RU2001112421A

RU2001112421A - Benzoylcyclohexanedione, a method for their preparation and their use as herbicides and plant growth regulators

Info

Publication number: RU2001112421A
Application number: RU2001112421/04A
Authority: RU
Inventors: АЛМЗИК Андреас ВАН; Лотар Вильмс; Томас Аулер; Херманн Бирингер; Кристофер Розингер
Original assignee: Авентис Кропсайенс Гмбх
Priority date: 1998-10-10
Filing date: 1999-09-09
Publication date: 2003-05-27

Claims

1. Benzoylcyclohexanedione of the general formula (I)

where R ¹ means, if necessary, a substituted hydrocarbon residue, which, if necessary, additionally contains one or more, same or different heteroatoms selected from the group consisting of phosphorus, oxygen, sulfur, nitrogen, fluorine, chlorine, bromine and iodine;

R ² , R ³ , R ⁴ and R ⁵ independently of one another are hydrogen, hydroxy, thio, amino, cyano, nitro, halogen or, if necessary, a substituted hydrocarbon residue, which, if necessary, additionally contains one or more identical or various heteroatoms selected from the group consisting of phosphorus, oxygen, sulfur, nitrogen, fluorine, chlorine, bromine and iodine;

R ⁶ represents OR ^12, alkylthio, haloalkylthio, alkenylthio, halo-LLLT, alkynylthio, galogenalkiniltio, alkylsulfinyl, haloalkyl-sulfinyl, alkenylsulfinyl, galogenalkenilsulfinil, alkinilsulfinil, galogenalkinilsulfinil, alkylsulfonyl, haloalkylsulfonyl, alkenylsulfonyl, galogenalkenilsulfonil, alkynylsulfonyl, halo-nalkinilsulfonil, cyano, cyanato, thiocyanato or halogen;

R ⁷ means hydrogen, tetrahydropyranyl-3, tetrahydropyranyl-4, tetrahydrothiopyranyl-3, alkyl, cycloalkyl, alkoxy, alkoxyalkyl, alkylcarbonyl, alkoxycarbonyl, alkylthio, phenyl, while the last eight above groups are optionally substituted with one or more identical or different residues from the group consisting of halogen, alkylthio and alkoxy, or two R ⁷ residues associated with a common carbon atom form a chain from the group OCH ₂ CH ₂ O, OCH ₂ CH ₂ CH ₂ O, SCH ₂ CH ₂ S, SCH ₂ CH ₂ CH ₂ S, wherein said chain is optionally substituted with 1-4 methyl groups, or two R ⁷ residues, bonded directly to adjacent carbon atoms, form a bond or form a 3-6 membered ring, optionally substituted with one or more, same or different radicals from the group consisting of halogen, with their carbon atoms alkyl, alkylthio and alkoxy;

R ¹² means hydrogen, alkyl, haloalkyl, alkoxyalkyl, formyl, alkyl-carbonyl, alkoxycarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylsulfonyl, haloalkylsulfonyl, benzoyl or phenylsulfonyl, with the latter two of the above groups being one or more, same or different, if necessary, substituted residues selected from the group consisting of alkyl, haloalkyl, alkoxy, haloalkoxy, halogen, cyano and nitro;

L means an alkylene chain with 1-6 carbon atoms, optionally substituted with one or more, same or different residues R ² ;

Y is a divalent moiety selected from the group O, S, NH, N-alkyl, CHR ⁷ or C (R ⁷ ) ₂ ;

Z is a single bond, a divalent moiety selected from the group O, S, SO, SO ₂ , NH, N-alkyl, CHR ⁷ or C (R ⁷ ) ₂ ;

v is 1 or 2;

w = 0, 1, 2, 3 or 4,

with the proviso that —LR ¹ should not mean, if necessary, substituted CH ₂ —O-phenyl, if R ² and R ³ are chlorine, respectively, and R ⁴ and R ⁵ are hydrogen, respectively.

