RU2002110816A - The method of gasification of organic substances and mixtures of substances - Google Patents

The method of gasification of organic substances and mixtures of substances

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Publication number
RU2002110816A
RU2002110816A RU2002110816/04A RU2002110816A RU2002110816A RU 2002110816 A RU2002110816 A RU 2002110816A RU 2002110816/04 A RU2002110816/04 A RU 2002110816/04A RU 2002110816 A RU2002110816 A RU 2002110816A RU 2002110816 A RU2002110816 A RU 2002110816A
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RU
Russia
Prior art keywords
heat transfer
zone
transfer medium
pyrolysis
heat
Prior art date
Application number
RU2002110816/04A
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Russian (ru)
Other versions
RU2240341C2 (en
Inventor
Хайнц-Юрген Мюлен
Кристоф ШМИД
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Др.Мюлен Гмбх Унд Ко.Кг
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Priority claimed from DE19945771A external-priority patent/DE19945771C1/en
Application filed by Др.Мюлен Гмбх Унд Ко.Кг filed Critical Др.Мюлен Гмбх Унд Ко.Кг
Publication of RU2002110816A publication Critical patent/RU2002110816A/en
Application granted granted Critical
Publication of RU2240341C2 publication Critical patent/RU2240341C2/en

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Claims (15)

