RU2012153201A - LUBRICANT OIL COMPOSITION FOR DIESEL ENGINES - Google Patents

LUBRICANT OIL COMPOSITION FOR DIESEL ENGINES Download PDF

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RU2012153201A
RU2012153201A RU2012153201/04A RU2012153201A RU2012153201A RU 2012153201 A RU2012153201 A RU 2012153201A RU 2012153201/04 A RU2012153201/04 A RU 2012153201/04A RU 2012153201 A RU2012153201 A RU 2012153201A RU 2012153201 A RU2012153201 A RU 2012153201A
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zinc
mass
nitrogen
amount
group
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RU2012153201/04A
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RU2560964C2 (en
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Киёси ХАНЬЮДА
Тецуо ВАКИЗОНО
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/12—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic compound containing atoms of elements not provided for in groups C10M141/02 - C10M141/10
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022—Ethene
    • C10M2205/0225—Ethene used as base material
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C10M2205/173—Fisher Tropsch reaction products used as base material
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C10M2215/065—Phenyl-Naphthyl amines
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/066—Arylene diamines
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086—Imides
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28—Amides; Imides
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40—Low content or no content compositions
    • C10N2030/42—Phosphor free or low phosphor content compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40—Low content or no content compositions
    • C10N2030/43—Sulfur free or low sulfur content compositions
    • C—CHEMISTRY; METALLURGY
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40—Low content or no content compositions
    • C10N2030/44—Boron free or low content boron compositions
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40—Low content or no content compositions
    • C10N2030/45—Ash-less or low ash content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
    • C10N2040/253—Small diesel engines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

1. Композиция смазочного масла для использования в дизельных двигателях, которая содержит в базовом масле, не более 0,3% (масс) сульфатной зольности, от 0,01 до 0,2% (масс) азота в сукцинимидах, от 0,05 до 0,12% (масс) цинка в дитиофосфатах цинка, от 0,02 до 0,3% (масс) азота в антиоксидантах на основе аминов и от 0,01 до 0,08% (масс) бора, которая, кроме того, имеет суммарное значение параметра [(количество цинка в дитиофосфатах цинка)·(количество азота в сукцинимидах)] и [(количество цинка в дитиофосфатах цинка)·(количество азота в антиоксидантах на основе аминов)], составляющее не менее 0,015, при этом композиция не содержит салицилатных фенолятных или сульфонатных металлосодержащих детергентов.2. Композиция смазочного масла по п.1, где вышеупомянутое масло представляет собой одно базовое масло или смесь базовых масел, выбранных из группы II, группы III, группы IV и группы V, и где содержание серного компонента базового масла составляет не более 50 м.д.3. Композиция смазочного масла по п.1 или 2, в которой моющая способность (TGF) согласно методу тестирования моющей способности моторных масел JASO М336:1998 составляет не более 30%, а износ клапанного механизма, определяемый методом тестирования износа клапанного механизма JASO М354:1999, составляет не более 95 мкм.4. Композиция смазочного масла по п.1 или 2, в которой вышеупомянутое масло содержит вторичные алкилдитиофосфаты цинка, алкильные группы которых содержат от 3 до 12 атомов углерода.1. The composition of the lubricating oil for use in diesel engines, which contains in the base oil, not more than 0.3% (mass) of sulphated ash, from 0.01 to 0.2% (mass) of nitrogen in succinimides, from 0.05 to 0.12% (mass) of zinc in zinc dithiophosphates, from 0.02 to 0.3% (mass) of nitrogen in amine-based antioxidants, and from 0.01 to 0.08% (mass) of boron, which, in addition, has the total value of the parameter [(amount of zinc in zinc dithiophosphates) · (amount of nitrogen in succinimides)] and [(amount of zinc in zinc dithiophosphates) · (amount of nitrogen in amine-based antioxidants)], s be not less than 0.015, wherein the composition contains no salicylate phenolate or sulfonate metal detergentov.2. The lubricating oil composition according to claim 1, where the aforementioned oil is one base oil or a mixture of base oils selected from group II, group III, group IV and group V, and where the sulfur content of the base oil component is not more than 50 ppm 3. The lubricating oil composition according to claim 1 or 2, in which the washing ability (TGF) according to the method of testing the washing ability of motor oils JASO M336: 1998 is not more than 30%, and the wear of the valve mechanism, determined by the method of testing the wear of the valve mechanism JASO M354: 1999, is not more than 95 microns. 4. The lubricating oil composition according to claim 1 or 2, wherein the aforementioned oil contains secondary zinc alkyldithiophosphates, the alkyl groups of which contain from 3 to 12 carbon atoms.