2. Benzoylcyclohexanedione according to claim 1, where R ¹ means cycloalkyl, cycloalkenyl, aryl, cycloalkoxy, cycloalkylalkoxy, tsikloalkilalkeniloksi, tsikloalkilalkiniloksi, cycloalkenyloxy, tsikloalkenilalkoksi, tsikloalkenilalkeniloksi, tsikloalkenilalkiniloksi, aryloxy, arylalkoxy, arilalkeniloksi, arilalkiniloksi, cycloalkylthio, tsikloalkilalkiltio, tsikloalkilalkeniltio, tsikloalkilalkiniltio, tsikloalkeniltio, tsikloalkenilalkiltio, tsikloalkenilalkeniltio, tsikloalkenilalkiniltio, arylthio, arylalkylthio , arylalkenylthio, arylalkynylthio, optionally substituted mono- or diar ylamino, optionally substituted mono- or digeteroarilaminogruppu, optionally substituted N-alkyl-N-arylamino, optionally substituted N-alkyl-N-heteroarylamino, cycloalkylamino, cycloalkenylamino, geterotsiklilalkilamino, geterotsiklilalkenilamino, tsikloalkilsulfonil, tsikloalkilalkilsulfonil, tsikloalkilalkenilsulfonil, tsikloalkilalkinilsulfonil , cycloalkenylsulfonyl, cycloalkenylalkylsulfonyl, cycloalkenylalkenylsulfonyl, cycloalkenylalkynylsulfonyl, arylsulfonyl, arylalkylsulfonyl nile, arilalkenilsulfonil, arilalkinilsulfonil, heteroarylsulfonyl, geteroarilalkilsulfonil, geteroarilalkenilsulfonil, geteroarilalkinilsulfonil, heterocyclylsulfonyl, geterotsiklilalkilsulfonil, geterotsiklilalkenilsulfonil, geterotsiklilalkinilsulfonil, tsikloalkilsulfinil, tsikloalkilalkilsulfinil, tsikloalkilalkenilsulfinil, tsikloalkilalkinilsulfinil, tsikloalkenilsulfinil, tsikloalkenilalkilsulfinil, tsikloalkenilalkenilsulfinil, tsikloalkenilalkinilsulfinil, arylsulfinyl, arilalkilsulfinil, arylalkyl ylsulfinyl, arilalkinilsulfinil, geteroarilsulfinil, geteroarilalkilsulfinil, geteroarilalkenilsulfinil, geteroarilalkinilsulfinil, geterotsiklilsulfinil, geterotsiklilalkilsulfinil, geterotsiklilalkenilsulfinil, geterotsiklilalkinilsulfinil, aminosulfonyl, optionally substituted mono- or dialkylaminosulfonyl, optionally substituted mono- or diarilminosulfonil if necessary, optionally substituted mono- or digeteroarilaminosulfonil, optionally substituted N -alkyl-N-arylaminosulfonyl, if necessary ti substituted N-alkyl-N-geteroarilaminosulfonil, alkylsulfonyloxy alkenilsulfoniloksi, alkinilsulfoniloksi, tsikloalkilsulfoniloksi, tsikloalkilalkilsulfoniloksi, tsikloalkilalkenilsulfoniloksi, tsikloalkilalkinilsulfoniloksi, tsikloalkenilsulfoniloksi, tsikloalkenilalkilsulfoniloksi, tsikloalkenilalkenilsulfoniloksi, tsikloalkenilalkinilsulfoniloksi, arylsulfonyloxy arilalkilsulfoniloksi, arilalkenilsulfoniloksi, arilalkinilsulfoniloksi, geteroarilsulfoniloksi, geteroarilalkilsulfoniloksi, heteroaryl kenilsulfoniloksi, geteroarilalkinilsulfoniloksi, geterotsiklilsulfoniloksi, geterotsiklilalkilsulfoniloksi, geterotsiklilalkenilsulfoniloksi, geterotsiklilalkinilsulfoniloksi, alkylsulfonylamino, alkenilsulfonilamino, alkinilsulfonilamino, tsikloalkilsulfonilamino, tsikloalkilalkilsulfonilamino, tsikloalkilalkenilsulfonilamino, tsikloalkilalkinilsulfonilamino, tsikloalkenilsulfonilamino, tsikloalkenilalkilsulfonilamino, tsikloalkenilalkenilsulfonilamino, tsikloalkenilalkinilsulfonilamino, arylsulfonyl O arilalkilsulfonilamino, arilalkenilsulfonilamino, arilalkinilsulfonilamino, heteroarylsulfonylamino, geteroarilalkilsulfonilamino, geteroarilalkenilsulfonilamino, geteroarilalkinilsulfonilamino, alkylsulfonyl-N-alkyl-amino, alkenylsulfonyl-N-alkyl-amino, alkynylsulfonyl-N-alkyl-amino, tsikloalkilsulfonil-N-alkyl-amino, tsikloalkilalkilsulfonil- N-alkyl-amino, cycloalkylalkenylsulfonyl-N-alkyl-amino, cycloalkylalkynylsulfonyl-N-alkyl-amino, cycloalkenylsulfonyl-N-alkyl-amino, cycloalkenylalkylsulfonyl-n-N-alkyl-amines but cycloalkenylalkenylsulfonyl-N-alkyl-amino, cycloloalkenylalkynylsulfonyl-N-alkyl-amino, arylsulfonyl-N-alkyl-amino, heteroarylsulfonyl-N-alkyl-amino, arylalkylsulfonyl-N-alkyl-alkyl-aryl-alkyl amino, arylalkenylsulfonyl-N-alkyl-amino, heteroarylalkenylsulphonyl-N-alkyl-amino, arylalkynylsulfonyl-N-alkyl-amino, heteroarylalkynylsulfonyl-N-alkyl-amino, heterocyclylsulfonyl-amino-alkyl-alkyl-amino heterocyclylalkenylsulfonyl-N-alkyl-amino, heterocyclylalkynylsulfonyl-N-a lkil-amino, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl, cycloalkylcarbonyl, tsikloalkilalkilkarbonil, tsikloalkilalkenilkarbonil, tsikloalkilalkinilkarbonil, cycloalkenylcarbonyl, tsikloalkenilalkilkarbonil, tsikloalkenilalkenilkarbonil, tsikloalkenilalkinilkarbonil, arylcarbonyl, arylalkylcarbonyl, arilalkenilkarbonil, arilalkinilkarbonil, heteroarylcarbonyl, heteroarylalkylcarbonyl, geteroarilalkenilkarbonil, geteroarilalkinilkarbonil, heterocyclylcarbonyl, carboxyl, alkoxycarbonyl, alkenyloxycarbonyl, alkynyloxy rbonil, cycloalkoxycarbonyl, cycloalkylalkoxycarbonyl, tsikloalkilalkeniloksikarbonil, tsikloalkilalkiniloksikarbonil, cycloalkenyloxycarbonyl, tsikloalkenilalkoksikarbonil, tsikloalkenilalkeniloksikarbonil, tsikloalkenilalkiniloksikarbonil, aryloxycarbonyl, arylalkoxycarbonyl, arilalkeniloksikarbonil, arilalkiniloksikarbonil, heteroaryloxycarbonyl, geteroarilalkoksikarbonil, geteroarilalkeniloksikarbonil, geteroarilalkiniloksikarbonil, heterocyclyloxycarbonyl, heterocyclylalkoxycarbonyl, geterotsiklilalkenilok icarbonyl, heterocyclylalkynyloxycarbonyl, aminocarbonyl, optionally substituted mono- or dialkylaminocarbonyl, optionally substituted mono- or diarylaminocarbonyl, optionally substituted mono- or diheteroarylaminocarbonyl, optionally substituted N-alkyl-N-arylamino-carbonyl-optionally heteroarylaminocarbonyl, optionally substituted mono- or diheteroarylaminocarbonyloxy, optionally substituted N-alkyl-N-arylaminocarbonyloxy, optionally substituted N-alkyl-N -heteroarylaminocarbonyloxy, aminocarbonylamino, optionally substituted mono- or dialkylaminocarbonylamino, optionally substituted mono- or diarylaminocarbonylamino, optionally substituted mono- or diheteroarylaminocarbonylamino, optionally substituted N-alkyl-N-arylamino-arylamino-aryl-arylamino-aryl-aryl-arylamino-aryl-arylamino-aryl-carbonyl , cycloalkylcarbonyloxy, cycloalkylalkenylcarbonyloxy, cycloalkylalkynylcarbonyloxy, cycloalkenylcarbonyloxy, cycloalkenylalkylcarbonyloxy, cy loalkenilalkenilkarboniloksi, tsikloalkenilalkinilkarboniloksi, arylcarbonyloxy, arilalkilkarboniloksi, arilalkenilkarboniloksi, arilalkinilkarboniloksi, geteroarilkarboniloksi, geteroarilalkilkarboniloksi, geteroarilalkenilkarboniloksi, geteroarilalkinilkarboniloksi, heterocyclylcarbonyloxy, geterotsiklilalkilkarboniloksi, geterotsiklilalkenilkarboniloksi, geterotsiklilalkinilkarboniloksi, optionally substituted mono- or dialkilkarbonilamino substituted mono- or diarylcarbonylamino, if necessary, with q.s. For example, substituted mono- or diheteroarylcarbonylamino, optionally substituted alkylcarbonyl-N-aryl-amino, optionally substituted arylcarbonyl-N-alkyl-amino, optionally substituted alkylcarbonyl-N-heteroaryl-amino, optionally substituted heteroarylcarbonyl-N-alkyl-amino , alkoxycarbonylamino, alkenyloxycarbonylamino, alkynyloxycarbonylamino, cycloalkoxycarbonylamino, cycloalkylalkyloxycarbonylamino, cycloalkylalkenyloxycarbonylamino, cycloalkylalkynyloxycarbonylamino, cycloalkenyloxycarbonylamino but tsikloalkenilalkoksikarbonilamino, tsikloalkenilalkeniloksikarbonilamino, tsikloalkenilalkiniloksikarbonilamino, aryloxycarbonylamino, arilalkoksikarbonilamino, arilalkeniloksikarbonilamino, arilalkiniloksikarbonilamino, geteroariloksikarbonilamino, geteroarilalkoksikarbonilamino, geteroarilalkeniloksikarbonilamino, geteroarilalkiniloksikarbonilamino, geterotsikliloksikarbonilamino, geterotsiklilalkoksikarbonilamino, geterotsiklilalkeniloksikarbonilamino, geterotsiklilalkiniloksikarbonilamino, alkoxycarbonyloxy , Alkeniloksikarboniloksi, alkiniloksikarboniloksi, tsikloalkoksikarboniloksi, tsikloalkilalkoksikarboniloksi, tsikloalkilalkeniloksikarboniloksi, tsikloalkilalkiniloksikarboniloksi, tsikloalkeniloksikarboniloksi, tsikloalkenilalkoksikarboniloksi, tsikloalkenilalkeniloksikarboniloksi, tsikloalkenilalkiniloksikarboniloksi, aryloxycarbonyloxy, arilalkoksikarboniloksi, arilalkeniloksikarboniloksi, arilalkiniloksikarboniloksi, geteroariloksikarboniloksi, geteroarilalkoksikarboniloksi, geteroarilalkeniloksikarboniloksi, n eroarilalkiniloksikarboniloksi, geterotsikliloksikarboniloksi, geterotsiklilalkoksikarboniloksi, geterotsiklilalkeniloksikarboniloksi, geterotsiklilalkiniloksikarboniloksi, alkoxycarbonylamino, alkeniloksikarbonilamino, alkynyloxycarbonyl-N-alkyl-amino, cycloalkoxycarbonyl-N-alkyl-amino, cycloalkylalkoxycarbonyl-N-alkyl-amino, tsikloalkilalkeniloksikarbonil-N-alkyl-amino-N- tsikloalkilalkiniloksikarbonil alkyl-amino, cycloalkenyloxycarbonyl-N-alkyl-amino, cycloalkenylalkoxycarbonyl-N-alkyl-amino, cycloalkenylalkenyloxy bonyl-N-alkyl-amino, cycloalkenylalkynyloxycarbonyl-N-alkyl-amino, aryloxycarbonyl-N-alkyl-amino, arylalkoxycarbonyl-N-alkyl-amino, arylalkenyloxycarbonyl-N-alkyl-amino, arylalkynyloxycarbonyl-amino N-alkyl-amino, heteroarylalkenyloxycarbonyl-N-alkyl-amino, N-alkylheteroarylalkynyloxycarbonyl-N-alkyl-amino, N-alkylheterocyclylalkoxycarbonyl-N-alkyl-amino, heterocyclylalkenyloxycarbonyl-N-alkylalkyl-amino-alkyl-amino formyl, haloalkoxy, haloalkenyloxy, g logenalkiniloksi, haloalkylthio, galogenalkeniltio, galogenalkiniltio, galogenalkilamino, galogenalkenilamino, galogenalkinilamino, haloalkylsulfonyl, galogenalkenilsulfonil, galogenalkinilsulfonil, halogenoalkylsulphinyl, galogenalkenilsulfinil, galogenalkinilsulfinil, haloalkylcarbonyl, galogenalkenilkarbonil, galogenalkinilkarbonil, haloalkoxycarbonyl, galogenalkeniloksikarbonil, galogenalkiniloksikarbonil, galogenalkilaminokarbonil, galogenalkenilaminokarbonil, galogenalkinilaminokarbonil, halogen alkylcarbonylamino, galogenalkenilkarbonilamino, galogenalkinilkarbonilamino, galogenalkoksikarbonilamino, galogenalkeniloksikarbonilamino, galogenalkiniloksikarbonilamino, galogenalkilkarboniloksi, galogenalkenilkarboniloksi, galogenalkinilkarboniloksi, galogenalkoksikarboniloksi, galogenalkeniloksikarboniloksi, galogenalkiniloksikarboniloksi, galogenalkilaminokarbonilamino, galogenalkenilaminokarbonilamino, galogenalkinilaminokarbonilamino, cyano, nitro, -P (= O) R ⁸ R ⁹ , -P (= O) OR ¹⁰ R ⁸ , -P (= O) OR ¹⁰ OR ^eleven , 2-tetrahydrofuranyl-hydroxymethyl, 3-tetrahydrofuranyl-oxymethyl, 2-tetrahydrothienyl-oxymethyl, 3-tetrahydrothienyl-hydroxymethyl, 2-tetrahydropyranyl-hydroxymethyl, with the remainder cycloalkyl, cycloalkenyl, aryl, tetrahydrofuranyl, tetrahydrofuranyl, tetrahydrofuranyl, tetrahydrofuranyl, tetrahydrofuranyl, tetrahydrofuranyl, tetrahydropyranyl-hydroxymethyl, heteroaryl and heterocyclyl, if necessary, can be substituted once or repeatedly, by the same or different R ² , or mean one of the groups -O- (CH ₂ ) _m -O- (CH ₂ ) _n -R ^2a , -O-CH ₂ -S- (O) _p R ^thirteen , -CONHNH- (CH ₂ ) _n -alkyl, -CONHNH- (CH ₂ ) _n aryl; R ^2a means cycloalkyl, cycloalkenyl, cycloalkylalkyl, cycloalkylalkenyl, tsikloalkilalkinil, cycloalkenylalkyl, aryl, arylalkyl, arylalkenyl, arylalkynyl, heteroaryl, heteroarylalkyl, heteroarylalkenyl, heteroarylalkynyl, heterocyclyl, heterocyclylalkyl, geterotsiklilalkenil, geterotsiklilalkinil, hydroxy, alkoxy, alkenyloxy, alkynyloxy, cycloalkoxy, cycloalkylalkoxy, tsikloalkilalkeniloksi , cycloalkylalkynyloxy, cycloalkenyloxy, cycloalkenylalkoxy, cycloalkenylalkenyloxy, cycloalkenylalkynyloxy, aryloxy, arylalkoxy, ar lalkeniloksi, arilalkiniloksi, heteroaryloxy, heteroarylalkoxy, geteroarilalkeniloksi, geteroarilalkiniloksi, heterocyclyloxy, geterotsiklilalkoksi, geterotsiklilalkeniloksi, geterotsiklilalkiniloksi, thio, alkylthio, alkenylthio, alkynylthio, cycloalkylthio, tsikloalkilalkiltio, tsikloalkilalkeniltio, tsikloalkilalkiniltio, tsikloalkeniltio, tsikloalkenilalkiltio, tsikloalkenilalkeniltio, tsikloalkenilalkiniltio, arylthio, arylalkylthio, arilalkeniltio, arylalkynylthio, heteroarylthio, heteroarylalkylthio, heteroarylalkenylthio, heteroaryl quinilthio, heterocyclylthio, heterocyclylalkylthio, heterocyclylalkenylthio, heterocyclylalkynylthio, amino, optionally substituted mono or dialkylamino, optionally substituted mono or diarylamino, optionally substituted mono- or diheteroarylamino-optionally N-optionally, optionally N-substituted alkyl N-heteroarylamino group, alkenylamino, alkynylamino, cycloalkylamino, cycloalkenylamino, heterocyclylalkylamino, heterocyclylalkenylamino, alkylsulfonyl, and kenilsulfonil, alkynylsulfonyl, tsikloalkilsulfonil, tsikloalkilalkilsulfonil, tsikloalkilalkenilsulfonil, tsikloalkilalkinilsulfonil, tsikloalkenilsulfonil, tsikloalkenilalkilsulfonil, tsikloalkenilalkenilsulfonil, tsikloalkenilalkinilsulfonil, arylsulfonyl, arylalkyl arilalkenilsulfonil, arilalkinilsulfonil, heteroarylsulfonyl, geteroarilalkilsulfonil, geteroarilalkenilsulfonil, geteroarilalkinilsulfonil, heterocyclylsulfonyl, geterotsiklilalkilsulfonil, geterotsiklilalkenilsulfonil, geterotsik ilalkinilsulfonil, alkylsulfinyl, alkenylsulfinyl, alkinilsulfinil, tsikloalkilsulfinil, tsikloalkilalkilsulfinil, tsikloalkilalkenilsulfinil, tsikloalkilalkinilsulfinil, tsikloalkenilsulfinil, tsikloalkenilalkilsulfinil, tsikloalkenilalkenilsulfinil, tsikloalkenilalkinilsulfinil, arylsulfinyl, arilalkilsulfinil, arilalkenilsulfinil, arilalkinilsulfinil, geteroarilsulfinil, geteroarilalkilsulfinil, geteroarilalkenilsulfinil, geteroarilalkinilsulfinil, geterotsiklilsulfinil, geterotsiklilalkilsulfinil, n erocyclylalkenylsulfinyl, heterocyclylalkynylsulfinyl, aminosulfonyl, optionally substituted mono- or dialkylaminosulfonyl, optionally substituted mono- or diarylaminosulfonyl, optionally substituted mono- or diheteroarylaminosulfonyl, optionally substituted N-alkyl-N-arylamino-sulfonyl heteroarylaminosulfonyl, alkylsulfonyloxy, alkenylsulfonyloxy, alkynylsulfonyloxy, cycloalkylsulfonyloxy, cycloalkylalkylsulfonyloxy, cycloalkylalkenylsulfone Locks tsikloalkilalkinilsulfoniloksi, tsikloalkenilsulfoniloksi, tsikloalkenilalkilsulfoniloksi, tsikloalkenilalkenilsulfoniloksi, tsikloalkenilalkinilsulfoniloksi, arylsulfonyloxy arilalkilsulfoniloksi, arilalkenilsulfoniloksi, arilalkinilsulfoniloksi, geteroarilsulfoniloksi, geteroarilalkilsulfoniloksi, geteroarilalkenilsulfoniloksi, geteroarilalkinilsulfoniloksi, geterotsiklilsulfoniloksi, geterotsiklilalkilsulfoniloksi, geterotsiklilalkenilsulfoniloksi, geterotsiklilalkinilsulfoniloksi, alkilsulf nilamino, alkenilsulfonilamino, alkinilsulfonilamino, tsikloalkilsulfonilamino, tsikloalkilalkilsulfonilamino, tsikloalkilalkenilsulfonilamino, tsikloalkilalkinilsulfonilamino, tsikloalkenilalkilsulfonilamino, tsikloalkenilalkenilsulfonilamino, tsikloalkenilalkinilsulfonilamino, arylsulfonylamino, arilalkilsulfonilamino, arilalkenilsulfonilamino, arilalkinilsulfonilamino, heteroarylsulfonylamino, geteroarilalkilsulfonilamino, geteroarilalkenilsulfonilamino, geteroarilalkinilsulfonilamino, dialkylsulfosuccinic yl-N-alkyl-amino, alkenylsulfonyl-N-alkyl-amino, alkynylsulfonyl-N-alkyl-amino, cycloalkylsulfonyl-N-alkyl-amino, cycloalkylalkylsulfonyl-N-alkyl-amino, cycloalkylalkenylsulfonyl-N-alkylalkylalkyl N-alkyl-amino, cycloalkenylsulfonyl-N-alkyl-amino, cycloalkenylalkylsulfonyl-N-alkyl-amino, cycloalkenylalkenylsulfonyl-N-alkyl-amino, cycloalkenylalkynylsulfonyl-N-alkyl-amino, arylsulfonyl-sulfonyl-amino alkyl amino, arylalkylsulfonyl-N-alkyl-amino, heteroarylalkylsulfonyl-N-alkyl-amine , Arilalkenilsulfonil-N-alkyl-amino, geteroarilalkenilsulfonil-N-alkyl-amino, arilalkinilsulfonil-N-alkyl-amino, geteroarilalkinilsulfonil-N-alkyl-amino, heterocyclylsulfonyl-N-alkyl-amino, geterotsiklilalkilsulfonil-N-alkyl-amino, geterotsiklilalkenilsulfonil -N-alkyl-amino, heterocyclylalkynylsulfonyl-N-alkyl-amino, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl, cycloalkylcarbonyl, cycloalkylalkylcarbonyl, cycloalkylalkenylcarbonyl, cycloalkylalkenylcarbonylalkenylcarbonyl lalkenilkarbonil, tsikloalkenilalkinilkarbonil, arylcarbonyl, arylalkylcarbonyl, arilalkenilkarbonil, arilalkinilkarbonil, heteroarylcarbonyl, heteroarylalkylcarbonyl, geteroarilalkenilkarbonil, geteroarilalkinilkarbonil, heterocyclylcarbonyl, heterocyclylalkylcarbonyl, geterotsiklilalkenilkarbonil, geterotsiklilalkinilkarbonil, carboxyl, alkoxycarbonyl, alkenyloxycarbonyl, alkynyloxycarbonyl, cycloalkoxycarbonyl, cycloalkylalkoxycarbonyl, tsikloalkilalkeniloksikarbonil, tsikloalkilalkiniloksikarbonil, cycloalkenyl ksikarbonil, tsikloalkenilalkoksikarbonil, tsikloalkenilalkeniloksikarbonil, tsikloalkenilalkiniloksikarbonil, aryloxycarbonyl, arylalkoxycarbonyl, arilalkeniloksikarbonil, arilalkiniloksikarbonil, heteroaryloxycarbonyl, geteroarilalkoksikarbonil, geteroarilalkeniloksikarbonil, geteroarilalkiniloksikarbonil, heterocyclyloxycarbonyl, heterocyclylalkoxycarbonyl, geterotsiklilalkeniloksikarbonil, getertsiklilalkiniloksikarbonil, alkylcarbonyloxy, alkenylcarbonyloxy, alkynylcarbonyloxy, cycloalkylcarbonyloxy, cyclo alkilalkenilkarboniloksi, tsikloalkilalkinilkarboniloksi, cycloalkenylcarbonyloxy, tsikloalkenilalkilkarboniloksi, tsikloalkenilalkenilkarboniloksi, tsikloalkenilalkinilkarboniloksi, arylcarbonyloxy, arilalkilkarboniloksi, arilalkenilkarboniloksi, arilalkinilkarboniloksi, geteroarilkarboniloksi, geteroarilalkilkarboniloksi, geteroarilalkenilkarboniloksi, geteroarilalkinilkarboniloksi, heterocyclylcarbonyloxy, geterotsiklilalkilkarboniloksi, geterotsiklilalkenilkarboniloksi, geterotsiklilalkinilkarboniloksi, aminokarb onyl, optionally substituted mono- or dialkylaminocarbonyl, optionally substituted mono- or diarylaminocarbonyl, optionally substituted mono- or diheteroarylaminocarbonyl, optionally substituted N-alkyl-N-arylaminocarbonyl, optionally substituted N-alkyl-N-heteroarylaminocarbonyl, if necessary substituted mono- or diheteroarylaminocarbonyloxy, optionally substituted N-alkyl-N-arylaminocarbonyloxy, optionally substituted N-alkyl-N-heteroarylaminocarbonyloxy, aminocarbonylamino, etc optionally substituted mono- or dialkylaminocarbonylamino, optionally substituted mono- or diarylaminocarbonylamino, optionally substituted mono- or diheteroarylaminocarbonylamino, optionally substituted N-alkyl-N-arylaminocarbonylamino, optionally substituted N-alkyl-N-heteroarylamino, optionally mono- or dialkylcarbonylamino, optionally substituted mono- or diarylcarbonylamino, optionally substituted mono- or diheteroarylcarbonylamino, if necessary and substituted alkylcarbonyl-N-aryl-amino, optionally substituted arylcarbonyl-N-alkyl-amino, optionally substituted alkylcarbonyl-N-heteroaryl-amino, optionally substituted heteroarylcarbonyl-N-alkyl-amino, alkoxycarbonyloxy, alkenyloxycarbonyloxy, alkynyloxycarbonyloxycarbonyl , cycloalkylalkoxycarbonyloxy, cycloalkylalkenyloxycarbonyloxy, cycloalkylalkynyloxycarbonyloxy, cycloalkenyloxycarbonyloxy, cycloalkenylalkoxycarbonyloxy, cycloalkenylalkenyloxycarbonyloxy, cyclo alkenilalkiniloksikarboniloksi, aryloxycarbonyloxy, arilalkoksikarboniloksi, arilalkeniloksikarboniloksi, arilalkiniloksikarboniloksi, geteroariloksikarboniloksi, geteroarilalkoksikarboniloksi, geteroarilalkeniloksikarboniloksi, geteroarilalkiniloksikarboniloksi, geterotsikliloksikarboniloksi, geterotsiklilalkoksikarboniloksi, getertsiklilalkeniloksikarboniloksi, geterotsiklilalkiniloksikarboniloksi, alkoxycarbonylamino, alkeniloksikarbonilamino, alkiniloksikarbonilamino, tsikloalkoksikarbonilamino, cycloalkylalkyl ksikarbonilamino, tsikloalkilalkeniloksikarbonilamino, tsikloalkilalkiniloksikarbonilamino, tsikloalkeniloksikarbonilamino, tsikloalkenilalkoksikarbonilamino, tsikloalkenilalkeniloksikarbonilamino, tsikloalkenilalkiniloksikarbonilamino, aryloxycarbonylamino, arilalkoksikarbonilamino, arilalkeniloksikarbonilamino, arilalkiniloksikarbonilamino, geteroariloksikarbonilamino, geteroarilalkoksikarbonilamino, geteroarilalkeniloksikarbonilamino, geteroarilalkiniloksikarbonilamino, geterotsikliloksikarbonilamino, heterocyclyl alkoxycarbonylamino, geterotsiklilalkeniloksikarbonilamino, geterotsiklilalkiniloksikarbonilamino, alkoxycarbonylamino, alkeniloksikarbonilamino, alkiniloksikarbonilamino, tsikloalkoksikarbonilamino, tsikloalkilalkoksikarbonilamino, N-alkiltsikloalkilalkeniloksikarbonil-amino tsikloalkilalkiniloksikarbonilamino, tsikloalkeniloksikarbonilamino, tsikloalkenilalkoksikarbonilamino, tsikloalkenilalkeniloksikarbonilamino, tsikloalkenilalkiniloksikarbonilaminoariloksikarbonilamino, arilalkoksikarbonilamino, arilalkeniloksika bonilamino, arilalkiniloksikarbonilamino, geteroarilalkoksikarbonilamino, geteroarilalkeniloksikarbonilamino, geteroarilalkiniloksikarbonilamino, geterotsiklilalkoksikarbonilamino, geterotsiklilalkeniloksikarbonilamino, geterotsiklilalkiniloksikarbonilamino, formyl, halogen, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, haloalkenyloxy, galogenalkiniloksi, haloalkylthio, galogenalkeniltio, galogenalkiniltio, galogenalkilamino, galogenalkenilamino, galogenalkinilamino, haloalkylsulfonyl, halogen kenilsulfonil, galogenalkinilsulfonil, halogenoalkylsulphinyl, galogenalkenilsulfinil, galogenalkinilsulfinil, haloalkylcarbonyl, galogenalkenilkarbonil, galogenalkinilkarbonil, haloalkoxycarbonyl, galogenalkeniloksikarbonil, galogenalkiniloksikarbonil, galogenalkilaminokarbonil, galogenalkenilaminokarbonil, galogenalkinilaminokarbonil, galogenalkoksikarbonilamino, galogenalkeniloksikarbonilamino, galogenalkiniloksikarbonilamino, galogenalkilaminokarbonilamino, galogenalkenilaminokarbonilamino, halogen kinilaminokarbonilamino, cyano, nitro or one of the groups -P (= O) R ⁸ R ⁹ , -P (= O) OR ¹⁰ R ⁸ , -P (= O) OR ¹⁰ OR ^eleven , -CH = N-NH- (CH ₂ ) _n -alkyl, -CH = N-NH- (CH ₂ ) _n -aryl, -CH = NO- (CH ₂ ) _n -alkyl, -CH = NO- (CH ₂ ) _n -aryl, -O- (CH ₂ ) _m -O- (CH ₂ ) _n -alkyl, -CONHNH- (CH ₂ ) _n -alkyl and -CONHNH- (CH ₂ ) _n aryl; R ² , R ³ , R ⁴ and R ⁵ independently mean R ^2a hydrogen, alkyl, alkenyl or alkynyl; R ⁸ and R ⁹ independently, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, optionally substituted aryl or optionally substituted arylalkyl; R ¹⁰ and R ^eleven independently hydrogen or R ⁸ , or R ¹⁰ and R ^eleven together form an alkylene chain with 2-5 carbon atoms; R ^thirteen means alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, or phenyl optionally substituted with one or more, same or different radicals selected from the group consisting of halogen, alkyl, haloalkyl or nitro; m is 1, 2 or 3; n = 0, 1,2 or 3, and p = 0, 1 or 2.

