RU2015127891A - APPLICATION OF SODIUM DIONIONITE IN THE CELLULOSE BOILING PROCESS - Google Patents

APPLICATION OF SODIUM DIONIONITE IN THE CELLULOSE BOILING PROCESS Download PDF

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Publication number
RU2015127891A
RU2015127891A RU2015127891A RU2015127891A RU2015127891A RU 2015127891 A RU2015127891 A RU 2015127891A RU 2015127891 A RU2015127891 A RU 2015127891A RU 2015127891 A RU2015127891 A RU 2015127891A RU 2015127891 A RU2015127891 A RU 2015127891A
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RU
Russia
Prior art keywords
cooking
dithionic acid
lignocellulose
salt
containing material
Prior art date
Application number
RU2015127891A
Other languages
Russian (ru)
Other versions
RU2649301C2 (en
Inventor
Штефан ЭРРЕН
Дитер ШЕНХАБЕР
Мартин ШАХТЛЬ
Штеффен ФИШЕР
Кристиан БАОЙРИХ
Original Assignee
Басф Се
Технише Университет Дрезден
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Application filed by Басф Се, Технише Университет Дрезден filed Critical Басф Се
Publication of RU2015127891A publication Critical patent/RU2015127891A/en
Application granted granted Critical
Publication of RU2649301C2 publication Critical patent/RU2649301C2/en

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00Regeneration of pulp liquors or effluent waste waters
    • D21C11/06Treatment of pulp gases; Recovery of the heat content of the gases; Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds
    • D21C11/08Deodorisation ; Elimination of malodorous compounds, e.g. sulfur compounds such as hydrogen sulfide or mercaptans, from gas streams
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/02Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/02Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
    • D21C3/022Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes in presence of S-containing compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/04Pulping cellulose-containing materials with acids, acid salts or acid anhydrides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/22Other features of pulping processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10Bleaching ; Apparatus therefor
    • D21C9/1084Bleaching ; Apparatus therefor with reducing compounds
    • D21C9/1089Bleaching ; Apparatus therefor with reducing compounds with dithionites

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Paper (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Claims (9)

1. Способ получения целлюлозы из содержащего лигноцеллюлозу материала посредством сульфитной или сульфатной варки в присутствии соли дитионистой кислоты, отличающийся тем, что соль дитионистой кислоты используют в количестве от 0,1 до 4,0 мас.% в пересчете на количество содержащего лигноцеллюлозу материала после сушки в печи.1. A method of producing cellulose from a lignocellulose-containing material by sulphite or sulphate cooking in the presence of a dithionic acid salt, characterized in that the dithionic acid salt is used in an amount of from 0.1 to 4.0 wt.% Based on the amount of lignocellulose-containing material after drying in the oven. 2. Способ по п. 1, причем соль дитионистой кислоты выбирают из группы, состоящей из: дитионита натрия, дитионита цинка, дитионита кальция.2. The method according to p. 1, and the salt of dithionic acid is selected from the group consisting of: sodium dithionite, zinc dithionite, calcium dithionite. 3. Способ по п. 1, причем солью дитионистой кислоты является дитионит натрия.3. The method according to claim 1, wherein the dithionic acid salt is sodium dithionite. 4. Способ по п. 1, причем сульфитную варку осуществляют в температурном интервале от 100 до 160°С и сульфатную варку в температурном интервале от 160 до 185°С.4. The method according to p. 1, and sulfite cooking is carried out in the temperature range from 100 to 160 ° C and sulfate cooking in the temperature range from 160 to 185 ° C. 5. Способ по п. 1, причем содержащим лигноцеллюлозу материалом является древесина.5. The method according to claim 1, wherein the lignocellulose-containing material is wood. 6. Способ по п. 1, причем способ осуществляют в периодическом режиме.6. The method according to p. 1, and the method is carried out in periodic mode. 7. Способ по одному из пп. 1-6, причем при сульфитной варке соль дитионистой кислоты добавляют, как только смесь варочной кислоты с подлежащим варке содержащим лигноцеллюлозу материалом при нагревании достигнет температуры от 60 до 110°С, причем полученную после добавления дитионистой кислоты смесь выдерживают при температуре от 100 до 110°С в течение промежутка времени от 30 до 90 мин (стадии пропитки).7. The method according to one of paragraphs. 1-6, moreover, when sulfite cooking, the salt of dithionic acid is added as soon as the mixture of cooking acid with the material to be cooked containing lignocellulose when heated reaches a temperature of from 60 to 110 ° C, and the mixture obtained after adding dithionic acid is kept at a temperature of from 100 to 110 ° C for a period of time from 30 to 90 minutes (impregnation stage). 8. Способ по одному из пп. 1-6, причем при сульфатной варке соль дитионистой кислоты добавляют на стадии пропитки, основной стадии или конечной стадии варки.8. The method according to one of paragraphs. 1-6, moreover, when sulfate cooking salt dithionic acid is added at the stage of impregnation, the main stage or the final stage of cooking. 9. Применение солей дитионистой кислоты для снижения концентрации веществ с неприятным запахом в способе получения целлюлозы из содержащего лигноцеллюлозу материала посредством сульфитной или сульфатной варки.9. The use of salts of dithionic acid to reduce the concentration of substances with an unpleasant odor in the method of producing cellulose from a lignocellulose-containing material by sulphite or sulphate cooking.
RU2015127891A 2012-12-12 2013-12-02 Use of sodium dithionite in a cellulose pulping process RU2649301C2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12196636.0 2012-12-12
EP12196636 2012-12-12
PCT/EP2013/075193 WO2014090609A1 (en) 2012-12-12 2013-12-02 Use of sodium dithionite in a cellulose pulping process

