RU1768565C - Composition for decoration of ceramic plate by method of seriography - Google Patents

Composition for decoration of ceramic plate by method of seriography

Info

Publication number
RU1768565C
RU1768565C SU914903570A SU4903570A RU1768565C RU 1768565 C RU1768565 C RU 1768565C SU 914903570 A SU914903570 A SU 914903570A SU 4903570 A SU4903570 A SU 4903570A RU 1768565 C RU1768565 C RU 1768565C
Authority
RU
Russia
Prior art keywords
composition
seriography
borax
starch
water
Prior art date
Application number
SU914903570A
Other languages
Russian (ru)
Inventor
Виктор Яковлевич Макаров
Александр Иванович Бенделев
Original Assignee
Керамический Завод "Красный Строитель"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Керамический Завод "Красный Строитель" filed Critical Керамический Завод "Красный Строитель"
Priority to SU914903570A priority Critical patent/RU1768565C/en
Application granted granted Critical
Publication of RU1768565C publication Critical patent/RU1768565C/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5007Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with salts or salty compositions, e.g. for salt glazing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0004Compounds chosen for the nature of their cations
    • C04B2103/0013Iron group metal compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Finishing Walls (AREA)

Abstract

Состав дл  декорировани  керамической плитки методом сериографии. Сущность изобретени : состав содержит растворимую соль металла из группы: никель , железо, кобальт, хром 40-50%, крахмал 2-3%, бура 1-5%, вода - остальное, Характеристики состава: износостойкость 0,11-0,13 г/см2, глубина пропитки при температуре 1080°С 1,5-2 мм, цвет покрыти  - бежевый, синий, красный, сине-зеленый . 2 табл.Composition for decorating ceramic tiles by seriography. The inventive composition contains a soluble salt of a metal from the group: nickel, iron, cobalt, chromium 40-50%, starch 2-3%, borax 1-5%, water - the rest, Composition characteristics: wear resistance 0.11-0.13 g / cm2, the depth of impregnation at a temperature of 1080 ° C is 1.5-2 mm, the color of the coating is beige, blue, red, blue-green. 2 tab.

Description

Изобретение относитс  к промышленности строительных материалов и может быть использовано дл  производства керамической плитки дл  пола с улучшенными потребительскими характеристиками.The invention relates to the building materials industry and can be used to produce ceramic floor tiles with improved consumer properties.

Известен способ окрашивани  горной породы или камн  пропиткой их солью металла (за вка Великобритании №2192628, С 04 В 41/85).A known method of coloring rock or stone by impregnating them with a metal salt (UK application No. 2192628, C 04 B 41/85).

Окрашивание провод т при пониженном давлении и температуре 200-300°С. Недостатком данного способа  вл етс  низка  износостойкость декоративного узора плитки .Staining is carried out under reduced pressure and a temperature of 200-300 ° C. The disadvantage of this method is the low wear resistance of the decorative tile pattern.

Наиболее близким  вл етс  декоративна  плитка с узором, полученным пропиткой лицевой поверхности составом, содержащим жидкий краситель и в зкое св зующее, например крахмал, выгорающее при температуре обжига (за вка Японии № 63-8064, С 04 В 33/13).The closest is a decorative tile with a pattern obtained by impregnating the front surface with a composition containing a liquid dye and a viscous binder, for example starch, which burns out at a firing temperature (Japanese application No. 63-8064, 04 B 33/13).

Недостатком данного технического решени   вл етс  то, что при декорированииThe disadvantage of this technical solution is that when decorating

плитки не достигаетс  достаточна  выразительность декоративного узора.tiles do not achieve sufficient expressiveness of the decorative pattern.

Целью насто щего изобретени   вл етс  повышение износостойкости и качества за счет увеличени  глубины пропитки, при сохранении декоративных свойств.The aim of the present invention is to increase the wear resistance and quality by increasing the depth of impregnation, while maintaining decorative properties.

