RU2010141752A - Полимерсодержащая композиция, ее получение и применение - Google Patents

Полимерсодержащая композиция, ее получение и применение Download PDF

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RU2010141752A
RU2010141752A RU2010141752/04A RU2010141752A RU2010141752A RU 2010141752 A RU2010141752 A RU 2010141752A RU 2010141752/04 A RU2010141752/04 A RU 2010141752/04A RU 2010141752 A RU2010141752 A RU 2010141752A RU 2010141752 A RU2010141752 A RU 2010141752A
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polymer
lactide
poly
containing composition
polymers
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Робин ВИНТЕРС (NL)
Робин ВИНТЕРС
Элвин СХОМАКЕР (NL)
Элвин СХОМАКЕР
ВОС Сибе Корнелис ДЕ (NL)
ВОС Сибе Корнелис ДЕ
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Акцо Нобель Н.В. (NL)
Акцо Нобель Н.В.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/06—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/08—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Medicinal Preparation (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)

Abstract

1. Способ получения полимерсодержащей композиции, включающий стадии: ! a) получения смеси, по меньшей мере, одного циклического мономера, выбранного из гликолида и лактида и слоистого двойного гидроксида, содержащего в качестве анионов компенсирующих заряд, от 10 до 100% органического аниона и от 0 до 90% гидроксида от общего количестве анионов, компенсирующих заряд, и ! b) полимеризации вышеупомянутого мономера необязательно в присутствии инициатора или катализатора полимеризации. ! 2. Способ по п.1, в котором лактидом является L-лактид. ! 3. Способ по п.2, в котором полимер представляет собой поли(L-лактид) или поли(L-лактид/гликолид). ! 4. Способ по любому из пп.1-3, в котором слоистый двойной гидроксид содержит только органический анион. ! 5. Способ по любому из пп.1-3, в котором органический анион, компенсирующий заряд, выбирают из жирных кислот, анионов на основе смолы и их комбинаций. ! 6. Способ по любому из пп.1-3, в котором на стадии b) присутствует инициатор или катализатор полимеризации. ! 7. Способ по любому из пп.1-3, в котором смесь на стадии а) дополнительно содержит один или несколько полимеров. ! 8. Способ по п.7, в котором полимер(ы) выбирают из группы, состоящей из полиолефинов, алифатических и ароматических сложных полиэфиров, поли(эфир эфиров), виниловых полимеров, (мет)акриловых полимеров, поликарбонатов, полиамидов, полиарамидов, полиимидов, поли(аминокислот), полимеров на основе полисахаридов, полиуретанов, полисульфонов и полиэпоксидов. ! 9. Полимерсодержащая композиция, получаемая способом по любому из предшествующих пунктов. ! 10. Применение полимерсодержащей композиции по п.9 в составах для покрытия, чернил, чистящих

Claims (11)

1. Способ получения полимерсодержащей композиции, включающий стадии:
a) получения смеси, по меньшей мере, одного циклического мономера, выбранного из гликолида и лактида и слоистого двойного гидроксида, содержащего в качестве анионов компенсирующих заряд, от 10 до 100% органического аниона и от 0 до 90% гидроксида от общего количестве анионов, компенсирующих заряд, и
b) полимеризации вышеупомянутого мономера необязательно в присутствии инициатора или катализатора полимеризации.
2. Способ по п.1, в котором лактидом является L-лактид.
3. Способ по п.2, в котором полимер представляет собой поли(L-лактид) или поли(L-лактид/гликолид).
4. Способ по любому из пп.1-3, в котором слоистый двойной гидроксид содержит только органический анион.
5. Способ по любому из пп.1-3, в котором органический анион, компенсирующий заряд, выбирают из жирных кислот, анионов на основе смолы и их комбинаций.
6. Способ по любому из пп.1-3, в котором на стадии b) присутствует инициатор или катализатор полимеризации.
7. Способ по любому из пп.1-3, в котором смесь на стадии а) дополнительно содержит один или несколько полимеров.
8. Способ по п.7, в котором полимер(ы) выбирают из группы, состоящей из полиолефинов, алифатических и ароматических сложных полиэфиров, поли(эфир эфиров), виниловых полимеров, (мет)акриловых полимеров, поликарбонатов, полиамидов, полиарамидов, полиимидов, поли(аминокислот), полимеров на основе полисахаридов, полиуретанов, полисульфонов и полиэпоксидов.
9. Полимерсодержащая композиция, получаемая способом по любому из предшествующих пунктов.
10. Применение полимерсодержащей композиции по п.9 в составах для покрытия, чернил, чистящих средств, резин или смол, в буровых растворах, в составах цемента, в составах штукатурок или при производстве бумаги.
11. Применение полимерсодержащей композиции по п.9 для получения клеящего состава, хирургического и медицинского инструмента, синтетической повязки на рану или бандажа, пены, пленки, материала для контролируемого выделения лекарственного препарата, пестицида или удобрения, нетканого полотна, ортопедического протеза, сорбента или керамического материала.
RU2010141752/04A 2008-03-12 2009-03-09 Полимерсодержащая композиция, ее получение и применение RU2010141752A (ru)

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EP08152640.2 2008-03-12
US3824408P 2008-03-20 2008-03-20
US61/038,244 2008-03-20

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US (1) US20110003719A1 (ru)
EP (1) EP2252644A1 (ru)
JP (1) JP2011517709A (ru)
KR (1) KR20100134020A (ru)
CN (1) CN101945918A (ru)
BR (1) BRPI0905885A2 (ru)
CA (1) CA2718165A1 (ru)
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US8252673B2 (en) * 2009-12-21 2012-08-28 International Business Machines Corporation Spin-on formulation and method for stripping an ion implanted photoresist
US20130319288A1 (en) * 2012-06-04 2013-12-05 Nadya Belcheva Environmentally Friendly Medical Packaging
CN105419395A (zh) * 2015-11-03 2016-03-23 河南师范大学 一种PDLA-n-HA/PLLA杂化材料的制备方法
CZ307487B6 (cs) 2015-11-05 2018-10-10 Ústav makromolekulární chemie AV ČR, v. v. i. Způsob přípravy polymerních materiálů
JP6704798B2 (ja) * 2016-06-03 2020-06-03 株式会社クレハ 資材、および、資材の製造方法
CN115246955B (zh) * 2021-04-28 2024-02-13 中国石油化工股份有限公司 一种层状结构吸酸剂及其制备方法和应用

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JP2003231743A (ja) * 2002-02-08 2003-08-19 Toyobo Co Ltd ポリエステル樹脂組成物及びその製造方法
JP4058683B2 (ja) * 2002-10-21 2008-03-12 戸田工業株式会社 生分解性樹脂組成物
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KR20070033379A (ko) * 2004-06-23 2007-03-26 아크조 노벨 엔.브이. 폴리머-함유 조성물, 이의 제조 방법 및 이의 용도
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KR20100134020A (ko) 2010-12-22
BRPI0905885A2 (pt) 2015-06-30
JP2011517709A (ja) 2011-06-16
CA2718165A1 (en) 2009-09-17
WO2009112441A1 (en) 2009-09-17
CN101945918A (zh) 2011-01-12
EP2252644A1 (en) 2010-11-24
US20110003719A1 (en) 2011-01-06

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