Claims (4)

1. Композиция смазочного масла для использования в дизельных двигателях, которая содержит в базовом масле, не более 0,3% (масс) сульфатной зольности, от 0,01 до 0,2% (масс) азота в сукцинимидах, от 0,05 до 0,12% (масс) цинка в дитиофосфатах цинка, от 0,02 до 0,3% (масс) азота в антиоксидантах на основе аминов и от 0,01 до 0,08% (масс) бора, которая, кроме того, имеет суммарное значение параметра [(количество цинка в дитиофосфатах цинка)·(количество азота в сукцинимидах)] и [(количество цинка в дитиофосфатах цинка)·(количество азота в антиоксидантах на основе аминов)], составляющее не менее 0,015, при этом композиция не содержит салицилатных фенолятных или сульфонатных металлосодержащих детергентов.1. The composition of the lubricating oil for use in diesel engines, which contains in the base oil, not more than 0.3% (mass) of sulphated ash, from 0.01 to 0.2% (mass) of nitrogen in succinimides, from 0.05 to 0.12% (mass) of zinc in zinc dithiophosphates, from 0.02 to 0.3% (mass) of nitrogen in amine-based antioxidants, and from 0.01 to 0.08% (mass) of boron, which, in addition, has the total value of the parameter [(amount of zinc in zinc dithiophosphates) · (amount of nitrogen in succinimides)] and [(amount of zinc in zinc dithiophosphates) · (amount of nitrogen in amine-based antioxidants)], s be not less than 0.015, wherein the composition does not contain phenolate or salicylate metal sulfonate detergents. 2. Композиция смазочного масла по п.1, где вышеупомянутое масло представляет собой одно базовое масло или смесь базовых масел, выбранных из группы II, группы III, группы IV и группы V, и где содержание серного компонента базового масла составляет не более 50 м.д.2. The lubricating oil composition according to claim 1, where the aforementioned oil is one base oil or a mixture of base oils selected from group II, group III, group IV and group V, and where the sulfur content of the base oil component is not more than 50 m d. 3. Композиция смазочного масла по п.1 или 2, в которой моющая способность (TGF) согласно методу тестирования моющей способности моторных масел JASO М336:1998 составляет не более 30%, а износ клапанного механизма, определяемый методом тестирования износа клапанного механизма JASO М354:1999, составляет не более 95 мкм.3. The lubricating oil composition according to claim 1 or 2, in which the washing ability (TGF) according to the method of testing the washing ability of motor oils JASO M336: 1998 is not more than 30%, and the wear of the valve mechanism, determined by the method of testing the wear of the valve mechanism JASO M354: 1999, is not more than 95 microns. 4. Композиция смазочного масла по п.1 или 2, в которой вышеупомянутое масло содержит вторичные алкилдитиофосфаты цинка, алкильные группы которых содержат от 3 до 12 атомов углерода. 4. The lubricating oil composition according to claim 1 or 2, in which the aforementioned oil contains secondary zinc alkyldithiophosphates, the alkyl groups of which contain from 3 to 12 carbon atoms.
RU2012153201/04A 2010-05-11 2011-05-11 Lubricating oil composition for diesel engines RU2560964C2 (en)

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JP2010109425 2010-05-11
JP2010-109425 2010-05-11
JP2011-104510 2011-05-09
JP2011104510A JP5687951B2 (en) 2010-05-11 2011-05-09 Lubricating oil composition for diesel engines
PCT/EP2011/057585 WO2011141495A1 (en) 2010-05-11 2011-05-11 Lubricating oil composition for diesel engines

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RU2012153201A true RU2012153201A (en) 2014-06-20
RU2560964C2 RU2560964C2 (en) 2015-08-20

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US (1) US20130267449A1 (en)
EP (1) EP2569404B1 (en)
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CN (1) CN102939365B (en)
BR (1) BR112012028762A2 (en)
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