PL9232B1 - A method of dyeing fur, hair, feathers and similar materials. - Google Patents
A method of dyeing fur, hair, feathers and similar materials. Download PDFInfo
- Publication number
- PL9232B1 PL9232B1 PL9232A PL923227A PL9232B1 PL 9232 B1 PL9232 B1 PL 9232B1 PL 9232 A PL9232 A PL 9232A PL 923227 A PL923227 A PL 923227A PL 9232 B1 PL9232 B1 PL 9232B1
- Authority
- PL
- Poland
- Prior art keywords
- feathers
- hair
- similar materials
- naphthalene
- dyeing fur
- Prior art date
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- 239000000463 material Substances 0.000 title claims description 6
- 238000004043 dyeing Methods 0.000 title claims description 4
- 210000003746 feather Anatomy 0.000 title claims description 3
- 238000000034 method Methods 0.000 title claims 2
- -1 naphthalene derivative salts Chemical class 0.000 claims description 5
- 239000007800 oxidant agent Substances 0.000 claims description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 2
- YDIKCZBMBPOGFT-DIONPBRTSA-N (2s,3r,4s,5s,6r)-2-[5,7-dihydroxy-2-(4-hydroxy-3,5-dimethoxyphenyl)chromenylium-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol;chloride Chemical compound [Cl-].COC1=C(O)C(OC)=CC(C=2C(=CC=3C(O)=CC(O)=CC=3[O+]=2)O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)=C1 YDIKCZBMBPOGFT-DIONPBRTSA-N 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- ZYECOAILUNWEAL-NUDFZHEQSA-N (4z)-4-[[2-methoxy-5-(phenylcarbamoyl)phenyl]hydrazinylidene]-n-(3-nitrophenyl)-3-oxonaphthalene-2-carboxamide Chemical compound COC1=CC=C(C(=O)NC=2C=CC=CC=2)C=C1N\N=C(C1=CC=CC=C1C=1)/C(=O)C=1C(=O)NC1=CC=CC([N+]([O-])=O)=C1 ZYECOAILUNWEAL-NUDFZHEQSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000002790 naphthalenes Chemical class 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000005811 Viola adunca Nutrition 0.000 description 1
- 240000009038 Viola odorata Species 0.000 description 1
- 235000013487 Viola odorata Nutrition 0.000 description 1
- 235000002254 Viola papilionacea Nutrition 0.000 description 1
- 244000172533 Viola sororia Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005001 aminoaryl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- RPVHPEWRRNBWEZ-UHFFFAOYSA-N naphthalen-1-yl hypochlorite Chemical compound C1=CC=C2C(OCl)=CC=CC2=C1 RPVHPEWRRNBWEZ-UHFFFAOYSA-N 0.000 description 1
- DMDOTRUOIVBPSF-UHFFFAOYSA-N naphthalene;hydrochloride Chemical compound Cl.C1=CC=CC2=CC=CC=C21 DMDOTRUOIVBPSF-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Description
Do farbowania futer, wlosów, piór i podobnych materjalów stosuje sie po¬ chodne naftalenu, zastapione przez grupy 4-amino-aryloammo szeregu benzolowego* Reszta naftylowa moze byc oprócz tego jeszcze zastapiona np, przez grupy oksy, amino, aminoarylo.Przez traktowanie zaprawionego lub niezaprawionego materjalu, przeznaczo¬ nego do farbowania wodnym roztworem soli pochodnych 4-aminoaryloamino-naf- talenu, a nastepnie pod dzialaniem od¬ powiedniego srodka utleniajacego po¬ wstaja na wlóknie zabarwienia czerwono- fioletowe az do odcieni niebiesko - czar¬ nych i zielono-popielatych.Przyklad L W kapieli, zawierajacej w litrze 2 g 2-^'aminofenyloaniino) chlo¬ rowodorku naftalenu, nieco alkoholu i bardzo mala ilosc kwasu chlorowodoro¬ wego, traktuje sie skóre niezaprawioma yzglednie zaprawiona przy zwyklej tem¬ peraturze przez kilka godzin. Po wypló- kaniu skóry traktuje sie ja przez 1 go¬ dzine w kapieli, zawierajacej w litrze 20 g dwuchromianu potasowego i 20 g 30% — kwasu octowego. Otrzymuje sie zabarwie¬ nie niebiesko-popielate.Skóra zaprawiona uprzednio dwuchro¬ mianem potasowym otrzymuje silniejsze niebieskie zabarwienie, gdy poddaje sie ja traktowaniu wedlug niniejszego przy¬ kladu, a nastepnie drugiemu traktowaniu dwutlenkiem wodoru w roztworze amo- njakalnym; wstepne zaprawianie skóry miedzia daje zabarwienie czarno-niebie¬ skie, Z l-(4' aminofenyloamino) chlorowo-dorku naftalenu otrzymuje sie, zaleznie od wymienionych warunków, odcienie czerwono-fioletowe, az do barwy koryntti.Przyklad