RO83047B - Process for the hydrosulphonation of asphalt-containing petroleum residues - Google Patents

Process for the hydrosulphonation of asphalt-containing petroleum residues

Info

Publication number
RO83047B
RO83047B RO78613A RO7861374A RO83047B RO 83047 B RO83047 B RO 83047B RO 78613 A RO78613 A RO 78613A RO 7861374 A RO7861374 A RO 7861374A RO 83047 B RO83047 B RO 83047B
Authority
RO
Romania
Prior art keywords
petroleum residues
proportion
hydrosulphonation
asphalt
catalytic composition
Prior art date
Application number
RO78613A
Other languages
Romanian (ro)
Other versions
RO83047A (en
Inventor
John Edward Conway
Original Assignee
Universal Oil Products Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Company filed Critical Universal Oil Products Company
Publication of RO83047A publication Critical patent/RO83047A/en
Publication of RO83047B publication Critical patent/RO83047B/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Prezenta inventie se refera la un procedeu de hidrosulfurare a unor reziduuri petroliere cu continut de asfaltene, prin tratarea acestora cu hidrogen, în prezenta unei compozitii catalitice, care contine, pe un suport de alumina, compusi cu sulf ai unui metal din grupa a-VI-a B a Tabelului periodic al elementelor ca, de exemplu, molibden, în proportie de 0,5...12% si 0,5...5% dintr-un compus al unui metal din grupa a VIII-a a Tabelului periodic, ca de exemplu cobalt, si se caracterizeaza prin aceea ca, în scopul îndepartarii sulfului din materia prima cu continut de asfaltene într-o proportie de cel putin 80...90%, utilizeaza o compozitie catalitica avînd o densitate cuprinsa între 1,05 si 1,30 g/cm3 si în care suportul de baza de gama-alumina are un diametru mediu al porilor cuprins între 20 si 300 A, un volum al porilor de 0,1...1 ml/g si o suprafata specifica de 100...500 m2/g.The present invention relates to a process for the hydrous sulphurisation of petroleum residues containing asphaltenes by treating them with hydrogen in the presence of a catalytic composition containing, on an alumina support, sulfur compounds of a Group VI metal B of the Periodic Table of the elements such as, for example, molybdenum in the proportion of 0.5-12% and 0.5-5% of a metal compound of Group VIII of Table periodically, such as cobalt, and characterized in that, in order to remove the sulfur from the raw material containing asphaltenes in a proportion of at least 80-90%, it uses a catalytic composition having a density of between 1, 05 and 1.30 g / cm3, and wherein the gamma-alumina base support has an average pore diameter of 20 to 300 A, a pore volume of 0.1 to 1 ml / g and a specific surface area 100 ... 500 m2 / g.

RO78613A 1973-04-30 1974-04-30 Process for the hydrosulphonation of asphalt-containing petroleum residues RO83047B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US35601373A 1973-04-30 1973-04-30

Publications (2)

Publication Number Publication Date
RO83047A RO83047A (en) 1984-04-12
RO83047B true RO83047B (en) 1984-05-30

Family

ID=23399743

Family Applications (1)

Application Number Title Priority Date Filing Date
RO78613A RO83047B (en) 1973-04-30 1974-04-30 Process for the hydrosulphonation of asphalt-containing petroleum residues

Country Status (20)

Country Link
JP (1) JPS5014703A (en)
AR (1) AR230070A1 (en)
BE (1) BE814376A (en)
BG (1) BG25201A3 (en)
BR (1) BR7403505D0 (en)
CA (1) CA1028970A (en)
DE (1) DE2418645B2 (en)
EG (1) EG11053A (en)
ES (1) ES425651A1 (en)
FR (1) FR2227317B1 (en)
GB (1) GB1458751A (en)
IE (1) IE39226B1 (en)
IN (1) IN142203B (en)
IT (1) IT1011296B (en)
MY (1) MY7900136A (en)
NL (1) NL7405335A (en)
NO (1) NO142311C (en)
PL (1) PL90499B1 (en)
RO (1) RO83047B (en)
SU (1) SU504501A3 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6216488Y2 (en) * 1978-11-21 1987-04-25
JPS5840452U (en) * 1981-09-14 1983-03-17 市光工業株式会社 Lever and knob fitting structure
JPH0714643Y2 (en) * 1989-08-22 1995-04-10 株式会社大井製作所 Holder for connecting rods
BRPI0405572A (en) * 2003-12-19 2005-08-30 Shell Int Research Methods of Producing a Transportable Fuel and Crude Petroleum Product, Heating Fuel, Lubricants or Chemicals, and Crude Oil Products

Also Published As

Publication number Publication date
FR2227317A1 (en) 1974-11-22
GB1458751A (en) 1976-12-15
JPS5014703A (en) 1975-02-17
NO142311B (en) 1980-04-21
DE2418645B2 (en) 1979-06-13
ES425651A1 (en) 1976-06-16
BE814376A (en) 1974-08-16
NL7405335A (en) 1974-11-01
NO741531L (en) 1974-10-31
RO83047A (en) 1984-04-12
BG25201A3 (en) 1978-08-10
IE39226L (en) 1974-10-30
DE2418645A1 (en) 1974-11-21
MY7900136A (en) 1979-12-31
IT1011296B (en) 1977-01-20
SU504501A3 (en) 1976-02-25
CA1028970A (en) 1978-04-04
PL90499B1 (en) 1977-01-31
BR7403505D0 (en) 1974-11-19
AR230070A1 (en) 1984-02-29
NO142311C (en) 1980-08-06
IE39226B1 (en) 1978-08-30
IN142203B (en) 1977-06-11
EG11053A (en) 1976-11-30
FR2227317B1 (en) 1977-09-30

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