PT879641E - PALLADIUM CATALYST UNDERSTANDING PALLADIUM DEPOSITED IN CARAVAN ACTIVATED - Google Patents

PALLADIUM CATALYST UNDERSTANDING PALLADIUM DEPOSITED IN CARAVAN ACTIVATED

Info

Publication number
PT879641E
PT879641E PT98108153T PT98108153T PT879641E PT 879641 E PT879641 E PT 879641E PT 98108153 T PT98108153 T PT 98108153T PT 98108153 T PT98108153 T PT 98108153T PT 879641 E PT879641 E PT 879641E
Authority
PT
Portugal
Prior art keywords
palladium
activated
caravan
deposited
understanding
Prior art date
Application number
PT98108153T
Other languages
Portuguese (pt)
Inventor
Carlo Rubini
Luigi Cavalli
Marinella Malentacchi
Original Assignee
Sued Chemie Mt Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sued Chemie Mt Srl filed Critical Sued Chemie Mt Srl
Publication of PT879641E publication Critical patent/PT879641E/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/392Metal surface area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/393Metal or metal oxide crystallite size
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42Separation; Purification; Stabilisation; Use of additives
    • C07C51/487Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/657Pore diameter larger than 1000 nm
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Removal Of Specific Substances (AREA)

Abstract

Hydrogenation catalysts comprising metallic palladium supported on activated carbon, wherein less than 50% by weight of the palladium is comprised within a surface layer with a depth of up to 50 microns, the remainder being comprised in a layer between 50 and 400 microns deep. The catalysts can be used in particular in purifying terephthalic acid obtained by oxidation of p-xylene. They are prepared by dry impregnation of the support.
PT98108153T 1997-05-19 1998-05-05 PALLADIUM CATALYST UNDERSTANDING PALLADIUM DEPOSITED IN CARAVAN ACTIVATED PT879641E (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT97MI001161A ITMI971161A1 (en) 1997-05-19 1997-05-19 HYDROGENATION CATALYSTS
CN98109754A CN1104949C (en) 1997-05-19 1998-05-18 Hydrogenation catalysts
US09/081,335 US6066589A (en) 1997-05-19 1998-05-19 Hydrogenation catalysts

Publications (1)

Publication Number Publication Date
PT879641E true PT879641E (en) 2003-09-30

Family

ID=27179193

Family Applications (1)

Application Number Title Priority Date Filing Date
PT98108153T PT879641E (en) 1997-05-19 1998-05-05 PALLADIUM CATALYST UNDERSTANDING PALLADIUM DEPOSITED IN CARAVAN ACTIVATED

Country Status (25)

