RU2044538C1 - Composition for washing body and hair - Google Patents

Abstract

FIELD: cosmetics. SUBSTANCE: this washing composition includes surfactant, sodium chloride, M. chamomile extract, dye, aromatic, water, extract prepared from either carrot seeds or rice refuse and carrot seeds, as part of compound CO₂ extract prepared from M. chamomile and carrot seeds or compound CO₂ extract prepared from M. chamomile, carrot seeds and rice refuse, plus hydrophytoconcentrate of calendula, resorcin and citric acid. Use of compound CO₂ extracts and hydrophytoconcentrate of calendula combined with the rest of formulation components promotes vitaminization of skin and hair, inhibits formation of dandruff, produces soft washing effect, retards cutaneous fatty secretion and reduces inflammatory reaction of skin. Ingredients of disclosed composition having bactericidal and antioxidizing properties ensure its long life. This composition is excellent remedy for treating seborrhea of head and body skin and in addition causes no discomfort. EFFECT: excellent cosmetic composition. 5 tbl

Description

 The invention relates to cosmetics and relates to detergents.

 Known hair detergent formulations containing plant extracts.

 Known means for washing hair containing ethoxylated Na-lauryl sulfate, alkylamidopropyl betaine, sodium chloride, water-alcohol-glycerin extract of nettle, chladonic extract of algae furcellaria, formalin, perfume and water, preventing the appearance of dandruff, which improves hair structure.

 Known means for washing hair containing ethoxylated sodium lauryl sulfate, sodium chloride, formalin, perfume and water, and also to ensure washing of any type of hair while strengthening and stimulating their growth, it additionally contains water-alcohol-glycerin extracts of sea buckthorn, horse chestnut , horseradish leaves, monolauryl sulfosuccinate, FFA diethanolamides, orthophosphoric acid, pearlescent concentrate.

 Known means for washing hair, in which the components are taken in the following ratio, wt.

Oxyethylated Lauryl Sulfate Na 15-20 Diethanolamides FFA 0.5-4.0 Sodium Chloride 0.5-4.0
Oil extracts: rhizomes of calamus 0.3-0.6 chilli pepper 0.03-0.1 chamomile flowers 0.2-0.4 Lactic acid 0.2-0.5 Preservative 0.03-0.1 Dye 0, 0001-0.001 Fragrance 0.5-1.5 Water to 100
The combination of the components used provides stimulation of hair growth.

 The purpose of the invention is an increase in the absorption of biologically active substances, an increase in the anti-dandruff effect, and a decrease in the irritating effect.

The goal is achieved by the fact that in the proposed tool for washing the body and hair containing surfactants, table salt, camomile extractives, dye, perfume and water, calendula hydrophytoconcentrate, resorcinol, citric acid are additionally introduced, and chamomile extractives as part of the complex CO ₂ extract from chamomile and carrot seeds or from chamomile, carrot seeds and rice waste in the following ratio of components, wt.

Na sulfa ethoxylates in terms of 100% 10-30
Monoethanolamides cas-
of torus oil or diethanolamides SJK 1-10 Salt 1-10
Hydrophytoconcentrate Calendula 0.001-0.1
CO ₂ extract complex -
chamomile and seed
carrots or CO ₂ extract
complex of chamomile,
seeds of carrots and rice waste 0.01-1.0 Resorcinol 0.1-1.0 Citric acid 0.005-0.1 Dye 0.0005-0.005 Fragrance 0.1-2.5 Water to 100
The goal is achieved in that the optimal composition, including the biologically active substances of the extracts, castor oil monoethanolamides, citric acid, table salt provides the conditions for the maximum absorption of biologically active substances, enhancing the anti-dandruff effect, and reducing the irritating effect.

The combination in a surfactant complex of a mixture of sodium sulfoethoxylates, castor oil monoethanolamides, complex CO ₂ extracts from chamomile and carrot seeds and rice waste, and carrot seeds or from chamomile, carrot seeds and rice waste, calendula hydrophytoconcentrate, sodium chloride, citric acid, resorcinol increases vitaminization of the skin and hair roots, enhances the conditioning effect, prevents dryness, brittle hair, prevents the formation of dandruff.

When using a product made according to the proposed recipe, in soapy water and foam, complex CO ₂ extracts from chamomile, carrot seeds and rice waste and calendula hydrophytoconcentrate are in a molecularly dispersed state and therefore have an increased ability to affect the skin and hair and penetrate in the pores of the skin, has a favorable general hygiene and therapeutic effect. A specially selected composition of the extracts in combination with the components of the formulation gives the skin elasticity, prevents the formation of dandruff, strengthens the hair, improves the condition of the skin.

