001-11-30 |
| JPH08295710A (ja) | 1996-11-12 |
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