Publications (2)

Publication Number Publication Date
RU2015127891A true RU2015127891A (en) 2017-01-19
RU2649301C2 RU2649301C2 (en) 2018-03-30

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2015127891A RU2649301C2 (en) 2012-12-12 2013-12-02 Use of sodium dithionite in a cellulose pulping process

Country Status (18)

Country Link
EP (1) EP2931968B1 (en)
JP (1) JP6290244B2 (en)
KR (1) KR20150093825A (en)
CN (1) CN104838065A (en)
AR (1) AR093929A1 (en)
AU (1) AU2013357649B2 (en)
BR (1) BR112015013578B1 (en)
CA (1) CA2892725A1 (en)
CL (1) CL2015001406A1 (en)
ES (1) ES2708216T3 (en)
MX (1) MX2015007586A (en)
PH (1) PH12015501255A1 (en)
PL (1) PL2931968T3 (en)
PT (1) PT2931968T (en)
RU (1) RU2649301C2 (en)
TW (1) TWI607041B (en)
WO (1) WO2014090609A1 (en)
ZA (1) ZA201504934B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021058483A1 (en) * 2019-09-23 2021-04-01 Université Catholique de Louvain Process for producing lignin components from lignocellulosic biomass
CN112900130B (en) * 2021-02-02 2022-08-12 大连工业大学 Method for reducing whiteness reduction of cooked plant fibers

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE912169C (en) * 1952-02-22 1954-05-24 Georg Jayme Dr Ing Process for the alkaline digestion of plant substances
FR1150451A (en) * 1956-05-04 1958-01-14 Saint Gobain Improvement in the manufacturing processes of semi-chemical cellulose pulps
FR2615874B1 (en) * 1987-05-25 1992-02-21 Atochem PROCESS FOR THE PREPARATION OF CHEMICOTHERMOMECHANICAL PASTES
RU2445414C2 (en) * 2006-05-19 2012-03-20 Дзе Рисерч Фаундейшн Оф Стейт Юниверсити Оф Нью Йорк Methods of carbonate pretreatment and pulping cellulosic material
US20080105392A1 (en) * 2006-11-03 2008-05-08 Duggirala Prasad Y Method and composition for improving fiber quality and process efficiency in mechanical pulping
US20090090478A1 (en) * 2007-10-05 2009-04-09 Hollomon Martha G Selectivity improvement in oxygen delignification and bleaching of lignocellulose pulp using singlet oxygen
US20120168102A1 (en) * 2009-04-02 2012-07-05 Sung-Hoon Yoon Pulping process for quality protection including methods for hemicellulose extraction and treatment of hemicellulose-extracted lignocellulosic materials

Also Published As

Publication number Publication date
PL2931968T3 (en) 2019-04-30
ZA201504934B (en) 2017-11-29
BR112015013578B1 (en) 2021-07-06
BR112015013578A2 (en) 2017-08-15
AU2013357649A1 (en) 2015-06-11
CN104838065A (en) 2015-08-12
TW201428031A (en) 2014-07-16
WO2014090609A1 (en) 2014-06-19
JP6290244B2 (en) 2018-03-07
JP2015537130A (en) 2015-12-24
PH12015501255A1 (en) 2015-08-17
AU2013357649B2 (en) 2017-06-08
EP2931968A1 (en) 2015-10-21
PT2931968T (en) 2019-01-11
CA2892725A1 (en) 2014-06-19
EP2931968B1 (en) 2018-10-31
TWI607041B (en) 2017-12-01
CL2015001406A1 (en) 2016-02-05
MX2015007586A (en) 2016-05-05
ES2708216T3 (en) 2019-04-09
AR093929A1 (en) 2015-07-01
RU2649301C2 (en) 2018-03-30
KR20150093825A (en) 2015-08-18

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