 As a surfactant, Na sulfoethoxylates are introduced into the formulation of the agents, which provide an excellent washing and foaming effect, as well as castor oil monoethanolamides, which have a softening effect on the skin, participate in the skin's fat balance, stabilize the foam in the formulation and drown out the aqueous concentrates of anionic surfactants.

 Citric acid improves foaming, washing in hard water, reduces the cloud point of formulations, as well as to create an acidic environment, which has a beneficial effect on the general condition of the skin and hair when using the proposed means for washing the body and hair.

 Resorcinol is formulated as an anti-transitional supplement.

 To increase the viscosity of the shampoo, sodium chloride was introduced into the formulation, which, in addition, acts as a preservative and stabilizer of the foam.

 As a dye, it is proposed to use an acid yellow methanilic dye, which is distinguished by brightness of tone, stability.

Complex CO ₂ extract N 21 from carrot and chamomile seeds is a complex mixture combining the properties of chamomile and carrot seeds.

The composition of the complex CO ₂ extract N 21 includes the following main components, saponified fraction of 18.65; free acids 2,3; waxes 0.78-1.22; essential oil 11.29; azulene 0.053; tocopherols 0.37; sterols 0.87; carotenoids (3.9-5.7) x 10 ^-3 . The composition of free acids includes 9.84% myristic, 39.35 palmitic acids.

 Extractive substances from chamomile pharmacy biologically active complex of anti-inflammatory, anti-allergic and disinfecting effects, this is a complex mixture of active substances of a lipoid, terpenoid nature. The lipid fraction contains, waxes 5.0-7.0; free and bound acids 5.4-10.0; phytosterols (vitamin D) 1.0-1.2; tocophenols 0.09-0.11; carotenoids 0.011-0.03. Terpene fractions contain a number of bioactive substances, including the main azulenogens, as well as bisabolol, etc. The presence of biologically active substances: components of essential oil (bisabolol, en-indicycloester) and essential acids (linoleic and linolenic) enhances the general effect of chamomile extractives. Carrot extractives are a vitamin complex of plasticizing, regenerating and nourishing action, which contains up to 49% of free acids and acidic components of esters, tocopherols, up to 0.02% sterols, 0.42% carotenoids, 0.002% phospholipids.

 Its value is also determined by the biologically active polyunsaturated fatty acids linoleic, linolenic (vitamin F factor).

 Complex extract N 21 is a vitamin complex of plasticizing, regenerating, nourishing effects. The biologically active substances included in the extract provide a vitaminizing, anti-inflammatory, anti-allergic, epithelizing effect.

Complex CO ₂ extract from chamomile carrot seeds and rice waste (N 27) combines the properties of chamomile, carrot seeds and rice waste. It consists of saponifiable 68.4% and unsaponifiable 18.44% functions, free acids 1.98% tocopherols 0.12% waxes 5.09% Acid fractions contain biologically active high molecular weight unsaturated acids, the lipid part is fat-soluble vitamins.

 Extractive substances of rice waste (rice flour) are a complex of hydratant, plasticizing and extinguishing substances containing free fatty acids 11.7% unsaponifiable fraction 27.3% saponifiable fraction 39.0% waxes 0.6% tocopherols.

Extractives extracted into the composition of the complex extract from rice waste have an exfoliating softening effect, have a nourishing and vitaminizing effect, are a plasticizing and biologically active additive. In the composition of the complex CO ₂ -extract form a film-forming effect. The lipid complex is represented by waxes up to 5.5% tocopherols up to 450 mg phospholipids. Polyunsaturated fatty acids (vitamin F factor are contained in a balanced ratio with the fatty oil fraction of carrot seed extractives.

 The combination of tocopherols of extractive substances of rice flour and carrot seeds and high molecular weight polyunsaturated fatty acids (vitamin F factor) enhance the synthesis of plant hormones that have a regenerating effect, increase O-B processes, stimulate the permeability of blood vessels and skin cells, which contributes to the great absorption of vitamins, enriches them skin cells, reduces porosity, increases tone and elasticity.

 Similar properties of the detergent are provided by the selection of certain biologically active components, which exhibit an enhanced effect when mixed.

The presence of free acids and acid components in the CO ₂ extract provides shampoo formulations when combined with a surfactant, reducing its alkalinity, which has a beneficial effect on the scalp, reducing its dryness, and reducing brittle hair.

 A fine dispersion of the biologically active components of the extract in the soap foam promotes their penetration into the pores of the skin and thus into the hair bags, which has a beneficial therapeutic and prophylactic effect.