3. benzoylcyclohexanediones according to claim 1 or 2, wherein R ¹ is cycloalkyl, cycloalkenyl, aryl, cycloalkoxy, cycloalkylalkoxy, tsikloalkilalkeniloksi, tsikloalkilalkiniloksi, cycloalkenyloxy, tsikloalkenilalkoksi, tsikloalkenilalkeniloksi, tsikloalkenilalkiniloksi, aryloxy, arylalkoxy, arilalkeniloksi, arilalkiniloksi, cycloalkylthio, tsikloalkilalkiltio, tsikloalkilalkeniltio, cycloalkylalkynylthio, cycloalkenylthio, cycloalkenylalkylthio, cycloalkenylalkenylthio, cycloalkenylalkynylthio, arylthio, arylalkylthio, arylalkenylthio, arylalkynylthio, tsikloalkilsulfonil, tsikloalkilalkilsulfonil, tsikloalkilalkenilsulfonil, tsikloalkilalkinilsulfonil, tsikloalkenilsulfonil, tsikloalkenilalkilsulfonil, tsikloalkenilalkenilsulfonil, tsikloalkenilalkinilsulfonil, arylsulfonyl, arylalkyl arilalkenilsulfonil, arilalkinilsulfonil, heteroarylsulfonyl, geteroarilalkilsulfonil, geteroarilalkenilsulfonil, geteroarilalkinilsulfonil, heterocyclylsulfonyl, geterotsiklilalkilsulfonil, geterotsiklilalkenilsulfonil, geterotsiklilalkinilsulfonil, tsikloalkilsul finil, tsikloalkilalkilsulfinil, tsikloalkilalkenilsulfinil, tsikloalkilalkinilsulfinil, tsikloalkenilsulfinil, tsikloalkenilalkilsulfinil, tsikloalkenilalkenilsulfinil, tsikloalkenilalkinilsulfinil, arylsulfinyl, arilalkilsulfinil, arilalkenilsulfinil, arilalkinilsulfinil, geteroarilsulfinil, geteroarilalkilsulfinil, geteroarilalkenilsulfinil, geteroarilalkinilsulfinil, geterotsiklilsulfinil, geterotsiklilalkilsulfinil, geterotsiklilalkenilsulfinil, geterotsiklilalkinilsulfinil, aminosulfonyl, if needs bridges substituted mono- or di-alkylaminosulfonyl, optionally substituted mono- or diarylaminosulfonyl, optionally substituted mono- or diheteroarylaminosulfonyl, optionally substituted N-alkyl-N-arylaminosulfonyl, optionally substituted N-alkyl-N-heteroaryl-aminosulfonyl, alkylsulfonoxy , alkenylsulfonyloxy, alkynylsulfonyloxy, cycloalkylsulfonyloxy, cycloalkylalkylsulfonyloxy, cycloalkylalkenylsulfonyloxy, cycloalkylalkynylsulfonyloxy, cycloalkenylsulfonyloxy, cycloalkenylalkyl lsulfoniloksi, tsikloalkenilalkenilsulfoniloksi, tsikloalkenilalkinilsulfoniloksi, arylsulfonyloxy arilalkilsulfoniloksi, arilalkenilsulfoniloksi, arilalkinilsulfoniloksi, geteroarilsulfoniloksi, geteroarilalkilsulfoniloksi, geteroarilalkenilsulfoniloksi, geteroarilalkinilsulfoniloksi, geterotsiklilsulfoniloksi, geterotsiklilalkilsulfoniloksi, geterotsiklilalkenilsulfoniloksi, geterotsiklilalkinilsulfoniloksi, alkylsulfonylamino, alkenilsulfonilamino, alkinilsulfonilamino, tsikloalkilsulfonilamino, q ikloalkilalkilsulfonilamino, tsikloalkilalkenilsulfonilamino, tsikloalkilalkinilsulfonilamino, tsikloalkenilsulfonilamino, tsikloalkenilalkilsulfonilamino, tsikloalkenilalkenilsulfonilamino, tsikloalkenilalkinilsulfonilamino, arylsulfonylamino, arilalkilsulfonilamino, arilalkenilsulfonilamino, arilalkinilsulfonilamino, heteroarylsulfonylamino, geteroarilalkilsulfonilamino, geteroarilalkenilsulfonilamino, geteroarilalkinilsulfonilamino, alkylsulfonyl-N-alkyl-amino, alkenylsulfonyl-N-alkyl-amino, alkinilsul b-alkyl-N-alkyl-amino, cycloalkylsulfonyl-N-alkyl-amino, cycloalkylalkylsulphonyl-N-alkyl-amino, cycloalkylalkenylsulphonyl-N-alkyl-amino, cycloalkylalkynylsulphonyl-alkyl-alkyl-alkyl-alkyl- N-alkyl-amino, cycloalkenylalkenylsulfonyl-N-alkyl-amino, cycloalkenylalkynylsulfonyl-N-alkyl-amino, arylsulfonyl-N-alkyl-amino, heteroarylsulfonyl-N-alkyl-amino, arylalkylsulfonyl-amino-alkyl-alkyl-alkyl-amino alkyl-amino, arylalkenylsulfonyl-N-alkyl-amino, heteroarylalkenylsul fonyl-N-alkyl-amino, arylalkynylsulfonyl-N-alkyl-amino, heteroarylalkynylsulfonyl-N-alkyl-amino, heterocyclylsulfonyl-N-alkyl-amino, heterocyclylalkylalkylsulfonyl-alkyl-cyclonyl-alkyl N-alkyl-amino, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl, cycloalkylcarbonyl, cycloalkylalkylcarbonyl, cycloalkylalkenylcarbonyl, cycloalkylalkynylcarbonyl, cycloalkenylcarbonyl, cycloalkenylalkylcarbonyl, cycloalkenylalkenyl yl, arylalkylcarbonyl, arilalkenilkarbonil, arilalkinilkarbonil, heteroarylcarbonyl, heteroarylalkylcarbonyl, geteroarilalkenilkarbonil, geteroarilalkinilkarbonil, heterocyclylcarbonyl, carboxyl, alkoxycarbonyl, alkenyloxycarbonyl, alkynyloxycarbonyl, cycloalkoxycarbonyl, cycloalkylalkoxycarbonyl, tsikloalkilalkeniloksikarbonil, tsikloalkilalkiniloksikarbonil, cycloalkenyloxycarbonyl, tsikloalkenilalkoksikarbonil, tsikloalkenilalkeniloksikarbonil, tsikloalkenilalkiniloksikarbonil, aryloxycarbonyl, arilalkoksikarbo nile, arilalkeniloksikarbonil, arilalkiniloksikarbonil, heteroaryloxycarbonyl, geteroarilalkoksikarbonil, geteroarilalkeniloksikarbonil, geteroarilalkiniloksikarbonil, heterocyclyloxycarbonyl, heterocyclylalkoxycarbonyl, geterotsiklilalkeniloksikarbonil, geterotsiklilalkiniloksikarbonil, aminocarbonyl, optionally substituted mono- or dialkylaminocarbonyl, optionally substituted mono- or diarilaminokarbonil if necessary, optionally substituted mono- or digeteroarilaminokarbonil if necessary substituted N-alkyl -N-arylaminocarbonyl, optionally substituted N-alkyl-N-heteroarylaminocarbonyl, optionally substituted mono- or dialkylcarbonylamino, optionally substituted mono- or diarylcarbonylamino, optionally substituted mono- or diheteroarylcarbonylamino, optionally substituted alkylcarbonyl-amino-aryl optionally substituted arylcarbonyl-N-alkyl-amino, optionally substituted alkylcarbonyl-N-heteroaryl-amino, optionally substituted heteroarylcarbonyl-N-alkyl-amino, formyl, haloalkoxy, ha logenalkeniloksi, galogenalkiniloksi, haloalkylthio, galogenalkeniltio, galogenalkiniltio, galogenalkilamino, galogenalkenilamino, galogenalkinilamino, haloalkylsulfonyl, galogenalkenilsulfonil, galogenalkinilsulfonil, halogenoalkylsulphinyl, galogenalkenilsulfinil, galogenalkinilsulfinil, haloalkylcarbonyl, galogenalkenilkarbonil, galogenalkinilkarbonil, haloalkoxycarbonyl, galogenalkeniloksikarbonil, galogenalkiniloksikarbonil, galogenalkilaminokarbonil, galogenalkenilaminokarbonil, galogenalkinilam inokarbonil, galogenalkilkarbonilamino, galogenalkenilkarbonilamino, galogenalkinilkarbonilamino, galogenalkoksikarbonilamino, galogenalkeniloksikarbonilamino, galogenalkiniloksikarbonilamino, galogenalkilkarboniloksi, galogenalkenilkarboniloksi, galogenalkinilkarboniloksi, galogenalkoksikarboniloksi, galogenalkeniloksikarboniloksi, galogenalkiniloksikarboniloksi, galogenalkilaminokarbonilamino, galogenalkenilaminokarbonilamino, galogenalkinilaminokarbonilamino, cyano, nitro, -P (= O) R ⁸ R ^9, P (= O) OR ^10, R ^8, -P (= O) OR ¹⁰ OR ^l1, tetrahydro-2 furanyloxymethyl, 3-tetrahydrofuranyloxymethyl, 2-tetrahydrothienyloxymethyl, 3-tetrahydrothienyl-hydroxymethyl, 2-tetrahydropyranyl-oxymethyl, with the remainder cycloalkyl, cycloalkenyl, aryl, tetrahydrofuranyl, tetrahydrothienyl, hetero, hetero, or the same or different R ² , or mean one of the groups —O— (CH ₂ ) _m —O— (CH ₂ ) _n —R ^2a , —O — CH ₂ —S- (O) _p R ¹³ , —CONHNH— (CH ₂ ) _n -alkyl and -CONHNH- (CH ₂ ) _n- aryl, and R ^2a is alkoxy with 1-6 carbon atoms, alkenyloxy with 2-6 carbon atoms, al kynyloxy with 3-6 carbon atoms, haloalkoxy with 1-6 carbon atoms, haloalkenyloxy with 2-6 carbon atoms, haloalkynyloxy with 3-6 carbon atoms, or phenyl, optionally substituted once or repeatedly with halogen, cyano, nitro, alkyl with 1 -6 carbon atoms, alkoxy with 1-6 carbon atoms, halogenated with 1-6 carbon atoms, or halogenated with 1-6 carbon atoms.