Цель изобретени  достигаетс  тем, что декоративный узор на лицевую поверхность нанос т методом сериографии, в пропитывающий состав, содержащий раствор солей металлов, загуститель, выгорающий при обжиге , добавл ют буру, при следующем соотношении компонентов, мас.%:The aim of the invention is achieved by the fact that a decorative pattern is applied to the front surface by the method of seriography, a borax is added to the impregnating composition containing a solution of metal salts, a thickening agent that burns out during firing, in the following ratio, wt.%:

Соли металловMetal salts

(Nl, Co, Fe, Cr) 40-50;(Nl, Co, Fe, Cr) 40-50;

Крахмал2-3Starch2-3

Бура1-5Borax1-5

ВодаОстальноеWater Else

Дл  получени  состава дл  декорировани  керамических изделий были подготовлены четыре смеси ингредиентов, содержащие кажда  загуститель (крахмал), буру, соли металлов (никель, хром, кобальт,To prepare a composition for decorating ceramic products, four mixtures of ingredients were prepared containing each thickener (starch), borax, metal salts (nickel, chromium, cobalt,

СОWith

сwith

VI оVI about

0000

ел о елeat about eat

железо), воду, дополнительно до ста процентов в каждой смеси.Iiron), water, in addition to one hundred percent in each mixture. I

Кажда  смесь готовитс  отдельно. В емкость засыпают предварительно взвешенные соли металлов (железо, кобальт, хром, никель), раствор ют в воде нагрева  до температуры 60-90°С.Each mixture is prepared separately. Pre-weighed metal salts (iron, cobalt, chromium, nickel) are poured into the container, dissolved in heating water to a temperature of 60-90 ° C.

Раствор буры с §ЗдЬй заливают в ем- кость с расгвором соли. Водную суспензию крахмалаТпри постШнйЪм перемешивании, добавл ют в гор чий раствор соли металла и буры,затем раствор охлаждают.A solution of borax with § ЗдЬй is poured into a tank with a solution of salt. An aqueous suspension of starch. With constant stirring, metal salts and borax are added to the hot solution, then the solution is cooled.

Приготовленный таким образом состав нанос т на плитку методом сериографии.The composition thus prepared is applied to the tile by seriography.

Полученные смеси имеют следующее содержание компонентов (см1, таблица N21).The resulting mixtures have the following content of components (cm1, table N21).

Физико-механические свойства указаны в таблице № 2.Physico-mechanical properties are shown in table No. 2.

Claims (1)

Формула изобретени The claims Состав дл  декорировани  керамической плитки методом сериографии, включающий растворимую соль металла из группы: никель, железо, кобальт, хром, крахмал и воду, отличающийс  тем, что, с целью повышени  износостойкости и качества за счет увеличени  глубины пропитки при сохранении декоративных свойств, он дополнительно содержит буру, при следующем соотношении компонентов, мас.%:A composition for decorating ceramic tiles by seriography, including a soluble salt of a metal from the group: nickel, iron, cobalt, chromium, starch and water, characterized in that, in order to increase wear resistance and quality by increasing the depth of impregnation while maintaining decorative properties, it is additionally contains borax, in the following ratio, wt.%: указанна  растворима indicated soluble соль металла40-50;metal salt 40-50; крахмал2-3;starch 2-3; бура1-5;borax 1-5; водаОстальноеwater else Таблица 1Table 1
SU914903570A 1991-01-21 1991-01-21 Composition for decoration of ceramic plate by method of seriography RU1768565C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU914903570A RU1768565C (en) 1991-01-21 1991-01-21 Composition for decoration of ceramic plate by method of seriography

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU914903570A RU1768565C (en) 1991-01-21 1991-01-21 Composition for decoration of ceramic plate by method of seriography

Publications (1)

Publication Number Publication Date
RU1768565C true RU1768565C (en) 1992-10-15

Family

ID=21556211

Family Applications (1)

Application Number Title Priority Date Filing Date
SU914903570A RU1768565C (en) 1991-01-21 1991-01-21 Composition for decoration of ceramic plate by method of seriography

Country Status (1)

Country Link
RU (1) RU1768565C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0960872A1 (en) * 1998-05-26 1999-12-01 BK Giulini Chemie GmbH & Co. OHG Use of stabile chromium (III) compounds as a paint for ceramics

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
За вка GB №2192628, кл. С 04 В 41/65, 1988. За вка JP №63-8064, кл. С 04 В 33/13, 1988. *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0960872A1 (en) * 1998-05-26 1999-12-01 BK Giulini Chemie GmbH & Co. OHG Use of stabile chromium (III) compounds as a paint for ceramics

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