RU2013144015A - AQUATIC BINDERS FOR GRAIN AND / OR FIBROUS SUBSTRATES - Google Patents

AQUATIC BINDERS FOR GRAIN AND / OR FIBROUS SUBSTRATES Download PDF

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RU2013144015A
RU2013144015A RU2013144015/05A RU2013144015A RU2013144015A RU 2013144015 A RU2013144015 A RU 2013144015A RU 2013144015/05 A RU2013144015/05 A RU 2013144015/05A RU 2013144015 A RU2013144015 A RU 2013144015A RU 2013144015 A RU2013144015 A RU 2013144015A
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monomer
polymerizate
carbon atoms
binder composition
composition according
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RU2624302C2 (en
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Кристиан Крюгер
Александер ЦЕНТНЕР
Оливер ЛАБИШ
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Басф Се
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    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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    • C09J133/24—Homopolymers or copolymers of amides or imides
    • C09J133/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
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    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
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    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N5/00—Roofing materials comprising a fibrous web coated with bitumen or another polymer, e.g. pitch
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    • C09J105/00—Adhesives based on polysaccharides or on their derivatives, not provided for in groups C09J101/00 or C09J103/00
    • C09J105/04—Alginic acid; Derivatives thereof
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D04H1/641—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions characterised by the chemical composition of the bonding agent

Abstract

1. Водная композиция связующего средства, содержащаяa) по меньшей мере один полимеризат P, состоящий из≥0,1 и ≤2,5 мас.% по меньшей мере одного содержащего кислотные группы этилен-ненасыщенного мономера (мономер A)≥0 и ≤4,0 мас.% по меньшей мере одного этилен-ненасыщенного нитрила или динитрила карбоновой кислоты (мономер B)≥0 и ≤2,0 мас.% по меньшей мере одного обладающего эффектом поперечной сшивки мономера по меньшей мере с двумя неконъюгированными этилен-ненасыщенными группами (мономер C)≥0 и ≤10 мас.% по меньшей мере одного α,β-моноэтилен-ненасыщенного амида монокарбоновой или дикарбоновой кислоты с 3-6 атомами углерода (мономер D)≥25 и ≤69,9 мас.% по меньшей мере одного этилен-ненасыщенного мономера, гомополимеризат которого обладает температурой стеклования ≤30°С, и который отличается от мономеров А-D (мономер E), и≥30 и ≤70 мас.% по меньшей мере одного этилен-ненасыщенного мономера, гомополимеризат которого обладает температурой стеклования ≥50°C, и который отличается от мономеров А-D (мономер F),в полимеризируемой форме, причем количества мономеров А-F в сумме составляют 100 мас.%, иb) по меньшей мере одно сахаридное соединение S, причем его количество таково, что оно составляет ≥10 и ≤400 частей по массе на 100 частей по массе полимеризата P.2. Водная композиция связующего средства по п.1, причем по меньшей мере один мономер E выбран из группы, включающей в себя конъюгированные алифатические диеновые соединения с 4-9 атомами углерода, сложные эфиры винилового спирта и монокарбоновой кислоты с 1-10 атомами углерода, алкилакрилат с 1-10 атомами углерода, алкилметакрилат с 5-10 атомами углерода, циклоалкилакрилат и циклоалкилметакрилат с 1. An aqueous binder composition comprising a) at least one polymerizate P consisting of ≥0.1 and ≤2.5 wt.% Of at least one ethylenically unsaturated monomer containing acid groups (monomer A) ≥0 and ≤4 , 0 wt.% Of at least one ethylenically unsaturated nitrile or dinitrile carboxylic acid (monomer B) ≥0 and ≤2.0 wt.% Of at least one monomer with the effect of crosslinking with at least two unconjugated ethylenically unsaturated groups (monomer C) ≥0 and ≤10 wt.% at least one α, β-monoethylen monocarboxylic or dicarboxylic acid amide with 3-6 carbon atoms (monomer D) ≥25 and ≤69.9 wt.% at least one ethylenically unsaturated monomer, the homopolymerizate of which has a glass transition temperature of ≤30 ° C, and which differs from monomers AD (monomer E), and ≥30 and ≤70 wt.