RU2018134912A - URANIUM EXTRACTION - Google Patents

URANIUM EXTRACTION Download PDF

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Publication number
RU2018134912A
RU2018134912A RU2018134912A RU2018134912A RU2018134912A RU 2018134912 A RU2018134912 A RU 2018134912A RU 2018134912 A RU2018134912 A RU 2018134912A RU 2018134912 A RU2018134912 A RU 2018134912A RU 2018134912 A RU2018134912 A RU 2018134912A
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RU
Russia
Prior art keywords
solution
resin
bringing
contact
separating
Prior art date
Application number
RU2018134912A
Other languages
Russian (ru)
Other versions
RU2018134912A3 (en
RU2735528C2 (en
Inventor
Яко БЕСТЕР
Софи КОРБЕ
Стефан ДЕЛАМЕЙЁР
МОЛИНА Вероника ГАРСИА
Эмманюэль Заганьяри
Original Assignee
Дау Глоубл Текнолоджиз, Ллк
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication of RU2018134912A publication Critical patent/RU2018134912A/en
Publication of RU2018134912A3 publication Critical patent/RU2018134912A3/ru
Application granted granted Critical
Publication of RU2735528C2 publication Critical patent/RU2735528C2/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C22B3/24Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J14/00Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02Obtaining thorium, uranium, or other actinides
    • C22B60/0204Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0221Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching
    • C22B60/0226Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching using acidic solutions or liquors
    • C22B60/0234Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching using acidic solutions or liquors sulfurated ion as active agent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02Obtaining thorium, uranium, or other actinides
    • C22B60/0204Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0252Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
    • C22B60/0265Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries extraction by solid resins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Claims (18)

1. Способ извлечения урана, включающий1. The method of extraction of uranium, including (a) приведение раствора (I) в контакт со смолой (I) с получением смеси, состоящей из раствора (II) и смолы (II), при этом указанный раствор (I) представляет собой водный раствор, содержащий от 30 до 200 г/л серной кислоты и содержащий от 1 г/л до 50 г/л урана, при этом указанная смола (I) представляет собой сильнокислотную катионообменную смолу, и(a) bringing the solution (I) into contact with the resin (I) to obtain a mixture consisting of solution (II) and resin (II), wherein said solution (I) is an aqueous solution containing from 30 to 200 g / l of sulfuric acid and containing from 1 g / l to 50 g / l of uranium, wherein said resin (I) is a strongly acidic cation exchange resin, and (b) отделение раствора (II) от смолы (II).(b) separating the solution (II) from the resin (II). 2. Способ по п. 1, отличающийся тем, что раствор (I) был получен способом, включающим приведение урановой руды в контакт с серной кислотой.2. The method according to p. 1, characterized in that the solution (I) was obtained by a method comprising contacting the uranium ore with sulfuric acid. 3. Способ по п. 1, дополнительно включающий3. The method according to p. 1, further comprising (cA) приведение раствора (III) в контакт со смолой (II) с получением смеси, состоящей из раствора (IV) и смолы (III), при этом указанный раствор (III) представляет собой водный раствор, содержащий 10% или более HCl по массе, (cA) bringing the solution (III) into contact with the resin (II) to obtain a mixture consisting of solution (IV) and resin (III), wherein said solution (III) is an aqueous solution containing 10% or more HCl in mass (dA) отделение смолы (IV) от смолы (III),(dA) separating the resin (IV) from the resin (III), (eA) приведение раствора (IV) в контакт со смолой (IV) с получением смеси, состоящей из смолы (V) и раствора (V), при этом указанная смола (IV) представляет собой сильноосновную анионообменную смолу или слабоосновную анионообменную смолу, и(eA) bringing the solution (IV) into contact with the resin (IV) to obtain a mixture consisting of resin (V) and solution (V), wherein said resin (IV) is a strongly basic anion exchange resin or a weakly basic anion exchange resin, and (fA) отделение смолы (V) от раствора (V).(fA) separating the resin (V) from the solution (V). 4. Способ по п. 3, дополнительно включающий4. The method according to p. 3, further comprising (gA) приведение раствора (VI) в контакт со смолой (V) с получением смеси раствора (VII) и смолы (VI), при этом указанный раствор (VI) содержит 95% или более воды по массе в расчете на массу раствора (VI), и(gA) bringing solution (VI) into contact with resin (V) to obtain a mixture of solution (VII) and resin (VI), wherein said solution (VI) contains 95% or more water by weight based on the weight of the solution (VI) ), and (hA) отделение смолы (VI) от раствора (VII).(hA) separating the resin (VI) from the solution (VII). 5. Способ по п. 1, дополнительно включающий5. The method according to p. 1, further comprising (cB) приведение раствора (X) в контакт со смолой (II) с получением смеси раствора (XI) и смолы (XI), при этом указанный раствор (X) представляет собой водный раствор, содержащий растворенный Na2SO4 или растворенный (NH4)2SO4, и(cB) bringing the solution (X) into contact with the resin (II) to obtain a mixture of the solution (XI) and resin (XI), wherein said solution (X) is an aqueous solution containing dissolved Na 2 SO 4 or dissolved (NH 4 ) 2 SO 4 , and (dB) отделение смолы (XI) от раствора (XI).(dB) the separation of the resin (XI) from the solution (XI). 6. Способ по п. 5, дополнительно включающий6. The method according to p. 5, further comprising (dB) приведение раствора (XII) в контакт со смолой (XI) с получением смеси раствора (XIII) и смолы (XII), при этом указанный раствор (XII) представляет собой водный раствор, содержащий растворенную H2SO4, и (dB) bringing the solution (XII) into contact with the resin (XI) to obtain a mixture of the solution (XIII) and the resin (XII), wherein said solution (XII) is an aqueous solution containing dissolved H 2 SO 4 , and (eB) отделение смолы (XII) от раствора (XIII).(eB) separating the resin (XII) from the solution (XIII).
RU2018134912A 2016-03-18 2017-03-15 Uranium extraction RU2735528C2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662310225P 2016-03-18 2016-03-18
US62/310,225 2016-03-18
PCT/US2017/022399 WO2017209828A2 (en) 2016-03-18 2017-03-15 Uranium recovery

