RU2016106920A - SHEET STEEL FOR A THICK-WALLED HIGH-STRENGTH MAIN PIPE, POSSESSING EXCELLENT RESISTANCE TO ACID ENVIRONMENT, CROSSING RESISTANCE AND LOW-TERM VERY SEVERE TOUCH. - Google Patents

SHEET STEEL FOR A THICK-WALLED HIGH-STRENGTH MAIN PIPE, POSSESSING EXCELLENT RESISTANCE TO ACID ENVIRONMENT, CROSSING RESISTANCE AND LOW-TERM VERY SEVERE TOUCH. Download PDF

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RU2016106920A
RU2016106920A RU2016106920A RU2016106920A RU2016106920A RU 2016106920 A RU2016106920 A RU 2016106920A RU 2016106920 A RU2016106920 A RU 2016106920A RU 2016106920 A RU2016106920 A RU 2016106920A RU 2016106920 A RU2016106920 A RU 2016106920A
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thick
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RU2637202C2 (en
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Такуя ХАРА
Таиси ФУДЗИСИРО
Ясухиро СИНОХАРА
Ейдзи ЦУРУ
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Ниппон Стил Энд Сумитомо Метал Корпорейшн
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/08Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
    • C21D9/14Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes wear-resistant or pressure-resistant pipes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/78Combined heat-treatments not provided for above
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2221/00Treating localised areas of an article
    • C21D2221/10Differential treatment of inner with respect to outer regions, e.g. core and periphery, respectively
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/10Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
    • C21D8/105Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies of ferrous alloys

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Manufacturing & Machinery (AREA)

Claims (44)

1. Толстолистовая сталь для толстостенной высокопрочной магистральной трубы, обладающая превосходными сопротивлением воздействию кислой среды, сопротивлением смятию и низкотемпературной вязкостью, представляющая собой:1. Steel plate for thick-walled high-strength trunk pipe, which has excellent resistance to acidic environment, shear resistance and low temperature viscosity, which is: толстолистовую сталь с толщиной от 25 мм до 45 мм, содержащую, мас.%:plate steel with a thickness of 25 mm to 45 mm, containing, wt.%: C: от 0,04 до 0,08;C: 0.04 to 0.08; Mn: от 1,2 до 2,0;Mn: 1.2 to 2.0; Nb: от 0,005 до 0,05;Nb: from 0.005 to 0.05; Ti: от 0,005 до 0,03;Ti: from 0.005 to 0.03; Ca: от 0,0005 до 0,0050, иCa: 0.0005 to 0.0050, and N: от 0,001 до 0,008, с ограничениями:N: from 0.001 to 0.008, with limitations: Si: 0,5 или меньше,Si: 0.5 or less Al: 0,05 или меньше,Al: 0.05 or less P: 0,03 или меньше,P: 0.03 or less S: 0,005 или меньше,S: 0.005 or less O: 0,005 или меньше, иO: 0.005 or less, and имеющую остаток из Fe и неизбежных примесей, при этомhaving a residue of Fe and inevitable impurities, while микроструктура части поверхностного слоя, расположенной от поверхности толстолистовой стали вниз в направлении толщины листа на от 0,9 мм до 1,1 мм, ограничена в процентах площади следующим образом:the microstructure of the part of the surface layer located from the plate steel surface downward in the direction of sheet thickness from 0.9 mm to 1.1 mm is limited in percentage of the area as follows: деформированный феррит: 5% или больше и Sfe1%, определяемый по следующей формуле 1a, или меньше, иdeformed ferrite: 5% or more and S fe1 %, determined by the following formula 1a or less, and смесь мартенсита и аустенита: 8% или меньше, иa mixture of martensite and austenite: 8% or less, and имеет остаток из одного или обоих из многоугольного феррита и бейнита, иhas a residue of one or both of polygonal ferrite and bainite, and микроструктура части, расположенной от центра толщины листа в направлении к передней и к задней сторонам толстолистовой стали в пределах 1 мм, составляющая центральную часть толщины, ограничена в процентах площади следующим образом:the microstructure of the part located from the center of the sheet thickness towards the front and rear sides of the steel plate within 1 mm, constituting the central part of the thickness, is limited in percentage of the area as follows: деформированный феррит: 5% или меньше,deformed ferrite: 5% or less смесь мартенсита и аустенита: 5% или меньше, иa mixture of martensite and austenite: 5% or less, and имеет остаток, состоящий из одного или обоих из игольчатого феррита и бейнита, иhas a residue consisting of one or both of acicular ferrite and bainite, and часть поверхностного слоя и центральная часть толщины имеют среднее значение эффективного размера зерна, измеренное дифракцией обратного рассеяния электронов, равное 20 мкм или меньше,part of the surface layer and the central part of the thickness have an average value of the effective grain size, measured by electron backscattering diffraction, of 20 μm or less, Sfe1=0,6552×TH-4,7826, (формула 1a),S fe1 = 0.6552 × T H -4.7826, (formula 1a), где TH: толщина толстолистовой стали для толстостенной высокопрочной магистральной трубы.where T H : thickness of plate steel for a thick-walled high-strength main pipe. 2. Толстолистовая сталь для толстостенной высокопрочной магистральной трубы, обладающая превосходными сопротивлением воздействию кислой среды, сопротивлением смятию и низкотемпературной вязкостью по п. 1, дополнительно содержащая одно или более из, мас.%:2. Plate steel for thick-walled high-strength trunk pipe, which has excellent resistance to acidic environment, shear resistance and low temperature viscosity according to claim 1, additionally containing one or more of, wt.%: Cu: 0,50 или меньше,Cu: 0.50 or less Ni: 0,50 или меньше,Ni: 0.50 or less Cr: 0,50 или меньше,Cr: 0.50 or less Mo: 0,50 или меньше,Mo: 0.50 or less W: 0,50 или меньше,W: 0.50 or less V: 0,10 или меньше,V: 0.10 or less Zr: 0,050 или меньше,Zr: 0.050 or less Ta: 0,050 или меньше,Ta: 0.050 or less B: 0,0020 или меньше,B: 0.0020 or less Mg: 0,010 или меньше,Mg: 0.010 or less REM: 0,0050 или меньше,REM: 0.0050 or less Y: 0,0050 или меньше,Y: 0.0050 or less Hf: 0,0050 или меньше, иHf: 0.0050 or less, and Re: 0,0050 или меньше.Re: 0.0050 or less. 3. Толстолистовая сталь для толстостенной высокопрочной магистральной трубы, обладающая превосходными сопротивлением воздействию кислой среды, сопротивлением смятию и низкотемпературной вязкостью по п.1 или 2, в которой содержание алюминия составляет 0,005 мас.% или меньше.3. Steel plate for a thick-walled high-strength main pipe, having excellent resistance to acidic conditions, shear resistance and low temperature viscosity according to claim 1 or 2, in which the aluminum content is 0.005 wt.% Or less. 4. Толстолистовая сталь для толстостенной высокопрочной магистральной трубы, обладающая превосходными сопротивлением воздействию кислой среды, сопротивлением смятию и низкотемпературной вязкостью по любому из пп. 1-3, которая имеет предел прочности от 500 до 700 МПа.4. Steel plate for thick-walled high-strength trunk pipe, which has excellent resistance to acidic environment, shear resistance and low temperature viscosity according to any one of paragraphs. 1-3, which has a tensile strength of 500 to 700 MPa.
5     5. Толстолистовая сталь для толстостенной высокопрочной магистральной трубы, обладающая превосходными сопротивлением воздействию кислой среды, сопротивлением смятию и низкотемпературной вязкостью по любому из пп. 1-3, которая имеет предел текучести после формирования трубы составляет 440 МПа или больше, предел прочности от 500 до 700 МПа, и 0,2% напряжение пластического течения при сжатии в круговом направлении после старения при температуре 200°C 450 МПа или больше.

