RU2018133459A - Серосодержащие биядерные молибдаты имидазолия в качестве присадок к смазкам - Google Patents
Серосодержащие биядерные молибдаты имидазолия в качестве присадок к смазкам Download PDFInfo
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- RU2018133459A RU2018133459A RU2018133459A RU2018133459A RU2018133459A RU 2018133459 A RU2018133459 A RU 2018133459A RU 2018133459 A RU2018133459 A RU 2018133459A RU 2018133459 A RU2018133459 A RU 2018133459A RU 2018133459 A RU2018133459 A RU 2018133459A
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- Russia
- Prior art keywords
- methylimidazolium
- compound
- group
- lubricating composition
- grease
- Prior art date
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- 239000000314 lubricant Substances 0.000 title claims 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims 2
- 229910052717 sulfur Inorganic materials 0.000 title claims 2
- 239000011593 sulfur Substances 0.000 title claims 2
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 title 1
- 239000000654 additive Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims 12
- 230000001050 lubricating effect Effects 0.000 claims 10
- 239000004519 grease Substances 0.000 claims 6
- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 claims 4
- LDVVBLGHGCHZBJ-UHFFFAOYSA-N 1-decyl-3-methylimidazolium Chemical compound CCCCCCCCCCN1C=C[N+](C)=C1 LDVVBLGHGCHZBJ-UHFFFAOYSA-N 0.000 claims 4
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 claims 4
- OFHIDEPGDSZYIT-UHFFFAOYSA-O 3-(5-ethyloctan-3-yl)-1H-imidazol-3-ium Chemical compound CCC(CC(CCC)CC)[N+]1=CNC=C1 OFHIDEPGDSZYIT-UHFFFAOYSA-O 0.000 claims 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 2
- -1 molybdate anion Chemical class 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011733 molybdenum Substances 0.000 claims 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 2
- 239000011574 phosphorus Substances 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- NWXVIUBYBJUOAY-UHFFFAOYSA-N 1,3-dibutylimidazol-1-ium Chemical compound CCCCN1C=C[N+](CCCC)=C1 NWXVIUBYBJUOAY-UHFFFAOYSA-N 0.000 claims 1
- XLJSMWDFUFADIA-UHFFFAOYSA-N 1,3-diethylimidazol-1-ium Chemical compound CCN1C=C[N+](CC)=C1 XLJSMWDFUFADIA-UHFFFAOYSA-N 0.000 claims 1
- HVVRUQBMAZRKPJ-UHFFFAOYSA-N 1,3-dimethylimidazolium Chemical compound CN1C=C[N+](C)=C1 HVVRUQBMAZRKPJ-UHFFFAOYSA-N 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 239000002199 base oil Substances 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 150000002641 lithium Chemical class 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 229930195734 saturated hydrocarbon Natural products 0.000 claims 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/22—Compounds containing sulfur, selenium or tellurium
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
- C01G39/06—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
- C07D233/58—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring nitrogen atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/56—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen
- C10M105/58—Amines, e.g. polyalkylene polyamines, quaternary amines
- C10M105/60—Amines, e.g. polyalkylene polyamines, quaternary amines having amino groups bound to an acyclic or cycloaliphatic carbon atom
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/44—Five-membered ring containing nitrogen and carbon only
- C10M133/46—Imidazoles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/18—Complexes with metals
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/1256—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids used as thickening agent
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/043—Ammonium or amine salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/12—Groups 6 or 16
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
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- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Lubricants (AREA)
Claims (17)
1. Соединение формулы I:
в котором:
R1-R5 и R6-R10 независимо выбирают из группы, состоящей из водорода, гидрокарбильных групп и гидрокарбильных групп, содержащих гетероатомы, так что общее число атомов углерода в противоионах Q1 и Q2 составляет от 6 до 166, и
молибдат-анион (Y) представляет собой биядерный серосодержащий дианион, выбранный из группы, состоящей из [Mo2S8O2]2-, [Mo2S9O]2- и [Mo2S10]2-.
2. Соединение по п. 1, в котором гидрокарбильные группы представляют собой линейные, разветвленные или циклические углеводороды, и насыщенные или ненасыщенные углеводороды, каждый из которых содержит от 0 до 16 атомов углерода.