Publications (3)

Publication Number Publication Date
RU2018134912A true RU2018134912A (en) 2020-04-03
RU2018134912A3 RU2018134912A3 (en) 2020-06-03
RU2735528C2 RU2735528C2 (en) 2020-11-03

Family

ID=59930746

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2018134912A RU2735528C2 (en) 2016-03-18 2017-03-15 Uranium extraction

Country Status (6)

Country Link
US (1) US20200332394A1 (en)
AU (1) AU2017274261A1 (en)
CA (1) CA3017957C (en)
RU (1) RU2735528C2 (en)
WO (1) WO2017209828A2 (en)
ZA (1) ZA201806406B (en)

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4199470A (en) * 1977-05-13 1980-04-22 Koei Chemical Co., Ltd. Material for recovering uranium and method for recovering a uranium solution of high purity and high concentration, using the same
JPS55136128A (en) * 1979-04-12 1980-10-23 Mitsubishi Chem Ind Ltd Uranium solution concentrating method
DE19737794C1 (en) * 1997-08-29 1999-01-21 Wismut Gmbh Uranium mixed oxide separation
RU2259412C1 (en) * 2004-01-13 2005-08-27 Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт химической технологии" Method for ion-exchange recovery of uranium from sulfuric acid solutions and pulps
US9394587B2 (en) * 2011-02-15 2016-07-19 Clean Teq Holdings Limited Method and system for extraction of uranium using an ion-exchange resin
RU2458164C1 (en) * 2011-05-31 2012-08-10 Открытое акционерное общество "Ведущий научно-исследовательский институт химической технологии" Method of ion-exchange uranium extraction from sulfuric solutions and pulps
WO2015135017A1 (en) 2014-03-11 2015-09-17 A-Cap Resources Ltd Method for the recovery of uranium from a strong sulfuric acid loaded strip or eluate

Also Published As

Publication number Publication date
WO2017209828A2 (en) 2017-12-07
RU2018134912A3 (en) 2020-06-03
AU2017274261A1 (en) 2018-10-25
US20200332394A1 (en) 2020-10-22
ZA201806406B (en) 2019-12-18
RU2735528C2 (en) 2020-11-03
CA3017957A1 (en) 2017-12-07
CA3017957C (en) 2024-04-02
WO2017209828A3 (en) 2018-02-15

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