Country Link
US (1) US6066589A (en)
EP (1) EP0879641B1 (en)
JP (2) JP4113615B2 (en)
KR (1) KR100515271B1 (en)
CN (1) CN1104949C (en)
AT (1) ATE243559T1 (en)
AU (1) AU736565B2 (en)
BR (1) BR9801657B1 (en)
CA (1) CA2237027C (en)
CZ (1) CZ97998A3 (en)
DE (1) DE69815754T2 (en)
DK (1) DK0879641T3 (en)
ES (1) ES2202690T3 (en)
HR (1) HRP980166B1 (en)
HU (1) HU221667B1 (en)
ID (1) ID22375A (en)
IT (1) ITMI971161A1 (en)
MX (1) MX208986B (en)
NO (1) NO317355B1 (en)
PL (1) PL326346A1 (en)
PT (1) PT879641E (en)
RU (1) RU2205686C2 (en)
SI (1) SI0879641T1 (en)
SK (1) SK283777B6 (en)
TW (1) TW470667B (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1306194B1 (en) * 1999-01-08 2001-05-30 Sued Chemie Mt Srl CATALYSTS FOR EXOTHERMAL REACTIONS ON A FIXED BED.
DE10104224A1 (en) * 2001-01-31 2002-08-01 Basf Ag Purification of crude terephthalic acid comprises catalytic hydrogenation at a catalyst material comprising a ca bon supported hydrogenation metal whereby the carbon support comprises carbon fibers
US6992037B2 (en) * 2001-09-17 2006-01-31 Engelhard Corporation Precious metal catalyst for debenzylation
US7659225B2 (en) * 2001-09-17 2010-02-09 Basf Catalysts Llc Precious metal catalyst for debenzylation
DE10228245B4 (en) * 2002-06-25 2004-07-15 Kpss-Kao Professional Salon Services Gmbh Hair Dye
RU2240182C1 (en) * 2003-07-10 2004-11-20 Украинцев Валерий Борисович Palladium-containing hydrogenation catalyst preparation method
JP4519438B2 (en) * 2003-10-08 2010-08-04 株式会社トクヤマ Catalysts for the reduction of polychlorinated alkanes.
JP2005225916A (en) * 2004-02-10 2005-08-25 Fuji Xerox Co Ltd Method for producing organic functional material, organic functional material and organic electroluminescent element using the same
JP4599868B2 (en) * 2004-03-30 2010-12-15 三菱化学株式会社 Hydrogenation catalyst and method for producing the same
CN100402144C (en) * 2004-06-18 2008-07-16 中国石油化工股份有限公司 Method for preparing catalyst for refining of crude terephthalic acid
DE102004059282A1 (en) * 2004-10-13 2006-04-27 Basf Ag selective hydrogenation catalyst
CN100473457C (en) * 2004-12-24 2009-04-01 中国石油化工集团公司 Carbon-supported noble metal catalyst and preparation method thereof
DE602006004279D1 (en) * 2005-09-09 2009-01-29 Mitsubishi Gas Chemical Co A process for the preparation of amino compounds having an aromatic ring using a shell catalyst
CN101121127A (en) * 2006-08-11 2008-02-13 中国石油化工股份有限公司 Method for preparing supported palladium/carbon catalyst
CN101347730B (en) * 2007-07-18 2011-07-13 中国石油化工股份有限公司 Hydrogenation catalyst for refinement of crude terephthalic acid
US7884254B2 (en) * 2007-08-08 2011-02-08 Honeywell International Inc. Dehydrochlorination of hydrochlorofluorocarbons using pre-treated activated carbon catalysts
CN102039122B (en) * 2009-10-13 2012-07-18 中国石油化工股份有限公司 Palladium carbon catalyst for hydrofining crude terephthalic acid
CN102070441B (en) * 2009-11-25 2014-02-12 中国石油化工股份有限公司 Method for catalytic hydrorefining of terephthalic acid
JP6403481B2 (en) * 2013-09-26 2018-10-10 株式会社日本触媒 Wastewater treatment catalyst and wastewater treatment method using the catalyst
CN104549284B (en) * 2013-10-15 2016-12-07 中国石油化工股份有限公司 Gaseous hydrocarbon self-heating conversion catalyst and preparation method thereof
JP6450352B2 (en) * 2016-09-26 2019-01-09 デクセリアルズ株式会社 Porous carbon material, method for producing the same, and catalyst for synthesis reaction
RU2641694C1 (en) * 2016-12-14 2018-01-22 Акционерное общество "Федеральный научно-производственный центр "Алтай" Method of obtaining catalyst and method of its use for repeated use in industrial process of two-stage hydrogenolysis in production of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo[5,5,0,03,11,05,9]dodecane
JP6646088B2 (en) 2018-02-21 2020-02-14 デクセリアルズ株式会社 Porous carbon material, method for producing the same, and catalyst for synthesis reaction
CN114260010B (en) * 2021-12-17 2024-05-28 江苏飞马催化剂有限公司 Preparation method of palladium-carbon catalyst for deprotection