% Of at least one ethylenically unsaturated monomer, the homopolymerizate of which has a glass transition temperature of ≥50 ° C, and which differs from the monomers AD (monomer F), in polymerizable form, and the amount of monomers A-F in the amount of 100 wt.%, and b) enshey least one saccharide compound S, where the amount thereof is such that it is ≥10 and ≤400 parts by weight per 100 parts by weight of polymer P.2. The aqueous binder composition of claim 1, wherein at least one monomer E is selected from the group consisting of conjugated aliphatic diene compounds with 4-9 carbon atoms, vinyl alcohol and monocarboxylic acid esters with 1-10 carbon atoms, alkyl acrylate with 1-10 carbon atoms, alkyl methacrylate with 5-10 carbon atoms, cycloalkyl acrylate and cycloalkyl methacrylate with

Claims (19)

1. Водная композиция связующего средства, содержащая1. An aqueous composition of a binder containing a) по меньшей мере один полимеризат P, состоящий изa) at least one polymerizate P, consisting of ≥0,1 и ≤2,5 мас.% по меньшей мере одного содержащего кислотные группы этилен-ненасыщенного мономера (мономер A)≥0.1 and ≤2.5 wt.% Of at least one ethylenically unsaturated monomer containing acid groups (monomer A) ≥0 и ≤4,0 мас.% по меньшей мере одного этилен-ненасыщенного нитрила или динитрила карбоновой кислоты (мономер B)≥0 and ≤4.0 wt.% At least one ethylenically unsaturated nitrile or dinitrile carboxylic acid (monomer B) ≥0 и ≤2,0 мас.% по меньшей мере одного обладающего эффектом поперечной сшивки мономера по меньшей мере с двумя неконъюгированными этилен-ненасыщенными группами (мономер C)≥0 and ≤2.0 wt% of at least one cross-linking monomer with at least two unconjugated ethylenically unsaturated groups (monomer C) ≥0 и ≤10 мас.% по меньшей мере одного α,β-моноэтилен-ненасыщенного амида монокарбоновой или дикарбоновой кислоты с 3-6 атомами углерода (мономер D)≥0 and ≤10 wt% of at least one α, β-monoethylenically unsaturated amide of monocarboxylic or dicarboxylic acid with 3-6 carbon atoms (monomer D) ≥25 и ≤69,9 мас.% по меньшей мере одного этилен-ненасыщенного мономера, гомополимеризат которого обладает температурой стеклования ≤30°С, и который отличается от мономеров А-D (мономер E), и≥25 and ≤69.9% by weight of at least one ethylenically unsaturated monomer whose homopolymerizate has a glass transition temperature of ≤30 ° C, and which differs from A-D monomers (monomer E), and ≥30 и ≤70 мас.% по меньшей мере одного этилен-ненасыщенного мономера, гомополимеризат которого обладает температурой стеклования ≥50°C, и который отличается от мономеров А-D (мономер F),≥30 and ≤70 wt.% At least one ethylene unsaturated monomer, the homopolymerizate of which has a glass transition temperature of ≥50 ° C, and which differs from the monomers AD (monomer F), в полимеризируемой форме, причем количества мономеров А-F в сумме составляют 100 мас.%, иin a polymerizable form, wherein the amounts of AF monomers total 100 mass%, and b) по меньшей мере одно сахаридное соединение S, причем его количество таково, что оно составляет ≥10 и ≤400 частей по массе на 100 частей по массе полимеризата P.b) at least one saccharide compound S, the amount thereof being such that it is ≥10 and ≤400 parts by weight per 100 parts by weight of polymerizate P. 2. Водная композиция связующего средства по п.1, причем по меньшей мере один мономер E выбран из группы, включающей в себя конъюгированные алифатические диеновые соединения с 4-9 атомами углерода, сложные эфиры винилового спирта и монокарбоновой кислоты с 1-10 атомами углерода, алкилакрилат с 1-10 атомами углерода, алкилметакрилат с 5-10 атомами углерода, циклоалкилакрилат и циклоалкилметакрилат с 5-10 атомами углерода, диалкилмалеинат с 1-10 атомами углерода и/или диалкилфумарат с 1-10 атомами углерода, и по меньшей мере один мономер F выбран из группы, включающей в себя винил-ароматический мономер и/или алкилметакрилат с 1-4 атомами углерода.2. The aqueous binder composition according to claim 1, wherein at least one monomer E is selected from the group consisting of conjugated aliphatic diene compounds with 4-9 carbon atoms, esters of vinyl alcohol and monocarboxylic acid with 1-10 carbon atoms, alkyl acrylate with 1-10 carbon atoms, alkyl methacrylate with 5-10 carbon atoms, cycloalkyl acrylate and cycloalkyl methacrylate with 5-10 carbon atoms, dialkyl maleate with 1-10 carbon atoms and / or dialkyl fumarate with 1-10 carbon atoms, and at least one monomer F is selected from the group comprising a vinyl aromatic monomer and / or alkyl methacrylate with 1-4 carbon atoms. 