RO86663B1 - Procedeu de sinteza a trialchilfosfatilor - Google Patents
Procedeu de sinteza a trialchilfosfatilorInfo
- Publication number
- RO86663B1 RO86663B1 RO113334A RO11333484A RO86663B1 RO 86663 B1 RO86663 B1 RO 86663B1 RO 113334 A RO113334 A RO 113334A RO 11333484 A RO11333484 A RO 11333484A RO 86663 B1 RO86663 B1 RO 86663B1
- Authority
- RO
- Romania
- Prior art keywords
- reaction
- alcohol
- trialkylphosphates
- added
- phosphorus oxychloride
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 230000002194 synthesizing effect Effects 0.000 title 1
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 abstract 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 3
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 abstract 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 abstract 1
- -1 aliphatic alcohols Chemical class 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 230000005587 bubbling Effects 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Abstract
Inventia se refera la un procedeu de sinteza a trialchilfosfatilor prin reactia dintre oxiclorura fosfor si alcooli alifatici alesi dintre metanol, n-propanol, n-hexanol sau n-heptanol, reactie care se efectueaza în prezenta unui solvent ales dintre clorura de metilen, cloroform, benzen sau barbotare de azot, la temperatura de 40...80 degree C, la presiunea atmosferica, la un raport molar oxiclorura de fosfor: alcool cuprins între 1:4...1:5, raportul între oxiclorura de fosfor si sovent fiind între 1:3...1:4,5 parti în greutate, alcoolul alifatic se adauga în doua trepte, ultimul mol de alcool adaugîndu-se dupa 3-4h de la adaugarea primei cantitati apoi se efectueaza neutralizarea acidului clorhidric ramas în masa de reactie cu bicarbonat de sodiu solid, urmata de anhidrizare cu sulfat de sodiu.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO113334A RO86663B1 (ro) | 1984-01-17 | 1984-01-17 | Procedeu de sinteza a trialchilfosfatilor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO113334A RO86663B1 (ro) | 1984-01-17 | 1984-01-17 | Procedeu de sinteza a trialchilfosfatilor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO86663A2 RO86663A2 (ro) | 1985-04-17 |
| RO86663B1 true RO86663B1 (ro) | 1985-05-01 |
Family
ID=20114277
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO113334A RO86663B1 (ro) | 1984-01-17 | 1984-01-17 | Procedeu de sinteza a trialchilfosfatilor |
Country Status (1)
| Country | Link |
|---|---|
| RO (1) | RO86663B1 (ro) |
-
1984
- 1984-01-17 RO RO113334A patent/RO86663B1/ro unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO86663A2 (ro) | 1985-04-17 |
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