RU2014139431A - Неводная жидкая композиция для нанесения покрытия - Google Patents

Неводная жидкая композиция для нанесения покрытия Download PDF

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RU2014139431A
RU2014139431A RU2014139431A RU2014139431A RU2014139431A RU 2014139431 A RU2014139431 A RU 2014139431A RU 2014139431 A RU2014139431 A RU 2014139431A RU 2014139431 A RU2014139431 A RU 2014139431A RU 2014139431 A RU2014139431 A RU 2014139431A
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groups
thiol
base
metal
coating composition
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RU2014139431A
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RU2632871C2 (ru
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Тако СХЕРЕР
БЕЛЕН Николас Якоб ВАН
ДЭР ПЮТТЭН Антониус Йозефус ВАН
АДРИХЕМ Арнольдус Адрианус Йозеф Мария ВАН
Дэвид Элиас БРЭЙН
Марселла ГАЛЬЯРДО
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Акцо Нобель Коатингс Интернэшнл Б.В.
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract

1. Неводная жидкая композиция для нанесения покрытия, содержащая:a) полиол,b) полиизоцианатный отвердитель,c) одно или несколько тиолсодержащих соединений,d) металлосодержащий катализатор отверждения для ускорения реакции присоединения изоцианатных групп и гидроксильных групп,e) основание, имеющее величину pKa по меньшей мере 7 и не взаимодействующее с изоцианатными группами со снижением основности, иf) одно или несколько содержащих кислотные группы соединений,где одно или несколько тиолсодержащих соединений содержится в количестве, обеспечивающем молярное отношение тиольных групп к атомам металла металлосодержащего катализатора отверждения, составляющее 1 или выше, и где основание содержится в молярном количестве, меньшем, чем молярное количество тиольных групп, и где молярное отношение кислотных групп и групп основания составляет 1:1 или выше.2. Композиция для нанесения покрытия по п. 1, где основание содержится в молярное количестве, равном или превышающем молярное количество атомов металла металлосодержащего катализатора отверждения.3. Композиция для нанесения покрытия по любому из предшествующих пунктов, где композиция для нанесения покрытия является композицией для нанесения прозрачного слоя.4. Способ получения композиции для нанесения покрытия по любому из предшествующих пунктов, включающий смешивание полиола, одного или нескольких тиолсодержащих соединений, металлосодержащего катализатора отверждения для ускорения реакции присоединения изоцианатных групп и гидроксильных групп, и основания, имеющего величину pKa по меньшей мере 7 и не взаимодействующего с изоцианатными группами со снижением основности, и одного ил

Claims (8)

1. Неводная жидкая композиция для нанесения покрытия, содержащая:
a) полиол,
b) полиизоцианатный отвердитель,
c) одно или несколько тиолсодержащих соединений,
d) металлосодержащий катализатор отверждения для ускорения реакции присоединения изоцианатных групп и гидроксильных групп,
e) основание, имеющее величину pKa по меньшей мере 7 и не взаимодействующее с изоцианатными группами со снижением основности, и
f) одно или несколько содержащих кислотные группы соединений,
где одно или несколько тиолсодержащих соединений содержится в количестве, обеспечивающем молярное отношение тиольных групп к атомам металла металлосодержащего катализатора отверждения, составляющее 1 или выше, и где основание содержится в молярном количестве, меньшем, чем молярное количество тиольных групп, и где молярное отношение кислотных групп и групп основания составляет 1:1 или выше.
2. Композиция для нанесения покрытия по п. 1, где основание содержится в молярное количестве, равном или превышающем молярное количество атомов металла металлосодержащего катализатора отверждения.
3. Композиция для нанесения покрытия по любому из предшествующих пунктов, где композиция для нанесения покрытия является композицией для нанесения прозрачного слоя.
4. Способ получения композиции для нанесения покрытия по любому из предшествующих пунктов, включающий смешивание полиола, одного или нескольких тиолсодержащих соединений, металлосодержащего катализатора отверждения для ускорения реакции присоединения изоцианатных групп и гидроксильных групп, и основания, имеющего величину pKa по меньшей мере 7 и не взаимодействующего с изоцианатными группами со снижением основности, и одного или нескольких соединений, содержащих кислотные группы, с образованием модуля связующего, и смешивание модуля связующего с полиизоцианатом, где одно или несколько тиолсодержащих соединений содержится в количестве, обеспечивающем молярное отношение тиольных групп к атомам металла металлосодержащего катализатора отверждения, составляющее 1 или выше, и где основание содержится в молярном количестве ниже, чем молярное количество тиольных групп, и где молярное отношение кислотных групп и групп основания составляет 1:1 или выше.
5. Набор для получения композиции для нанесения покрытий по любому из пп. 1-3, включающий:
i) модуль связующего, содержащий полиол, одно или несколько тиолсодержащих соединений, металлосодержащий катализатор отверждения для ускорения реакции присоединения изоцианатных групп и гидроксильных групп, основание, имеющее величину pKa по меньшей мере 7 и не взаимодействующее с изоцианатными группами со снижением основности, и одно или несколько соединений, содержащих кислотные группы, и
ii) модуль отвердителя, содержащий полиизоцианатный отвердитель, где одно или несколько тиолсодержащих соединений содержится в количестве, обеспечивающем молярное отношение тиольных групп к атомам металла металлосодержащего катализатора отверждения, составляющее 1 или выше, и где основание содержится в молярном количестве ниже молярного количества тиольных групп, и где молярное отношение кислотных групп и групп основания составляет 1:1 или выше.
6. Набор для получения композиции для нанесения покрытия по одному из предшествующих пп. 1-3, включающий:
i) модуль связующего, содержащий полиол и основание, имеющее величину pKa по меньшей мере 7 и не взаимодействующее с изоцианатными группами со снижением основности,
ii) модуль отвердителя, содержащий полиизоцианатный отвердитель, и
iii) модуль разбавителя, содержащий летучий органический разбавитель, металлосодержащий катализатор отверждения для ускорения реакции присоединения изоцианатных групп и гидроксильных групп и одно или несколько тиолсодержащих соединений, где одно или несколько тиолсодержащих соединений содержится в количестве, обеспечивающем молярное отношение тиольных групп к атомам металла металлосодержащего катализатора отверждения, составляющее 1 или выше,
и где основание содержится в молярном количестве меньше молярного количества тиольных групп, и где по меньшей мере один из модулей содержит соединение, содержащее кислотные группы, и где молярное отношение кислотных групп и групп основания составляет 1:1 или выше.
7. Способ получения покрытия для по меньшей мере части внешней поверхности транспортного средства, где способ включает стадии нанесения жидкой композиции для покрытия по любому из предшествующих пп. 1-3 на по меньшей мере часть внешней поверхности транспортного средства, и отверждение нанесенной композиции для покрытия в температурном интервале от 5 до 80°C.
8. Способ по п. 7, где жидкую композицию для покрытия наносят в виде прозрачного слоя сверху пигментированного базового покрытия.
RU2014139431A 2012-03-07 2013-03-04 Неводная жидкая композиция для нанесения покрытия RU2632871C2 (ru)

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