RU2010118167A - METHOD FOR CARRYING OUT PYROLYSIS - Google Patents
METHOD FOR CARRYING OUT PYROLYSIS Download PDFInfo
- Publication number
- RU2010118167A RU2010118167A RU2010118167/05A RU2010118167A RU2010118167A RU 2010118167 A RU2010118167 A RU 2010118167A RU 2010118167/05 A RU2010118167/05 A RU 2010118167/05A RU 2010118167 A RU2010118167 A RU 2010118167A RU 2010118167 A RU2010118167 A RU 2010118167A
- Authority
- RU
- Russia
- Prior art keywords
- pyrolysis
- stage
- boiler
- product
- additional
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
- C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
- C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/482—Gasifiers with stationary fluidised bed
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
- C10J3/64—Processes with decomposition of the distillation products
- C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
- C10K3/003—Reducing the tar content
- C10K3/006—Reducing the tar content by steam reforming
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1246—Heating the gasifier by external or indirect heating
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
- C10J2300/1606—Combustion processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1625—Integration of gasification processes with another plant or parts within the plant with solids treatment
- C10J2300/1637—Char combustion
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1659—Conversion of synthesis gas to chemicals to liquid hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1665—Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Gasification And Melting Of Waste (AREA)
Abstract
1. Способ осуществления пиролиза, при котором первый исходный материал подают в котел для сжигания, а второй исходный материал подают в реактор пиролиза, которые объединены друг с другом; при этом в котле для сжигания из первого исходного материала получают энергию и передают ее из котла для сжигания в реактор пиролиза с помощью теплоносителя, теплоноситель нагревают в котле для сжигания, а в реакторе пиролиза из второго исходного материала получают газообразные и жидкие фракции продукта посредством быстрого пиролиза, отличающийся тем, что второй исходный материал смешивают с газом-носителем для получения смеси, а нагретый теплоноситель направляют в данную смесь, и получение фракций продукта пиролиза и энергии регулируют путем оптимизации выбора исходного материала, состава суммарного продукта и себестоимости производства, цены и качества по меньшей мере одной из фракций продукта посредством изменения технологических параметров, которые выбирают из группы, включающей первый исходный материал, второй исходный материал, количества исходных материалов, выбор дополнительных веществ, технологический режим, выбор дополнительной стадии процесса, состав и количество применяемого газа-носителя, количество кислорода, выбор теплоносителя и содержание влаги в исходном материале. ! 2. Способ по п.1, отличающийся тем, что газообразные фракции продукта, полученные во время пиролиза, главным образом, конденсируют в жидкие продукты пиролиза. ! 3. Способ по п.1, отличающийся тем, что исходный материал выбирают из группы, включающей органическое вещество, стружки, щепу лесоматериалов, древесину, кору, опилки, солому, угол 1. A method for carrying out pyrolysis, in which a first raw material is fed to a combustion boiler, and a second raw material is fed to a pyrolysis reactor, which are combined with each other; while in the combustion boiler, energy is obtained from the first source material and transferred from the combustion boiler to the pyrolysis reactor using a heat carrier, the heat carrier is heated in the combustion boiler, and in the pyrolysis reactor, gaseous and liquid product fractions are obtained from the second starting material by means of rapid pyrolysis characterized in that the second starting material is mixed with a carrier gas to obtain a mixture, and the heated heat carrier is directed into this mixture, and the production of pyrolysis product and energy fractions is controlled by optimizing the choice of the starting material, the composition of the total product and the production cost, price and quality at least one of the product fractions by changing technological parameters, which are selected from the group including the first starting material, the second starting material, the amount of starting materials, the choice of additional substances, the technological mode, the choice of an additional stage of the process, the composition and the amount of applied o carrier gas, amount of oxygen, choice of heat carrier and moisture content of the feed. ! 