3. Соединение по п. 2, в котором каждая из гидрокарбильных групп содержит от 1 до 10 атомов углерода.
4. Соединение по п. 1, в котором Q1 и Q2 одинаковы.
5. Соединение по п. 1, в котором Q1 и Q2 независимо выбирают из группы, состоящей из 1,3-диметилимидазолия, 1,3-диэтилимидазолия, 1,3-дибутилимидазолия, 1,3-ди-2-этилгексилимидазолия, 1-этил-3-метилимидазолия, 1-бутил-3-метилимидазолия и 1-децил-3-метилимидазолия.
6. Соединение по п. 1, выбранное из группы, состоящей из (1-этил-3-метилимидазолий)2[Mo2S8O2], (1-н-децил-3-метилимидазолий)2[Mo2S8O2], (1-н-бутил-3-метилимидазолий)2[Mo2S8O2] и (1,3-ди-2-этилгексилимидазолий)2[Mo2S8O2].
7. Смазочная композиция, содержащая смазочное базовое масло или консистентную смазку в количестве, по меньшей мере, 90 массовых % от смазочной композиции, и одно или более соединений по п. 1, в которой соединение формулы I присутствует в количестве, обеспечивающем введение 100-15000 ч/млн молибдена в смазочную композицию.
8. Смазочная композиция по п. 7, в которой соединение формулы I выбирают из группы, состоящей из (1-этил-3- метилимидазолий)2[Mo2S8O2], (1-н-децил-3-метилимидазолий)2[Mo2S8O2], (1-н-бутил-3-метилимидазолий)2[Mo2S8O2] и (1,3-ди-2-этилгексилимидазолий)2[Mo2S8O2].
9. Смазочная композиция по п. 7, содержащая также фосфор- или азотсодержащее противоизносное соединение, присутствующее в количестве от 0,005 масс.% до 10,000 масс.%.
10. Смазочная композиция по п. 11, в которой фосфор- или азотсодержащее противоизносное соединение выбирают из группы, состоящей из диалкилдитиокарбаматов цинка, диалкилдитиофосфатов цинка, эфиров диалкилдитиофосфорной кислоты и солей кислых алкилфосфатов с аминами.
11. Смазочная композиция по п. 7, в которой смазочная основа представляет собой консистентную смазку.
12. Смазочная композиция по п. 11, в которой консистентная смазка представляет собой консистентную смазку на основе литиевых комплексов.
13. Смазочная композиция по п. 7, в которой соединение формулы I выбирают из группы, состоящей из (1-этил-3- метилимидазолий)2[Mo2S8O2], (1-н-децил-3-метилимидазолий)2[Mo2S8O2], (1-н-бутил-3-метилимидазолий)2[Mo2S8O2] и (1,3-ди-2-этилгексилимидазолий)2[Mo2S8O2], в количестве, обеспечивающем введение 100-15000 ч/млн молибдена в смазочную композицию, и в которой консистентная смазка представляет собой консистентную смазку на основе литиевых комплексов.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662298737P | 2016-02-23 | 2016-02-23 | |
| US62/298,737 | 2016-02-23 | ||
| PCT/US2017/017799 WO2017146938A1 (en) | 2016-02-23 | 2017-02-14 | Imidazolium sulfur-containing binuclear molybdate salts as lubricant additives |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2018133459A3 RU2018133459A3 (ru) | 2020-03-24 |
| RU2018133459A true RU2018133459A (ru) | 2020-03-24 |
| RU2736493C2 RU2736493C2 (ru) | 2020-11-17 |
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| RU2018133459A RU2736493C2 (ru) | 2016-02-23 | 2017-02-14 | Серосодержащие биядерные молибдаты имидазолия в качестве присадок к смазкам |
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| Country | Link |
|---|---|
| US (1) | US9902915B2 (ru) |
| EP (1) | EP3420057B1 (ru) |
| JP (1) | JP6633770B2 (ru) |
| KR (1) | KR102650427B1 (ru) |
| CN (1) | CN108699472B (ru) |
| AU (1) | AU2017223195B2 (ru) |
