RU2017129065A - Поддерживающий материал, содержащий поливиниловый спирт, и его применение в ксерографическом послойном наращивании - Google Patents

Поддерживающий материал, содержащий поливиниловый спирт, и его применение в ксерографическом послойном наращивании Download PDF

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RU2017129065A
RU2017129065A RU2017129065A RU2017129065A RU2017129065A RU 2017129065 A RU2017129065 A RU 2017129065A RU 2017129065 A RU2017129065 A RU 2017129065A RU 2017129065 A RU2017129065 A RU 2017129065A RU 2017129065 A RU2017129065 A RU 2017129065A
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toner
toner material
supporting
xerographic
polyvinyl alcohol
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RU2017129065A
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RU2017129065A3 (ru
RU2747648C2 (ru
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Варун Самбху
Джон С. ФАЧЧИ
Элиуд РОБЛЕС-ФЛОРЕС
Дэвид С. ДЕРЛЕТ
Дэвид С. КРЕЙГ
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Зирокс Корпорейшн
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/087Binders for toner particles
    • G03G9/08775Natural macromolecular compounds or derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/0802Preparation methods
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/0802Preparation methods
    • G03G9/081Preparation methods by mixing the toner components in a liquefied state; melt kneading; reactive mixing
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/087Binders for toner particles
    • G03G9/08702Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08706Polymers of alkenyl-aromatic compounds
    • G03G9/08708Copolymers of styrene
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/087Binders for toner particles
    • G03G9/08702Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08722Polyvinylalcohols; Polyallylalcohols; Polyvinylethers; Polyvinylaldehydes; Polyvinylketones; Polyvinylketals
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/087Binders for toner particles
    • G03G9/08702Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08726Polymers of unsaturated acids or derivatives thereof
    • G03G9/08731Polymers of nitriles
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/087Binders for toner particles
    • G03G9/08702Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08737Polymers derived from conjugated dienes
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/087Binders for toner particles
    • G03G9/08702Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/0874Polymers comprising hetero rings in the side chains
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/087Binders for toner particles
    • G03G9/08742Binders for toner particles comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • G03G9/08766Polyamides, e.g. polyesteramides
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00Developers
    • G03G9/08Developers with toner particles
    • G03G9/087Binders for toner particles
    • G03G9/08775Natural macromolecular compounds or derivatives thereof
    • G03G9/08777Cellulose or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L39/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
    • C08L39/04Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C08L39/06Homopolymers or copolymers of N-vinyl-pyrrolidones
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/22Apparatus for electrographic processes using a charge pattern involving the combination of more than one step according to groups G03G13/02 - G03G13/20
    • G03G15/221Machines other than electrographic copiers, e.g. electrophotographic cameras, electrostatic typewriters
    • G03G15/224Machines for forming tactile or three dimensional images by electrographic means, e.g. braille, 3d printing

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Developing Agents For Electrophotography (AREA)

Claims (25)

1. Частица поддерживающего тонерного материала для применения в ксерографическом послойном наращивании, содержащая:
полимер поливинилового спирта (PVA); и
смесь добавок, содержащую:
хитозан; и
поливинилпирролидон (PVP),
где количество смеси добавок выбрано так, чтобы обеспечить Tg полимера PVA в пределах от примерно 1°C до примерно 20°C относительно Tg требуемого модельного тонерного материала.
2. Частица поддерживающего тонерного материала по п. 1, отличающаяся тем, что количество смеси добавок выбрано так, чтобы обеспечить Tg полимера PVA в пределах от примерно 1°C до примерно 10°С относительно Tg требуемого модельного тонерного материала.
3. Частица поддерживающего тонерного материала по п. 1, дополнительно содержащая тонерные поверхностные добавки.
4. Частица поддерживающего тонерного материала по п. 3, отличающаяся тем, что тонерные поверхностные добавки содержат один или более из диоксида кремния, диоксида титана, силиконового масла, агента для регулирования заряда.
5. Ксерографическая тонерная система, содержащая
модельный тонерный материал; и
поддерживающий тонерный материал;
где поддерживающий тонерный материал содержит:
полимер поливинилового спирта (PVA); и
смесь добавок, содержащую:
хитозан; и
поливинилпирролидон (PVP),
где количество смеси добавок выбрано так, чтобы обеспечить Tg полимера PVA в пределах от примерно 1°C до примерно 20°C относительно Tg указанного модельного тонерного материала.
6. Ксерографическая тонерная система по п. 5, отличающаяся тем, что количество смеси добавок выбрано так, чтобы обеспечить Tg полимера PVA в пределах от примерно 1°C до примерно 20°С относительно Tg требуемого модельного тонерного материала.
7. Ксерографическая тонерная система по п. 5, отличающаяся тем, что модельный материал содержит акрилонитрил-бутадиен-стирол (ABS).
8. Ксерографическая тонерная система по п. 7, отличающаяся тем, что ABS имеет Tg от примерно 100 до примерно 130°C.
9. Способ получения поддерживающего тонерного материала, включающий:
смешивание поливинилового спирта со смесью добавок, содержащей хитозан и поливинилпирролидон; и
получение поддерживающих тонерных частиц после стадии смешивания.
10. Способ по п. 9, дополнительно включающий смешивание поверхностных добавок с поддерживающими тонерными частицами.
RU2017129065A 2016-09-07 2017-08-15 Поддерживающий материал, содержащий поливиниловый спирт, и его применение в ксерографическом послойном наращивании RU2747648C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/258,190 US9857710B1 (en) 2016-09-07 2016-09-07 Support material comprising polyvinylalcohol and its use in xerographic additive manufacturing
US15/258190 2016-09-07

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RU2017129065A true RU2017129065A (ru) 2019-02-15
RU2017129065A3 RU2017129065A3 (ru) 2020-12-30
RU2747648C2 RU2747648C2 (ru) 2021-05-11

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US (2) US9857710B1 (ru)
EP (1) EP3293578B1 (ru)
JP (1) JP7067882B2 (ru)
KR (1) KR102208445B1 (ru)
CN (1) CN107797399B (ru)
CA (1) CA2977100C (ru)
RU (1) RU2747648C2 (ru)

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JP7067882B2 (ja) 2022-05-16
RU2017129065A3 (ru) 2020-12-30
CN107797399A (zh) 2018-03-13
US9857710B1 (en) 2018-01-02
RU2747648C2 (ru) 2021-05-11
JP2018039257A (ja) 2018-03-15
USRE47920E1 (en) 2020-03-31
EP3293578B1 (en) 2019-07-31
CN107797399B (zh) 2023-09-22
KR20180028008A (ko) 2018-03-15
EP3293578A1 (en) 2018-03-14
KR102208445B1 (ko) 2021-01-26
CA2977100A1 (en) 2018-03-07
CA2977100C (en) 2020-01-07

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