2. A method according to claim 1, characterized in that the gaseous product fractions obtained during pyrolysis are mainly condensed into liquid pyrolysis products. ! 3. The method according to claim 1, characterized in that the source material is selected from the group including organic matter, shavings, wood chips, wood, bark, sawdust, straw, angle
Claims (15)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US20075721 | 2007-10-11 | ||
FI20075721A FI123455B (en) | 2007-10-11 | 2007-10-11 | Procedure for performing pyrolysis |
PCT/FI2008/050558 WO2009047387A1 (en) | 2007-10-11 | 2008-10-08 | Method for carrying out pyrolysis |
Publications (2)
Publication Number | Publication Date |
---|---|
RU2010118167A true RU2010118167A (en) | 2011-11-20 |
RU2502779C2 RU2502779C2 (en) | 2013-12-27 |
Family
ID=38656868
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2010118167/05A RU2502779C2 (en) | 2007-10-11 | 2008-10-08 | Method of conducting pyrolysis |
Country Status (8)
Country | Link |
---|---|
US (1) | US20110041388A1 (en) |
EP (1) | EP2209871A1 (en) |
CN (1) | CN101868516A (en) |
BR (1) | BRPI0817547A2 (en) |
CA (1) | CA2702193A1 (en) |
FI (1) | FI123455B (en) |
RU (1) | RU2502779C2 (en) |
WO (1) | WO2009047387A1 (en) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2647564C (en) | 2006-04-03 | 2016-08-30 | Pharmatherm Chemicals Inc. | Thermal extraction method and product |
US7905990B2 (en) | 2007-11-20 | 2011-03-15 | Ensyn Renewables, Inc. | Rapid thermal conversion of biomass |
RU2011153516A (en) * | 2009-05-28 | 2013-07-10 | ТАННХОЙЗЕР ГЁЛЬ Айпи АГ | ENERGY PRODUCTION PROCESS FROM ORGANIC MATERIALS AND / OR BIOMASS |
FI125814B (en) | 2009-06-02 | 2016-02-29 | Valmet Technologies Oy | Method for performing pyrolysis and pyrolysis apparatus |
US8519203B2 (en) | 2010-02-17 | 2013-08-27 | Uop Llc | Low oxygen biomass-derived pyrolysis oils and methods for producing the same |
US20110284359A1 (en) | 2010-05-20 | 2011-11-24 | Uop Llc | Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas |
US8499702B2 (en) | 2010-07-15 | 2013-08-06 | Ensyn Renewables, Inc. | Char-handling processes in a pyrolysis system |
US8519205B2 (en) | 2010-07-23 | 2013-08-27 | Ensyn Renewables, Inc. | Low water biomass-derived pyrolysis oils and processes for producing the same |
US20120061618A1 (en) * | 2010-09-11 | 2012-03-15 | James Santoianni | Plasma gasification reactors with modified carbon beds and reduced coke requirements |
US9441887B2 (en) | 2011-02-22 | 2016-09-13 | Ensyn Renewables, Inc. | Heat removal and recovery in biomass pyrolysis |
US9347005B2 (en) | 2011-09-13 | 2016-05-24 | Ensyn Renewables, Inc. | Methods and apparatuses for rapid thermal processing of carbonaceous material |
US10041667B2 (en) | 2011-09-22 | 2018-08-07 | Ensyn Renewables, Inc. | Apparatuses for controlling heat for rapid thermal processing of carbonaceous material and methods for the same |
US9044727B2 (en) | 2011-09-22 | 2015-06-02 | Ensyn Renewables, Inc. | Apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material |
US10400175B2 (en) | 2011-09-22 | 2019-09-03 | Ensyn Renewables, Inc. | Apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material |
US9109177B2 (en) | 2011-12-12 | 2015-08-18 | Ensyn Renewables, Inc. | Systems and methods for renewable fuel |
MX348722B (en) * | 2012-05-18 | 2017-06-26 | Japan Blue Energy Co Ltd | Biomass gasifier device. |
US9670413B2 (en) | 2012-06-28 | 2017-06-06 | Ensyn Renewables, Inc. | Methods and apparatuses for thermally converting biomass |
