RO87191B1 - Procedeu de recuperare a cromului, manganului si cuprului din catalizatorii uzati - Google Patents
Procedeu de recuperare a cromului, manganului si cuprului din catalizatorii uzatiInfo
- Publication number
- RO87191B1 RO87191B1 RO111487A RO11148783A RO87191B1 RO 87191 B1 RO87191 B1 RO 87191B1 RO 111487 A RO111487 A RO 111487A RO 11148783 A RO11148783 A RO 11148783A RO 87191 B1 RO87191 B1 RO 87191B1
- Authority
- RO
- Romania
- Prior art keywords
- copper
- manganese
- chromium
- solubilization
- catalyst
- Prior art date
Links
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title abstract 6
- 229910052804 chromium Inorganic materials 0.000 title abstract 5
- 239000011651 chromium Substances 0.000 title abstract 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title abstract 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229910052802 copper Inorganic materials 0.000 title abstract 4
- 239000010949 copper Substances 0.000 title abstract 4
- 229910052748 manganese Inorganic materials 0.000 title abstract 4
- 239000011572 manganese Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 230000007928 solubilization Effects 0.000 abstract 2
- 238000005063 solubilization Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical class [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 abstract 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract 1
- 229910000365 copper sulfate Inorganic materials 0.000 abstract 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
Abstract
Procedeul de recuperare a cromului, manganului si cuprului din catalizatorii uzati de la fabricarea n-metilpirolidonei, conform inventiei consta în aceea ca pentru aducerea în solutie a elementelor utile se foloseste prajirea oxidativa a catalizatorului cu carbonat de sodiu în raport de 1 parte greutate catalizator: 2 parti greutate carbonat la temperatura de 1150 degree C, timp de 0,5 h dupa care pentru extractia cromului topitura se solubilizeaza în apa la un raport solid: apa= 1: 2, cand în solutie trece cromul sub forma de cromat, care se prelucreaza apoi la bicromat si, dupa separarea cromului, din amestecul ramas de oxizi de mangan si cupru se separa manganul prin solubilizare cu acid sulfuric 1% si alcool etilic iar dupa separarea cromului si manganului, cuprul se separa prin solubilizarea oxizilor ramasi cu acid sulfuric 20% prin refluxare timp de 30 min, urmata de separarea cuprului sub forma de sulfat de cupru cristalizat.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO111487A RO87191B1 (ro) | 1983-07-01 | 1983-07-01 | Procedeu de recuperare a cromului, manganului si cuprului din catalizatorii uzati |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO111487A RO87191B1 (ro) | 1983-07-01 | 1983-07-01 | Procedeu de recuperare a cromului, manganului si cuprului din catalizatorii uzati |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RO87191B1 true RO87191B1 (ro) | 1985-07-31 |
Family
ID=40903834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO111487A RO87191B1 (ro) | 1983-07-01 | 1983-07-01 | Procedeu de recuperare a cromului, manganului si cuprului din catalizatorii uzati |
Country Status (1)
| Country | Link |
|---|---|
| RO (1) | RO87191B1 (ro) |
-
1983
- 1983-07-01 RO RO111487A patent/RO87191B1/ro unknown
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