| BR (1) | BR112018017257B1 (ru) |
| CA (1) | CA3010106C (ru) |
| ES (1) | ES2881897T3 (ru) |
| MX (1) | MX2018010164A (ru) |
| RU (1) | RU2736493C2 (ru) |
| WO (1) | WO2017146938A1 (ru) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY196917A (en) | 2019-07-08 | 2023-05-10 | Petroliam Nasional Berhad Petronas | Friction and wear reduction additives |
| EP3907268A1 (en) * | 2020-05-04 | 2021-11-10 | Total Marketing Services | Lubricating composition for reducing wear and tear on dlc parts used in internal combustion engines |
| CN111569908A (zh) * | 2020-06-04 | 2020-08-25 | 深圳市汇德丰控股集团有限公司 | 一种加氢脱氮催化剂及其制备方法与应用 |
| CN117402666B (zh) * | 2023-10-23 | 2024-04-16 | 众联晟通(苏州)科技有限公司 | 一种汽车发动机润滑保护剂及其制备方法 |
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| US3356702A (en) | 1964-08-07 | 1967-12-05 | Vanderbilt Co R T | Molybdenum oxysulfide dithiocarbamates and processes for their preparation |
| US4370245A (en) | 1980-12-05 | 1983-01-25 | Gulf Research & Development Company | Grease compositions containing quaternary ammonium thiomolybdates |
| ATE131953T1 (de) | 1990-04-17 | 1996-01-15 | Ecole Polytech | Photovoltaische zellen |
| US5238889A (en) | 1992-08-10 | 1993-08-24 | Eastman Kodak Company | Process for the separation of oligomeric materials from a catalyst mixture |
| CA2343309A1 (en) | 1998-09-10 | 2000-03-23 | Ramzi Yanni Saleh | Process for making aromatic aldehydes using ionic liquids |
| US7259284B2 (en) | 2000-05-31 | 2007-08-21 | Chevron Phillips Chemical Company, Lp | Method for manufacturing high viscosity polyalphaolefins using ionic liquid catalysts |
| JP4884643B2 (ja) | 2001-03-20 | 2012-02-29 | ビーエーエスエフ ソシエタス・ヨーロピア | 沸点近接又は共沸混合物を分離するための選択的添加剤であるイオン性液体 |
| MY138064A (en) | 2002-01-24 | 2009-04-30 | Basf Ag | Method for the separation of acids from chemical reaction mixtures by means of ionic fluids |
| CN1203032C (zh) | 2002-11-12 | 2005-05-25 | 石油大学(北京) | 以复合离子液体为催化剂制备烷基化油剂的方法 |
| CA2543969A1 (en) | 2003-10-31 | 2005-05-12 | Chevron Phillips Chemical Company Lp | Method and system to add high shear to improve an ionic liquid catalyzed chemical reaction |
| CN1894183B (zh) | 2003-12-18 | 2010-09-08 | 埃克森美孚化学专利公司 | 氢化或相关方面的改进 |
| US7432409B2 (en) | 2004-12-21 | 2008-10-07 | Chevron U.S.A. Inc. | Alkylation process using chloroaluminate ionic liquid catalysts |
| JP5203590B2 (ja) * | 2006-10-27 | 2013-06-05 | 出光興産株式会社 | 潤滑油組成物 |
| US8268760B2 (en) * | 2009-02-20 | 2012-09-18 | Exxonmobil Research And Engineering Company | Method for reducing friction/wear of formulated lubricating oils by use of ionic liquids as anti-friction/anti-wear additives |
| JP5797832B2 (ja) * | 2011-04-15 | 2015-10-21 | ヴァンダービルト ケミカルズ、エルエルシー | ジアルキルジチオカルバミン酸モリブデン組成物、およびこれらを含有する潤滑組成物 |
| US20140171348A1 (en) | 2012-12-14 | 2014-06-19 | Exxonmobil Research And Engineering Company | Ionic liquids as lubricating oil base stocks, cobase stocks and multifunctional functional fluids |
| IS2934B (is) | 2013-09-25 | 2016-01-15 | Háskóli Íslands | Mólýbden efnasambönd til notkunar við meðferð á sýaníðeitrun |
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| ES2881897T3 (es) | 2021-11-30 |
| EP3420057A4 (en) | 2019-10-30 |
| BR112018017257A2 (pt) | 2019-01-15 |
| CN108699472B (zh) | 2019-06-04 |
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