US10633606B2 (en) | 2012-12-10 | 2020-04-28 | Ensyn Renewables, Inc. | Systems and methods for renewable fuel |
GB2503065B (en) | 2013-02-20 | 2014-11-05 | Recycling Technologies Ltd | Process and apparatus for treating waste comprising mixed plastic waste |
CN104138886B (en) * | 2014-06-30 | 2016-03-02 | 中国科学技术大学 | A kind of method of fixed-contamination thing organophosphorus ester in copyrolysis process |
US10337726B2 (en) | 2015-08-21 | 2019-07-02 | Ensyn Renewables, Inc. | Liquid biomass heating system |
MY193949A (en) | 2016-12-29 | 2022-11-02 | Ensyn Renewables Inc | Demetallization Of Liquid Biomass |
WO2021054897A1 (en) * | 2019-09-17 | 2021-03-25 | National University Of Singapore | Waste treatment system |
GB2618830A (en) * | 2022-05-19 | 2023-11-22 | Quantafuel Asa | Processing of plastic |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3039955A (en) * | 1958-08-21 | 1962-06-19 | United Eng & Constructors Inc | Pyrolysis process |
US4064018A (en) * | 1976-06-25 | 1977-12-20 | Occidental Petroleum Corporation | Internally circulating fast fluidized bed flash pyrolysis reactor |
US4225392A (en) * | 1978-09-05 | 1980-09-30 | Taylor Leland T | Pyrolysis apparatus |
US4412910A (en) * | 1981-10-21 | 1983-11-01 | Westinghouse Electric Corp. | Recovery of fuel from oil shale |
US5136117A (en) * | 1990-08-23 | 1992-08-04 | Battelle Memorial Institute | Monomeric recovery from polymeric materials |
EP0823590B1 (en) * | 1996-02-29 | 2005-02-02 | Mitsubishi Heavy Industries, Ltd. | Method and apparatus for producing superheated steam using heat generated through incineration of wastes |
RU2125585C1 (en) * | 1997-07-11 | 1999-01-27 | Саратовский государственный технический университет | Method of thermally processing slate |
FI117512B (en) * | 1998-10-14 | 2006-11-15 | Valtion Teknillinen | Method and apparatus for producing pyrolysis oil |
FI116902B (en) * | 1998-10-14 | 2006-03-31 | Valtion Teknillinen | Method and apparatus for improving the quality of the pyrolysis liquid |
DE19945771C1 (en) * | 1999-09-24 | 2001-02-22 | Muehlen Gmbh & Co Kg Dr | Process for gasifying organic materials comprises cracking the materials by contacting with a hot heat carrier medium which is removed from a solid carbonaceous residue after leaving the pyrolysis reactor and conveyed to a heating zone |
FI120909B (en) * | 2001-04-12 | 2010-04-30 | Neste Oil Oyj | A method for treating carbonaceous material |
FI20030241A (en) * | 2003-02-17 | 2004-08-18 | Fortum Oyj | A method for producing a synthesis gas |
RU2240339C1 (en) * | 2003-06-02 | 2004-11-20 | Забарский Борис Лаврентьевич | Installation for pyrolysis of hydrocarbonaceous raw material |
RU2268910C2 (en) * | 2003-10-28 | 2006-01-27 | ОАО "Стройтрансгаз" | Method of large-capacity production of a lump fuel charcoal and a device for its realization |
CA2606488A1 (en) * | 2005-04-29 | 2006-11-09 | Hycet, Llc | System and method for conversion of hydrocarbon materials |
FI122778B (en) * | 2008-03-31 | 2012-06-29 | Metso Power Oy | Pyrolysis method in conjunction with a boiler, and pyrolysis device |
-
2007
- 2007-10-11 FI FI20075721A patent/FI123455B/en active IP Right Grant
-
2008
- 2008-10-08 EP EP08805480A patent/EP2209871A1/en not_active Withdrawn
- 2008-10-08 WO PCT/FI2008/050558 patent/WO2009047387A1/en active Application Filing
- 2008-10-08 US US12/682,695 patent/US20110041388A1/en not_active Abandoned
- 2008-10-08 CN CN200880116721A patent/CN101868516A/en active Pending
- 2008-10-08 BR BRPI0817547 patent/BRPI0817547A2/en not_active Application Discontinuation
- 2008-10-08 RU RU2010118167/05A patent/RU2502779C2/en active
- 2008-10-08 CA CA2702193A patent/CA2702193A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
BRPI0817547A2 (en) | 2015-03-31 |
US20110041388A1 (en) | 2011-02-24 |
FI123455B (en) | 2013-05-15 |
WO2009047387A1 (en) | 2009-04-16 |
RU2502779C2 (en) | 2013-12-27 |
EP2209871A1 (en) | 2010-07-28 |
FI20075721A0 (en) | 2007-10-11 |
CN101868516A (en) | 2010-10-20 |
FI20075721A (en) | 2009-04-12 |
CA2702193A1 (en) | 2009-04-16 |
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