PL97378B1 - METHOD OF MANUFACTURING LAMINATES AND AMINE MOLDS WITH INCREASED STAIN RESISTANCE - Google Patents

METHOD OF MANUFACTURING LAMINATES AND AMINE MOLDS WITH INCREASED STAIN RESISTANCE Download PDF

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Publication number
PL97378B1
PL97378B1 PL18827676A PL18827676A PL97378B1 PL 97378 B1 PL97378 B1 PL 97378B1 PL 18827676 A PL18827676 A PL 18827676A PL 18827676 A PL18827676 A PL 18827676A PL 97378 B1 PL97378 B1 PL 97378B1
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PL
Poland
Prior art keywords
amine
stearamide
stain resistance
molds
laminates
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Application number
PL18827676A
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Polish (pl)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to PL18827676A priority Critical patent/PL97378B1/en
Publication of PL97378B1 publication Critical patent/PL97378B1/en

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Description

Przedmiotem wynalazku jest sposób wytwarzania laminatów i wyprasek aminowych o zwiekszonej odpor¬ nosci na plamienie poprzez modyfikacje ich powierzchni.Wypraski z tloczyw aminowych a zwlaszcza melaminowych sa stosowane w zyciu codziennym najczesciej w postaci naczyn stolowych. Naczynia stolowe narazone na czeste dzialanie potraw zawierajacych substancje barwne latwo ulegaja plamieniu. Laminaty dekoracyjne z wierzchnia warstwa zywicy melaminowej stosowane na blaty stolów i biurek równiez czesto narazone sa na plamienie, na przyklad atramentem. Plamy zmniejszaja wartosc estetyczna i uzytkowa laminatów i wyprasek. . .Stwierdzono, ze odpornosc na plamienie powierzchni laminatów i wyprasek aminowych mozna zwiekszyc przez traktowanie ich roztworem stearamidu lub metylolostearamidu w rozpuszczalniku organicznym. Stearamid modyfikuje chemicznie powierzchnie wyprasek aminowych reagujac ze znajdujacymi sie na jej powierzchni wolnymi grupami metylolowymi. Metylolostearamid reaguje z grupami —NH- lub —NH2 polikondensatów aminowo-formaldehydowych. Jako rozpuszczalnik uzywa sie zwiazki rozpuszczajace stearamid lub metylolostear¬ amid, nietoksyczne, które ewentualnie moga byc ogrzane bez niebezpieczenstwa zapalenia sie, z wyjatkiem takich zwiazków, które moglyby reagowac z metylolostearamidem, na przyklad alkoholu. Temperatura roztwo¬ ru nie powinna przekraczac 150°C ze wzgledu na mozliwy wówczas rozklad laminatu lub wypraski. Czas dzialania roztworu stearamidu lub metylolostearamidu jest tym krótszy im wyzsza jest temperatura jego dzialania. Stezenie roztworu stearamidu lub metylolostearamidu nie wplywa w sposób istotny na modyfikacje powierzchni, zapewnia jedynie doplyw stearamidu lub metylolostearamidu do mogacych byc modyfikowanymi grup -CH2 OH, -NH- lub -NH2.Przykla d I. Krazek standardowy o srednicy 100 mm i grubosci 4 mm z tloczywa melaminowego prasuje sie 6 minut w temperaturze 150°C i zanurza na 15 minut do wrzacego 1% roztworu stearamidu w etanolu. Nastepnie krazek wyjmuje sie, oplukuje sie alkoholem i woda, osusza. Powierzchnia wypraski nie plami sie w ogóle pod dzialaniem kawy a pod dzialaniem atramentu plamy wystepuja po 120 minutach. Dla2 97 378 porównania krazek wyjsciowy ulega poplamieniu kawa po uplywie 14 dni jej dzialania a atramentem po minutach. Wypraska poddana analogicznemu dzialaniu roztworu stearyny w etanolu ulega zaplamieniu atramentem po 20 minutach.Przyklad II. Bialy, dekoracyjny laminat melaminowy zanurza sie na dziesiec minut do 3% roztworu metylolostearamidu w toluenie o temperaturze 100°C. Po wyjeciu oplukuje sie laminat alkoholem i woda.Trwale zaplamienie atramentem tak potraktowanego laminatu nastepuje po 115 minutach oddzialywania, podczas gdy wyjsciowego laminatu nietraktowanego — po 8 minutach. PLThe subject of the invention is a method of producing laminates and amine moldings with increased resistance to staining by modifying their surfaces. Moldings made of amine molds, especially melamine moldings, are used in everyday life, most often in the form of tableware. Tableware, which is often exposed to food containing colored substances, stains easily. Decorative laminates with a top layer of melamine resin used for table and desk tops are also often prone to staining, for example with ink. Stains reduce the aesthetic and functional value of laminates and moldings. . It has been found that the stain resistance of the surfaces of laminates and amine moldings can be increased by treating them with a solution of stearamide or methylol stearamide in an organic solvent. Stearamide chemically modifies the surface of the amine moldings by reacting with free methylol groups located on its surface. Methylolostearamide reacts with the -NH- or -NH2 groups of the amino-formaldehyde polycondensates. The solvent used is stearamide or methylol stearamide dissolving compounds, which are non-toxic and may possibly be heated without risk of burning, except for those compounds which might react with methylol stearamide, for example alcohol. The temperature of the solution should not exceed 150 ° C in view of possible decomposition of the laminate or compact. The operating time of a stearamide or methylol stearamide solution is shorter the higher its operating temperature. The concentration of the stearamide or methylol stearamide solution does not significantly affect the surface modification, it only provides the inflow of stearamide or methylol stearamide to the modified -CH2 OH, -NH- or -NH2 groups. Example I. Standard spline 100 mm in diameter and 4 mm thick the melamine molding material is pressed for 6 minutes at 150 ° C and immersed for 15 minutes into a boiling 1% solution of stearamide in ethanol. Then the disc is taken out, rinsed with alcohol and water, and dried. The surface of the molded part does not stain at all under the action of coffee and under the action of ink stains appear after 120 minutes. For comparison, the output disc becomes stained after 14 days of use, and ink stains after minutes. The compact, subjected to the analogous treatment of the stearin solution in ethanol, becomes stained with ink after 20 minutes. Example II. The white, decorative melamine laminate is immersed for ten minutes in a 3% solution of methylol stearamide in toluene at 100 ° C. After removal, the laminate is rinsed with alcohol and water. Permanent ink staining of the treated laminate occurs after 115 minutes of exposure, while the original untreated laminate - after 8 minutes. PL

