PL87447B1 - - Google Patents

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Publication number
PL87447B1
PL87447B1 PL16398573A PL16398573A PL87447B1 PL 87447 B1 PL87447 B1 PL 87447B1 PL 16398573 A PL16398573 A PL 16398573A PL 16398573 A PL16398573 A PL 16398573A PL 87447 B1 PL87447 B1 PL 87447B1
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PL
Poland
Prior art keywords
parts
weight
amount
polyvinyl butyral
butyral resin
Prior art date
Application number
PL16398573A
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Polish (pl)
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Priority to PL16398573A priority Critical patent/PL87447B1/pl
Publication of PL87447B1 publication Critical patent/PL87447B1/pl

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Description

Przedmiotem wynalazku jest farba zaroodporna przeznaczona do zabezpieczania powierzchni meta¬ lowych przed korozja i dzialaniem temperatury do 400°C.Dotychczas znane sa farby i emalie zaroodporne zabezpieczajace przed korozja i dzialaniem tempe¬ ratury do 400°C na bazie zywicy metylosikonowej z zastosowaniem pylu cynkowego. Wymagaja one suszenia powlok w temperaturze 200°C i posiadaja bardzo krótka stabilnosc w czasie magazynowania.Z monografii Schildeknechfa „Polimery winylo¬ we" PWT 1965 r. strona 369 znane jest stosowanie poliwinylobutyralu do warstw gruntowych na stal.Z opisu patentowego NRD numer 30 284 znany jest lakier antykorozyjny o dobrych wlasnosciach mechanicznych i odpornosci na przedluzone dzia¬ lanie temperatury 150°C. Lakier ten jako skladnik powlokotwórczy zawiera kompozycje zywic: epo¬ ksydowej o równowazniku epoksydowym od 425 do 700, aminowej i poliwinylobutyralowej. Powloki z tego lakieru wymagaja suszenia w temperaturze 175 do 220°C. W celu obnizenia temperatury wypa¬ lania powlok i skrócenia czasu wypalania, lakier ten wymaga dodatku katalizatora kwasnego, co obniza stabilnosc wyrobu w czasie magazynowania.Nieznane sa farby zaroodporne oparte na samej zywicy poliwinylobutyralowej o dobrych wlasnos¬ ciach mechanicznych, antykorozyjnych i odpornosci na dzialanie temperatury do 400CC wysychajace za¬ równo w temperaturze otoczenia oraz w tempera¬ turze podwyzszonej do 130°C.Istota wynalazku jest farba zaroodporna z zasto¬ sowaniem zywicy poliwinylobutyralowej skladajaca sie z zywicy poliwinylobutyralowej o stopniu poli¬ meryzacji od 30 do 60 w ilosci od 7,0 do 8,0 czesci wagowych, pylu cynkowego wysokometalicznego w ilosci od 0 do 25 czesci wagowych, proszku alu¬ miniowego w ilosci od 9 do 16 czesci wagowych, spirytusu posulfitowego bezwodnego w ilosci od 35 do 50 czesci wagowych, toluenu w ilosci od 10 do czesci wagowych, butanolu w ilosci od 10 do 15 czesci wagowych, tlenku magnezu w ilosci od 0,1 do 0,2 czesci wagowych oraz glinokrzemianu w ilo¬ sci od 0,02 do 0,05 czesci wagowych.Farba zaroodporna wedlug wynalazku przezna¬ czona jest do malowania powierzchni metalowych w celu zabezpieczenia przed korozja i dzialaniem temperatury do 400°C. Farba wedlug wynalazku mo¬ ze byc w zaleznosci od uzytych proporcji skladni¬ ków stosowana jako farba podkladowa lub jako emalia (farba) nawierzchniowa.Farba zaroodporna wedlug wynalazku charakte¬ ryzuje sie dobra stabilnoscia w czasie magazyno¬ wania, dobra termoodpornoscia powloki na tempe¬ ratury do 400°C oraz mozliwoscia suszenia powloki zarówno w temperaturze otoczenia jak i w tempe¬ raturze podwyzszonej. 87 44787 447 Przyklad I zywica poliwinylobutyralowa pyl cynkowy wy sokometali czny proszek aluminiowy spirytus posulfitowy bezwodny toluen glinokrzemian 20% roztwór w ksylenie butanol tlenek magnezu 7,4 czesci wagowych 22,3 czesci wagowych 9,6 czesci wagowych 38,0 czesci wagowych ,0 czesci wagowych 2,3 czesci wagowych ,2 czesci wagowych 0,2 czesci wagowych 100,0 czesci wagowych Przyklad II zywica poliwinylobutyralowa proszek aluminiowy spirytus posulfitowy bezwodny toluen 8,0 czesci wagowych 16,0 czesci wagowych 47,0 czesci wagowych 13,9 czesci wagowych butanol glinokrzemian 20% roztwór w ksylenie tlenek magnezu 13,7 czesci wagowych 1,3 czesci wagowych 0,1 czesci wagowych 100,0 czesci wagowych PLThe subject of the invention is a heat-resistant paint intended for the protection of metal surfaces against corrosion and the action of temperatures up to 400 ° C. So far, heat-resistant paints and enamels protecting against corrosion and the action of temperatures up to 400 ° C are known, based on methyl silicone resin with the use of zinc dust. They require drying of the coatings at a temperature of 200 ° C and have a very short storage stability. From Schildeknech's monograph "Vinyl polymers" PWT 1965, page 369, it is known to use polyvinyl butyral for steel ground layers. GDR Patent No. 30,284 Anticorrosive varnish with good mechanical properties and resistance to prolonged exposure to the temperature of 150 ° C is known. This varnish, as a coating component, contains resin compositions: epoxy with epoxy equivalent from 425 to 700, amine and polyvinyl butyral. at a temperature of 175 to 220 ° C. In order to lower the baking temperature of the coatings and shorten the baking time, this varnish requires the addition of an acid catalyst, which reduces the stability of the product during storage. There are no heat-resistant paints based on polyvinyl butyral resin alone with good properties. mechanical, anti-corrosion and temperature resistance up to 400CC w Drying both at ambient temperature and at temperatures elevated to 130 ° C. The essence of the invention is a heat-resistant paint with the use of polyvinyl butyral resin consisting of a polyvinyl butyral resin with a degree of polymerization from 30 to 60 in an amount from 7.0 to 8.0 parts by weight, high-metal zinc dust in an amount from 0 to 25 parts by weight, alumina powder in an amount of 9 to 16 parts by weight, anhydrous sulfite spirit in an amount of 35 to 50 parts by weight, toluene in an amount of 10 to parts parts by weight, 10 to 15 parts by weight of butanol, 0.1 to 0.2 parts by weight of magnesium oxide and 0.02 to 0.05 parts by weight of aluminosilicate. The heat-resistant paint according to the invention is intended for is for painting metal surfaces in order to protect against corrosion and exposure to temperatures up to 400 ° C. The paint according to the invention can, depending on the proportions of components used, be used as a base paint or as a topcoat enamel (paint). The heat-resistant paint according to the invention is characterized by good storage stability, good heat resistance to temperature up to 400 ° C and the possibility of drying the coating both at ambient temperature and at elevated temperature. 87 44787 447 Example I polyvinyl butyral resin zinc dust aluminum powder aluminum powder sulfite spirit anhydrous toluene aluminosilicate 20% solution in xylene butanol magnesium oxide 7.4 parts by weight 22.3 parts by weight 9.6 parts by weight 38.0 parts by weight, 0 parts by weight 2.3 parts by weight, 2 parts by weight 0.2 parts by weight 100.0 parts by weight Example II polyvinyl butyral resin aluminum powder sulfite spirit anhydrous toluene 8.0 parts by weight 16.0 parts by weight 47.0 parts by weight 13.9 parts by weight butanol aluminosilicate 20% solution in xylene magnesium oxide 13.7 parts by weight 1.3 parts by weight 0.1 parts by weight 100.0 parts by weight

