RO84449B1 - Benzene derivative and process for obtaining the same - Google Patents

Benzene derivative and process for obtaining the same

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Publication number
RO84449B1
RO84449B1 RO108237A RO10823782A RO84449B1 RO 84449 B1 RO84449 B1 RO 84449B1 RO 108237 A RO108237 A RO 108237A RO 10823782 A RO10823782 A RO 10823782A RO 84449 B1 RO84449 B1 RO 84449B1
Authority
RO
Romania
Prior art keywords
degrees
benzene
obtaining
benzene derivative
same
Prior art date
Application number
RO108237A
Other languages
Romanian (ro)
Other versions
RO84449A2 (en
Inventor
Ioan Bestiuc
Zoltan Kelemen
Valeriu Popescu
Adrian Caraculacu
Alexandru Pascariu
Tinca Buruiana
Original Assignee
Institutul De Chimie Macromoleculara "Petru Poni"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institutul De Chimie Macromoleculara "Petru Poni" filed Critical Institutul De Chimie Macromoleculara "Petru Poni"
Priority to RO108237A priority Critical patent/RO84449B1/en
Publication of RO84449A2 publication Critical patent/RO84449A2/en
Publication of RO84449B1 publication Critical patent/RO84449B1/en

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Inventia se refera la un derivat de benzen, utilizat ca agent purtator de caldura, caracterizat prin aceea ca are structura corespunzatoare formulei generale: (vezi formula) în care n are valoarea 1...5 si este un produs lichid cu aspect de ulei de culoare galben-brun, cu greutate specifica la 20 degree C de 0,977...0,978 g/cm3, caldura specifica la 25 degree C de 0,35 kcal/kg, vîscozitate la 20 degree C de 300...350 Ps, punct de aprindere prin metoda Marcusson de 208 degree C, punct de ardere de 227 degree C. Procedeul de obtinere a derivatului conform inventiei se caracterizeaza prin aceea ca se aduc în reactie cu benzenul cu dicloretanul, în raport molar de 4:1 pîna la 6:1, temperatura de reflux, în prezenta unei cantitati de 0,04...0,07 mol/1 clorura de aluminiu, produsul de reactie fiind supus apoi distilarii la presiunea atmosferica, pentru îndepartarea excesului de benzen si apoi la 5...10 torr si 140...200 degree C, pentru separarea fractiunilor volatile care pot fi, eventual recirculate în proces.The invention relates to a benzene derivative used as a heat carrier, characterized in that it has the structure corresponding to the general formula: (see formula) wherein n is 1 ... 5 and is an oil-like liquid product yellow-brown color, specific gravity at 20 degrees C of 0.977 ... 0.978 g / cm3, specific heat at 25 degree C of 0.35 kcal / kg, viscosity at 20 degrees C of 300 ... 350 ps, ignition by the Marcusson method of 208 degrees C, a combustion point of 227 degrees C. The process for obtaining the derivative according to the invention is characterized in that it is reacted with benzene with dichloroethane in a molar ratio of 4: 1 to 6: 1, reflux temperature, in the presence of 0.04 ... 0.07 mol / l aluminum chloride, the reaction product being subjected to distillation at atmospheric pressure to remove excess benzene and then to 5 ... 10 torr and 140 ... 200 degrees C, to separate the volatile fractions which may be, e.g., entwally recirculated in the process.

RO108237A 1982-07-23 1982-07-23 Benzene derivative and process for obtaining the same RO84449B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RO108237A RO84449B1 (en) 1982-07-23 1982-07-23 Benzene derivative and process for obtaining the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RO108237A RO84449B1 (en) 1982-07-23 1982-07-23 Benzene derivative and process for obtaining the same

Publications (2)

Publication Number Publication Date
RO84449A2 RO84449A2 (en) 1984-06-21
RO84449B1 true RO84449B1 (en) 1984-08-30

Family

ID=20111855

Family Applications (1)

Application Number Title Priority Date Filing Date
RO108237A RO84449B1 (en) 1982-07-23 1982-07-23 Benzene derivative and process for obtaining the same

Country Status (1)

Country Link
RO (1) RO84449B1 (en)

Also Published As

Publication number Publication date
RO84449A2 (en) 1984-06-21

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