4. Benzoylcyclohexanedione according to one of claims 1 to 3, where R ² , R ³ , R ⁴ and R ^{5 are} independently hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, cycloalkylalkyl, aryl, arylalkyl, heteroaryl, heteroarylalkyl , heterocyclyl, heterocyclylalkyl, hydroxy, alkoxy, cycloalkoxy, aryloxy, heteroaryloxy, heterocyclyloxy, alkylthio, arylthio, heteroarylthio, heterocyclylthio, heterocyclylalkylamino, mono-acylo-arylo-acylo-arylo-arylo-arylo-arylo-arylo-arylo-arylo-arylo-acylo , alkylsulfonyl, arylsulfonyl, alkylsulfinyl, amine osulfonyl, mono- or dialkylaminosulfonyl, mono- or diarylaminosulfonyl, N-alkyl-N-arylaminosulfonyl, N-alkyl-N-heteroarylaminosulfonyl, alkylsulfonylamino, cycloalkylsulfonylamino, arylsulfonylamino-alkylsulfonylamino-aryl-sulfonylamino-amino-alkylamino-sulfonylamino-amino-alkylamino N-alkylamino, heterocyclylsulfonyl-N-alkylamino, alkylcarbonyl, cycloalkylcarbonyl, arylcarbonyl, arylalkylcarbonyl, heteroarylcarbonyl, heterocyclylcarbonyl, carboxyl, alkoxycarbonyl, aryloxycarbonyl, arylalkoxy arbonyl, alkylcarbonyloxy, arylcarbonyloxy, arylalkylcarbonyloxy, aminocarbonyl, mono- or dialkylaminocarbonyl, N-alkyl-N-arylaminocarbonyl, N-alkyl-N-heteroarylaminocarbonyl-mono-arylamino-di-aryl-amino-di-aryl-amino-di-arylo-amino-di-aryl-aminocarbonyl-amino, mono- or diheteroarylaminocarbonylamino, N-alkyl-N-arylaminocarbonylamino, mono- or dialkylcarbonylamino, mono- or diarylcarbonylamino, alkylcarbonyl-N-arylamino, arylcarbonyl-N-alkylamino, alkoxycarbonyloxy, cycloalkyl xi, aryloxycarbonyloxy, arilalkoksikarboniloksi, alkoxycarbonylamino, tsikloalkoksikarbonilamino, aryloxycarbonylamino, alkoxycarbonyl-N-alkylamino, formyl, halogen, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, haloalkenyloxy, galogenalkiniloksi, haloalkylthio, galogenalkeniltio, galogenalkiniltio, galogenalkilamino, galogenalkenilamino, galogenalkinilamino, haloalkylsulfonyl, galogenalkenilsulfonil, haloalkynylsulfonyl, haloalkylsulfinyl, haloalkenylsulfinyl, haloalkynylsul finil, haloalkylcarbonyl, galogenalkenilkarbonil, galogenalkinilkarbonil, galogenalkoksilkarbonil, galogenalkeniloksikarbonil, galogenalkiniloksikarbonil, galogenalkilaminokarbonil, galogenalkenilaminokarbonil, galogenalkinilaminokarbonil, galogenalkoksikarbonilamino, galogenalkilaminokarbonilamino, cyano, nitro, arilalkoksialkoksi or alkoxyalkoxyalkoxy; R ⁶ is OR ¹² , alkylthio, alkylsulfonyl, cyano, cyanato, thiocyanato or halogen; R ⁷ means hydrogen, alkyl, cycloalkyl, alkoxy, alkoxyalkyl, alkylcarbonyl, alkoxycarbonyl, alkylthio or phenyl, or two R ⁷ residues associated with a common carbon atom form an OCH ₂ CH ₂ O and OCH ₂ CH ₂ CH ₂ O group, with this group is optionally substituted with 1-4 methyl groups, or two R ⁷ residues, bonded directly to adjacent carbon atoms, form a simple bond or form a 3-6 membered ring with carbon atoms having them, optionally substituted by one or more, identical or different residues, select data from the group consisting of halogen, alkyl, alkylthio or alkoxy; R ⁸ and R ⁹ , independently of one another, are alkyl, alkenyl, alkynyl, haloalkyl, optionally substituted aryl or optionally substituted arylalkyl; R ¹² means hydrogen, haloalkyl, alkoxyalkyl, formyl, alkylcarbonyl, alkoxycarbonyl, alkylsulfonyl, haloalkylsulfonyl, benzoyl or phenylsulfonyl, both of the latter groups being optionally substituted with one or more, same or different residues selected from the group including alkyl , haloalkyl, alkoxy, haloalkoxy, halogen, cyano and nitro; L means an alkylene chain with 1-6 carbon atoms, optionally substituted with 1-4, identical or different residues R ² ; Y is a divalent moiety selected from the group O, NH, N-alkyl, CHR ⁷ or C (R ⁷ ) ₂ ; Z is a single bond, a divalent moiety selected from the group O, S, SO ₂ , N-alkyl, CHR ⁷ or C (R ⁷ ) ₂ , and w = 0,1,2 or 3.