Claims (1)

1. Zastrzezenie patentowe Sposób wytwarzania laminatów iwyprasek aminowych o zwiekszonej odpornosci na plamienie, zna¬ mienny tym, ze uformowane i utwardzone laminaty lub wypraski poddaje sie dzialaniu stearamidu lub metylolostearamidu w rozpuszczalniku organicznym w temperaturze nie przekraczajacej 150°C. Prac. Poligraf. UP PRL naklad 120+18 Cena 45 zl PL1. Patent claim A method of producing amine laminates and moldings with increased stain resistance, characterized in that the formed and hardened laminates or compacts are subjected to the action of stearamide or methylol stearamide in an organic solvent at a temperature not exceeding 150 ° C. Wash. Typographer. UP PRL, circulation 120 + 18 Price PLN 45 PL
PL18827676A 1976-03-26 1976-03-26 METHOD OF MANUFACTURING LAMINATES AND AMINE MOLDS WITH INCREASED STAIN RESISTANCE PL97378B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL18827676A PL97378B1 (en) 1976-03-26 1976-03-26 METHOD OF MANUFACTURING LAMINATES AND AMINE MOLDS WITH INCREASED STAIN RESISTANCE

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL18827676A PL97378B1 (en) 1976-03-26 1976-03-26 METHOD OF MANUFACTURING LAMINATES AND AMINE MOLDS WITH INCREASED STAIN RESISTANCE

Publications (1)

Publication Number Publication Date
PL97378B1 true PL97378B1 (en) 1978-02-28

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Application Number Title Priority Date Filing Date
PL18827676A PL97378B1 (en) 1976-03-26 1976-03-26 METHOD OF MANUFACTURING LAMINATES AND AMINE MOLDS WITH INCREASED STAIN RESISTANCE

Country Status (1)

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PL (1) PL97378B1 (en)

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