RU2014118724A - Панель с противопожарными свойствами - Google Patents

Панель с противопожарными свойствами Download PDF

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Publication number
RU2014118724A
RU2014118724A RU2014118724/03A RU2014118724A RU2014118724A RU 2014118724 A RU2014118724 A RU 2014118724A RU 2014118724/03 A RU2014118724/03 A RU 2014118724/03A RU 2014118724 A RU2014118724 A RU 2014118724A RU 2014118724 A RU2014118724 A RU 2014118724A
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RU
Russia
Prior art keywords
layer
fire
polyurethane
panel
foam
Prior art date
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RU2014118724/03A
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English (en)
Other versions
RU2609044C2 (ru
Inventor
Джузеппе ВАЙРО
Маурицио ГУАНДАЛИНИ
Лука ЛОТТИ
Франческа ПИНЬЯНЬОЛИ
Луиджи БЕРТУЧЕЛЛИ
Original Assignee
ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи
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Publication of RU2014118724A publication Critical patent/RU2014118724A/ru
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Publication of RU2609044C2 publication Critical patent/RU2609044C2/ru

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Abstract

1. Панель (22), содержащая:- металлическую облицовку (12, A);- изоляционный слой (D) пеноматериала и,- по меньшей мере, один противопожарный слой (B, C) между металлической облицовкой (12, A) и слоем (D) пеноматериала, причем противопожарный слой (слои) (B, C) содержит дисперсию, по меньшей мере, одного из следующих материалов: вспениваемый графит, пористый диоксид кремния, полые стеклянные микросферы, стеклянные волокна и неорганическая керамообразующую композицию, включающую силикатный минерал и неорганический фосфат, в полиуретан/полимочевинной полимерной матрице, изготовленной в реакции водного раствора силиката щелочного металла с гидрофильным изоцианатсодержащим форполимером, или в полиуретановой полимерной матрице, или в полиуретан/полиизоциануратной полимерной матрице.2. Панель (22) по п. 1, в которой противопожарный слой (B, C) является непрерывным и непрерывно присоединяется к металлической облицовке (12, A) и к изоляционному слою (D) пеноматериала.3. Панель (22) по п. 1 или 2, в которой противопожарный слой (B, C) включает дисперсию вспениваемого графита в полиуретан/полиизоциануратной полимерной матрице, у которой изоцианатный индекс составляет 1,8 или более.4. Панель (22) по п. 1 или 2, в которой толщина противопожарного слоя (B, C) составляет от 2 до 20 мм.5. Способ изготовления панели (22) по любому из предшествующих пунктов, включающий следующие стадии:- обеспечение первой металлической облицовки (12, A) с по меньшей мере одним противопожарным слоем (B, C);- нанесение изоляционного слоя (D) пеноматериала в виде жидкой реакционной смеси на противопожарный слой (слои) (B, C) и- нанесение второй металлической облицовки (20, A) на изоляционный слой (D)

Claims (13)