5 5. Plate steel for a thick-walled high-strength main pipe, which has excellent resistance to acidic environment, shear resistance and low temperature viscosity according to any one of paragraphs. 1-3, which has a yield strength after pipe formation is 440 MPa or more, a tensile strength of 500 to 700 MPa, and 0.2% stress of plastic flow during compression in the circular direction after aging at a temperature of 200 ° C of 450 MPa or more.
6. Толстостенная высокопрочная магистральная труба, изготовленная формованием толстолистовой стали для толстостенной высокопрочной магистральной трубы, обладающей превосходными сопротивлением воздействию кислой среды, сопротивлением смятию и низкотемпературной вязкостью по любому из пп. 1-4, в трубу с последующей дуговой сваркой примыкающих концов, имеющая предел текучести 440 МПа или больше, предел прочности от 500 до 700 МПа и 0,2% напряжение пластического течения при сжатии в круговом направлении после старения при температуре 200°C, равное 450 МПа или больше. 6. Thick-walled high-strength main pipe made by molding of steel plate for a thick-walled high-strength main pipe with excellent acid resistance, crushing resistance and low temperature viscosity according to any one of paragraphs. 1-4, into a pipe followed by arc welding of adjacent ends, having a yield strength of 440 MPa or more, a tensile strength of 500 to 700 MPa and 0.2% stress of plastic flow during compression in a circular direction after aging at a temperature of 200 ° C, equal to 450 MPa or more.
RU2016106920A 2013-08-30 2014-08-29 Sheet steel for a thick-strengthen high-strengthening pipe threading with excellent resistance to acid environment, resistance to smoke and low-temperature viscosity and also a main pipe RU2637202C2 (en)

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PCT/JP2014/072833 WO2015030210A1 (en) 2013-08-30 2014-08-29 Steel sheet for thick-walled high-strength line pipe having exceptional souring resistance, crush resistance properties, and low-temperature ductility, and line pipe

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