3. Водная композиция связующего средства по п.1, причем полимеризат P содержит ≥0,1 и ≥1,5 мас.% по меньшей мере одного мономера C в полимеризированной форме.3. The aqueous binder composition according to claim 1, wherein the polymerizate P contains ≥0.1 and ≥1.5 wt.% Of at least one monomer C in polymerized form. 4. Водная композиция связующего средства по п.1, причем полимеризат P применяют в форме водной дисперсии полимеризата.4. The aqueous binder composition according to claim 1, wherein the polymerizate P is used in the form of an aqueous dispersion of the polymerizate. 5. Водная композиция связующего средства по п.4, причем среднечисленный диаметр частиц полимеризата в водной дисперсии полимеризата составляет ≥50 и ≤400 нм.5. The aqueous binder composition according to claim 4, wherein the number average particle diameter of the polymerizate in the aqueous dispersion of the polymerizate is ≥50 and ≤400 nm. 6. Водная композиция связующего средства по п.1, причем полимеризат P состоит из6. The aqueous binder composition according to claim 1, wherein the polymerizate P consists of ≥0,5 и ≤2,0 мас.% по меньшей мере одного мономера A;≥0.5 and ≤2.0 wt.% At least one monomer A; ≥0,1 и ≤1,5 мас.% по меньшей мере одного мономера C;≥0.1 and ≤1.5 wt.% At least one monomer C; ≥0 и ≤4,0 мас.% по меньшей мере одного мономера D;≥0 and ≤4.0 wt.% At least one monomer D; ≥30 и ≤60 мас.% по меньшей мере одного мономера E и≥30 and ≤60 wt.% At least one monomer E and ≥40 и ≤70 мас.% по меньшей мере одного мономера F.≥40 and ≤70 wt.% At least one monomer F. 7. Водная композиция связующего средства по п.1, причем полимеризат P состоит из7. The aqueous binder composition according to claim 1, wherein the polymerizate P consists of ≥1,0 и ≤2,0 мас.% акриловой кислоты, метакриловой кислоты и/или итаконовой кислоты;≥1.0 and ≤2.0 wt.% Acrylic acid, methacrylic acid and / or itaconic acid; ≥0,3 и ≤1,2 мас.% 1,4-бутиленгликольдиакрилата, аллилметакрилата и/или дивинилбензола;≥0.3 and ≤1.2 wt.% 1,4-butylene glycol diacrylate, allyl methacrylate and / or divinylbenzene; ≥0 и ≤4,0 мас.% акриламида, метакриламида, N-метилолакриламида и/или N-метилолметакриламида≥0 and ≤4.0 wt.% Acrylamide, methacrylamide, N-methylolacrylamide and / or N-methylol methacrylamide ≥30 и ≤50 мас.% 2-этилгексилакрилата, н-бутилакрилата, 1,4-бутадиена и/или этилакрилата и≥30 and ≤50 wt.% 2-ethylhexyl acrylate, n-butyl acrylate, 1,4-butadiene and / or ethyl acrylate and ≥40 и ≤60 мас.% метилметакрилата, стирола и/или трет-бутилметакрилата.≥40 and ≤60 wt.% Methyl methacrylate, styrene and / or tert-butyl methacrylate. 8. Водная композиция связующего средства по п.1, причем вид и количество мономеров A, B, D, E и F выбирают так, чтобы синтезированный из них полимеризат обладал температурой стеклования ≥5 и ≤35°C.8. The aqueous composition of the binder according to claim 1, wherein the type and amount of monomers A, B, D, E and F are selected so that the polymerizate synthesized from them has a glass transition temperature of ≥5 and ≤35 ° C. 9. Водная композиция связующего средства по п.1, причем в качестве по меньшей мере одного сахаридного соединения S применяют крахмал, целлюлозу, гуаран, ксантан, альгинат, пектин, хитозан, гуммиарабик и/или геллан.9. The aqueous binder composition according to claim 1, wherein starch, cellulose, guaran, xanthan, alginate, pectin, chitosan, gum arabic and / or gellan are used as the at least one saccharide compound S. 10. Водная композиция связующего средства по п.1, причем в качестве сахаридного соединения S применяют крахмал, производное крахмала и/или продукты его замещения.10. The aqueous binder composition according to claim 1, wherein starch, a starch derivative and / or substitution products thereof are used as the saccharide compound S. 11. Водная композиция связующего средства по п.1, причем сахаридное соединение S имеет среднемассовую молекулярную массу ≥5000 и ≤25000 г/моль.11. The aqueous binder composition according to claim 1, wherein the saccharide compound S has a weight average molecular weight of ≥5000 and ≤25000 g / mol. 12. Водная композиция связующего средства по п.1, причем используют ≥10 и ≤70 частей по массе сахаридного соединения S на 100 частей по массе полимеризата P.12. The aqueous binder composition according to claim 1, wherein ≥10 and ≤70 parts by weight of saccharide compound S are used per 100 parts by weight of polymerizate P. 13. Водная композиция связующего средства по одному из пп.1-12, дополнительно содержащая ≤1 мас.