Complex CO ₂ -extracts N 21 from chamomile and carrot seeds or N 27 from chamomile, carrot seeds and rice waste are joint balanced products containing biologically active, pharmacoactive, aromatic, coloring substances and other valuable components. This allows you to refuse to enter into the formulation of synthetic components whose functions have been successfully replaced by complex natural extracts.

Calendula hydrofitoconcentrate is a dry extract of the aqueous extract of the waste of calendula raw material after CO ₂ extraction, its properties are determined by the biologically active substances of calendula, which have become part of the hydrofitoconcentrate. They exhibit antispasmodic properties, antiseptic, anti-inflammatory, wound healing. Glycosides, mucous and bitter substances, salicylic acid, ascorbic acid (up to 6.0%), hydrocarbons, alcohols, flavonoids, etc. are transferred to the hydrophytoconcentrate. Calendula preparations have a wide spectrum of pharmacological activity, which is due to the rich content of flavonoids, vitamins, tannins and etc.

 Vitamin C affects intracellular respiration, participates in protein and carbohydrate metabolism, strengthens blood vessels, participates in the synthesis of the melanin pigment, stimulates collagen synthesis, accelerates tissue regeneration (wound healing), and normalizes the permeability of skin capillaries.

 Salicylic acid increases the tension and density of the skin, acts in a disinfecting manner, degreases the skin and hair.

 Inositol (6-atomic cyclohexane alcohol) due to the physiological effect is associated with B vitamins, takes part in fat metabolism. Its reduced content in the hair leads to baldness. Recommended for hair loss, graying, impaired lipid metabolism of the skin.

 Extract carotenoids in combination with vitamin F and tocopherols stabilize the inositol content.

 Carotenoids in combination with minerals (NaCl) activate areas of the skin in water, fat and mineral metabolism.

 Free and bound fatty acids of the extract (linoleic, linolenic factor of vitamin F prevents hair thinning, fragility, hair loss, dandruff formation.

 The lipid function of the extracts provides a balanced thickness of the protective layer on the surface of the skin and hair, through which nutrients penetrate, on the one hand, and on the other, protect the skin from surfactant surpluses, which when deeply penetrated into the skin lead to fragility at the roots and hair loss.

 Waxes and sterols of extracts introduced into the recipe together with MEA of castor oil provide swelling and enhance the saturation of hair, create a thin film on their surface, which contributes to better hair styling and preservation of hair.

The CO ₂ extract from the seeds of carrots, chamomile and rice waste in combination with biologically active substances of calendula hydrophytoconcentrate reduce the sebum secretion of hair, inflammatory skin reactions, resorption of psoriatic papules.

 Due to the emollient properties of chamomile extractives, the irritating effect of anionic surfactants on the skin and hair is partially removed.

 Azulene, introduced into the formulation with biologically active substances of the extracts, causes granulation and epithelization of damaged skin. Chamomile extractives in combination with the calendula vitamin complex accelerate tissue regeneration (wound healing), normalizes the permeability of skin capillaries. They promote the formation of melanin and at the same time soften the skin.

 A biologically active complex (linoleic, linolenic acid, factor F extracts enhance the effect of resorcinol as an anti-surface additive. Since resorcinol acts on the skin as a corrosive and cauterizing method, its use in the formulation of the drug in combination with plant extracts that have properties that remove the irritating effect of other components is appropriate.

 In general, the biologically active substances of the extracts normalize the metabolic processes of the skin, increase its tugor, increase blood flow to the hair follicles, strengthen hair and accelerate their growth, expand capillaries, and have a general tonic effect on the skin. In addition, the extracts exhibit bactericidal and wound healing properties.

 Being weak bacteriostats, such components of extracts as glycerides and free acids in combination with castor oil MEA contribute to the implementation of the sanitary-hygienic function of the skin as a protective organ of the human body, since at least partial removal of fat occurs during the interaction of detergents with the surface of the skin and hair films from their surface.

 Absorbed on the surface of the hair, mainly in the places of damage, surfactants in combination with biologically active substances of the extracts form a protective absorption film, give the hair smoothness.

Under the influence of biologically active substances of the extracts, the proposed tool promotes the influx of amino acids, phosphates, affects the enzymatic processes, the exchange of sulfur, keratization of the epithelium, the exchange of proteins, amino acids, fats, carbohydrates, minerals. In the presence of CO ₂ extracts rich in tocopherols, the content of vitamin complexes is stabilized for a long time.

 The set of biologically active substances of the extracts, introduced together in the formulation of the proposed funds, creates the conditions for enhancing mutual penetration and their effects on the scalp and hair.