Claims (1)

1. Zastrzezenie patentowe Farba zaroodporna z zastosowaniem zywicy poli- winylobutyralowej znamienna tym, ze sklada sie z zywicy poliwinylobutyralowej o stopniu polime¬ ryzacji od 30 do 60 w ilosci od 7,0 do 8,0 czesci wagowych, pylu cynkowego wysokometalicznego w ilosci od 0 do 25 czesci wagowych, proszku alumi¬ niowego w ilosci od 9 do 16 czesci wagowych, spi¬ rytusu posulfitowego w ilosci od 35 do 50 czesci wagowych, toluenu w ilosci od 10 do 15 czesci wa¬ gowych, butanolu w ilosci od 10 do 15 czesci wa- wych, tlenku magnezu w ilosci od 0,1 do 0,2 czesci wagowych oraz glinokrzemianu w ilosci od 0,02 do 0,05 czesci wagowych. WD.L, zam. 3352. 115 Cena 10 zl PL1. Patent claim Resistant paint with the use of polyvinyl butyral resin characterized in that it consists of a polyvinyl butyral resin with a degree of polymerization from 30 to 60 in an amount from 7.0 to 8.0 parts by weight, high-metal zinc dust in an amount from 0 up to 25 parts by weight, 9 to 16 parts by weight of aluminum powder, 35 to 50 parts by weight of sulfite alcohol, 10 to 15 parts by weight of toluene, 10 to 15 parts of butanol parts by weight, magnesium oxide in an amount of 0.1 to 0.2 parts by weight and an aluminosilicate in an amount of 0.02 to 0.05 parts by weight. WD.L, res. 3352. 115 Price PLN 10 PL
PL16398573A 1973-07-11 1973-07-11 PL87447B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL16398573A PL87447B1 (en) 1973-07-11 1973-07-11

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL16398573A PL87447B1 (en) 1973-07-11 1973-07-11

Publications (1)

Publication Number Publication Date
PL87447B1 true PL87447B1 (en) 1976-06-30

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Application Number Title Priority Date Filing Date
PL16398573A PL87447B1 (en) 1973-07-11 1973-07-11

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