1. Способ получения целевого газа с высокой теплотворной способностью из органических веществ или смеси веществ, при котором циркулирующая в контуре теплонесущая среда проходит зону нагрева, реакционную зону, зону пиролиза и зону разделения и после этого возвращается в зону нагрева, причем органические вещества или смесь веществ расщепляются в зоне пиролиза путем контактирования с нагретой теплонесущей средой на твердый углеродсодержащий остаток и пиролизный газ в качестве летучей фазы, после прохождения зоны пиролиза твердый углеродсодержащий остаток на стадии разделения отделяют от теплонесущей среды, и пиролизный газ смешивают с водяным паром в качестве реагента, и в реакционной зоне путем обмена части тепла, содержащегося в нагретой теплонесущей среде, снова нагревают, с получением целевого газа с высокой теплотворной способностью, отличающийся тем, что водяной пар подмешивают к пиролизному газу в зоне пиролиза, собранный твердый углеродсодержащий остаток подают в специальную топку и там сжигают, и горячие отходящие газы из указанной топки пропускают в находящуюся в зоне нагрева сыпучую массу теплонесущей среды, причем большую часть заметного тепла определенным образом передают теплонесущей среде.1. A method of producing a target gas with a high calorific value from organic substances or a mixture of substances, in which the heat transfer medium circulating in the circuit passes the heating zone, the reaction zone, the pyrolysis zone and the separation zone and then returns to the heating zone, wherein the organic substances or mixture of substances split in the pyrolysis zone by contacting with a heated heat-transfer medium into a solid carbon-containing residue and pyrolysis gas as a volatile phase, after passing through the pyrolysis zone, solid carbon containing the remainder in the separation stage is separated from the heat transfer medium, and the pyrolysis gas is mixed with water vapor as a reagent, and in the reaction zone, by exchanging part of the heat contained in the heated heat transfer medium, it is heated again to obtain the target gas with high calorific value, characterized in that water vapor is mixed with the pyrolysis gas in the pyrolysis zone, the collected solid carbon-containing residue is fed to a special furnace and burned there, and hot exhaust gases from the specified furnace are passed to Yusya heating zone in loose weight heat-carrying medium, the most significant heat transfer in a certain way the heat-carrying medium. 2. Способ по п.1, отличающийся тем, что водяной пар подмешивают к пиролизному газу в зоне пиролиза, вблизи от выхода смеси теплонесущей среды и твердого углеродсодержащего остатка.2. The method according to claim 1, characterized in that the water vapor is mixed with the pyrolysis gas in the pyrolysis zone, close to the outlet of the mixture of the heat transfer medium and the solid carbon-containing residue. 3. Способ по п.1, отличающийся тем, что часть пиролизного газа или целевого газа сжигают в топке для углеродсодержащего остатка или в отдельной топке, и образовавшееся при этом тепло используют в зоне пиролиза и реакционной зоне.3. The method according to claim 1, characterized in that part of the pyrolysis gas or the target gas is burned in a furnace for a carbon-containing residue or in a separate furnace, and the heat generated in this process is used in the pyrolysis zone and the reaction zone. 4. Способ по п.1, отличающийся тем, что реакцию пиролизного газа с водяным паром проводят в присутствии катализатора.4. The method according to claim 1, characterized in that the reaction of the pyrolysis gas with water vapor is carried out in the presence of a catalyst. 5. Способ по п.1, отличающийся тем, что теплонесущая среда состоит из огнестойкого вещества, такого как песок, гравий, щебень, алюмосиликат, корунд, серая вакка, кварцит или кордиерит.5. The method according to claim 1, characterized in that the heat transfer medium consists of a fire-resistant substance, such as sand, gravel, crushed stone, aluminosilicate, corundum, gray wax, quartzite or cordierite. 6. Способ по п.1, отличающийся тем, что теплонесущая среда состоит из формованных тел из металлических, предпочтительно магнитных, материалов, или неметаллических керамических материалов, а также спеченных материалов или отдельных гранул.6. The method according to claim 1, characterized in that the heat transfer medium consists of molded bodies of metallic, preferably magnetic, materials, or non-metallic ceramic materials, as well as sintered materials or individual granules. 7. Способ по п.1, отличающийся тем, что совокупность применяемых теплонесущих сред, по меньшей мере, частично состоит из каталитически активного в реакционной зоне материала.7. The method according to claim 1, characterized in that the set of heat-transferring media used at least partially consists of a material catalytically active in the reaction zone. 8. Способ по п.1 или 5, отличающийся тем, что отделение теплонесущей среды от твердого углеродсодержащего остатка после оставления им зоны пиролиза осуществляют с помощью магнита.8. The method according to claim 1 or 5, characterized in that the separation of the heat transfer medium from the solid carbon-containing residue after leaving it with the pyrolysis zone is carried out using a magnet. 9. Способ по п.1, отличающийся тем, что отделение теплонесущей среды от твердого углеродсодержащего остатка после оставления им зоны пиролиза осуществляют пневматически с помощью воздушной сепарации, причем в качестве сепарирующего средства предпочтителен воздух; с одной стороны, предпочтительно, используют воздух для горения или отходящий газ, а, с другой стороны, предпочтителен возвратный отходящий газ из топки.9. The method according to claim 1, characterized in that the separation of the heat transfer medium from the solid carbon-containing residue after leaving it with the pyrolysis zone is carried out pneumatically by air separation, with air being preferred as a separation agent; on the one hand, combustion air or flue gas is preferably used, and, on the other hand, return flue gas from the furnace is preferred. 10. Способ по п.1, отличающийся тем, что транспортирование, по меньшей мере, одной из следующих сред при оставлении зоны пиролиза осуществляют непрерывно или периодически: органическое вещество, теплонесущая среда, твердый углеродсодержаший остаток, смесь теплонесущей среды и твердого углеродсодержащего остатка.10. The method according to claim 1, characterized in that the transportation of at least one of the following environments while leaving the pyrolysis zone is carried out continuously or periodically: organic matter, heat transfer medium, solid carbon-containing residue, a mixture of heat-carrying medium and solid carbon-containing residue. 11. Способ по п.1, отличающийся тем, что заметное тепло целевого газа и отходящих газов топки, по меньшей мере, частично используют для производства водяного пара в качестве реагента или для подогрева воздуха для горения.11. The method according to claim 1, characterized in that the appreciable heat of the target gas and the exhaust gases of the furnace is at least partially used for the production of water vapor as a reagent or for heating combustion air. 12. Способ по п.1, отличающийся тем, что заметное тепло целевого газа и отходящих газов топки, по меньшей мере, частично прямо или косвенно используют для предварительной сушки и нагрева органического вещества.12. The method according to claim 1, characterized in that the appreciable heat of the target gas and the exhaust gases of the furnace, at least partially directly or indirectly used for pre-drying and heating of the organic substance. 13. Способ по п.1, отличающийся тем, что теплонесущую среду после прохождения зоны нагрева разделяют на часть, которая проходит через реакционную зону, и часть, которую непосредственно подают в зону пиролиза, и теплонесущую среду, которая проходит через реакционную зону, снова направляется в зону пиролиза или оставшуюся теплонесущую среду прибавляют после зоны пиролиза.13. The method according to claim 1, characterized in that the heat transfer medium after passing through the heating zone is divided into a part that passes through the reaction zone, and a part that is directly fed to the pyrolysis zone, and the heat transfer medium that passes through the reaction zone is again directed in the pyrolysis zone or the remaining heat transfer medium is added after the pyrolysis zone. 14. Способ по п.1, отличающийся тем, что наряду с теплонесущей средой через зону пиролиза пропускают сильно основное твердое вещество, предпочтительно оксид кальция, гидроксид кальция, карбонат кальция, которые затем отделяют от теплонесущей среды и либо пропускают через топку, либо сразу выводят наружу.14. The method according to claim 1, characterized in that, along with the heat transfer medium, a strongly basic solid, preferably calcium oxide, calcium hydroxide, calcium carbonate, is passed through the pyrolysis zone, which are then separated from the heat transfer medium and either passed through the furnace or immediately removed out. 15. Способ по п.1, отличающийся тем, что целевой газ охлаждают, и образующийся при этом конденсат очищают и снова используют для производства технологического пара, или добавляют в топку, или к теплонесущей среде, или углеродсодержащему остатку для испарения и сжигания содержащихся в нем горючих частей.15. The method according to claim 1, characterized in that the target gas is cooled, and the resulting condensate is purified and again used to produce process steam, or added to the furnace, or to a heat-carrying medium, or a carbon-containing residue for evaporation and burning contained therein combustible parts.
RU2002110816/04A 1999-09-24 2000-09-22 Process of gasification of organic substances and mixtures thereof RU2240341C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19945771A DE19945771C1 (en) 1999-09-24 1999-09-24 Process for gasifying organic materials comprises cracking the materials by contacting with a hot heat carrier medium which is removed from a solid carbonaceous residue after leaving the pyrolysis reactor and conveyed to a heating zone
DE19945771.9 1999-09-24

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JP (1) JP4264525B2 (en)
CN (1) CN1213129C (en)
AT (1) ATE295401T1 (en)
AU (1) AU7780200A (en)
BR (1) BR0014217B1 (en)
CA (1) CA2387690C (en)
CZ (1) CZ20021021A3 (en)
DE (2) DE19945771C1 (en)
ES (1) ES2244476T3 (en)
HR (1) HRP20020246B1 (en)
HU (1) HUP0202874A2 (en)
MX (1) MXPA02003116A (en)
PL (1) PL194326B1 (en)
PT (1) PT1226222E (en)
RU (1) RU2240341C2 (en)
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