5. Benzoylcyclohexanedione according to one of claims ^{1 to 4} , where R ¹ means haloalkoxy with 1-6 carbon atoms, haloalkenyloxy with 2-6 carbon atoms, haloalkynyloxy with 3-6 carbon atoms, halogenoalkylthio with 1-6 carbon atoms, halogenoalkenylthio with 2-6 carbon atoms, halogenated with 3-6 carbon atoms, halogenated with 1-6 carbon atoms, halogenated with 2-6 carbon atoms, halogenated with 3-6 carbon atoms, halogenated with 1-6 carbon atoms, halogenated with 2- 6 carbon atoms, halogenated silt with 3-6 carbon atoms, haloalkylsulfinyl with 1-6 carbon atoms, haloalkenylsulfinyl with 2-6 carbon atoms, haloalkynylsulfinyl with 3-6 carbon atoms, haloalkylcarbonyl, where alkyl with 1-6 carbon atoms, haloalkenylcarbonyl, where alkenyl with 2- 6 carbon atoms, haloalkynylcarbonyl, where alkynyl with 3-6 carbon atoms, halogenoalkoxycarbonyl, where alkoxy with 1-6 carbon atoms, halogenoalkenyloxycarbonyl, where alkenyl with 2-6 carbon atoms, haloalkynyloxycarbonyl, where alkynyl with 3-6 carbon atoms, halogenoalkylaminocarbon nyl, where alkyl with 1-6 carbon atoms, haloalkenylaminocarbonyl, where alkenyl with 2-6 carbon atoms, haloalkynylaminocarbonyl, where alkynyl with 3-6 carbon atoms, haloalkylcarbonylamino, where alkyl with 1-6 carbon atoms, halogenalkenylcarbonylamino, where alkenyl c 2 -6 carbon atoms, haloalkynylcarbonylamino, where alkynyl with 3-6 carbon atoms, haloalkoxycarbonylamino, where alkoxy with 1-6 carbon atoms, haloalkenyloxycarbonylamino, where alkenyl with 2-6 carbon atoms, haloalkynyloxycarbonylamino, where alkynyl with 2-6 carbon atoms carbon, haloalkylcarbonyloxy, where alkyl with 1-6 carbon atoms, haloalkenylcarbonyloxy, where alkenyl with 2-6 carbon atoms, haloalkynylcarbonyloxy, where alkynyl with 3-6 carbon atoms, halogenoalkoxycarbonyloxy, where alkoxy with 1-6 carbon atoms, halogenoalkenyloxyalkenyloxycarbonyl with 2-6 carbon atoms, haloalkynyloxycarbonyloxy, where alkynyl with 3-6 carbon atoms, haloalkylaminocarbonylamino, where alkyl with 1-6 carbon atoms, haloalkenylaminocarbonylamino, where alkenyl with 2-6 carbon atoms, haloalkynyls inocarbonylamino, where alkynyl with 3-6 carbon atoms, -O- (CH ₂ ) _m -O- (CH ₂ ) _n -R ^2a , -P (= O) R ⁸ R ⁹ , -P (= O) OR ¹⁰ R ⁸ , -P (= O) OR ¹⁰ OR ¹¹ , 2-tetrahydrofuranyl-hydroxymethyl, 3-tetrahydrofuranyl-oxymethyl, 2-tetrahydrothienyl-oxymethyl, 3-tetrahydrothienyl-oxymethyl, 2-tetrahydropyran-hydroxymethyl, cycloalkylalkyl, where 3 cycloalkyl -6 carbon atoms and alkyl with 1-6 carbon atoms, cycloalkylalkenyl, where cycloalkyl with 3-6 carbon atoms and alkenyl with 2-6 carbon atoms, cycloalkylalkoxy, where cycloalkyl with 3-6 carbon atoms and alkoxy with 1-6 carbon atoms , cycloalkylalkylalkoxy, where cyclo alkyl with 3-6 carbon atoms, alkyl with 1-6 carbon atoms and alkoxy with 1-6 carbon atoms, cycloalkyl-alkyl-alkenyloxy, where cycloalkyl with 3-6 carbon atoms, alkyl with 1-6 carbon atoms and alkenyl with 2 -6 carbon atoms, cycloalkyl-alkyl-alkynyloxy, where cycloalkyl with 3-6 carbon atoms, alkyl with 1-6 carbon atoms and alkynyl with 2-6 carbon atoms, cycloalkenyloxy with 3-6 carbon atoms, cycloalkenyl-alkoxy, where cycloalkenyl with 3-6 carbon atoms and alkoxy with 1-6 carbon atoms, cycloalkenyl-alkenyloxy, where cycloalkenyl with 3-6 carbon atoms and alkenes l with 2-6 carbon atoms, cycloalkenyl-alkynyloxy, where cycloalkenyl with 3-6 carbon atoms and alkynyl with 2-6 carbon atoms, while the last 15 of the above residues are replaced by one or more, same or different residues selected from the group including hydrogen, alkyl with 1-6 carbon atoms, halogenated with 1-6 carbon atoms, alkoxy with 1-6 carbon atoms, halogenated with 1-6 carbon atoms, alkylthio with 1-6 carbon atoms, halogenated with 1-6 carbon atoms, alkylsulfinyl with 1-6 carbon atoms, haloalkylsulfinyl with 1-6 a ohms carbon, alkylsulfonyl of 1-6 carbon atoms, haloalkylsulfonyl having 1-6 carbon atoms, alkylcarbonylamino wherein the alkyl group having 1-6 carbon atoms, alkylsulfonylamino group having 1-6 carbon atoms, halogen, nitro and cyano.