 In order for the hair to be able to absorb beneficial substances, certain conditions must be created. The scaly, mosaic surface of the hair is predominantly hydrophobic. The general condition of the surface depends on many factors, and not least on the moisture content. The surface of the hair accessible for absorption depends on the lipid content, moisture, and on the time of contact with the surfactant solution, since the fibers of kerotin, swelling, unfold and present additional active centers for adsorption. The maximum adsorption with respect to anionic surfactants occurs in an acidic medium.

 In the alkaline environment of detergents, hair is usually very susceptible to damage, becoming brittle and excessively dry. Therefore, the creation of an acidic environment due to the significant amount of acids in the extracts in combination with citric acid has a beneficial effect on the general condition of the hair when using the developed product.

 Due to the combination of plant extracts with a pronounced antimicrobial effect in the detergent formulation, sodium chloride, which partially acts as a preservative, and citric acid, which broadens the spectrum of the antimicrobial action of the components of the formulation, it became possible not to introduce special preservative components, such as formalin, which have an irritating effect on the skin, especially on skin with hypersensitivity.

 Thus, the proposed tool can be attributed to dermatologically soft, recommended for people with sensitive skin.

 In accordance with the task of creating a new detergent formulation that provides increased assimilation of biologically active substances, enhances the anti-dandruff effect, and reduces the irritating effect, components are selected that together provide the properties of the shampoo.

The effect of dosages of a complex CO ₂ extract from chamomile and carrot or chamomile seeds, carrot seeds and rice waste and calendula hydrophytoconcentrate, citric acid, NaCl on the physicochemical parameters of shampoo and the content of valuable biologically active substances was studied using mathematical planning according to the Latin orthogonal scheme rectangles for four factors on four levels.

 The boundary values of the dosages of the extract are calculated by the content of the main biologically active components, the sum of azulenogens and the amount of coloring, which include carotenoids as the main component.

где Р_э дозировка СО₂-экстракта,
Р_БАВ дозировка по имеющимся рецептурам,
С_БАВ концентрация в экстракте,
Ориентировочная дозировка комплексных СО₂-экстрактов N 21 или N 27 принята от от содержания в них суммы азуленогенов и суммы красящих веществ и существующих пределов их внесения в косметические препараты. Граничные значения остальных компонентов приняты в соответствии с нормами их внесения в различные косметические продукты.Dosage calculation for biologically active components is carried out according to the formula
P _e =

where P _{e the} dosage of CO ₂ extract,
R _BAS dosage according to the available formulations,
With _{biologically active substances, the} concentration in the extract,
The approximate dosage of complex CO ₂ extracts N 21 or N 27 is taken from the content of the sum of azulenogens and the amount of dyes and the existing limits of their introduction into cosmetic preparations. The boundary values of the remaining components are adopted in accordance with the norms of their inclusion in various cosmetic products.

Based on the matrix, taking into account the selected concentration levels of the complex CO ₂ -extract N 21 (27), citric acid, sodium chloride, calendula hydrophytoconcentrate, an experimental plan is drawn up.

 The studied parameters for evaluating the quality of shampoo were physical and chemical indicators: the value of the hydrogen index, foam number, foam stability and the content of the main surfactants; carotenoids, tocopherols, waxes.

As the levels of factor A, "complex CO ₂ -extract" (N 21 or N 27) were determined 0.005-0.5-0.1-0.7; factor B "calendula hydrophytoconcentrate"0.001-0.005-0.01-0.2; factor D "sodium chloride"0.5-4.0-8.0-12.0; factor C, citric acid 0.001-0.01-0.1-0.2; factor D "sodium chloride" 0.5-4.0-8.0-12.0.

 An experimental plan was drawn up for the selected levels of the studied factors (Table 1), the concentrations of the remaining components were fixed at one (averaged) level.

 The studies were carried out in the following sequence.

 According to the plan, prepared samples of mixtures according to the recipe with different dosages of the components.

 Samples were aged for 3, 30, and 90 days. After the expiration of the period, samples were analyzed.

 The data obtained are mathematically processed in order to determine the effects of the levels of each factor for all indicators (table. 2).

An analysis of the data showed that the optimal values of detergent quality indicators are achieved with the following formulation ratios, a complex CO ₂ extract from chamomile and carrot seeds or a complex CO ₂ extract from chamomile, carrot seeds, and rice flour 0.01-0.5; calendula hydrophytoconcentrate 0.01-0.1; sodium sulfoethoxylates 10-30; castor oil monoethanolamides 1-10; sodium chloride 1-10; citric acid 0.005-0.1; resorcinol 0.1-1.0; dye 0.0005-0.005; perfume 0.1-2.5; water up to 100.