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3138560A (en) * 1959-12-17 1964-06-23 Engelhard Ind Inc Process for producing palladium on carbon catalysts
DE2509251C3 (en) * 1975-03-04 1978-07-13 Hoechst Ag, 6000 Frankfurt Process for the preparation of a palladium catalyst
US4421676A (en) * 1981-10-29 1983-12-20 Standard Oil Company Process for preparation of palladium on carbon catalysts used in the purification of crude terephthalic acid
US4476242A (en) * 1981-10-29 1984-10-09 Standard Oil Company (Indiana) Process for preparing palladium on carbon catalysts for purification of crude terephthalic acid
US4467111A (en) * 1981-10-29 1984-08-21 Standard Oil Company (Indiana) Process for purification of crude terephthalic acid
US4415479A (en) * 1981-10-29 1983-11-15 Standard Oil Company (Indiana) Palladium on carbon catalyst for purification of crude terephthalic acid
US4791226A (en) * 1983-06-23 1988-12-13 Amoco Corporation Catalyst and process for purification of crude terephthalic acid
US4629715A (en) * 1985-10-07 1986-12-16 Amoco Corporation Purification of terephthalic acid to relatively low levels of 4-carboxybenzaldehyde and catalyst therefor
SU1660282A1 (en) * 1989-11-13 1997-02-10 Институт катализа СО АН СССР Catalyst for terephthalic acid hydrorefining and method of its producing
DE4209832A1 (en) * 1992-03-26 1993-09-30 Henkel Kgaa Shell catalyst, its production process and its use
JP3250675B2 (en) * 1992-05-15 2002-01-28 花王株式会社 Supported catalyst composition for amine production
GB9310070D0 (en) * 1992-05-29 1993-06-30 Ici Plc Process for the production of purified terephthalic acid
JP3402515B2 (en) * 1994-05-23 2003-05-06 日本碍子株式会社 Hydrogen separator, hydrogen separator using the same, and method for producing hydrogen separator
JPH09263566A (en) * 1996-03-29 1997-10-07 Cosmo Sogo Kenkyusho:Kk Purification of crude benzenedicarboxylic acid, catalyst used for purification and its production

Also Published As

Publication number Publication date
HUP9801037A2 (en) 1999-01-28
AU736565B2 (en) 2001-08-02
SI0879641T1 (en) 2003-12-31
DK0879641T3 (en) 2003-10-20
ITMI971161A0 (en) 1997-05-19
SK283777B6 (en) 2004-01-08
KR19980086653A (en) 1998-12-05
NO317355B1 (en) 2004-10-18
ES2202690T3 (en) 2004-04-01
TW470667B (en) 2002-01-01
HRP980166B1 (en) 2003-02-28
HUP9801037A3 (en) 1999-03-29
KR100515271B1 (en) 2005-12-06
CZ97998A3 (en) 1998-12-16
CN1104949C (en) 2003-04-09
ITMI971161A1 (en) 1998-11-19
HRP980166A2 (en) 1999-08-31
SK64898A3 (en) 1998-12-02
ATE243559T1 (en) 2003-07-15
JP4113615B2 (en) 2008-07-09
DE69815754D1 (en) 2003-07-31
US6066589A (en) 2000-05-23
JPH1190223A (en) 1999-04-06
NO982261D0 (en) 1998-05-18
HU9801037D0 (en) 1998-07-28
CN1205244A (en) 1999-01-20
BR9801657A (en) 1999-10-05
CA2237027A1 (en) 1998-11-19
JP4920616B2 (en) 2012-04-18
JP2008183557A (en) 2008-08-14
ID22375A (en) 1999-10-07
DE69815754T2 (en) 2004-05-19
PL326346A1 (en) 1998-11-23
AU6710898A (en) 1998-11-19
CA2237027C (en) 2007-07-10
EP0879641A1 (en) 1998-11-25
EP0879641B1 (en) 2003-06-25
MX208986B (en) 2002-07-17
RU2205686C2 (en) 2003-06-10
HU221667B1 (en) 2002-12-28
BR9801657B1 (en) 2008-11-18
NO982261L (en) 1998-11-20

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