6. Benzoylcyclohexanedione according to one of claims 1 to 5, where R ² , R ³ , R ⁴ , independently of one another, are hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, cycloalkylalkyl, hydroxy, alkoxy, cycloalkoxy, alkylthio, amino, mono- and dialkylamino, cycloalkylamino, alkylsulfonyl, alkylsulfinyl, aminosulfonyl, mono- and dialkylamino-sulfonyl, alkylsulfonylamino, cycloalkylsulfonylamino, alkylcarbonyl, cycloalkylcarbonylalkyl, alkoxycarbonylalkyl, alkoxycarbonylalkyl, aminocarbonylalkyl, alkoxycarbonyloxy, amyl boniloksi, alkoxycarbonylamino, formyl, halogen, haloalkyl, haloalkenyl, haloalkynyl, haloalkoxy, haloalkenyloxy, galogenalkiniloksi, haloalkylthio, galogenalkeniltio, galogenalkiniltio, galogenalkilamino, galogenalkenilamino, galogenalkinilamino, haloalkylsulfonyl, galogenalkenilsulfonil, galogenalkinilsulfonil, halogenoalkylsulphinyl, galogenalkenilsulfinil, galogenalkinilsulfinil, haloalkylcarbonyl, haloalkoxycarbonyl, galogenalkeniloksikarbonil, haloalkynyloxycarbonyl, halogen ylaminocarbonyl, cyano, nitro, R ⁵ is hydrogen, R ⁶ represents OR ¹² or alkylthio of 1-6 carbon atoms; R ⁷ means hydrogen, alkyl with 1-6 carbon atoms, cycloalkyl with 3-6 carbon atoms, alkoxy with 1-6 carbon atoms, alkylthio with 1-6 carbon atoms, or phenyl; R ⁸ and R ⁹ , independently of one another, are alkyl with 1-6 carbon atoms, alkenyl with 2-6 carbon atoms, alkynyl with 2-6 carbon atoms, haloalkyl with 1-6 carbon atoms, aryl or benzyl; R ¹² means hydrogen, halogenated with 1-6 carbon atoms, alkylcarbonyl, where alkyl with 1-6 carbon atoms, alkoxycarbonyl, where alkoxy with 1-6 carbon atoms, alkylsulfonyl with 1-6 carbon atoms, benzoyl or phenylsulfonyl, both the latter of the above groups are optionally substituted with one or more, same or different residues selected from the group consisting of alkyl with 1-6 carbon atoms, haloalkyl with 1-6 carbon atoms, alkoxy with 1-6 carbon atoms, haloalkoxy with 1- 6 carbon atoms, halogen, cyano and nitro; L means an alkylene chain with 1-3 carbon atoms, optionally substituted with 1-4, identical or different residues R ² ; Y is a divalent moiety selected from the group N-alkyl, CHR ⁷ or C (R ⁷ ) ₂ , and Z is a single bond, a divalent moiety selected from the group CHR ⁷ or C (R ⁷ ) ₂ .