% полиольного соединения с молекулярной массой ≤200 г/моль с по меньшей мере 2 гидроксигруппами, относительно суммы общего количества полимеризата P и сахаридного соединения S.13. The aqueous binder composition according to one of claims 1 to 12, additionally containing ≤1 wt.% Polyol as one compound with a molecular weight of ≤200 g / mol with at least 2 hydroxy groups, relative to the sum of the total amount of polymerizate P and saccharide compound S. 14. Применение водной композиции связующего средства по одному из пп.1-13 в качестве связующего средства для зернистых и/или волокнистых субстратов, а также нецементных покрытий, герметиков и клеящих веществ.14. The use of an aqueous composition of a binder according to one of claims 1 to 13 as a binder for granular and / or fibrous substrates, as well as cementless coatings, sealants and adhesives. 15. Способ получения формованного изделия из зернистых и/или волокнистых субстратов, отличающийся тем, что на зернистый и/или волокнистый субстрат наносят водную композицию связующего средства по пп.1-13, обработанный таким образом зернистый и/или волокнистый субстрат при необходимости помещают в форму, а затем полученный таким образом зернистый и/или волокнистый субстрат проводят через этап термической обработки при температуре ≥110°C.15. A method of obtaining a molded product from granular and / or fibrous substrates, characterized in that an aqueous binder composition according to claims 1 to 13 is applied to a granular and / or fibrous substrate, the granular and / or fibrous substrate thus treated is, if necessary, placed in the form, and then the granular and / or fibrous substrate thus obtained, is conducted through a heat treatment step at a temperature of ≥110 ° C. 16. Способ получения формованного изделия по п.15, отличающийся тем, что количество водной композиции связующего средства выбирают так, чтобы на 100 г зернистого и/или волокнистого субстрата наносили ≥1 и ≤100 г связующего средства (что соответствует сумме общих количеств полимеризата P и полисахаридного соединения S).16. The method of producing the molded product according to item 15, wherein the amount of the aqueous composition of the binder is chosen so that ≥1 and ≤100 g of binder are applied per 100 g of granular and / or fibrous substrate (which corresponds to the sum of the total amounts of polymerizate P and polysaccharide compound S). 17. Применение формованного изделия, получаемого по способу согласно одному из пп.15 или 16, для получения битумированных кровельных полотен.17. The use of a molded product obtained by the method according to one of paragraphs.15 or 16, to obtain tarred roofing paintings. 18. Битумированные кровельные полотна, полученные с применением формованного изделия, получаемого согласно способу по одному из пп.15 или 16.18. Bitumen roofing sheets obtained using a molded product obtained according to the method according to one of paragraphs.15 or 16. 19. Водная дисперсия полимеризата, полимеризат которой в полимеризованной форме состоит из следующих компонентов:19. An aqueous dispersion of a polymerizate, the polymerizate of which in the polymerized form consists of the following components: ≥0,1 и ≤2,5 мас.% по меньшей мере одного мономера A,≥0.1 and ≤2.5 wt.% At least one monomer A, ≥0 и ≤4,0 мас.% по меньшей мере одного мономера B,≥0 and ≤4.0 wt.% At least one monomer B, ≥0 и ≤2,0 мас.% по меньшей мере одного мономера C,≥0 and ≤2.0 wt.% At least one monomer C, ≥0 и ≤10 мас.% по меньшей мере одного мономера D,≥0 and ≤10 wt.% At least one monomer D, ≥25 и ≤69,9 мас.% по меньшей мере одного мономера E и≥25 and ≤69.9 wt.% At least one monomer E and ≥30 и ≤70 мас.% по меньшей мере одного мономера F,≥30 and ≤70 wt.% At least one monomer F, причем количества мономеров А-F в сумме составляют 100 мас.%. moreover, the amount of monomers A-F in the amount of 100 wt.%.
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