 In addition, the boundary values of the dosages of the extracts were specified for the stabilized content of carotenoids and vitamin C using tocopherol extracts.

 All data on the comparative characteristics of the new detergent was obtained by comparing the options of the prototype with the boundary and average values of the concentration of the components and the proposed detergent.

 The conditions for obtaining maximum values of quality indicators are given in table. 3.

The method of preparation of the developed detergent is as follows. The water digester loaded with a temperature of 65-75 ° ^C. Under stirring (60-65 rev / min) and fed preliminarily heating switched molten monoethanolamides. After complete dissolution, ethoxylated sodium lauryl sulfate is fed slowly, in separate portions with constant stirring, then the complex extract N 21 (N 27), calendula hydrophytoconcentrate, previously dissolved in a small amount of water.

The mass is cooled and at 45-50 ^{° C} is fed citric acid, perfume, colorant, resorcinol, salt. After cooling, the shampoo is ready.

 Below are examples of the preparation of shampoo according to formulations 3 and 6 (table. 4) per 10 kg of the finished product.

PRI me R 1. In a digester load water in the amount of 6.664 kg are heated to 65-75 ^about C. When the stirrer is running and the heating is on, pre-molten monoethanolamides in the amount of 0.5 kg are fed. After their complete dissolution, slowly, in portions, with constant stirring, ethoxylated sodium lauryl sulfate in the amount of 2.0 kg is supplied. Then served complex CO ₂ -extract N 21 in an amount of 0.02 kg, calendula hydrophytoconcentrate in an amount of 0.005 kg, previously dissolved in a small amount of water. The mass is cooled and at 45-50 ^{° C} is fed citric acid in an amount of 0.001 kg resorcinol 0.05 kg, 0.13 kg of perfume, colorant 0.00025 kg salt 0.5 kg. After cooling the entire mass, the shampoo is ready.

PRI me R 2. In a digester load water in an amount of 4.579 kg with a temperature of 65-75 ^about C. When the stirrer is running and the heating is on, pre-molten monoethanolamides in an amount of 1.0 kg are fed. After complete dissolution, 3.0 kg of ethoxylated sodium lauryl sulfate is fed slowly, in portions with constant stirring, then 0.05 kg complex CO ₂ -extract No. 27, calendula hydrophytoconcentrate 0.01 kg, previously dissolved in a small amount of water. The whole mass is cooled and at 45-50 ^{° C} is fed citric acid 0.01 kg, 0.25 kg of perfume, colorant 0.0005 kg resorcinol in an amount of 0.1 kg, 1.0 kg common salt. After cooling, the shampoo is ready.

 The study of the quality indicators of the proposed shampoo was carried out in comparison with the prototype.

According to the results of the analysis of the data on the comparative characteristics of the three options of the proposed product and the three options of the prototype shampoo, taking into account the minimum, average and maximum dosage values of all components, the following was established:
various combinations of the components of the developed product improved the physicochemical parameters of the shampoo, such as pH, foam number and foam stability;
the content of azulenogens in the active part of the extracts in terms of their dosage in the composition of the shampoo increased significantly compared with the data of the prototype, in which there were only traces of azulenogens;
shampoo samples containing varying concentrations of complex CO ₂ extracts and hydrophytoconcentrate in combination with other components of the formulation are stable, since the bactericidal and antioxidant properties of the substances in its composition prevent deterioration of the detergent and increase its shelf life.

 The proposed detergent with a mild cleansing effect is recommended for people suffering from seborrhea of the scalp, trunk. However, it does not irritate the skin. When using funds, there is a decrease in sebum secretion, a decrease in inflammatory skin reactions.

 The introduction of the proposed shampoo into the production will expand the range of cosmetic products for therapeutic purposes.

Claims (1)

BODY AND HAIR CARE, containing surfactants, table salt, chamomile extractives, dye, perfume and water, characterized in that it additionally contains calendula hydrophytoconcentrate, citric acid, resorcinol, and chamomile extractives as part of complex CO ₂ extract from chamomile and carrot seeds, or from chamomile, carrot seeds and rice waste, as surfactants Na sulfoethoxylates, castor oil monoethanolamides or FFA diethanolamides in the following elations components, wt. Sulfoethoxylates Na 10 30
Castor oil monoethanolamides or FFA diethanolamides 1 10
Common salt 1 10
Hydrophytoconcentrate calendula 0.001 0.1
Complex _2- extract from chamomile and carrot seeds or _2- complex extract from chamomile, carrot seeds and rice waste 0,01 1,0
Resorcinol 0.1 1.0
Citric acid 0.005 0.1
Dye 0.0005 0.005
Fragrance 0.1 2.5
Water Else

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