7. Benzoylcyclohexanedione according to one of claims 1 to 6, wherein R ¹ is haloalkoxy with 1-6 carbon atoms, haloalkenyloxy with 2-6 carbon atoms, haloalkynyloxy with 3-6 carbon atoms, haloalkylthio with 1-6 carbon atoms, halogenalkenylthio with 2-6 carbon atoms, halogenated with 3-6 carbon atoms, halogenated with 1-6 carbon atoms, halogenated with 2-6 carbon atoms, halogenated with 3-6 carbon atoms, halogenated with 1-6 carbon atoms, halogenated with 2- 6 carbon atoms, halogenated silt with 3-6 carbon atoms, haloalkylsulfinyl with 1-6 carbon atoms, haloalkenylsulfinyl with 2-6 carbon atoms, haloalkynylsulfinyl with 3-6 carbon atoms, haloalkylcarbonyl, where alkyl with 1-6 carbon atoms, haloalkenylcarbonyl, where alkenyl with 2- 6 carbon atoms, haloalkynylcarbonyl, where alkynyl with 3-6 carbon atoms, halogenoalkoxycarbonyl, where alkoxy with 1-6 carbon atoms, halogenoalkenyloxycarbonyl, where alkenyl with 2-6 carbon atoms, halogenoalkynyloxycarbonyl, where alkynyl with 3-6 carbon atoms, haloalkylaminaminocar onyl, where is alkyl with 1-6 carbon atoms, haloalkenylaminocarbonyl, where alkenyl with 2-6 carbon atoms, haloalkynylaminocarbonyl, where alkynyl with 3-6 carbon atoms, haloalkylcarbonylamino, where alkyl with 1-6 carbon atoms, halogenalkenylcarbonylamino, where alkenyl c 2 -6 carbon atoms, haloalkynylcarbonylamino, where alkynyl with 3-6 carbon atoms, haloalkoxycarbonylamino, where alkoxy with 1-6 carbon atoms, haloalkenyloxycarbonylamino, where alkenyl with 2-6 carbon atoms, haloalkynyloxycarbonylamino, where alkynyl with 3-6 atoms and carbon, haloalkylcarbonyloxy, where alkyl with 1-6 carbon atoms, haloalkenylcarbonyloxy, where alkenyl with 2-6 carbon atoms, haloalkynylcarbonyloxy, where alkynyl with 3-6 carbon atoms, haloalkoxycarbonyloxy, where alkoxy with 1-6 carbon atoms, haloalkenyloxycarbonyloxy alkenyl with 2-6 carbon atoms, halogenoalkynyloxycarbonyloxy, where alkynyl with 3-6 carbon atoms, haloalkylaminocarbonylamino, where alkyl with 1-6 carbon atoms, haloalkenylaminocarbonylamino, where alkenyl with 2-6 carbon atoms, halogenalkini aminocarbonylamino, wherein alkynyl of 3-6 carbon atoms, -O- (CH ₂₎ _m -O- (CH ₂₎ _n -N ^2a; R ² and R ³ , independently of one another, mean hydrogen, alkyl with 1-6 carbon atoms, haloalkyl with 1-6 carbon atoms, alkoxy with 1-6 carbon atoms, haloalkoxy with 1-6 carbon atoms, alkylthio with 1-6 carbon atoms, haloalkylthio with 1-6 carbon atoms, alkylsulfinyl with 1-6 carbon atoms, haloalkylsulfinyl with 1-6 carbon atoms, alkylsulfonyl with 1-6 carbon atoms, haloalkylsulfonyl with 1-6 carbon atoms, halogen, nitro and cyano; R ⁴ means hydrogen; R ⁶ means OR ¹² ; R ⁷ means hydrogen or alkyl with 1-6 carbon atoms; R ¹² means hydrogen, alkylsulfonyl with 1-6 carbon atoms, benzoyl, phenylsulfonyl, while the last two of the above groups are optionally substituted with one or more, same or different residues from the group consisting of alkyl with 1-6 carbon atoms, halogenated with 1 -6 carbon atoms, alkoxy with 1-6 carbon atoms, haloalkoxy with 1-6 carbon atoms, halogen, cyano or nitro; L means a CH ₂ fragment, optionally substituted with one or two, same or different alkyl radicals with 1-6 carbon atoms or alkoxyl radicals with 1-6 carbon atoms; Y and Z, independently from each other, mean CHR ⁷ or C (R ⁷ ) ₂ ; v = 1, and w = 0, 1, or 2.

8. A herbicidal agent, characterized in that it contains at least one compound of the general formula (I) according to one of claims 1 to 7 in a herbicidally effective amount.

9. The herbicidal agent of claim 8 in a mixture with additives for the preparation of preparative forms.

10. A method for controlling undesirable plants, characterized in that an effective amount of at least one compound of the general formula (I) according to one of claims 1 to 7 or one herbicidal agent according to claim 8 or 9 is applied per plant or in place unwanted plant growth.

11. The use of compounds of general formula (I) according to one of claims 1 to 7 or herbicidal agents according to claim 8 or 9 for controlling undesirable plants.

12. The use according to claim 11, characterized in that the compounds of general formula (I) are used to control undesirable plants in useful plant cultures.

13. The use according to claim 12, characterized in that the beneficial plants are transgenic beneficial plants.