1. Панель (22), содержащая:
- металлическую облицовку (12, A);
- изоляционный слой (D) пеноматериала и,
- по меньшей мере, один противопожарный слой (B, C) между металлической облицовкой (12, A) и слоем (D) пеноматериала, причем противопожарный слой (слои) (B, C) содержит дисперсию, по меньшей мере, одного из следующих материалов: вспениваемый графит, пористый диоксид кремния, полые стеклянные микросферы, стеклянные волокна и неорганическая керамообразующую композицию, включающую силикатный минерал и неорганический фосфат, в полиуретан/полимочевинной полимерной матрице, изготовленной в реакции водного раствора силиката щелочного металла с гидрофильным изоцианатсодержащим форполимером, или в полиуретановой полимерной матрице, или в полиуретан/полиизоциануратной полимерной матрице.
2. Панель (22) по п. 1, в которой противопожарный слой (B, C) является непрерывным и непрерывно присоединяется к металлической облицовке (12, A) и к изоляционному слою (D) пеноматериала.
3. Панель (22) по п. 1 или 2, в которой противопожарный слой (B, C) включает дисперсию вспениваемого графита в полиуретан/полиизоциануратной полимерной матрице, у которой изоцианатный индекс составляет 1,8 или более.
4. Панель (22) по п. 1 или 2, в которой толщина противопожарного слоя (B, C) составляет от 2 до 20 мм.
5. Способ изготовления панели (22) по любому из предшествующих пунктов, включающий следующие стадии:
- обеспечение первой металлической облицовки (12, A) с по меньшей мере одним противопожарным слоем (B, C);
- нанесение изоляционного слоя (D) пеноматериала в виде жидкой реакционной смеси на противопожарный слой (слои) (B, C) и
- нанесение второй металлической облицовки (20, A) на изоляционный слой (D) пеноматериала.
6. Способ по п. 5, в котором по меньшей мере один противопожарный слой (B, C): (a) наносят в виде жидкой реакционной смеси или (b) наносят в твердой форме.
7. Способ по п. 6, в котором, в случае жидкой реакционной смеси, она включает дисперсию в реакционной смеси на изоцианатной основе по меньшей мере одного из следующих материалов: пористый диоксид кремния; полые стеклянные микросферы; стеклянные волокна; неорганическая керамообразующая композиция; вспениваемый графит.
8. Способ по п. 6, в котором, в случае противопожарного слоя (B, C), нанесенного в твердой форме, он представляет собой дисперсию пористого диоксида кремния в предварительно изготовленной полимерной матрице.
9. Способ изготовления панели (22), содержащей первую и вторую металлические облицовки (12, A; 20, A); изоляционный слой (D) пеноматериала и по меньшей мере один противопожарный слой (B, C) между металлической облицовкой (12, A) и изоляционным слоем (D) пеноматериала, причем противопожарный слой (слои) (B, C) содержит по меньшей мере один из следующих материалов: пористый диоксид кремния; полые стеклянные микросферы; стеклянные волокна, минеральные волокна, базальтовые волокна или углеродные волокна; неорганическую керамообразующую композицию, включающую силикатный минерал и неорганический фосфат; дисперсию вспениваемого графита в полиуретановой полимерной матрице, или в полиуретан/полиизоциануратной полимерной матрице, или в полиуретан/полимочевинной полимерной матрице, при этом данный способ включает следующие стадии:
- обеспечение первой металлической облицовки (12, A) с по меньшей мере одним противопожарным слоем (B, C), наносимым в виде жидкой реакционной смеси;
- нанесение изоляционного слоя (D) пеноматериала в виде жидкой реакционной смеси на противопожарный слой (слои) (B, C) и
- нанесение второй металлической облицовки (20, A) на изоляционный слой (D) пеноматериала.
10. Панельная конструкция (46), содержащая:
- две или более прилегающих панелей (22), опционально, по любому из п.п. 1-4, причем каждая панель (22) содержит металлическую облицовку (12, A) и изоляционный слой (D) пеноматериала, и
- противопожарный материал (B), расположенный в соединительной области (50) между прилегающими панелями (22),
при этом противопожарный материал (B) содержит по меньшей мере, один из следующих материалов: пористый диоксид кремния; полые стеклянные микросферы; стеклянные волокна; неорганическаякерамообразующая композиция, включающая силикатный минерал и неорганический фосфат; дисперсия вспениваемого графита в
полиуретановой полимерной матрице или в полиуретан/полиизоциануратной полимерной матрице, или в полиуретан/полимочевинной полимерной матрице.
11. Способ изготовления панельной конструкции (46) по п. 10, включающий следующие стадии:
- обеспечение панели (22) с противопожарным материалом (B); и
- размещение одной или нескольких дополнительных панелей (22), прилегающих к первой панели (22), таким образом, что противопожарный материал (B) расположен в соединительной области (50) между прилегающими панелями (22).
12. Противопожарная композиция (B, C), включающая:
- пористый диоксид кремния, диспергированный в полиуретан/полимочевинной полимерной матрице, получаемой посредством реакции водного раствора силиката щелочного металла с изоцианатсодержащим форполимером.
13. Реагент для изготовления противопожарной композиции (B, C), включающий:
- дисперсию пористого диоксида кремния в водном растворе силиката щелочного металла в качестве реагента, подходящего для реакции с изоцианатсодержащим форполимерным реагентом, в которой образуется полиуретан/полимочевинный полимер.
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CN103874575A (zh) 2014-06-18
JP2014534097A (ja) 2014-12-18
IN2014CN02641A (ru) 2015-08-07
EP2766181A1 (en) 2014-08-20
ES2773331T3 (es) 2020-07-10
RU2609044C2 (ru) 2017-01-30
PL2766181T3 (pl) 2020-07-13
CN103874575B (zh) 2016-09-21
EP3613583A1 (en) 2020-02-26
EP2766181B1 (en) 2020-01-22
EP2581216A1 (en) 2013-04-17
US20170067248A1 (en) 2017-03-09
CN106393878A (zh) 2017-02-15
US20140212619A1 (en) 2014-07-31
CA2851914A1 (en) 2013-04-18
BR112014008643A2 (pt) 2017-04-25
WO2013053566A1 (en) 2013-04-18
MX2014004488A (es) 2014-08-01
MX350888B (es) 2017-09-22

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