II. W kapipli, zawierajacej w litrze 5 g 2- (4* aminofenyloamino) - ó- oksy - chlorowodorku naftalenu nieco al¬ koholu i mala ilosc kwasu chlorowodo¬ rowego, poddaje sie materjal przeznaczo¬ ny do farbowania, w danym razie zapra¬ wiony traktowaniu przez kilka godzin w zwyklej temperaturze. Po plókaniu zosta¬ je on nastepnie traktowany srodkami u- tleniajacemi. Pod dzialaniem zakwaszo¬ nego roztworu dwuchromianu otrzymuje sie ciemne zielono-niebieskie odcienie po¬ pielate.Z 2- (4'-ammof enyloamino) -6- ^'-ami¬ nofenyloamino) chlorowodorku naftalenu otrzymuje sie podobne, wiecej zielonawe odcienie popielate; l-(4'^amanofenyloami- no) -5-(4'aminofenyloamino)- chlorowodo¬ rek naftalenu daje przy pózniejszem trak¬ towaniu roztworem dwuchromianu alka¬ licznego i kwasu octowego zabarwienie fioletowo - popielate, 1- (4 'aminofenyloami¬ no) -5-oksy chlorowodorek naftalenu daje w tych samych warunkach niebiesko - fio¬ letowa barwe; 2- (4'aminofenyloamino) -7- (4'aminofenyloamino chlorowodorek naf¬ talenu wytwarza fioletowo - popielate od¬ cienie, które przy dluzszem traktowaniu dwuchromianem i kwasem octowym prze¬ chodza w zabarwienia fioletowe lub nie¬ bieskawe.Podstawianie grupy fenylowej, np. przez alkyl lub chlorowiec, nie wplywa u- jemnie na uzycie wymienionych pochod¬ nych naftalenu. PLFor the dyeing of fur, hair, feathers and similar materials, naphthalene derivatives are used, replaced by 4-amino-arylammo groups of the benzol series. The naphthyl residue may also be replaced, for example, by oxy, amino, aminoaryl groups. untreated material, intended for dyeing with an aqueous solution of salts of 4-aminoarylamino-naphthalene derivatives, and then, under the action of an appropriate oxidizing agent, the fibers develop red-violet colors up to bluish-black and green-gray shades Example LW in a bath, containing 2 g of naphthalene 2-aminophenylamine hydrochloride per liter, some alcohol and a very small amount of hydrochloric acid, treat untreated skin thoroughly seasoned at ordinary temperature for several hours. After the skin has been rinsed, it is treated for 1 hour in a bath containing 20 g of potassium dichromate and 20 g of 30% acetic acid per liter. A bluish-gray color is obtained. Leather previously treated with potassium dicatate acquires a stronger blue color when subjected to the treatment according to the present example, followed by a second treatment with hydrogen dioxide in an ammoniacal solution; the pre-treatment of the copper skin gives a black-blue color. From 1- (4 'aminophenylamino) naphthalene hydrochloride, depending on the conditions mentioned, red-violet shades up to the Corinthian color are obtained. Example II. In a capsule containing 5 g of 2- (4-aminophenylamino) oxy-naphthalene hydrochloride per liter, a little alcohol and a small amount of hydrochloric acid, the material to be dyed is subjected to, if necessary treated with for several hours at normal temperature. After it has been swallowed, it is then treated with an oxidizing agent. Dark green-blue shades of ash are obtained under the action of the acidic dichromate solution. From 2- (4'-ammophenylamino) -6-'-amino-phenylamino) naphthalene hydrochloride, similar, more greenish, ash shades are obtained; 1- (4'amanophenylamino) -5- (4'aminophenylamino) naphthalene hydrochloride gives on subsequent treatment with a solution of alkaline dichromate and acetic acid a violet-gray color, 1- (4'aminophenylamino) ) Naphthalene -5-oxy hydrochloride gives a blue-violet color under the same conditions; 2- (4'aminophenylamino) -7- (4'aminophenylamino) naphthalene hydrochloride produces a violet-ashy shade which, on prolonged treatment with dichromate and acetic acid, turns violet or off-blue. Substitution of the phenyl group, e.g. . by alkyl or halogen, does not negatively affect the use of the mentioned naphthalene derivatives. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL9232B1 true PL9232B1 (en) | 1928-09-29 |
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